cat Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01570C, Research ArticleFei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing WuA novel palladium-catalyzed cascade reaction of o-iodostyrenes, internal alkynes and formates to access various indene-1-acetates through sequential double carbopalladation and aryloxycarbonylation under a palladium/air system was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01562B, Research ArticleXinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin FanA versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01841A, Research ArticleXunhua Wang, Jianhua Wang, Xiaoxun LiA gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01638F, Research ArticleAijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei DingA highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01703J, Review ArticleYa-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan CaoRecent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Visible-light mediated selective phosphonylation modification of tryptophan residues in oligopeptides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6287-6292DOI: 10.1039/D4QO01028K, Research ArticleWenfang Xiong, Junye He, Jinyao Liu, Peiru Chen, Shiqi Xu, Yipeng Liu, Shiting Chen, Yuanyuan You, Zhenyu Chen, Jinwu ZhaoA direct C2-H phosphonylation strategy driven by visible light for specific modification of tryptophan-containing peptides has been reported, providing a plethora of phosphorylated tryptophan-containing peptidesThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Pd-catalyzed S-glycosylation of cysteine-containing peptides at room temperature By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6347-6352DOI: 10.1039/D4QO01389A, Research ArticleLinhua Shen, Franck Le Bideau, Gong Chen, Samir MessaoudiThis study reports the synthesis of thioglycopeptides via a Pd-catalyzed coupling of cysteine-containing peptides with iodoglycals. A variety of cysteine-containing peptides and other thiol nucleophiles including thiosugars and thiophenols were used.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6367-6379DOI: 10.1039/D4QO01452A, Research ArticleSubal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut GhoshHerein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6340-6346DOI: 10.1039/D4QO01376J, Research ArticleQinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong LianWe developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat A cucurbit[8]uril-mediated host–guest complex for red-light photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6327-6332DOI: 10.1039/D4QO01492H, Research ArticleWeiquan Xu, Yinghao Du, He Ma, Xingchen Tang, Jiang-Fei Xu, Xi ZhangTwo-step host–guest complexation can occur between an elongated dye and CB[8], leading to the formation of CB[8]@2TPP and 3CB[8]@2TPP sequentially. Of these species, 3CB[8]@2TPP in particular can act as an efficient red-light photocatalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6426-6436DOI: 10.1039/D4QO01551G, Research ArticleMao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long ZhaoA cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6319-6326DOI: 10.1039/D4QO01368A, Research ArticleYu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming WangA variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6393-6410DOI: 10.1039/D4QO01451K, Research ArticleJiaoyang Liu, Li-juan Huang, Zeang Sun, Juan LiDFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6470-6476DOI: 10.1039/D4QO01532K, Research ArticleXiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu LiA novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6450-6458DOI: 10.1039/D4QO01528B, Research ArticleXiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi HanA silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6437-6443DOI: 10.1039/D4QO01265H, Research ArticleDabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou CaiIn this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6459-6469DOI: 10.1039/D4QO01555J, Research ArticleXin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang ZhangA nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Sulfenylation of bioactive maleimides, acrylates and cyclohexenones under ambient organophotocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6503-6509DOI: 10.1039/D4QO01342E, Research ArticleDebanjana Bag, Rajjakfur Rahaman, Anindya S. Manna, Subhasis Pal, Rajesh Nandi, Shobhon Aich, Narendra Nath Ghosh, Dilip K. MaitiA novel visible light-induced sulfenylation of biologically important maleimides, acrylates and cyclohexenones has been developed using cheap and easily available organophotoredox catalyst Eosin Y with thiols under ambient conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6311-6318DOI: 10.1039/D4QO01474J, Research ArticleJiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng ChenCo-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Transition-metal-catalyzed C–Ge coupling reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6558-6572DOI: 10.1039/D4QO01637H, Review ArticleJie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan HeThis review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6573-6588DOI: 10.1039/D4QO01644K, Review ArticleZhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You HuangRecent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01844C, Research ArticleShuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu XuThis article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01560F, Research ArticleHong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu WangThrough crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01309C, Research ArticleJiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao ShengA visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Folding of a dynamic macrocyclic system to stabilize its cation radical state By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01566E, Research ArticleArnab Dutta, Krzysztof Dzieszkowski, Marco Farinone, Łukasz Orzeł, Krzysztof Kruczała, Monika Kijewska, Miłosz PawlickiA precisely designed π-extended system responds to different stimuli by folding the structure, which prevents overoxidation and stabilizes the cation radical.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat A Stereoselective Organocatalyzed C-Glycosylation of Indole: Implications of Acceptor-Catalyst-Donor Interaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01873G, Research ArticleLihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa XuA stereoselective pyridinium hexafluorophosphate-catalyzed C-glycosylation of indole is presented, featuring the plausible formation of a catalyst-acceptor complex and a crucial H-bond between the indole N-H and the oxygen at C6...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01963F, HighlightYingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie WuAs the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Thiocyanoalkylation of Alkenes via Dual Photoredox and Copper Catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01864H, Research ArticleXu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua ZhangOrganic thiocyanates are commonly used as an essential organic synthesis intermediate and widely present in various drug molecules and bioactive molecules. Herein, a copper and photoredox catalyzed thiocyanoalkylation reaction of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01627K, Research ArticleBo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long ZhuWe report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Integrating electrocatalysis with biocatalysis for asymmetric synthesis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01899K, HighlightYuqi Lin, Jiage Yu, Ke-Yin YeThis highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01877J, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cintya Pinilla, Mario García-Zarza, Ana C. AlbénizThe mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01573H, Research ArticleZhaolin Quan, Yubo Duan, Zhengkai ChenA straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01831A, Research ArticleJiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang LiA method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01810A, Research ArticleÁngel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-CastellsCyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01879F, Research ArticleYuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin FanOxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01816H, Research ArticleSheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng ZhaoSkeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01592D, Research ArticleBin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao HeThe development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01734J, Research ArticleYuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing LiTransition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat Mahabubnagar District Education Officer in ACB net By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:16:55 +0530 Full Article Telangana
cat Mental health and resilience in higher education institutions as a mission By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:10:51 +0530 A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing Full Article Telangana
cat Lorry ferrying EV cars to Hyderabad catches fire By www.thehindu.com Published On :: Sun, 10 Nov 2024 22:51:21 +0530 Full Article Telangana
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cat Are you ready to crack CAT? By www.thehindu.com Published On :: Sun, 08 Nov 2015 17:01:00 +0530 Building concepts and optimising test performance should be the two objectives of preparation. Full Article Careers
cat On 'kaniyan koothu', an art form dedicated to the graveyard god By www.thehindu.com Published On :: Sat, 30 Jun 2018 16:00:00 +0530 Sudalai Madan was banished to earth after it was discovered that he preferred eating human flesh to divine nectar Full Article Society
cat Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35163-35171DOI: 10.1039/D4RA06595F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng HuangGraphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
cat A comparative study on the thermal runaway process mechanism of a pouch cell based on Li-rich layered oxide cathodes with different activation degrees By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35074-35080DOI: 10.1039/D4RA06355D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wei Quan, Jinghao Liu, Jinhong Luo, Hangfan Dong, Zhimin Ren, Guohua Li, Xiaopeng Qi, Zilong Su, Jiantao WangLi-rich layered oxide (LLO) is regarded as one of the most promising candidates for the next-generation batteries.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article