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Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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The dark side of moviedom

The harrowing tales of women in the Malayalam cinema industry should be a wake-up call to uphold the dignity and safety of women in the workplace



  • From the Viewsroom

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India flight tests missile-assisted torpedo release system

The system was launched around 8.30 am from the ground mobile launcher.




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n-Type redox-tuneable conducting polymer optical nanoantennas

J. Mater. Chem. C, 2024, 12,17469-17474
DOI: 10.1039/D4TC03038A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Suraya Kazi, Pravallika Bandaru, Haoran Tang, Yulong Duan, Shangzhi Chen, Fei Huang, Magnus P. Jonsson
We show that the n-type conducting polymer PBFDO can be optically metallic for wavelengths above around 695 nm after post-treatment, and that nanostructures of the material can act as optical nanoantennas that are dynamically switchable.
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Nanomaterial-based regulation of redox metabolism for enhancing cancer therapy

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00404C, Review Article
Xiaodan Jia, Yue Wang, Yue Qiao, Xiue Jiang, Jinghong Li
This review provides a comprehensive summary of the dysregulation of redox metabolism in cancer cells and the advantages and the latest advances in nanomaterial-assisted redox metabolic regulation therapy.
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PEDOT-based stretchable optoelectronic materials and devices for bioelectronic interfaces

Chem. Soc. Rev., 2024, 53,10575-10603
DOI: 10.1039/D4CS00541D, Review Article
Weizhen Li, Yiming Li, Ziyu Song, Yi-Xuan Wang, Wenping Hu
This review summarized the strategies and mechanisms for improving the conductivity, mechanical properties and stability of PEDOT:PSS, as well as the reliable micropatterning technologies and optoelectronic devices applied at bio-interfaces.
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U.S. Open: Wimbledon champion Krejcikova crashes out in 2nd round; Shelton and Tiafoe to meet in 3rd round

Frances Tiafoe is getting the rematch he wants, a second shot at Ben Shelton at the U.S. Open




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Wimbledon to replace line judges with electronic line calling after 147 years

While popular with players, the decision will sadden traditionalists and likely mean the end of the arguments over line calls that are part of Wimbledon folklore




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Video | Three men + one purpose = Freedom Wall




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Abstract paintings by Chennai artist Bhagwan Chavan comments on freedom and responsibility

A collection of abstract paintings by Bhagwan Chavan deliberates on freedom and the responsibility that it comes with it




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The ‘livery of India’s freedom’ is under threat

The Government has failed to build a global audience for Indian handlooms; what is worse, even the Mahatma’s khadi is being denied its identity, writes Sonia Gandhi in this exclusive article for The Hindu




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A Pure Hedonic Theory of Utility and Status: Unhappy but Efficient Invidious Comparisons [electronic journal].




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New Characteristics and Hedonic Price Index Numbers [electronic journal].




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Media Freedom in the Shadow of a Coup [electronic journal].




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Measuring Unfair Inequality: Reconciling Equality of Opportunity and Freedom from Poverty [electronic journal].




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Can Subsidized Employment Tackle Long-Term Unemployment? Experimental Evidence from North Macedonia [electronic journal].




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Bargaining Failure and Freedom to Operate: Re-evaluating the Effect of Patents on Cumulative Innovation [electronic journal].




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Deciphering the active species and reaction mechanism in water oxidation catalyzed by a copper complex with redox-active ligands

Inorg. Chem. Front., 2024, 11,2365-2372
DOI: 10.1039/D4QI00163J, Research Article
Qing Fan, Cong Yang, Mengdi Li, Chen Wang, Guixia Wang, Xiangfei Kong, Qiping Zhu
This theoretical study unveils active species and the reaction mechanism in electrochemical water oxidation catalyzed by a copper complex with redox-active ligands.
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An immunochromatographic strip sensor for rapid and sensitive detection of candesartan, olmesartan medoxomil, and irbesartan in herbal beverages

Anal. Methods, 2024, 16,2359-2367
DOI: 10.1039/D4AY00151F, Paper
Dingyu Li, Aihong Wu, Liqiang Liu, Hua Kuang, Chuanlai Xu, Xiaoling Wu
Sartans, as a class of antihypertensive drugs, pose a threat to human health when illegally added to herbal beverages.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Anti-schistosomal activity and ADMET properties of 1,2,5-oxadiazinane-containing compound synthesized by visible-light photoredox catalysis

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD90044H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kennosuke Itoh, Hiroki Nakahara, Atsushi Takashino, Aya Hara, Akiho Katsuno, Yuriko Abe, Takaaki Mizuguchi, Fumika Karaki, Shigeto Hirayama, Kenichiro Nagai, Reiko Seki, Noriko Sato, Kazuki Okuyama, Masashi Hashimoto, Ken Tokunaga, Hitoshi Ishida, Fusako Mikami, Kofi Dadzie Kwofie, Hayato Kawada, Bangzhong Lin, Kazuto Nunomura, Toshio Kanai, Takeshi Hatta, Naotoshi Tsuji, Junichi Haruta, Hideaki Fujii
To cite this article before page numbers are assigned, use the DOI form of citation above.
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China’s credo: No give, only take

The book calls for a resetting of the thorny China-India ties




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Editorial. States score major win on financial freedom

The Supreme Court has ruled that States had a perfect right to tax their minerals




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Ben Hur: Chariots of boredom

Even the cinematic feat of evoking pathos cannot make up for Ben-Hur’s failure to resonate with its viewer.




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Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis

Org. Chem. Front., 2024, 11,6573-6588
DOI: 10.1039/D4QO01644K, Review Article
Zhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You Huang
Recent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thiocyanoalkylation of Alkenes via Dual Photoredox and Copper Catalysis

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01864H, Research Article
Xu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua Zhang
Organic thiocyanates are commonly used as an essential organic synthesis intermediate and widely present in various drug molecules and bioactive molecules. Herein, a copper and photoredox catalyzed thiocyanoalkylation reaction of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01627K, Research Article
Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
We report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.
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Oxygen redox activities governing high-voltage charging reversibility of Ni-rich layered cathodes

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03832K, Paper
Gi-Hyeok Lee, Suwon Lee, Jiliang Zhang, Bernardine L. D. Rinkel, Matthew J. Crafton, Zengqing Zhuo, Youngju Choi, Jialu Li, Junghoon Yang, Jongwook W. Heo, Byungchun Park, Bryan D. McCloskey, Maxim Avdeev, Wanli Yang, Yong-Mook Kang
A schematic illustration indicative of the improved structural reversibility through stabilizing oxidized oxygen by Al doping.
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A novel high-performance all-liquid formic acid redox fuel cell: simultaneously generating electricity and restoring the capacity of flow batteries

Energy Environ. Sci., 2024, 17,8545-8556
DOI: 10.1039/D4EE02450H, Paper
Dongbo Wei, Lyuming Pan, Jing Sun, Meisheng Han, Manrong Song, Jincong Guo, Qing Zhang, Cailin Xiao, Zheng Li, Shuaibin Wan, Yubai Li, Lin Zeng, Lei Wei, Tianshou Zhao
This work presents an all-liquid formic acid redox fuel cell using degraded redox flow battery electrolyte as the cathode fuel. This approach efficiently generates power while regenerating the electrolyte, advancing energy conversion and storage.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Birthday Boy Dhoni Spotted At Wimbledon

Dhoni will be 41 on July 7.




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Regulation of redox enzymes by nutraceuticals: a review of the roles of antioxidant polyphenols and peptides

Food Funct., 2024, 15,10956-10980
DOI: 10.1039/D4FO03549F, Review Article
Joy I. Obeme-Nmom, Raliat O. Abioye, Samanta S. Reyes Flores, Chibuike C. Udenigwe
Several nutraceutical compounds, such as polyphenols and peptides, modulate the enzymatic antioxidant defence system, providing an avenue for the development of multifunctional functional foods.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Exosome-like nanoparticles from Arbutus unedo L. mitigate LPS-induced inflammation via JAK-STAT inactivation

Food Funct., 2024, 15,11280-11290
DOI: 10.1039/D4FO03646H, Paper
Cristian Martínez Fajardo, Lucía Morote, Elena Moreno-Giménez, Susana López-López, Ángela Rubio-Moraga, María José M. Díaz-Guerra, Gianfranco Diretto, Alberto J. López Jiménez, Oussama Ahrazem, Lourdes Gómez-Gómez
Exosomes have garnered attention as a potential cell-free therapy for inflammatory diseases due to their immunomodulatory and anti-inflammatory properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The quest for freedom: is the ‘will’ truly free?

Free will, simply defined, is the power to make choices unconstrained by external agencies. However, this definition might be a bit misleading, for human beings are constantly constrained by such outward forces



  • Text and Context

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College textbooks have no mention of freedom fighters from T.N., says Governor Ravi




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In Freedom We're Born: Songs from the American Revolution

New lyrics set to familiar (or some not so familiar) English melodies, recorded using 18th-century instrumentation to recreate the ambience of a small tavern or public meeting place.




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Freedom goes




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Influence of redox treatments on the low-temperature water gas shift reaction over Pt/CeO2 catalysts

Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper
Open Access
Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H2 reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO2 catalysts by increasing the number of active Pt0 NPs. A 12 h oxidative post-treatment at 500 °C which forms PtOx species easily activated also leads to improvement.
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Folic acid-targeted redox responsive polylactic acid-based nanoparticles co-delivering pirarubicin and salinomycin suppress breast cancer tumor growth in vivo

Nanoscale, 2024, 16,20131-20146
DOI: 10.1039/D4NR02365J, Paper
Priya Gupta, Ankushi Bansal, Harshdeep Kaur, Mohd Anees, Neetu Singh, Harpal Singh
Schematic illustration of design, administration, and mechanism of action of Pira/Sal dual-loaded FA-conjugated redox responsive [S-(PLA-b-PEG-CONH)]2 block copolymeric nanoparticles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The ancient history of the Egyptians, Carthaginians, Assyrians, Babylonians. Medes and Persians, Macedonians, and Grecians. / by Mr Rollin, Sometime Principal of the University of Paris, afterwards Professor of Eloquence in the Royal College, and Member o

Edinburgh : Printed for Hamilton and Balfour, Kincaid and Donaldson, and W. Gray., MDCCLVIII. [1758]




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StoreDot’s flash battery gets BP backing




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Iron/photoredox dual-catalyzed redox-neutral double decarboxylative C(sp3)–C(sp3) cross-coupling

Green Chem., 2024, 26,11334-11339
DOI: 10.1039/D4GC04523H, Paper
Qi Zhang, Shanghui Wu, Xuesong Wu
An efficient iron porphyrin/photoredox dual catalytic system for the double decarboxylative radical C(sp3)–C(sp3) cross-coupling under redox-neutral and mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tennis players switching to pickleball: Former Wimbledon finalist Eugenie Bouchard says ‘I feel like I belong a little more’




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‘Wanted to go and play where I could find some freedom’: KL Rahul reflects on leaving LSG




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Moviedom Mourns Sharda Sinha

'The great singer Shardaji took Bhojpuri music and singing to the national and international level with her singing!'




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How to raise a boy: In a shifting world, my son’s freedom of mind is his greatest strength




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Rahul Gandhi writes: Match-fixing monopoly vs fairplay business — time to choose freedom over fear




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Songs of freedom: On the making of ‘Mile Sur Mera Tumhara’ 

The writer takes a trip down memory lane and revisits working on the much-loved ad film, ‘Mile Sur’ It is the 75th year of India’s Independence. And time for a little nostalgia




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US economy faces a comedown from a sugar high

Signs of strength are largely unrelated to government policy





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Sparks of freedom

On the anniversary of religious freedom for Christians in Italy, OM Arts International hosts its first OM Arts School of Missions at Forterocca.




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Sharing about freedom

Three patients in a hospital for drug addicts pray a prayer of repentance after hearing testimonies from students in OM Russia’s missions school.