catalyst

Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

MOFs based on 1D structural sub-domains with Brønsted acid and redox active sites as effective bi-functional catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00235F, Paper
José María Moreno, Alexandra Velty, Urbano Díaz
Low-dimensional MOF-type catalysts containing Brønsted acid and redox active sites, based on assembled 1D organic–inorganic nanoribbons, for one-pot two-step reactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

From cellulose to 1,2,4-benzenetriol via catalytic degradation over a wood-based activated carbon catalyst

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00424C, Paper
Qiong Wu, Baozheng Zhao, Shiwei Liu, Shitao Yu, Lang Huang, Arthur J. Ragauskas
1,2,4-Benzenetriol was obtained from cellulose hydrothermal degradation using phosphoric acid-activated wood-based AC as the catalyst.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Oxygen vacancy-rich amorphous porous NiFe(OH)x derived from Ni(OH)x/Prussian blue as highly efficient oxygen evolution electrocatalysts

Nanoscale, 2020, 12,9557-9568
DOI: 10.1039/D0NR00607F, Paper
Shuang Wang, Xingbo Ge, Chao Lv, Cun Hu, Hongtai Guan, Jing Wu, Zhengnan Wang, Xianhui Yang, Yan Shi, Jiangfeng Song, Zhi Zhang, Akira Watanabe, Jinguang Cai
Oxygen vacancy-rich amorphous porous NiFe(OH)x on carbon paper is prepared through a two-step electrochemical depostion of Prussian blue nanocrystal layer and Ni(OH)x layer followed by an alkaline etching process for efficient OER catalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Designing transition-metal-boride-based electrocatalysts for applications in electrochemical water splitting

Nanoscale, 2020, 12,9327-9351
DOI: 10.1039/D0NR01279C, Review Article
Yuanyuan Jiang, Yizhong Lu
Recent progresses made in transition metal boride (TMB)-based electrocatalysts for electrochemical water splitting are summarized.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

NiSe2-anchored N, S-doped graphene/Ni foam as a free-standing bifunctional electrocatalyst for efficient water splitting

Nanoscale, 2020, 12,9866-9872
DOI: 10.1039/D0NR00879F, Paper
Jinhao Zhou, Zegao Wang, Dongxu Yang, Fei Qi, Xin Hao, Wanli Zhang, Yuanfu Chen
A strategy to synthesize free-standing electrocatalysts coupling active nanostructured NiSe2 with conductive S, N-doped 3D graphene foam (3DSNG) is presented and the hybrid delivers superior performances for the HER, OER and overall water splitting.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Efficient polyalcohol oxidation electrocatalysts enabled by PtM (M = Fe, Co, and Ni) nanocubes surrounded by (200) crystal facets

Nanoscale, 2020, 12,9842-9848
DOI: 10.1039/D0NR00163E, Paper
Tongxin Song, Fei Gao, Yangping Zhang, Chunyan Chen, Cheng Wang, Shujin Li, Hongyuan Shang, Yukou Du
The (200)-enclosed Pt4M nanocubes (NCs) exhibit ascendant catalytic property towards GOR and EGOR due to the introduction of transition metals.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

MnV2O6/Graphene Nanocomposite as an Efficient Electrocatalyst for the Oxygen Evolution Reaction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02325F, Communication
Kyeong-Ho Kim, Yun-Hyuk Choi, Seong-Hyeon Hong
MnV2O6/graphene nanocomposite was fabricated through hydrothermal synthesis and high energy mechanical milling as an electrocatalyst for oxygen evolution reaction (OER). MnV2O6/graphene (20 wt%) nanocomposite deposited on carbon fiber paper (CFP)...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Efforts to promote tourism as a catalyst for urban redevelopment in Florida




catalyst

Supercritical carbon dioxide aided preparation of nickel oxide/alumina aerogel catalyst




catalyst

Copper and iron complexes of linear and crosslinked polymers as catalysts for phosphoester hydrolysis and oxidative transformation of phenolic and catecholic substrates




catalyst

Urban fabric as a catalyst for architectural awareness




catalyst

Optimization of a ball-milled photocatalyst for wastewater treatment through use of an orthogonal-array experimental design




catalyst

Effect of catalyst preparation conditions on the performance of eggshell cobalt/sio2 catalysts for fischer-tropsch synthesis




catalyst

Elementary teachers' perceptions of technology as a catalyst for constructivist practices in the classroom :




catalyst

[ASAP] RuPhos Pd Precatalyst and MIDA Boronate as an Effective Combination for the Precision Synthesis of Poly(3-hexylthiophene): Systematic Investigation of the Effects of Boronates, Halides, and Ligands

Macromolecules
DOI: 10.1021/acs.macromol.0c00137




catalyst

[ASAP] Catalyst-Free Multicomponent Tandem Polymerizations of Alkyne and Amines toward Nontraditional Intrinsic Luminescent Poly(aminomaleimide)s

Macromolecules
DOI: 10.1021/acs.macromol.0c00525




catalyst

Artificial metalloenzymes : modified proteins as tuneable transition metal catalysts and their application in oxidative lignin degradation / Megan V. Doble.

St Andrews, 2019.




catalyst

[ASAP] Broad-Spectral-Response Photocatalysts for CO<sub>2</sub> Reduction

ACS Central Science
DOI: 10.1021/acscentsci.0c00325




catalyst

[ASAP] Poisoning-Resistant NO<sub><italic toggle="yes">x</italic></sub> Reduction in the Presence of Alkaline and Heavy Metals over H-SAPO-34-Supported Ce-Promoted Cu-Based Catalysts

Environmental Science & Technology
DOI: 10.1021/acs.est.0c00100




catalyst

[ASAP] Integrating Green Chemistry into Teaching Laboratories: Aqueous Suzuki–Miyaura Cross-Coupling Reaction Using a Recyclable Fluorous Precatalyst

Journal of Chemical Education
DOI: 10.1021/acs.jchemed.0c00072




catalyst

[ASAP] Development of a Large-Enrollment Course-Based Research Experience in an Undergraduate Organic Chemistry Laboratory: Structure–Function Relationships in Pyrylium Photoredox Catalysts

Journal of Chemical Education
DOI: 10.1021/acs.jchemed.9b00786




catalyst

[ASAP] Synthesis and Use of a Nickel Oxidation Catalyst Using Glove Box Methods

Journal of Chemical Education
DOI: 10.1021/acs.jchemed.0c00004




catalyst

Simple guidelines could make designing catalysts for electrochemical reactions easy

Theoretical model uses readily available data to predict catalysts for tackling energy challenges




catalyst

[ASAP] Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere

Organometallics
DOI: 10.1021/acs.organomet.9b00815




catalyst

[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




catalyst

[ASAP] A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst

Organometallics
DOI: 10.1021/acs.organomet.0c00193




catalyst

[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




catalyst

Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




catalyst

Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
The content of this RSS Feed (c) The Royal Society of Chemistry