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Rampant Messi hits another hat-trick as Miami break MLS points record

By www.thehindu.com
Published On :: Sun, 20 Oct 2024 09:06:11 +0530

Messi, who came off the bench in the 58th minute and led the late flurry of goals, has now scored 20 goals in 19 appearances in MLS with his former Barcelona team-mate Suarez also notching 20, from 27 games


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Vinicius hat-trick saves Real Madrid in Champions League, Villa go top

By www.thehindu.com
Published On :: Wed, 23 Oct 2024 06:19:49 +0530

Real Madrid beats Borussia Dortmund 5-2 with Vinicius Junior’s hat-trick, while Aston Villa stays unbeaten in Champions League


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Champions League: Raphinha scores hat-trick as Barcelona romps Bayern; Liverpool, City notch up wins

By www.thehindu.com
Published On :: Thu, 24 Oct 2024 06:00:00 +0530

Liverpool edged Leipzig 1-0 with a goal from Darwin Nunez; Manchester City routed Sparta Prague 5-0 with Erling Haaland scoring twice.


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Olmo fires Barca past Espanyol as Simeone's son strikes for Atletico

By www.thehindu.com
Published On :: Mon, 04 Nov 2024 03:47:00 +0530

Barcelona have started life under Flick in sensational form and after beating Bayern Munich and Real Madrid last week, earned their 10th win in 11 La Liga matches.


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Jewellery retailers fear a lacklustre Akshaya Tritiya this year due to soaring gold prices

By www.thehindubusinessline.com
Published On :: Fri, 12 Apr 2024 20:55:10 +0530

Akshaya Tritiya, which falls on May 10 this year, is considered auspicious to buy gold


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  • Gold & Silver
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Dip in gold prices ahead of Akshaya Tritiya to boost demand

By www.thehindubusinessline.com
Published On :: Tue, 23 Apr 2024 19:10:45 +0530

Lingering global uncertainty may boost prices again


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  • Gold & Silver
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Akshaya Tritiya: Planning to buy gold? Here are things to remember

By www.thehindubusinessline.com
Published On :: Fri, 10 May 2024 10:56:48 +0530

Gold has proven to be a safe haven with increasing returns over the years


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  • Gold & Silver
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Despite high prices, gold demand picks up this Akshaya Tritiya

By www.thehindubusinessline.com
Published On :: Fri, 10 May 2024 20:33:55 +0530

The high price for gold has also given a boost to diamond jewellers as customers look for alternatives


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  • Gold & Silver
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RBI’s gold holding increases by 27.46 metric tonnes in FY24, reaching 822.10 metric tonnes mark

By www.thehindubusinessline.com
Published On :: Tue, 14 May 2024 08:07:57 +0530

The report noted that the ratio of short-term debt to reserves has decreased, and foreign exchange reserves covering imports have increased to 11 months


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  • Gold & Silver
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India’s import of gold, silver from UAE rises 210% to $10.7 billion in 2023-24: GTRI

By www.thehindubusinessline.com
Published On :: Mon, 17 Jun 2024 20:23:13 +0530

`Concessional customs duty under the India-UAE CEPA must be revised’


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As prices soften, festival period triggers buying interest in gold jewellery

By www.thehindubusinessline.com
Published On :: Mon, 09 Sep 2024 19:12:05 +0530

Sales up 20% during Ganesh Chathurthi, wedding demand could buoy demand for the precious metal further


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  • Gold & Silver
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Gold steadies after Iran strikes spark surge of haven buying

By www.thehindubusinessline.com
Published On :: Wed, 02 Oct 2024 09:24:12 +0530

Gold has rallied nearly 30 per cent this year, hitting a series of record highs.


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  • Gold & Silver
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Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9]

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02698E, Paper
Zhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua Zhang
Non-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...
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Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02496F, Paper
Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena Shubina
Octahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...
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Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02303J, Paper
Tao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan Wang
Ni/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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Syntheses, structures and characterization of noncentrosymmetric MZnPO4 (M = K, NH4)

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02530J, Paper
Jiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai An
Two phosphates, KZnPO4 and NH4ZnPO4, were successfully synthesized, and both structures show a three-way skeleton of isolated PO4 and ZnO4 tetrahedra. And NCS KZnPO4 and NH4ZnPO4 can exhibit SHG responses of 0.4 × KDP and 1 × KDP.
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Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Price pooling mantra: Wake up to expensive electricity

By www.thehindubusinessline.com
Published On :: Tue, 02 Apr 2013 13:15:05 +0530


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  • Siddhartha P Saikia
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A trip to Panchmarhi

By www.thehindu.com
Published On :: Sun, 25 Aug 2024 02:54:00 +0530

A college tour to the picturesque destination breaks the ice


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Modelling the thermoelectric effect

By physicsworld.com
Published On :: 2018-01-18T14:33:00Z

Register now: 28 February 2018
A webinar sponsored by COMSOL


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Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 04:25:28 +0530

After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy


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Tribals seek internal reservation, FRA implementation

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 22:54:32 +0530

A memorandum will be submitted to Chief Minister Siddaramaiah during his visit to H.D. Kote on Tuesday


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Farmers in Yadgir district sow groundnut as major crop for rabi season

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 19:50:22 +0530


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Vinicius 'tricks' Real Madrid to win!

By www.rediff.com
Published On ::

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.


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A parade of patriotism

By www.thehindubusinessline.com
Published On :: Sun, 02 Feb 2014 13:21:29 +0530


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  • T E Raja Simhan
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Once Samson starts striking, it’s hard to stop him: South Africa captain Markram on whirlwind century

By www.thehindu.com
Published On :: Sat, 09 Nov 2024 08:22:42 +0530

“Plans to negate him and better plans will help us going forward,” said Aiden Markram


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Vinícius nets hat trick in win as three Real Madrid players go down injured; Militão tears ACL

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 07:46:05 +0530

Vinícius Júnior shines with hat trick in Real Madrid win overshadowed by Militão ACL injury in La Liga.


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Women’s Asian Champions Trophy: Sangita’s double strike hands India comfortable 4-0 win over Malaysia 

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 18:45:02 +0530

India scored through Sangita Kumari (8th, 55th minutes), Preeti Dubey (43rd) and Udita (44th).


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Hat-trick hero Ferguson says 'insane' T20 win massive for NZ against SL

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 05:49:13 +0530

New Zealand were only able to put a modest score on the board as Sri Lanka spinner Wanindu Hasaranga took 4-17 despite being clearly hampered by injury


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A novel graphene oxide–microalgae hybrid material for the removal of pentavalent arsenic from natural water and industrial wastewater

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, 10,2796-2808
DOI: 10.1039/D4EW00308J, Paper
Eliana S. Lemos, Evelyn M. Valdés Rodríguez, Adrián Bonilla Petriciolet, Andrea M. Ray, Leticia B. Escudero
The adsorption process using bionanomaterials based on graphene oxide and green microalgae for the removal of arsenic from complex samples of natural water and industrial wastewater.
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Investigation of the effect of Al2O3/water nanofluid on the performance of a thermoelectric cooler to harvest water from humid air

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, 10,3035-3044
DOI: 10.1039/D4EW00367E, Paper
Emad Nazari, Mohammad Hassan Vakili, Mahdi Reiszadeh
One of the sources of fresh water, especially in desert and water-scarce areas is atmospheric air.
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A comprehensive study on the physicochemical characteristics of faecal sludge from septic tank and single pit latrine facilities in a typical semi-urban Indian town: a case study of Rajasthan, India

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, 10,2906-2928
DOI: 10.1039/D4EW00127C, Paper
Open Access
Harishvar Jothinathan, Ajit Pratap Singh
Faecal sludge (FS) samples were analysed to assess their characteristics. FS has high chemical oxygen demand, ranging from 4406 to 160 000 mg l−1, influenced by sludge age, sanitation type, and inflow/outflow to onsite sanitation contaminants.
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Investigating water quality and preservation strategies in Abuja's distribution system: a Nigerian case study

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, 10,2869-2881
DOI: 10.1039/D4EW00613E, Paper
Begmyrat Kulmedov, Lucy Achobe Akaiku, Onyebuchi Nwabueze Mogbo
The study explores how treated water quality degrades during distribution due to pipe material release and biofilm formation, with a focus on intermittent supply systems and the decreasing effectiveness of disinfectants.
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A Logic-Based Resilience Metric for Water Resource Recovery Facilities

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4EW00649F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anna Stefania Laino, Ben Wooding, Sadegh Soudjani, Russell James Davenport
This study develops quantifiable metrics to describe the resilience of Water Resource Recovery Facilities (WRRFs) to extreme and exceptional shock and stress events, such as those posed by long-term challenges...
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Sludge-derived novel Fe3O4–MgO@C composites for tetracycline abatement from wastewater using sustainable bio-electro-Fenton and nutrient recovery with co-precipitation: a waste-to-resource strategy

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00684D, Paper
Azhan Ahmad, Monali Priyadarshini, Shraddha Yadav, Makarand M. Ghangrekar, Rao Y. Surampalli
Developing efficient Fenton catalysts for the remediation of emerging pollutants is one of the challenges for researchers.
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