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A new versatile crystalline sponge for organic structural analysis without the need of activation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07946E, Paper
Jin chang Liu, Weiping Huang, Yuxin Tian, Wei Xu, Wen-Cai Ye, Ren-Wang Jiang
Crystalline sponges made “crystallography without crystals” and received current attentions, but were difficult to apply directly because of the tedious activation procedures. It was important to prepare crystalline sponges that...
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Investigating the Lithium Plating Triggering Criterion for Graphite Electrode

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00244J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiani Li, Lubing Wang, Jun Xu
Lithium plating is considered an undesirable side reaction due to its potential to induce capacity fade and pose safety concerns in Li-ion batteries. The timely detection of lithium plating onset...
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Synthesis of a pyridine-based covalent organic framework as an anode material for lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00892H, Paper
Shixi Zhong, He Zhao, Yingming Ji, Xiuhua Li, Ting Shu, Zhiming Cui, Shijun Liao
Covalent organic framework (COF) materials with redox activity have emerged as promising electrode materials for lithium-ion batteries.
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Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00736K, Review Article
Reza Abazari, Soheila Sanati, Ashok Kumar Nanjundan, Qiyou Wang, Deepak P. Dubal, Min Liu
The current review discusses on vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
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Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
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Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica with promoted CO insertion and C–C coupling for higher alcohol synthesis from syngas

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01179A, Paper
Zhuoshi Li, Siqi Fan, Zhuang Zeng, Shaoxia Guo, Xiaofeng Pei, Shouying Huang, Yong Wang, Yue Wang, Xinbin Ma
Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica showed superior performance for HAS than catalysts with uncoated and amorphous supports.
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Reduction on Specific Lattice Planes for Metal-organic Frameworks/Poly-pyrrole Composites with Dilated Porosity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00766B, Paper
Wenxiu He, Xu Zhai, Zhipeng Qiao, Huan Chen, Weiliang Tian, Yu Fu, Junyi Chen
Owing to the microporosity, metal-organic frameworks (MOFs) have attracted great attention in various applications, whereas their potential in mass transfer and diffusion of larger molecules have been limited. To break...
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Tuning the ion conductivity of Zr-based metal organic framework ionogels by linker functionalization

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06986A, Paper
Open Access
Antonija Ferbezar, Roman Zettl, Katharina Hogrefe, Harald Fitzek, Bernhard Gadermaier, Martin Wilkening, Ilie Hanzu
Solid-state ion conductors have improved significantly in the past decade. Envisioned applications range from metal anode batteries and fuel cells to sensors and medical technologies. The choice of solid electrolytes...
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An electrically conducting 3D coronene-based metal–organic framework

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07120K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marina I. Schönherr, Patricia I. Scheurle, Laura Frey, Marta Martínez-Abadía, Markus Döblinger, Andre Mähringer, Dominik Fehn, Lena Gerhards, Irina Santourian, Alfred Schirmacher, Tatjana Quast, Gunther Wittstock, Thomas Bein, Karsten Meyer, Aurelio Mateo-Alonso, Dana D. Medina
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy-cata-hexabenzocoronene (c-HBC) and FeIII ions is presented.
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Data-driven discovery of carbonyl organic electrode molecules: machine learning and experiment

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00136B, Paper
Jiayi Du, Jun Guo, Qiqi Sun, Wei Liu, Tong Liu, Gang Huang, Xinbo Zhang
In this work, a universal strategy for the identification of high-performance OEMs for LIBs has been illustrated. The predicted molecule, naphthalene-1,4,5,8-tetraone, exhibits excellent electrochemical performance in terms of capacity and lifetime.
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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
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Enhancing CO2 gasification-reforming of municipal solid waste with Ni/CeO2 and Ni/ZrO2 catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00665H, Paper
Shiyu Zhang, Yibing Peng, Mengna Wu, Qinghai Li, Yanguo Zhang, Hui Zhou
CO2 gasification-reforming facilitates CO2 utilization and yields CO-rich syngas for municipal waste management. Catalysts are essential for enhancing syngas production via catalytic tar reforming.
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Enhanced Hydrogen Production by Assisted Biomass Gasification Using Lithium Manganate as Bifunctional Material

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00224E, Paper
Open Access
Carlos Hernández-Fontes, Nan Wang, Nayeli Gómez-Garduño, Heriberto Pfeiffer
The rising energy demand, among other economic and technological factors, increases the greenhouse gas emissions. Therefore, it is crucial to develop technologies to produce clean energy, such as hydrogen (H2)...
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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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Farmers want baby canal alongside Kalingarayan Canal to be developed

A proposal to set up an effluent treatment plant and to carry out concrete lining of the baby canal, submitted in 2021-22, is under government’s consideration, says a senior official in the Water Resources Department




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Stray dog kills calf at Sugavaneswarar temple’s goshala in Salem




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Legal battle over permanent English teacher appointments in high school continues

Govt cites financial problems; PSC rank-holders say posts are being created for other language subjects




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Alert against hepatitis A in Kollam




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Ambulance aggregator service under consideration: Ganesh Kumar

Aimed at enhancing emergency response across Kerala




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Mamata calls for unity of hills and plains; focuses on development in north Bengal

This is her first official visit to Darjeeling in two years; she did not go to the hills even during the 2024 Lok Sabha election campaigns




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Telangana BJP seeks judicial probe into Vikarabad incident




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Govt. charges BRS with hatching conspiracies to stall development projects for political gains

Dy CM says involvement of BRS leader in Lagacharla incident exposes the party’s intentions




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Indian households accumulated USD 9.7 trillion in wealth over last ten years: Morgan Stanley




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India IT spending to reach USD 160 billion in 2025 fueled by application and infrastructure software market growth: Gartner




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EU, Belgium, Denmark and Germany envoys visit Adani's Khavda, Mundra businesses, Gautam Adani says It was a privilege




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Integrated manufacturing cluster to be developed in Bihar's Gaya




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Gaining the Molecular Design Principles for Efficient Diarylethene Photoacid and Photohydride Generators Based on Photochemical Reaction Mechanism

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06202G, Edge Article
Open Access
Yifan Su, Dexin Zheng, Lingfeng Ge, Le Yu, David Lee Phillips, Jiani Ma, Yu Fang
Abstract: Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile protecting groups that release acid and hydride, respectively. Over the past decade, great efforts have been devoted to developing...
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Goalpara Sainik school gave countless cadets to country: Assam Guv




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Providing better healthcare biggest priority: PM Modi ahead of Darbhanga AIIMS inauguration




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Chandigarh's air quality continues to be worse than Punjab, Haryana




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No gaps in management of biodegradable waste, Kerala tells NGT




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HC quashes magistrate court’s directive to register FIR against police officers

Magistrate court’s order to file FIR against police officers, including IPS officer and former Malappuram Superintendent of Police Sujith Das, in connection with an alleged sexual assault case quashed




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‘Anti-war’ comedy play riles Bulgarian nationalists

Last week’s premiere of Arms and the Man by renowned Irish-born playwright George Bernard Shaw sparked raucous protests by nationalist groups




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Discovery of hybrid Glypromate conjugates with neuroprotective activity against paraquat-induced toxicity

RSC Med. Chem., 2024, 15,3711-3727
DOI: 10.1039/D4MD00584H, Research Article
Sara C. Silva-Reis, Vera M. Costa, Daniela Correia da Silva, David M. Pereira, Xavier Cruz Correia, Xerardo García-Mera, José E. Rodríguez-Borges, Ivo E. Sampaio-Dias
A series of bicyclic-based Glypromate conjugates with reduction of protein aggregation elicited by Aβ25–35 and neuroprotective activity against paraquat-induced toxicity is reported, paving the way for the discovery of novel neurotherapeutics.
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Stachydrine, a pyrrole alkaloid with promising therapeutic potential against metabolic syndrome and associated organ dysfunction

RSC Med. Chem., 2024, 15,3652-3673
DOI: 10.1039/D4MD00425F, Review Article
Semim Akhtar Ahmed, Prasenjit Manna, Jagat Chandra Borah
Metabolic syndrome is a multifaceted condition marked by interconnected risk factors, significantly increasing the risk of serious diseases like cardiovascular disease, type 2 diabetes, and stroke.
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Evaluating the therapeutic potential of genetically engineered probiotic Zbiotics (ZB183) for non-alcoholic steatohepatitis (NASH) management via modulation of the cGAS-STING pathway

RSC Med. Chem., 2024, 15,3817-3836
DOI: 10.1039/D4MD00477A, Research Article
Maha Saad, Walaa Ibrahim, Amany Helmy Hasanin, Aya Magdy Elyamany, Marwa Matboli
ZBiotics administration in the NASH model downregulated the RNA panel (MAPK3, EDN1, TNF, miR-6888-5p, lncRNA RABGAP1L-DT-206), restored intestinal barrier integrity, reduced hepatic inflammation, and improved lipid profiles and liver enzymes.
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Hydrophobic CPP/HDO conjugates: a new frontier in oligonucleotide-warheaded PROTAC delivery

RSC Med. Chem., 2024, 15,3695-3703
DOI: 10.1039/D4MD00546E, Research Article
Miyako Naganuma, Nobumichi Ohoka, Motoharu Hirano, Daishi Watanabe, Genichiro Tsuji, Takao Inoue, Yosuke Demizu
A novel hydrophobic cell-penetrating peptide (CPP) and heteroduplex oligonucleotide (HDO)-conjugated PROTAC, CPP/HDO-PROTAC, was designed to enhance its intracellular delivery and degradation efficiency.
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Anticancer potential of copper(I) complexes based on isopropyl ester derivatives of bis(pyrazol-1-yl)acetate ligands

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00610K, Research Article
Open Access
Maura Pellei, Carlo Santini, Miriam Caviglia, Jo' Del Gobbo, Chiara Battocchio, Carlo Meneghini, Simone Amatori, Chiara Donati, Eleonora Zampieri, Valentina Gandin, Cristina Marzano
In this paper, the isopropyl ester derivatives LOiPr and L2OiPr of bis(pyrazol-1-yl)acetic acid and bis(3,5-dimethyl-pyrazol-1-yl)acetic acid were used as chelators for the preparation of the new Cu(I) phosphane complexes 1-4....
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Mangaluru Junction - CSMT Superfast Express to get LHB coaches in March 2025

Train No. 12133 Mumbai CSMT-Mangaluru Junction Superfast Express will get an LHB rake from March 1 while its pairing service, Train No. 12134 Mangaluru Junction-Mumbai CSMT Superfast Express, will get an LHB rake from March 2




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Sakhi centre inaugurated at Vizianagaram Collectorate




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All set for Urus festival at Pedda Dargah in Kadapa

Thousands of devotees from across Andhra Pradesh, Tamil Nadu, Karnataka and Maharashtra expected to converge at the famous Sufi shrine for the week-long event starting on November 16




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Andhra Pradesh government deploys drones to detect ganja palnatations

State collaborates with NCB and Google to map and track cannabis plantations using satellite imagery technology




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Andhra Pradesh govt. reaffirms commitment to ‘irrigating every acre of farmland’ in State through river-interlinking projects




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Jagan dares govt. to arrest him, says will continue to ‘expose failures’




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Police book Sri Reddy for posting ‘defamatory content’ against Chandrababu Naidu, Pawan Kalyan




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Varun Hospitality announces eco-friendly mixed-use project to replace The Gateway Hotel in Visakhapatnam




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Supreme Court sets pan-India guidelines against ‘bulldozer justice,’ calls demolitions without due process unconstitutional

The Apex court maintains that these guidelines do not apply in cases of unauthorized public land construction or where demolition is mandated by a court ruling




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GlobalLogic opens delivery centre in Hyderabad to spread wings, ramp up hiring in Telangana 

The company will consider spreading wings to one more such location, in addition to Mahbubnagar where it has about 350 employees