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Bihar: PM Modi lays foundation stone of multiple projects including AIIMS in Darbhanga

Prime Minister Narendra Modi laid the foundation stone for multiple projects in Bihar, including an AIIMs in Darbhanga district.




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Supreme Court mandates demolition rules with legal consequences for violations

The Supreme Court has issued a series of directives governing the demolition of unauthorized structures across the country. The court has cautioned that any violation of these directives by state officials will result in criminal contempt and prosecution.




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Genetic mutation may help people stop craving sugary foods: Study

An international team of scientists has now found that a genetic mutation may enable people to cut down their sugar intake.




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India hosts senior cancer physicians, policymakers from Bay of Bengal countries

India hosted senior cancer physicians and policymakers from BIMSTEC countries during the annual meeting of National Cancer Grid (NCG) held at Mumbai's Tata Memorial Hospital.




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Dhargalim set to shine as Sunburn Goa 2024 EDM venue

The electronic dance music (EDM) festival, Sunburn Goa, is set to take place in a new location for its upcoming edition. The festival, which has been a staple in the EDM scene since its inception, will be held at Dhargalim in North Goa from December 28 to 30, 2024.




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'Yeh Kaali Kaali Ankhein' season 2 trailer ups the game, sees the entry of Gurmeet Choudhary

The trailer of the upcoming season of the streaming series 'Yeh Kaali Kaali Ankhein' was unveiled on Wednesday. It shows how the lead character of Purva is kidnapped instead of being assassinated at the behest of Tahir Raj Bhasin's character of Vikrant.




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Salman Khan has no association with The Great Indian Kapil Show or its legal disputes

In a recent development, Salman Khan's representative has clarified that the actor has no association with the show "The Great Indian Kapil Show" on Netflix.




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World Diabetes Day 2024: Top 5 Early Warning Signs of High Blood Sugar Levels That Appear In Morning - TheHealthSite

  1. World Diabetes Day 2024: Top 5 Early Warning Signs of High Blood Sugar Levels That Appear In Morning  TheHealthSite
  2. Tackling diabetes epidemic  The Hindu
  3. World Diabetes Day 2024: Why type 2 diabetes often goes unnoticed, early signs of this silent killer, and associated risks  The Economic Times
  4. World Diabetes Day 2024  PIB
  5. 86% diabetics in India facing anxiety, depression; women more affected: Report  Gujarat Samachar




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Suryakumar Yadav Reveals 'Sacrifice' For Tilak Varma That Worked Wonders For India Against South Afr.. - NDTV Sports

  1. Suryakumar Yadav Reveals 'Sacrifice' For Tilak Varma That Worked Wonders For India Against South Afr..  NDTV Sports
  2. India create history, set a new T20 world record during thrilling win against South Africa  The Times of India
  3. Flying ants to burnt toast: 5 bizarre reasons that stopped a cricket match  Business Standard
  4. Va-va-voom Varma powers India to unbeatable series lead  Cricbuzz
  5. India registers their eighth 200-plus total in T20Is this year  Hindustan Times








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Won’t back off from ‘Pharma Village’, says Telangana CM’s brother - The Siasat Daily

  1. Won’t back off from ‘Pharma Village’, says Telangana CM’s brother  The Siasat Daily
  2. Lagcherla: KTR named in remand report  Deccan Chronicle
  3. Ex-BRS MLA held over mob attack on Vikarabad collector  Hindustan Times
  4. Video | Violence Over Land Row In Telangana Chief Minister's Constituency, 55 Detained  NDTV
  5. Govt. charges BRS with hatching conspiracies to stall development projects for political gains  The Hindu






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Why Your Small Business Growth Stalled — And How to Kickstart It Again

It's possible to scale sustainably even in uncertain times.




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Jinneng Clean Energy Technology Ltd vs Sunedison Energy Holding (Singapore) ... on 2 September, 2024

The above Original Petition has been filed by the successful Award Holder under Chapter I Part II of the Arbitration and Conciliation Act, 1996 to recognize the Final Award dated 22.02.2021 and the addendum to the Final Award dated 08.03.2021.

______________ Page No 3 of 184 https://www.mhc.tn.gov.in/judis Arb.O.P.(Com.Div.)No.186 of 2023

2. The respective legal contentions of the Petitioner (the claimant) and the Award Debtor Respondent No.2 (the Engineering Company) and the Award Debtor Respondent No.3 (the Project Company) shall be adverted after narrating the facts of the case. I propose to narrate the facts in two parts.




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Ranjana Garg vs Gnctd on 13 November, 2024

:

The Appellant filed an (offline) RTI application dated 29.03.2023 seeking the following information:

Page 1 of 4

"I Ranjana Garg wife of Shri Keshav Kumar Garg, resident of xxx, Vasant Vihar, New Delhi 110057, wish to seek information, under the RTI Act, 2005. The copy of complete document information needed as per details given below:

4. Copy of complete documents of 0-4 shumar no. 5770, SDM/RA Case No. 206/RA/92 dated 08/01/1994, Khasra # 1084, land measuring 1 bigha 1 biswa in the name of Ranjana Garg wife of Keshav Kumar Garg, situated in the revenue estate of Urbanised Village Rangpuri alias Malikpur Kohi, Tehsil Vasant Vihar, New Delhi."




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Manish Agarwal vs Military Engineer Services on 13 November, 2024

:

The Appellant filed an (online) RTI application dated 24.04.2023 seeking the following information:

Querry is in reference to Chief Engineer Central Command. Index No 5-28

-Central Command. For renewal of Security Deposit of FDR wherein many letters were sent for sending to bank FDRs for renewal. However, no reply has been received. Letters dated 08.08.2022, No 4501-244 dated 08.08.2022, letter No 4501-245 dated 06.10.2022, dated 15.11.2022 & dated 20.12.2022 & letter No 4501-248 datet25.01.2023, and 20.03.2023.

FDR bearing No.7 15474 Folio 127180-98 dt.25.9-98 for Rs.60,000.00, (Maturity Date :3-7-2001 FDR bearing No.715475 Follo 127198/98) dated 23.9.98 for Rs.60,000.00.




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Rahul Gandhi: വയനാട് സുരക്ഷിതം, ടൂറിസം മേഖല തകരാൻ പാടില്ല; സിപ് ലൈനിൽ കയറി രാഹുൽ ​ഗാന്ധി

Rahul Gandhi: ചൂരൽമല മുണ്ടക്കൈ ദുരന്തത്തിന്റെ പശ്ചാതലത്തിൽ വയനാട് സുരക്ഷിതമാണെന്ന സന്ദേശം നൽകുന്നതിനാണ് അദ്ദേഹം സിപ് ലൈനിൽ കയറിയത്. 




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Actor John Krasinski named 'Sexiest Man Alive 2024' by People magazine

Krasinski's win adds him to an esteemed group of past honourees like George Clooney, Brad Pitt, Idris Elba, and Michael B. Jordan.




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Here's why Anupamaa-fame Rupali Ganguly is seeking Rs 50 crore in defamation compensation from stepdaughter Esha Verma

Rupali Ganguly's lawyer Sana Raees Khan of Bigg Boss 17-fame reveals why Anupamaa actress is asking for Rs 50 crore as defamation compensation from her stepdaughter Esha Verma.




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This actor lived on a rooftop, starved for days, gatecrashed film sets for food; became one of India's biggest OTT stars

This actor, who once used to starve for days, gatecrash film sets for food, later became a superstar.




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A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00244J, Research Article
Hui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping Xu
An efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.
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Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00103F, Research Article
Xihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui Wang
Steric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00227J, Review Article
Min Tan, Bram B. C. Peters, Pher G. Andersson, Taigang Zhou
This review summarizes the recent advances (2016–2023) in the stereoselective metal-catalyzed hydrogenation of cyclic α,β-unsaturated ketones, lactams and lactones since considerable developments were made. Where possible the application of these methodologies in synthesis is outlined.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Computational insights into the synergistic interplay of ligand and fluorine effects in palladium-catalyzed regiodivergent decarboxylative allylic alkylation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00147H, Research Article
Shiyu Wang, Hongli Wu, Xiangyang Tang, Genping Huang
DFT calculations were performed to investigate palladium-catalyzed decarboxylative allylic alkylation of allyl difluoro-β-ketoesters. The synergistic effects of ligand and fluorine substituents on regioselectivity were uncovered.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00148F, Research Article
Dong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei Xu
The challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.
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Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00141A, Research Article
Tong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er Chen
An asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.
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Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage

Org. Chem. Front., 2024, 11,2277-2282
DOI: 10.1039/D3QO01999C, Research Article
Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo
We describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold

Org. Chem. Front., 2024, 11,2178-2181
DOI: 10.1039/D4QO00269E, Research Article
Vojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy Bertrand
Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.
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Contributors to the Organic Chemistry Frontiers Emerging Investigator Series 2022–2023

Org. Chem. Front., 2024, 11,2149-2154
DOI: 10.1039/D4QO90025A, Profile

This profile article showcases researchers who have contributed an article to the Organic Chemistry Frontiers Emerging Investigator Series.
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Regioselective Oxidative Cleavage of Conjugated Dienes to Access α,β–Unsaturated Nitriles

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D3QO02101G, Research Article
Yuqing Fu, Yijia Leng, Haotong Bai, Jiaxi Xu, Ning Chen
A highly regioselective oxidative cleavage method has been developed for the synthesis of α,β-unsaturated nitriles from unsymmetric conjugated dienes. This transformation selectively cleaved the terminal C=C double bond, providing moderate...
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Palladium-catalyzed and ligand-controlled divergent cycloadditions of vinylidenecyclopropane-diesters with para-quinone methides enabled by zwitterionic π-propargyl palladium species

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00368C, Research Article
Jia-Hao Shen, Yong-Jie Long, Min Shi, Yin Wei
A palladium-catalyzed and ligand-controlled divergent synthesis of spiro-cyclohexadienones from p-quinone methides and VDCP-diesters was realized via zwitterionic π-propargyl palladium species and the mechanism was clarified by DFT calculations.
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A Hierarchical Surrogate Approach to Biomass Ethanolysis Reaction Kinetic Modelling

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00378K, Paper
Ailís O'Shea, Conall McNamara, Prajwal Rao, Mícheál Séamus Howard, Mohammad Reza Ghaani, Stephen Dooley
The reaction mechanism and kinetics of the sulfuric acid catalysed ethanolysis of glucose, cellulose, xylan, and corncob was investigated using a combination of experiments and empirical reaction mechanism modelling. The...
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Let's ensure resounding victory together: Rahul Gandhi to Wayanad voters

‘She [Priyanka Gandhi Vadra] will be more than just a representative – she will be your sister, your daughter, and your advocate’, says Rahul Gandhi in a post on X on bypoll day




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Panel to look into ‘disruption’ of Kerala School Sports & Games




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Thiruvananthapuram Zoo welcomes new species from Shivamogga

Arrival of hyenas, jackals, marsh crocodiles, and palm civets raise species count to 94




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Quiz competition on AI in Karunagapally




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Principal Secretary to PM highlights mitigating risks associated with glacial lakes to ensure safer future




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Rahul Gandhi's video promoting Wayanad as tourist destination goes viral




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Rahul Gandhi experiences Kerala's longest zipline in Wayanad




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Genetic mutation may help people stop craving sugary foods: Study




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Autocomplete Interview - Megan Thee Stallion Answers The Web's Most Searched Questions

Musician Megan Thee Stallion visits WIRED to answer her most searched for questions on Google. Where did Megan Thee Stallion get her name? What's her favorite anime? What is Megan Thee Stallion's typical workout routine? What does Megan Thee Stallion call her fans? Answers to these questions and many more await on the WIRED Autocomplete Interview. 'Megan Thee Stallion: In Her Words' is now streaming on Prime Video. Megan Thee Stallion's deluxe album 'Megan: Act II" is now available to stream. Director: Justin Wolfson Director of Photography: Kevin Dynia Editor: Daniel Poler Talent: Megan Thee Stallion Line Producer: Joseph Buscemi Associate Producer: Brandon White; Paul Gulyas Production Manager: Peter Brunette Production Coordinator: Rhyan Lark Talent Booker: Jenna Caldwell Camera Operator: Caleb Weiss Sound Mixer: Michael Guggino Production Assistant: Ryan Coppola Post Production Supervisor: Christian Olguin Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Additional Editor: Jason Malizia Assistant Editor: Justin Symonds




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Rejuvenating manganese-based rechargeable batteries: fundamentals, status and promise

J. Mater. Chem. A, 2024, 12,8617-8639
DOI: 10.1039/D4TA00466C, Review Article
Weizhai Bao, Hao Shen, Yangyang Zhang, Chengfei Qian, Dingyu Cui, Jingjie Xia, He Liu, Cong Guo, Feng Yu, Jingfa Li, Kaiwen Sun
Energy storage devices with advanced rechargeable batteries are highly demanded by our modern society.
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Unveiling the fundamental understanding of two dimensional π-conjugated FeN4+4 sites for boosting peroxymonosulfate activation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01195C, Paper
Sijia Jin, Wenxian Tan, Xiaofeng Tang, Xia Yao, Yingjian Bao, Haiyan Zhang, Shuang Song, Tao Zeng
The precisely defined FeN4+4 active sites in fully π-conjugated polyphthalocyanine frameworks establish a dual-pump-driven electron fast shuttle path—electron-rich Fe centers and electron-poor C atoms—ensuring continuous production of 1O2.
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Superhydrophilic covalent organic frameworks accelerate photocatalytic production of hydrogen peroxide through proton channels

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01785D, Paper
Xiaojuan Bai, Linlong Guo, Tianqi Jia, Zhuofeng Hu
Superhydrophilic COFs with D–A structure accelerate photocatalytic synthesis of H2O2 using water as a proton supply reservoir.
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Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
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Aggregation between oligomeric Ir photosensitizers promote efficient and long-lifetime photocatalytic hydrogen evolution

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07365C, Paper
Yifan Huang, Shihan Liu, Bo Wang, Ying Wang, Yifan Zhang, Pengyang Deng
In this paper, the aggregation effect between oligomeric Ir photosensitizers on photocatalytic hydrogen evolution was first discovered and investigated. Four oligomeric Ir photosensitizers were synthesized by copolymerization of [Ir(ppy)2(dabpy)](PF6) (H1)...
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