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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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Flexible multifunctional MXene@Ag nanowires/cotton fabric inspired by transport of nutrients by roots for electromagnetic shielding, infrared stealth, Joule/solar heating and flame retardancy

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06712F, Paper
Jiatong Yan, Meimei Chen, Rui Tan, Chuanxi Lin, Shan Jiang, Weijie Wang, Songyue Pan, Hongyan Xiao, Erhui Ren, Ronghui Guo
With the rapid development of 5G intelligent detection technology, electromagnetic shielding/infrared stealth fabrics with Joule/solar heating performance can meet the needs of wearable electronic devices for multi-application scenarios.
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Mike Tomlin on run of AFC North games: I don't care when we play teams

The Steelers will make a little NFL history this weekend.




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DeMeco Ryans: No setback for Nico Collins, game-time decision to sit him Sunday night

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How Jameis Winston's arm could boost fantasy teams in Week 11

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Joe Mixon primed for a huge game vs. Cowboys

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NFL Commissioner Roger Goodell all but said this week that the league will play a game in Berlin next season.




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Modern Gamer Chooses Safe Casino

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Where are the Legal for Playing Joo Casino Games?

  Contents Financial Transaction Times and Methods at Joo Casino Developers of gambling sites with the greatest payout that specialise in casino Where can I discover reputable online casinos to play at? The Number One Guide to the Best Online Casinos Available to Australian Gamblers You needn’t look much farther than Joo Casino for that, […]




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Players Review Box24 Casino Play Games Online

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99 Finest Rated Free Sex Video Games Play The Highest Adult Video Games

So you simply select the class you want to take a look at, go through critiques I’ve carried out for you, resolve what platform fits your wants the most effective, and go on taking half in nude video games online! No want to search the Internet for i want a sexting partner hours within the […]




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Arte, Mujer y Memoria: Online Exhibition Museum of Latin American Art

For example, the comparison with the OECD appears limited by the fact that the Chilean indicator focusses on all employed individuals aged 15 years old, or above, whereas the OECD indicator covers the entire population between years. This caveat withstanding, the extent of the gap in Chile is wider than the OECD average. At nine […]




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Russian Girls Vs American Girls: Exploring Cultural Variations

Content Romance Travel To Laxa, sweden Loveforheart ~ Take Motion And Find Your Soulmate! Your search may take a few months, so calculate mail order bride pricingon courting platforms within 6 months on common. As for the language barrier, it’s going to hardly be a problem. As we’ve mentioned before, plenty of Japanese women for […]




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Wall street game Tips For Newcomers

The stock market is a fantastic place to devote your finances, especially above the long term. However there are a number of important things to remember before jumping in. These tips can help you avoid flaws that can run you big and boost your odds of a successful voyage. One of the most prevalent reasons […]




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On-line Technologies and Games Mainly because an Educational Tool

Online systems and video games more helpful hints often get a bad hiphop from father and mother and educators who make an effort to pull kids away from the screens and encourage them to carry out more educational or much healthier activities. Yet , what if we embraced the technology and allowed children to play […]




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Devotional platform AppsForBharat raises $18 mn led by Fundamentum

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Silver-incorporated NiCo metal–organic frameworks with controlled morphology for enhanced cycling in flexible supercapacitor applications

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper
Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA15-MOF/NF was 1317 F g−1, which was significantly higher compared to the NCA0-MOF/NF. After 15 000 charge–discharge cycles, the NCA15-MOF/NF retained 89% of its initial specific capacitance.
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Application of metal organic frameworks (MOFs) and their derivatives in the cathode materials of aqueous zinc-ion batteries

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article
Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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A metal–organic framework enhanced single network organohydrogel with superior low-temperature adaptability and UV-blocking capability towards human-motion sensing

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper
Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH2 nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Microfluidic synthesis of monodispersed sharp emitting perovskite CsPbBr3 quantum dots via multidimensional parameterization

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04104F, Paper
Yunhao Ning, Shuo Guan, Chuantong Cheng, Bao Zhang, Bingyu Qin, Beiju Huang
A microfluidic chip is employed for continuous synthesis of CsPbBr3 perovskite quantum dots, which feature tunable emission across various dimensions and wavelengths, and effects of multidimensional parameters on their properties are investigated.
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Promoting productivity in Latin America



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Fundamentals of the recycling of spent lithium-ion batteries

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00362D, Review Article
Pengwei Li, Shaohua Luo, Yicheng Lin, Jiefeng Xiao, Xiaoning Xia, Xin Liu, Li Wang, Xiangming He
Fundamentals of battery recycling play a vital role in addressing the challenges posed by spent lithium-ion batteries by providing the theoretical foundation and technical tools necessary for the efficient recycling of LIBs.
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A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00521J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu, Jianchun Jiang
Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement.
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Electrodegradation of nitrogenous pollutants in sewage: from reaction fundamentals to energy valorization applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00517A, Review Article
Ming-Lei Sun, Hao-Yu Wang, Yi Feng, Jin-Tao Ren, Lei Wang, Zhong-Yong Yuan
This review provides a comprehensive insight into the electrodegradation processes of nitrogenous pollutants in sewage, highlighting the reaction mechanisms, theoretical descriptors, catalyst design, and energy valorization strategies.
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Metal–phenolic network composites: from fundamentals to applications

Chem. Soc. Rev., 2024, 53,10800-10826
DOI: 10.1039/D3CS00273J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhixing Lin, Hai Liu, Joseph J. Richardson, Wanjun Xu, Jingqu Chen, Jiajing Zhou, Frank Caruso
This review provides a guideline for the rational design of metal–phenolic network (MPN) composites—which are fabricated from MPN and one or more functional components (e.g., drugs, proteins)—for various applications across diverse disciplines.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Personalization Pyramid: A Framework for Designing with User Data

As a UX professional in today’s data-driven landscape, it’s increasingly likely that you’ve been asked to design a personalized digital experience, whether it’s a public website, user portal, or native application. Yet while there continues to be no shortage of marketing hype around personalization platforms, we still have very few standardized approaches for implementing personalized UX.

That’s where we come in. After completing dozens of personalization projects over the past few years, we gave ourselves a goal: could you create a holistic personalization framework specifically for UX practitioners? The Personalization Pyramid is a designer-centric model for standing up human-centered personalization programs, spanning data, segmentation, content delivery, and overall goals. By using this approach, you will be able to understand the core components of a contemporary, UX-driven personalization program (or at the very least know enough to get started). 

Growing tools for personalization: According to a Dynamic Yield survey, 39% of respondents felt support is available on-demand when a business case is made for it (up 15% from 2020).

Source: “The State of Personalization Maturity – Q4 2021” Dynamic Yield conducted its annual maturity survey across roles and sectors in the Americas (AMER), Europe and the Middle East (EMEA), and the Asia-Pacific (APAC) regions. This marks the fourth consecutive year publishing our research, which includes more than 450 responses from individuals in the C-Suite, Marketing, Merchandising, CX, Product, and IT.

Getting Started

For the sake of this article, we’ll assume you’re already familiar with the basics of digital personalization. A good overview can be found here: Website Personalization Planning. While UX projects in this area can take on many different forms, they often stem from similar starting points.      

Common scenarios for starting a personalization project:

  • Your organization or client purchased a content management system (CMS) or marketing automation platform (MAP) or related technology that supports personalization
  • The CMO, CDO, or CIO has identified personalization as a goal
  • Customer data is disjointed or ambiguous
  • You are running some isolated targeting campaigns or A/B testing
  • Stakeholders disagree on personalization approach
  • Mandate of customer privacy rules (e.g. GDPR) requires revisiting existing user targeting practices
Workshopping personalization at a conference.

Regardless of where you begin, a successful personalization program will require the same core building blocks. We’ve captured these as the “levels” on the pyramid. Whether you are a UX designer, researcher, or strategist, understanding the core components can help make your contribution successful.  

From the ground up: Soup-to-nuts personalization, without going nuts.

From top to bottom, the levels include:

  1. North Star: What larger strategic objective is driving the personalization program? 
  2. Goals: What are the specific, measurable outcomes of the program? 
  3. Touchpoints: Where will the personalized experience be served?
  4. Contexts and Campaigns: What personalization content will the user see?
  5. User Segments: What constitutes a unique, usable audience? 
  6. Actionable Data: What reliable and authoritative data is captured by our technical platform to drive personalization?  
  7. Raw Data: What wider set of data is conceivably available (already in our setting) allowing you to personalize?

We’ll go through each of these levels in turn. To help make this actionable, we created an accompanying deck of cards to illustrate specific examples from each level. We’ve found them helpful in personalization brainstorming sessions, and will include examples for you here.

Personalization pack: Deck of cards to help kickstart your personalization brainstorming.

Starting at the Top

The components of the pyramid are as follows:

North Star

A north star is what you are aiming for overall with your personalization program (big or small). The North Star defines the (one) overall mission of the personalization program. What do you wish to accomplish? North Stars cast a shadow. The bigger the star, the bigger the shadow. Example of North Starts might include: 

  1. Function: Personalize based on basic user inputs. Examples: “Raw” notifications, basic search results, system user settings and configuration options, general customization, basic optimizations
  2. Feature: Self-contained personalization componentry. Examples: “Cooked” notifications, advanced optimizations (geolocation), basic dynamic messaging, customized modules, automations, recommenders
  3. Experience: Personalized user experiences across multiple interactions and user flows. Examples: Email campaigns, landing pages, advanced messaging (i.e. C2C chat) or conversational interfaces, larger user flows and content-intensive optimizations (localization).
  4. Product: Highly differentiating personalized product experiences. Examples: Standalone, branded experiences with personalization at their core, like the “algotorial” playlists by Spotify such as Discover Weekly.

Goals

As in any good UX design, personalization can help accelerate designing with customer intentions. Goals are the tactical and measurable metrics that will prove the overall program is successful. A good place to start is with your current analytics and measurement program and metrics you can benchmark against. In some cases, new goals may be appropriate. The key thing to remember is that personalization itself is not a goal, rather it is a means to an end. Common goals include:

  • Conversion
  • Time on task
  • Net promoter score (NPS)
  • Customer satisfaction 

Touchpoints

Touchpoints are where the personalization happens. As a UX designer, this will be one of your largest areas of responsibility. The touchpoints available to you will depend on how your personalization and associated technology capabilities are instrumented, and should be rooted in improving a user’s experience at a particular point in the journey. Touchpoints can be multi-device (mobile, in-store, website) but also more granular (web banner, web pop-up etc.). Here are some examples:

Channel-level Touchpoints

  • Email: Role
  • Email: Time of open
  • In-store display (JSON endpoint)
  • Native app
  • Search

Wireframe-level Touchpoints

  • Web overlay
  • Web alert bar
  • Web banner
  • Web content block
  • Web menu

If you’re designing for web interfaces, for example, you will likely need to include personalized “zones” in your wireframes. The content for these can be presented programmatically in touchpoints based on our next step, contexts and campaigns.

Contexts and Campaigns

Once you’ve outlined some touchpoints, you can consider the actual personalized content a user will receive. Many personalization tools will refer to these as “campaigns” (so, for example, a campaign on a web banner for new visitors to the website). These will programmatically be shown at certain touchpoints to certain user segments, as defined by user data. At this stage, we find it helpful to consider two separate models: a context model and a content model. The context helps you consider the level of engagement of the user at the personalization moment, for example a user casually browsing information vs. doing a deep-dive. Think of it in terms of information retrieval behaviors. The content model can then help you determine what type of personalization to serve based on the context (for example, an “Enrich” campaign that shows related articles may be a suitable supplement to extant content).

Personalization Context Model:

  1. Browse
  2. Skim
  3. Nudge
  4. Feast

Personalization Content Model:

  1. Alert
  2. Make Easier
  3. Cross-Sell
  4. Enrich

We’ve written extensively about each of these models elsewhere, so if you’d like to read more you can check out Colin’s Personalization Content Model and Jeff’s Personalization Context Model

User Segments

User segments can be created prescriptively or adaptively, based on user research (e.g. via rules and logic tied to set user behaviors or via A/B testing). At a minimum you will likely need to consider how to treat the unknown or first-time visitor, the guest or returning visitor for whom you may have a stateful cookie (or equivalent post-cookie identifier), or the authenticated visitor who is logged in. Here are some examples from the personalization pyramid:

  • Unknown
  • Guest
  • Authenticated
  • Default
  • Referred
  • Role
  • Cohort
  • Unique ID

Actionable Data

Every organization with any digital presence has data. It’s a matter of asking what data you can ethically collect on users, its inherent reliability and value, as to how can you use it (sometimes known as “data activation.”) Fortunately, the tide is turning to first-party data: a recent study by Twilio estimates some 80% of businesses are using at least some type of first-party data to personalize the customer experience. 

Source: “The State of Personalization 2021” by Twilio. Survey respondents were n=2,700 adult consumers who have purchased something online in the past 6 months, and n=300 adult manager+ decision-makers at consumer-facing companies that provide goods and/or services online. Respondents were from the United States, United Kingdom, Australia, and New Zealand.Data was collected from April 8 to April 20, 2021.

First-party data represents multiple advantages on the UX front, including being relatively simple to collect, more likely to be accurate, and less susceptible to the “creep factor” of third-party data. So a key part of your UX strategy should be to determine what the best form of data collection is on your audiences. Here are some examples:

Figure 1.1.2: Example of a personalization maturity curve, showing progression from basic recommendations functionality to true individualization. Credit: https://kibocommerce.com/blog/kibos-personalization-maturity-chart/

There is a progression of profiling when it comes to recognizing and making decisioning about different audiences and their signals. It tends to move towards more granular constructs about smaller and smaller cohorts of users as time and confidence and data volume grow.

While some combination of implicit / explicit data is generally a prerequisite for any implementation (more commonly referred to as first party and third-party data) ML efforts are typically not cost-effective directly out of the box. This is because a strong data backbone and content repository is a prerequisite for optimization. But these approaches should be considered as part of the larger roadmap and may indeed help accelerate the organization’s overall progress. Typically at this point you will partner with key stakeholders and product owners to design a profiling model. The profiling model includes defining approach to configuring profiles, profile keys, profile cards and pattern cards. A multi-faceted approach to profiling which makes it scalable.

Pulling it Together

While the cards comprise the starting point to an inventory of sorts (we provide blanks for you to tailor your own), a set of potential levers and motivations for the style of personalization activities you aspire to deliver, they are more valuable when thought of in a grouping. 

In assembling a card “hand”, one can begin to trace the entire trajectory from leadership focus down through a strategic and tactical execution. It is also at the heart of the way both co-authors have conducted workshops in assembling a program backlog—which is a fine subject for another article.

In the meantime, what is important to note is that each colored class of card is helpful to survey in understanding the range of choices potentially at your disposal, it is threading through and making concrete decisions about for whom this decisioning will be made: where, when, and how.

Scenario A: We want to use personalization to improve customer satisfaction on the website. For unknown users, we will create a short quiz to better identify what the user has come to do. This is sometimes referred to as “badging” a user in onboarding contexts, to better characterize their present intent and context.

Lay Down Your Cards

Any sustainable personalization strategy must consider near, mid and long-term goals. Even with the leading CMS platforms like Sitecore and Adobe or the most exciting composable CMS DXP out there, there is simply no “easy button” wherein a personalization program can be stood up and immediately view meaningful results. That said, there is a common grammar to all personalization activities, just like every sentence has nouns and verbs. These cards attempt to map that territory.




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Wo die grünen Ameisen träumen (1984) / written and directed by Werner Herzog [DVD].

[Germany] : ArtHaus, [2005]




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Khodorkovsky : how the richest man in Russia became its most famous political prisoner (2011) / written, produced and directed by Cyril Tuschi [DVD].

[U.K.] : Trinity film, [2012]




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The imitation game (2014) / directed by Morten Tyldum [DVD].

[U.K.] : StudioCanal, [2015]




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Ford v Ferrari (2019) / produced and directed by James Mangold [DVD].

Beverly Hills, California : Twentieth Century Fox Home Entertainment, [2019]




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The enforcer (1976) / directed by James Fargo [DVD].

[U.K.] : Warner Bros., [2009]




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Captain America : the first Avenger (2011) / directed by Joe Johnston [DVD].

[U.K.] : Marvel Studios, [2013]




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Cameraperson (2016) / starring, produced and directed by Kirsten Johnson [DVD].

[U.K.] : Dogwoof, [2017]




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At the video store (2019) / produced, written and directed by James Westby [DVD].

[U.S.A.] : ETR Media, [2019]




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American gangster (2007) / directed by Ridley Scott [DVD].

[U.K.] : Universal Pitcures (UK), [2008]