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Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Broadening the substrate range of serine palmitoyltransferase by protein engineering and applications to 3-keto-dihydrosphingosine analogs

Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper
Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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Photocatalytic H2O2 production with perylene(bis-imide)-doped periodic mesoporous silica using micropollutants as sacrificial donors

Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper
Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H2O2 from aerated polluted water samples under light soaking.
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Dual defect sites at g-C3N4 synergistically induce the electron localization effect for boosting photocatalytic H2O2 production

Catal. Sci. Technol., 2024, 14,6701-6709
DOI: 10.1039/D4CY01101E, Paper
Jingjing Jiang, Yuyao Chen, Shijian Zhou, Haoran Xie, Changlai Li, Zheng Wei, Yan Kong
Defect engineering (such as doping of non-metallic elements or vacancies) is a universally effective modification to improve the electronic structure and physical properties of g-C3N4, which has been widely applied in various photocatalytic systems.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Enhancing coking resistance of nickel-based catalysts for dry reforming of methane via nitric oxide abatement: a support study

Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper
Open Access
Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review

Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article
Open Access
Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Correction: 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
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Elucidation of Ce/Zr ratio effects on the physical properties and catalytic performance of CuOx/CeyZr1−yO2 catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01012D, Paper
Mohammed Sifat, Michal Luchowski, Amol Pophali, Wenhui Jiang, Yunfan Lu, Byeongseok Kim, Gihan Kwon, Kwangsuk Yoon, Jihun Kim, Kwangjin An, Sang Eun Shim, Hocheol Song, Taejin Kim
Although cerium oxide (CeO2) is widely used as a catalyst support, its limited defect sites and surface oxygen vacancy/mobility should be improved.
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Bifunctional catalysts based on PdZn/ZnO and hierarchical zeolites in the direct synthesis of dimethyl ether from CO-rich syngas: influence of the support and the Zn/Pd molar ratio

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00860J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bing Wang, Nicola Da Roit, Michael Zimmermann, Markus Boese, Thomas Zevaco, Silke Behrens
Pd/Zn-nanoparticles were used as precursors to study the influence of the molar Zn/Pd ratio and hierarchical HZSM-5 zeolites in the syngas-to-dimethyl ether process.
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Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper
Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.
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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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Material design of biodegradable primary batteries: boosting operating voltage by substituting the hydrogen evolution reaction at the cathode

Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview
Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Effect of graphene electrode functionalization on machine learning-aided single nucleotide classification

Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper
Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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Unlocking new possibilities: application of MXenes in 3D bioprinting for advanced therapy

Nanoscale, 2024, 16,20037-20047
DOI: 10.1039/D4NR02906B, Minireview
Yusuf Olatunji Waidi, Nipun Jain
This article presents MXenes' potential in 3D bioprinting, discussing their benefits for bio-printed scaffolds, 3D bioprinting techniques, bio-ink criteria, applications of MXene-incorporated constructs, current challenges, and future directions.
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor

Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper
Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Preparation and application of high thermal conductivity phase change microcapsules with fluorescence characteristics based on a ZnWO4 shell

Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper
H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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Effective enrichment of glycated proteome using ultrasmall gold nanoclusters functionalized with boronic acid

Nanoscale, 2024, 16,20147-20154
DOI: 10.1039/D4NR03283G, Paper
Hongmae Heo, Seonghyeon Cho, Yuhyeon Kim, Soomin Ahn, Jeong-hun Mok, Hookeun Lee, Dongil Lee
A novel approach was developed for the first time by combining ultrasmall Au22 nanoclusters with boronic acid (BA) affinity chemistry, achieving highly efficient enrichment of early-stage glycated peptides.
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Nucleic acid detection with single-base specificity integrating isothermal amplification and light-up aptamer probes

Nanoscale, 2024, 16,20067-20072
DOI: 10.1039/D4NR01638F, Communication
Jaekyun Baek, Jihyun Park, Youngeun Kim
CLASSIC is a label-free DNA detection platform with single-nucleotide specificity and attomolar sensitivity. This assay offers rapid and sequence-specific DNA analysis through single-strand conversion and split light-up aptamer probes.
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Dual metal centers within a water-stable Co/Ni bimetallic metal-triazolate framework contribute to durable photocatalysis for water treatment

Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication
Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
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Applications of nanotheranostics in the second near-infrared window in bioimaging and cancer treatment

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03058C, Review Article
Huimin Li, Pengju Li, Jiarui Zhang, Ziyi Lin, Lintao Bai, Heyun Shen
This review summarized the application of the second near-infrared nano-platform in the field of nano-agents design, optical imaging and cancer treatment, aiming at providing profound insights into its development status and future challenges.
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Interfacial coupling of NiSe in heterostructures promotes electrocatalytic hydrolysis of MoS2

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03180F, Paper
Feng Jiao, Jun Tang, Jinzhao Huang, Zehui Liu, Jing Xiao
NiSe@MoS2 was prepared using a hydrothermal method. Interfacial effects between the two phases lead to electronic restructuring of the interfacial region, resulting in more active sites.
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Oxygen electrode catalysis in N-doped graphene: the role of nitrogen coordination and solvation effects

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03645J, Paper
Junxian Liu, Yun Wang, Yuantong Gu, Liangzhi Kou
The significance of explicit solvents in describing the adsorption behaviors of ORR/OER intermediates is emphasized. A higher HOMO level of active sites enhances binding to oxygen intermediates, thereby improving ORR/OER activity.
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Controlling TiO2 photocatalytic behaviour via perhydropolysilazane-derived SiO2 ultrathin shell

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03566F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Darya Burak, Jae Hyun Han, Joon Soo Han, In Soo Kim, Md Abdur Rahman, Joel K. W. Yang, So-Hye Cho
PHPS was transformed via TiO2 photocatalytic properties into ultrathin SiO2 shells, passivating TiO2 activity while retaining its whiteness and high refractive index—perfect for cosmetics, paints, and optical coatings.
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Facile Approach for Fabricating Efficient and Stable Perovskite Solar Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03705G, Paper
Sajid Sajid, Salem Alzahmi, Nouar Tabet, Mohammad Y. Al-Haik, Saleh T. Mahmoud, Yousef Haik, Ahmed Mourtada Elseman, Ihab M Obaidat
Perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs) can be produced using a variety of methods, such as different fabrication methods, device layout modification, and ingredients and interfaces...
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Facile synthesis of defective ZnS-ZnO composite nanosheets for efficient piezocatalytic H2 production

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03733B, Paper
Xiaoxiao Lu, Xiaojing Zhao, Xiangyu Chen, Miaoqiong Xu, Miaoling Huang, Wen-Jie Chen, Yubin Liu, Xiaoyang Pan
A facile approach was developed for the synthesis of ultrathin ZnS-ZnO nanosheets. By simply manipulating the synthetic temperature, ZnS-ZnO composite nanosheets with sulfur vacancy are successfully obtained using ZnS(en)0.5 as...
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Insights into the electrochemical catalytic mechanism of atomically dispersed metal on h-BCN monolayer

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02845G, Paper
Na Zhou, Yanning Wang, Jiao Wang, Panchao Zhao, Hang Zhang
Exploiting efficient and inexpensive electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of great significance for the rapid development of renewable energy technologies.
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Design of a new process for the stabilization of FeS–Bi2S3 hybrid nanostructure and its application as a field emitter

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04138K, Paper
Arushi Arora, Anima Mahajan, Nausad Khan, Santanu Ghosh, Menaka Jha
Design of a new process for the fabrication of FeS–Bi2S3 anisotropic nanostructure for field emission application.
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pH controlled synthesis of end to end linked Au nanorod dimer in an aqueous solution for plasmon enhanced spectroscopic applications

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03235G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Satyajit Patra, Shubhangi Sharma, Théo Minchella, Susmita Pradhan, Davy Gerard, Quanbo Jiang
End-to-end linked nanorod dimer nanogap antennas exhibit superior plasmonic enhancement compared to monomers due to the coupling of localized surface plasmon resonances (LSPR) of individual nanorods. However, controlling the assembly...
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Synthesis, Characterization, Genotoxicity Assessment and Antibacterial Applications of Zanthoxylum armatum Silver Nanoparticles (ZASNP) with Antibiotic Efficacy Enhancement Potential

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03608E, Paper
Open Access
Nikita Quadri, Manjunath M. Setty, Anshumali Awasthi, Usha Yogendra Nayak, Minakshi Singh, Sharad Sharma
The study aimed to develop alternative antibacterial treatments by combining traditional herbal knowledge with modern nanotechnology. This approach targets multiple bacterial strains, combats antibiotic resistance, and offers solutions for treating...
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Impact of catalyst support on water-assisted CO oxidation over PdO/MO2 (M = Sn, Ti, and Si) catalysts: experimental and theoretical investigation

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03963G, Paper
Kun Liu, Luliang Liao, Guangfu Liao
This study investigates the influence of different supports on PdO-based catalysts during CO oxidation, particularly under humid conditions.
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Exploring Graphene's Impact on Graphite/PANI Matrix Composites: High-Press Fabrication and Enhanced Thermal-Electrical Properties

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03171G, Paper
Murat OZLEK, Merve Sehnaz Akbulut, Engin Burgaz
This study investigates the effects of graphene content and applied press on electrical and thermal conductivities of graphite/polyaniline (GP) and graphite/graphene/polyaniline (GGP) composites which were produced by using direct mixing...
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Electrode Informatics Accelerated Optimization for Catalyst Layer Key Parameters in Direct Methanol Fuel Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03026E, Paper
Lishou Ban, Danyang Huang, Yanyi Liu, Pengcheng Liu, Xihui Bian, Kaili Wang, Yifan Liu, Xijun Liu, Jia He
As the core component of direct methanol fuel cell, the catalyst layer plays the key role of material, proton and electron transport channels. However, due to the complexity of its...
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Emerging chiral sulfur-based nanomaterials for chiroptical applications

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03736G, Review Article
Hammad Hasan, Md Ifzal Azhar, Santosh Kumar Behera, Md Palashuddin Sk
This review covers fundamental principles and techniques for measuring chiral properties as well as the synthesis of chiral sulfur-based nanomaterials, their optical and chiroptical properties, and possible applications.
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Bifunctional electrocatalytic hybrid heterostructures for polysulfide anchoring/conversion for a stable lithium–sulfur battery

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03190C, Paper
Sakthivel Kaliyaperumal, Karthik Kiran Sarigamala, Padmini Moorthy, Balaji Ramachandran, Narendhar Chandrasekar, Tim Albrecht
In situ phase engineering of transition metal dichalcogenides (TMDs) based hybrid heterostructures with controlled sulfur vacancies offers a promising strategy for superior-performance lithium–sulfur (Li–S) batteries.
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Improving Dynamic Control of Toehold-Mediated Strand Displacement Reactions through Phosphorothioate Modifications

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper
Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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