Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00821A, Review Article

Toyese Oyegoke, Franck Dumeignil, Baba E.-Yakubu Jibril, Carine Michel, Robert Wojcieszak
This review explores the mechanisms and factors influencing the selective oxidation of HMF and furfural into valuable products using gold, platinum, and palladium catalysts.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper

Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
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Catal. Sci. Technol., 2024, 14,6155-6175
DOI: 10.1039/D4CY00627E, Review Article

A. Anantha Krishnan, Sreehari Harikumar, M. A. Aneesh Kumar, Revathy B. Nair, Sajith Kurian, M. Ameen Sha, P. S. Arun
NiFe₂O₄ is a potential catalyst for energy conversion and storage, owing to their electrical conductivity, catalytic activity, and stability.
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Catal. Sci. Technol., 2024, 14,6186-6197
DOI: 10.1039/D4CY00693C, Paper

Open Access

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Abdulrhman Moshantaf, Michael Wesemann, Simeon Beinlich, Heinz Junkes, Julia Schumann, Baris Alkan, Pierre Kube, Clara Patricia Marshall, Nils Pfister, Annette Trunschke
Digitalisation in experimental catalysis research: we are introducing machine-readable standard operating procedures combined with automated data acquisition, storage and sharing to improve research efficiency and reproducibility.
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Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper

Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe₁/Ti₂CO₂ is an efficient catalyst that can remove indoor formaldehyde.
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Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper

Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO₂ into cyclic carbonates from flue gas under atmospheric pressure.
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Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper

Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO₂ reduction, resulting in the dynamic evolution of i-CuO_x species. The in situ formed i-CuO_x plays decisive roles in promoting C–C coupling.
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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper

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Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H₂ reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO₂ catalysts by increasing the number of active Pt⁰ NPs. A 12 h oxidative post-treatment at 500 °C which forms PtO_x species easily activated also leads to improvement.
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper

Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper

Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO₂ with H₂O—known as artificial photosynthesis—is important.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper

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Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO₂ methanation and is extendable to other catalytic processes.
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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper

Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper

Open Access

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Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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Catal. Sci. Technol., 2024, 14,6351-6362
DOI: 10.1039/D4CY00893F, Paper

Jiaxuan Li, Xin Chen, Siyu Li, Kunrong Mei, Lequan Liu, Jinhua Ye
An O₃–Fe/TiO₂ reactor is designed for efficient air disinfection by catalytically converting ozone into reactive oxygen species (ROS).
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Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper

Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper

Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C₃N₄ catalyst.
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Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper

Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH₃ can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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Catal. Sci. Technol., 2024, 14,6420-6429
DOI: 10.1039/D4CY00906A, Paper

Shilin Li, Yunhui Tian, Guangxin Zhang
The regulations of the Bi₂MoO₆ structure, such as dopant incorporation, composite formation, and synthesis condition modification, have garnered significant attention due to their implications for enhancing photocatalytic activity.
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Catal. Sci. Technol., 2024, 14,6278-6285
DOI: 10.1039/D4CY00983E, Paper

Open Access

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Meng Wang, Jingyi Wang, Yan Zhang, Yunbo Yu, Wenpo Shan
High-temperature calcination usually induces the sintering of catalysts, thus resulting in negative effects on their performance.
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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper

Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS₂ play a similar role to the amino acid residues in PS II.
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Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication

Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Catal. Sci. Technol., 2024, 14,6180-6185
DOI: 10.1039/D4CY01117A, Communication

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Ren-Rui Xu, Chang-Sheng Kuai, Xiao-Feng Wu
An efficient strategy for the synthesis of acrylamides via palladium-catalyzed carbonylation, using 1,2-dichloroethane and amines as starting materials has been developed.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper

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Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al₂O₃ in fixed bed mode.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00779D, Paper

Suchitra N. Sapakal, Arvind Singh, Ayesha Khan, Mayur Gaikwad, Jin H. Kim, Anamika Kadam
HER: overpotential for HER, OER: overpotential for OER; R_s: solution resistance, R_ct: charge transfer resistance. The comparison of various parameters of the MoO₂@Fe₂O₃ electrode in KOH and H₂SO₄ electrolytes.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper

Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00758A, Paper

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Tshepo Molefe, Roy Peter Forbes, Neil John Coville
Decreasing the carbon shell thickness increased the reducibility of Co₃O₄. The reducibility of Co₃O₄ was further achieved by adding an Os promoter outside of the sphere showing that H spillover was favoured over H₂ diffusion/Co reduction by carbon.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01076K, Paper

Zhaochun He, Yonghua Liu, Tao Wang
We computationally identified Ni₃Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper

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Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper

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Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni₉₉Pt₁/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01006J, Paper

Kai Cui, Jiaming Yang, Yuli Jing, Junwen Chen, Chen Zhao, Peng Wu, Xiaohong Li
A Cu–0.03Mo/SiO₂ catalyst realized the one-pot deep hydrogenation of maleic anhydride to 1,4-butanediol at 200 °C, under 5 MPa of hydrogen pressure with 100% conversion and 88.3% selectivity, one of the highest values for this target reaction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01115E, Paper

Xinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen Zhao
A series of Co₃O₄ catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co₃O₄ catalyst exhibits the best catalytic performance for soot combustion.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article

Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00858H, Paper

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Claudia J. Keijzer, Pim T. Weide, Kristiaan H. Helfferich, Justyna Zieciak, Marco de Ridder, Remco Dalebout, Tracy L. Lohr, John R. Lockemeyer, Peter van den Brink, Petra E. de Jongh
Crystalline AgReO₄ was formed in Re-promoted Ag catalysts. The effect of Re on catalysis and EO isomerization was tested without and with the industrially relevant ethyl chloride. EO isomerization was greatly affected by both Re and Cl.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00745J, Paper

Lijin Gan, Zekun Liu, Lei Feng, Yi Duan, Guangyuan Xu, Si Chen, Huan Yan
Adipic aldehyde, as a precursor for polymers, has significant industrial applications, where the hydroformylation of 1,3-butadiene is a promising routine to fabricate adipic aldehyde. However, the heterogeneous hydroformylation of 1,3-butadiene...
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper

Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01056F, Paper

Ruitao Nie, Xiaolong Deng, Haoyu Yang, Hongwei Chen, Jie Yang, Meiyi Lu, Keqi Peng, Xiaoyu Zhou, Yang Chen, Juan Xie, Hu Wang
Electrocatalytic selective reduction of CO₂ to liquid phase products, particularly methanol, is a promising technique for CO₂ utilization. However, the challenge is daunting because the reduction of carbon dioxide to...
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Catal. Sci. Technol., 2024, 14,6503-6512
DOI: 10.1039/D4CY00760C, Paper

Bruce A. Lobo Sacchelli, Suellen M. P. Onguene, Ruben S. M. Almeida, Alexandra M. M. Antunes, Dmytro S. Nesterov, Leandro H. Andrade, Elisabete C. B. A. Alegria, Martin H. G. Prechtl
Tuning selectivities with oxidants: O₂ oxidises methanol to the carboxylate level and N₂O oxidises it to the formaldehyde level.
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Catal. Sci. Technol., 2024, 14,6443-6465
DOI: 10.1039/D4CY00822G, Review Article

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Shuang Deng, Nannan Wang, Yanqiu Zhu, Kunyapat Thummavichai
Nowadays, the excessive use of fossil fuels has led to a global energy shortage and exacerbated the greenhouse effect.
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Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper

Open Access

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Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Catal. Sci. Technol., 2024, 14,6609-6620
DOI: 10.1039/D4CY00968A, Paper

Nien-Chi Chang Liao, R. Sidick Basha, Bo-Hao Shih, Chia-Chun Liu, Miao-Han Wang, Po-Heng Lin, Chin-Fa Lee
Three distinct copper cluster complexes (A–C) were synthesized and their bonding was investigated by XRD studies. These complexes effectively catalyze the C–S coupling reaction of less reactive aliphatic thiols to synthesize thioether derivatives.
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Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper

Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt₁/Nb₂O₅, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb₂O₅ selectively promotes the hydrogenolysis of the –CH₂OH group rather than the hydrogenation of the –CHO group.
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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper

Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO₄ solution by electrochemical technology to catalyze the reduction of N₂ to NH₃. It was found that the applied magnetic field can significantly increase the current density.
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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper

Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper

Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H₂O₂ dissociation on heteroatom-doped carbon nanomaterials.
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Catal. Sci. Technol., 2024, 14,6641-6650
DOI: 10.1039/D4CY00913D, Paper

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D. J. Ward, D. J. Saccomando, F. Vilela, G. Walker, S. M. Mansell
Flow chemistry helped optimise the conversion of a branched primary alcohol to an alkene. Mass balance was achieved through the elimination of by-products, including alkene oligomers, and the setup could be optimised to give up to 98% alkene product.
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Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper

Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO₂ nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO₂ and methanol, attributed to their superior surface acidity, basicity, Ce³⁺ concentration, and oxygen vacancies.
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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper

Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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