catalyst

Photocatalyst converts fatty acids to diesel and jet-fuel molecules selectively

By feedproxy.google.com
Published On :: 07 Mar 2020 11:27:30 +0000

Method provides petroleum-free way to turn industrial biowaste into valuable commodity


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Eliminating catalyst defects boosts activity and extends lifetime

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Published On :: 26 Mar 2020 17:19:47 +0000

Nearly perfect, long-lasting crystalline catalyst turns CO<sub>2</sub> into valuable products


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A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity

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Energy Environ. Sci., 2020, 13,1231-1239
DOI: 10.1039/C9EE03492G, Paper
Mi Yoo, Young-Sang Yu, Hyunwoo Ha, Siwon Lee, Jin-Seok Choi, Sunyoung Oh, Eunji Kang, Hyuk Choi, Hyesung An, Kug-Seung Lee, Jeong Young Park, Richard Celestre, Matthew A. Marcus, Kasra Nowrouzi, Doug Taube, David A. Shapiro, WooChul Jung, Chunjoong Kim, Hyun You Kim
Catalytic supremacy of Pt-single atoms achieved by CeOx–TiO2 interfaces.
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From metal–organic frameworks to single/dual-atom and cluster metal catalysts for energy applications

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Energy Environ. Sci., 2020, Advance Article
DOI: 10.1039/C9EE04040D, Review Article
Chun-Chao Hou, Hao-Fan Wang, Caixia Li, Qiang Xu
Single/dual-atom and cluster metal catalysts have emerged as a new frontier in catalysis. This review highlights recent advances and provides a state-of-the-art understanding of MOF-based synthesis strategies and their prospective applications.
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Side-chain tuning in conjugated polymer photocatalysts for improved hydrogen production from water

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Energy Environ. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0EE01213K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Duncan J Woods, Sam Hillman, Drew Pearce, Liam Wilbraham, Lucas Flagg, Warren Duffy, Iain Mcculloch, James Durrant, Anne Guilbert, Martijn Zwijnenburg, Reiner Sebastian Sprick, Jenny Nelson, Andrew Cooper
Structure-property-activity relationships in solution processable polymer photocatalysts for hydrogen production from water were probed by varying the chemical structure of both the polymer side-chains and the polymer backbone. In both...
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[ASAP] Preparation of Integrated CuO/ZnO/OS Nanocatalysts by Using Acid-Etched Oyster Shells as a Support for CO<sub>2</sub> Hydrogenation

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Published On :: Tue, 28 Apr 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01712


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[ASAP] Production of a Renewable Functionalized 1,3-Diene from Furfural–Acetone Adduct over Supported Heteropolyacid Catalysts

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Published On :: Wed, 29 Apr 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01890


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[ASAP] HZ-ZrP Catalysts with Adjustable Ratio of Brønsted and Lewis Acids for the One-Pot Value-Added Conversion of Biomass-Derived Furfural

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Published On :: Wed, 29 Apr 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01259


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[ASAP] Design and Synthesis of Highly Performing Bifunctional Ni-NiO-MoNi Hybrid Catalysts for Enhanced Urea Oxidation and Hydrogen Evolution Reactions

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Published On :: Thu, 30 Apr 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01637


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[ASAP] Functionalized Biochar with Superacidity and Hydrophobicity as a Highly Efficient Catalyst in the Synthesis of Renewable High-Density Fuels

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Published On :: Fri, 01 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.9b07367


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[ASAP] Novel MOF-Derived Nickel Nitride as High-Performance Bifunctional Electrocatalysts for Hydrogen Evolution and Urea Oxidation

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Published On :: Tue, 05 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01450


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[ASAP] Fe-Doped Ni–Co Phosphide Nanoplates with Planar Defects as an Efficient Bifunctional Electrocatalyst for Overall Water Splitting

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Published On :: Tue, 05 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01467


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[ASAP] Two-Dimensional Metal Hexahydroxybenzene Frameworks as Promising Electrocatalysts for an Oxygen Reduction Reaction

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Published On :: Tue, 05 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01908


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[ASAP] In situ Grown Ni phosphate@Ni<sub>12</sub>P<sub>5</sub> Nanorod Arrays as a Unique Core–Shell Architecture: Competitive Bifunctional Electrocatalysts for Urea Electrolysis at Large Current Densities

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Published On :: Thu, 07 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01814


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[ASAP] Development of Au and 1D Hydroxyapatite Nanohybrids Supported on 2D Boron Nitride Sheets as Highly Efficient Catalysts for Dehydrogenating Glycerol to Lactic Acid

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Published On :: Fri, 08 May 2020 04:00:00 GMT

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.9b06997


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Biocatalysts and enzyme technology / Klaus Buchholz, Volker Kasche and Uwe T. Bornscheuer

By prospero.murdoch.edu.au
Published On ::

Buchholz, Klaus, 1941-


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Minimization of Pt-electrocatalyst deactivation in CO2 reduction using a polymer electrolyte cell

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2020, Advance Article
DOI: 10.1039/D0RE00083C, Paper
Shofu Matsuda, Shigehisa Tamura, Shota Yamanaka, Yuuki Niitsuma, Yoshitsugu Sone, Minoru Umeda
An effective poisoning elimination method for CH4 production from CO2 reduction using a Pt/C electrocatalyst in a polymer electrolyte cell has been established by controlling the Pt–CO/Pt–H ratio and re-arranging the surface adsorption.
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Hydrogenolysis of lignin-derived aryl ethers to monomers over a MOF-derived Ni/N–C catalyst

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React. Chem. Eng., 2020, 5,886-895
DOI: 10.1039/D0RE00040J, Paper
Xing-Gang Si, Yun-Peng Zhao, Qing-Lu Song, Jing-Pei Cao, Rui-Yu Wang, Xian-Yong Wei
A highly efficient Ni/N–C catalyst was synthesized by facile pyrolysis of a Ni-MOF, and its catalytic hydrogenolysis performance towards C–O bonds in lignin was evaluated in detail using diphenyl ether (DPE) as a model compound.
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NH3-SCR of NO with novel active, supported vanadium-containing Keggin-type heteropolyacid catalysts

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React. Chem. Eng., 2020, 5,935-948
DOI: 10.1039/D0RE00033G, Paper
Anna Bukowski, Leonhard Schill, David Nielsen, Susanne Mossin, Anders Riisager, Jakob Albert
Supported vanadium-substituted Keggin polyoxometalates (POMs) were applied as catalysts for the selective catalytic reduction of NO using NH3 as reductant (NH3-SCR).
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Catalyst Acquisition by Data Science (CADS): a web-based catalyst informatics platform for discovering catalysts

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React. Chem. Eng., 2020, 5,903-911
DOI: 10.1039/D0RE00098A, Paper
Jun Fujima, Yuzuru Tanaka, Itsuki Miyazato, Lauren Takahashi, Keisuke Takahashi
An innovative web-based integrated catalyst informatics platform, Catalyst Acquisition by Data Science (CADS), is developed for use towards the discovery and design of catalysts.
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[ASAP] Hydrothermal Stability of High-Surface-Area a-Al<sub>2</sub>O<sub>3</sub> and Its Use as a Support for Hydrothermally Stable Fischer–Tropsch Synthesis Catalysts

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Published On :: Fri, 08 May 2020 04:00:00 GMT

Chemistry of Materials
DOI: 10.1021/acs.chemmater.0c01587


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[ASAP] Continuous Flow Photo-oxidations Using Supported Photocatalysts on Silica

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Published On :: Thu, 16 Jan 2020 05:00:00 GMT

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00420


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[ASAP] Evaluation of Sponge Metal Catalysts in a Trickle Bed Reactor for the Continuous Hydrogenation of an Aliphatic Nitro Intermediate

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Published On :: Fri, 24 Jan 2020 05:00:00 GMT

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00447


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[ASAP] Copper(I) Diphosphine Bifluoride Complexes as Efficient Preactivated Catalysts for Nucleophilic Addition on Unsaturated Functional Groups

By feedproxy.google.com
Published On :: Fri, 24 Jan 2020 05:00:00 GMT

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00443


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[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

By feedproxy.google.com
Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054


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[ASAP] Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

By feedproxy.google.com
Published On :: Fri, 08 May 2020 04:00:00 GMT

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00511


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Enhancing aqueous pollutants photodegradation via Fermi level matched Z-scheme BiOI/Pt/g-C3N4 photocatalyst: unobstructed photogenerated charge behavior and degradation pathway exploration

By feeds.rsc.org
Published On ::

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00429D, Paper
Jingjing Jiang, Yueyu Song, Xingyue Wang, Tianren Li, Mingyu Li, Yanhong Lin, Tengfeng Xie, Shuangshi Dong
Z-scheme photocatalytic system was widely requisited to solve water pollution problem. However, the degradation mechanism for pollutants with Z-scheme photocatalyst has been ambiguous. In this work, an efficient all solid-state...
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Hydrodeoxygenation of anisole to benzene over an Fe2P catalyst by a direct deoxygenation pathway

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00046A, Paper
Shuyuan Wang, Dan Xu, Yunlei Chen, Song Zhou, Di Zhu, Xiaodong Wen, Yong Yang, Yongwang Li
Fe2P catalyst was highly selective for the cleavage of C–O bond of anisole via direct deoxygenation pathway.
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Water-soluble NHC-stabilized platinum nanoparticles as recoverable catalysts for hydrogenation in water

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00481B, Paper
Andrea M. Ruiz-Varilla, Edwin A. Baquero, Bruno Chaudret, Ernesto de Jesús, Camino Gonzalez-Arellano, Juan C. Flores
Aromatic compounds have been hydrogenated in water using recoverable catalysts based on water-soluble platinum nanoparticles capped with NHC ligands.
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Molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) – metal and surface dependent structure and stability

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00504E, Paper
Fan Wang, Teng Li, Yun Shi, Haijun Jiao
The surface and metal-dependent morphologies and energies of molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) have been systematically investigated on the basis of periodic density functional theory computations.
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Deactivation and regeneration of carbon supported Pt and Ru catalysts in aqueous phase hydrogenation of 2-pentanone

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00163E, Paper
Jiajie Huo, Hien N. Pham, Yan Cheng, Hsi-Hsin Lin, Luke T. Roling, Abhaya K. Datye, Brent H. Shanks
Aqueous phase conversion of biomass-derived molecules requires development of catalysts and operating strategies that create viable operation for extended performance as necessitated for industrial applications.
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Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

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Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
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Microemulsion solventing-out co-precipitation strategy for fabricating highly active Cu–ZnO/Al2O3 dual site catalysts for reverse water gas shift

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Catal. Sci. Technol., 2020, 10,2343-2352
DOI: 10.1039/C9CY02608H, Paper
Ziheng Zhen, Wenxiang Tang, Wei (Willy) Chu, Tao Zhang, Li Lv, Shengwei Tang
A new strategy for the preparation of dual site catalysts is introduced, which combines microemulsion technology and anti-solvent extraction technology.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

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Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

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Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

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Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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980 nm NIR light driven overall water splitting over a combined CdS–RGO–NaYF4–Yb3+/Er3+ photocatalyst

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Catal. Sci. Technol., 2020, 10,2389-2397
DOI: 10.1039/D0CY00256A, Paper
Wei Gao, Yuqi Wu, Gongxuan Lu
Infrared light (NIR) accounts for more than 50% of the energy donated by the Sun to the Earth, but most of this type of energy is not utilized in photocatalytic reactions.
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Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

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Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

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Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes

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Catal. Sci. Technol., 2020, 10,2583-2592
DOI: 10.1039/D0CY00471E, Paper
Chandran Rajendran, Govindaswamy Satishkumar, Charlotte Lang, Eric M. Gaigneaux
AlSBA-15 catalysts possessing Brønsted acid and Lewis acid–base bifunctionalities catalyze the direct arylation of benzyl alcohols to diarylmethanes with an 85% product yield through C–O bond activation.
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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

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Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

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Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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Carbon deposits during catalytic combustion of toluene on Pd–Pt-based catalysts

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Catal. Sci. Technol., 2020, 10,2452-2461
DOI: 10.1039/D0CY00101E, Paper
Yu Yang, Gang Wang, Peng Zheng, Falu Dang, Jiannian Han
Carbon is easily deposited on a catalyst during the catalytic combustion of toluene, resulting in catalyst deactivation.
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Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

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Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
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Aerobic oxidation of 1,6-hexanediol to adipic acid over Au-based catalysts: the role of basic supports

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Catal. Sci. Technol., 2020, 10,2644-2651
DOI: 10.1039/D0CY00183J, Paper
Open Access
Noemi Capece, Achraf Sadier, Camila Palombo Ferraz, Joëlle Thuriot-Roukos, Mariusz Pietrowski, Michał Zieliński, Sébastien Paul, Fabrizio Cavani, Robert Wojcieszak
1,6-Hexanediol is a relevant building blocks that could be obtained from biomass and transformed under base free conditions into adipic acid used for polymer synthesis.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

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Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00188K, Paper
Margarida M. Antunes, Auguste Fernandes, Diogo Falcão, Martyn Pillinger, Filipa Ribeiro, Anabela A. Valente
Eco-friendly solid bases possessing hierarchical MFI structure for D-glucose isomerization to D-fructose. Optimizing catalyst synthesis and composition for enhanced stability.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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