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Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
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Clues from an ionic cocrystal structure: from catalysis to mechanochemistry

RSC Adv., 2024, 14,34843-34847
DOI: 10.1039/D4RA05652C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bandana Sar, Mollah Rohan Ahsan, Arijit Mukherjee
A crystal structure is no longer conceived as a static entity; rather, it often mirrors crystallization pathways, linking crystal structures with a solution scenario.
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Probing intrinsic defects of aluminium-doped CuO thin films for solar cell applications

RSC Adv., 2024, 14,35184-35197
DOI: 10.1039/D4RA06413E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adithya Prakash, Vikash Mishra, Mahesha M. G.
Defect-engineered Al-doped CuO thin films deposited via chemical spray pyrolysis find application in solar cell absorbers.
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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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Enhancing skin delivery of tranexamic acid via esterification: synthesis and evaluation of alkyl ester derivatives

RSC Adv., 2024, 14,34996-35004
DOI: 10.1039/D4RA06266C, Paper
Open Access
Yutong Zeng, Mengrui Ma, Yongfeng Chen, Huichao Xie, Pingtian Ding, Keda Zhang
An alkyl esterification prodrug strategy enhances skin penetration and deposition of tranexamic acid.
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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Superior low temperature activity over α-MnO2/β-MnOOH catalyst for selective catalytic reduction of NOx with ammonia

RSC Adv., 2024, 14,35498-35504
DOI: 10.1039/D4RA05934D, Paper
Open Access
Masanori Takemoto, Haruko Fujinuma, Yoshihiro Sugawara, Yukichi Sasaki, Kenta Iyoki, Tatsuya Okubo, Kazuya Yamaguchi, Toru Wakihara
α-MnO2/β-MnOOH catalysts were synthesized by post-synthetic planetary ball milling for OMS-2, enhancing catalytic activity in low-temperature NH3-SCR.
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Statistically driven automated method for catalytic glucose conversion optimisation

RSC Adv., 2024, 14,35578-35584
DOI: 10.1039/D4RA06038E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joseph Install, Rui Zhang, Jukka Hietala, Timo Repo
A statistically driven, automated approach to optimize glucose transformations to platform chemicals, methyl lactate and levulinic acid, is reported.
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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
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A dual-response fluorescence sensor for SO2 derivatives and polarity and its application in real water and food samples

RSC Adv., 2024, 14,35638-35643
DOI: 10.1039/D4RA04805A, Paper
Open Access
Jianfeng Wang, Ruiji Li, Tao Ou, Yamin Fu, Chang Gao, Yehao Yan
A dual-response fluorescent probe for SO2 derivatives and polarity and their application in real samples.
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An efficient extraction device for microplastics in marine sediments and its applications

RSC Adv., 2024, 14,35610-35617
DOI: 10.1039/D4RA04347B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wang Jiahan, Liu Xiaowei, Yang Feng, Yang Xiujiu, Jiao Wenguang, Tang Kai, Wang Jinli, Chen Yan
Microplastics, defined as small pieces of plastic with a size less than 5 millimeters, constitute a significant sink for microplastics in marine sediments.
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Retraction: Fabrication of novel quantum dots for the estimation of COVID-19 antiviral drug using green chemistry: application to real human plasma

RSC Adv., 2024, 14,35696-35696
DOI: 10.1039/D4RA90133A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Baher I. Salman, Adel Ehab Ibrahim, Sami El Deeb, Roshdy E. Saraya
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Electromagnetic wave effects on Mn-doped superparamagnetic iron oxide nanofluids: applications in enhanced oil recovery

RSC Adv., 2024, 14,35671-35678
DOI: 10.1039/D4RA04500A, Paper
Open Access
Mohamad Amin Bin Hamid, Beh Hoe Guan, Chan Kar Tim, Hassan Soleimani
This study reveals that both direct current (DC) and alternating current (AC) electromagnetic fields can effectively reduce the interfacial tension (IFT) of Mn-doped Fe3O4 nanofluids, with AC fields showing more predictable and pronounced effects.
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Reversible Zn and Mn deposition in NiFeMn-LDH cathodes for aqueous Zn–Mn batteries

RSC Adv., 2024, 14,35704-35714
DOI: 10.1039/D4RA06616B, Paper
Open Access
Yuan Ge, Dong Pan, Lin Li, Jiaxin Fan, Wei Liu
NiFeMn-LDH was utilized as a novel cathode material for zinc–manganese batteries. By adjusting the electrolyte ratio, it was discovered that a molar ratio of zinc to manganese of 4 : 1 can achieve a balance between capacity and stability.
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Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
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Revolutionizing applications: the impact of controlled surface chemistry on marble powder

RSC Adv., 2024, 14,35727-35742
DOI: 10.1039/D4RA06342B, Review Article
Open Access
Ali Zia Noor, Sadia Bibi, Maryam Asrar, Muhammad Imran, Sadia Afzal, Sadiqa Abdal, Muhammad Atif
A large amount of marble powder is abundantly available as a byproduct and waste in the marble industry, and its reinforcement has been attempted in several applications through surface modification.
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LCST/UCST behavior of polysaccharides for hydrogel fabrication

RSC Adv., 2024, 14,35754-35768
DOI: 10.1039/D4RA06240J, Review Article
Open Access
Seo Hyung Moon, Sol Ji Park, Ye Won Lee, Yun Jung Yang
This review discusses the classification, mechanisms, characteristics, and recent advancements of thermo-responsive polysaccharides in biomedical applications.
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Retraction: Highly sensitive cadmium sulphide quantum dots as a fluorescent probe for estimation of doripenem in real human plasma: application to pharmacokinetic study

RSC Adv., 2024, 14,35992-35992
DOI: 10.1039/D4RA90134G, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marwa F. B. Ali, Baher I. Salman, Samiha A. Hussein, Mostafa A. Marzouq
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Characterization and quantification of the phytochemical constituents and anti-inflammatory properties of Lindera aggregata

RSC Adv., 2024, 14,36101-36114
DOI: 10.1039/D4RA05643D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Song-Song Wen, Yong-Jun Liu, Yu-Lin Liu, Yan Zhao, Xiao-Xi Xu, Chang-Chuan Guo, Chong Niu, Wei-Jian Wang, Yu-Wen Xu, Na Zhang
This study developed a method to analyze the bioactive compounds in Lindera aggregata roots, identifying 80 compounds, with 16 quantified, and found that specific compounds exhibit anti-inflammatory effects.
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Synthesis of Cu/Mn/Ce polymetallic oxide catalysts and catalytic ozone treatment of wastewater

RSC Adv., 2024, 14,35993-36004
DOI: 10.1039/D4RA06052K, Paper
Open Access
Jinlong Zhong, Xue feng Mao, Guanyu Wang, Heng Li, Junfang Li, Sijian Qu, Jianwei Zhao
Non-homogeneous ozone-catalyzed oxidation technology is one of the effective ways of treating wastewater, the core of which lies in the development of efficient ozone oxidation catalysts.
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Effect of magnetic field on the rate performance of a Fe2O3/LiFePO4 composite cathode for Li-ion batteries

RSC Adv., 2024, 14,36005-36015
DOI: 10.1039/D4RA06707J, Paper
Open Access
Emmanuel Iheonu Nduka, Nazgul Assan, Mukagali Yegamkulov, Aliya Mukanova, Zhumabay Bakenov
Application of magnetic field upon drying of LiFePO4 cathode enhances its electrochemical performance. It is further enhanced with Fe2O3 nanoparticle additives, thereby reducing polarization and improving conductivity and lithium-ion diffusion.
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A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
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Chitosan supported ionic liquid, a multifaceted catalyst for streamlined and efficient synthesis of carboxylic, amino acid and carbohydrate esters

RSC Adv., 2024, 14,36193-36208
DOI: 10.1039/D4RA05725B, Paper
Open Access
Praachi Kakati, Satish Kumar Awasthi
Development of a solid heterogeneous catalyst in the form of an ionic liquid incorporated in chitosan which shows high recyclability. This was used in a solvent free esterification reaction of carboxylic acids, amino acids and carbohydrates.
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Distance-based paper microfluidic devices for rapid visual quantification of heavy metals in herbal supplements and cosmetics

RSC Adv., 2024, 14,36142-36151
DOI: 10.1039/D4RA05358C, Paper
Open Access
Yanawut Manmana, Mirek Macka, Nantana Nuchtavorn
The ion exchange paper shows strongly retain anionic metallochromic reagents, enabling clear endpoint detection on DμPADs. This method allows rapid heavy metal screening in real samples, with the predeposited reagents stable for at least 2 months.
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In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity

RSC Adv., 2024, 14,36209-36225
DOI: 10.1039/D4RA06890D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda Hakim
A facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.
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Porous CaMnO3-promoted g-C3N4 as an effective photocatalyst for tetracycline degradation

RSC Adv., 2024, 14,36181-36192
DOI: 10.1039/D4RA06407K, Paper
Open Access
Bo Zhang, Chaoqi Li, Shasha Liu, Lixuan Zhuang, Weiqi Zhang, Limei Huang, Zhenzhen Jia, Dongdong Chen, Xiang Li
Non-expensive CaMnO3 perovskite oxide can assist in developing efficient g-C3N4-based photocatalysts aimed at removing antibiotics from wastewater.
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Facile fabrication of g-C3N4/Bi2S3 coated melamine foam for oil/water separation applications

RSC Adv., 2024, 14,36132-36141
DOI: 10.1039/D4RA07030E, Paper
Open Access
Swathi A. C., Maneesh Chandran
Oil/water separation using g-C3N4/Bi2S3 foam.
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Applications and interventions of polymers and nanomaterials in alveolar bone regeneration and tooth dentistry

RSC Adv., 2024, 14,36226-36245
DOI: 10.1039/D4RA06092J, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Prashish Sharma, Sushmita Saurav, Zeba Tabassum, Bhawana Sood, Anil Kumar, Tabarak Malik, Anand Mohan, Madhuri Girdhar
Inflammatory diseases exert a significant influence on the periodontium, serving as a primary contributor to the development of periodontitis and alveolar bone loss.
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Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
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Synthesis of green fluorescent carbon dots and their application in mercury ion detection

RSC Adv., 2024, 14,36273-36280
DOI: 10.1039/D4RA06635A, Paper
Open Access
Juan Hou, Qinqin Chen, Xiangzhi Meng, Huiling Liu, Wei Feng
Green fluorescent carbon dots were prepared for effective detection of Hg2+ ions through fluorescence quenching, demonstrating high sensitivity and selectivity.
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Hundreds relocated in Gujarat as heavy rains flood districts, disrupt daily life

Due to heavy rains, the district administration has declared a holiday for all educational institutions




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National film award dedicated to Assam women’s stork army

IPS officer Partha Sarathi Mahanta has directed the 19-minute documentary film on the Hargila Army comprising women of Dadara Pasaria village




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With qualification done, Olympic champion Neeraj Chopra has his task cut out

The other Indian Kishore Jena could not qualify for finals while the only medal hope for Pakistan Arshad Nadeem qualified for finals.




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Faster, higher, longer: decathlete Jashbir Nayak sets his sights on the Asian Games

The 22-year-old has advanced swiftly in a short period, registering an overall increase of 1244 points since last May. This has both underlined his potential in athletics’ toughest discipline and propelled his ambition to excel at the prestigious continental event in two years’ time




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Thousands join effort to clean up catastrophic Spanish floods

Volunteers went to Valencia's City of Arts and Sciences for the first coordinated clean-up organised by regional authorities




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BBFS ties up with Southampton FC for coaches’ education




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Gold purification: Provide small and medium refineries licences, says industry association

Merchants’ association urges Centre to review decision on mandatory hallmarking and HUIC certification for purifying old ornaments



  • Gold & Silver

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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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What is the key factor affecting the cathodoluminescence intensity of europium complexes?

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02501F, Communication
Rongdeng Lu, Tinghui Huang, Alexander Goloveshkin, Dmitry Kopytov, Kseniya Orekhova, Ivan Khanbekov, Valentina V. Utochnikova
Cathodoluminescence of lanthanide coordination compounds correlates with PLQY/τ in the saturation regime and with PLQY when saturation is not reached. Understanding this, a brightly cathodoluminescent europium complex was obtained.
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Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02696A, Perspective
Ankita Sharma, Unnikrishnan Nair K, Subrata Kundu
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...
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Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02645D, Paper
Ketan Maru, Sarita Kalla, Ritambhara Jangir
The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Rational fabrication of an anionic zinc carboxylate framework as a fluorescent probe for 2,6-pyridinedicarboxylic acid

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02529F, Paper
Hui-Hui Xie, Hao Yu, Xiuling Xu, Si-Fu Tang
An anionic zinc carboxylate framework has been fabricated as a fluorescent sensor for the detection of 2,6-pyridinedicarboxylic acid (DPA).
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Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02713B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sophie C. Corner, Gemma K. Gransbury, David P. Mills
We present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.
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Switchable, chiral aluminium catalysts for ring opening polymerisations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02831G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntosh
A switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.
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Indium-Catalyzed Hydrosilylation of Nitroarenes to Aromatic Amines

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02861A, Paper
Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda
Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures...
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