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WhatsApp rolls out ‘channel notification’ feature for beta users

WhatsApp channel notification feature is available for both iOS and Android users




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YouTube hikes its premium subscription prices across categories in India

The family plan, which allows users to share their subscription benefits with up to five members, has witnessed the highest price increase




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GST payers get communication to first show irreversible ITC and then reverse, experts advise caution in filing Nov GSTR-3B

In August 2022 this year, Central Board of Indirect Taxes & Custom (CBIC) issued a detailed clarification on reporting of information about reversal of ITC as well as ineligible ITC




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‘Sharp increase in Railway freight traffic indicative of strong revival in economic activity post-Covid’

Revenue-earning freight traffic for April–Nov period was saw an 8.3 per cent higher y-o-y at 976.8 million tonnes




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Catholic Council of India national conference in Pala




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Latin Catholic Church criticises government for delay in resolving Munnambam land dispute; calls for all- party meeting

Expresses solidarity with the agitating families




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Centre asks State to quicken caste verification of SC/ST employees




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Judges need their vacations, but justice can’t take a holiday

In a frank and outspoken discussion, retired HC judge V.G. Palshikar explains why courts have long vacations and how that relic of colonial rule could be replaced. He also spoke about the judiciary overstepping its limits, time wasted dealing with PILs, and the Bombay HC’s huge backlog of cases




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Finding ways to not let school interfere with education




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Financial aid and social mobility [electronic resource] : evidence from Colombia's Ser Pilo Paga / Juliana Londono-Velez, Catherine Rodriguez, Fabio Sanchez, Luis E. Alvarez-Arango

Cambridge, MA. : National Bureau of Economic Research, 2023




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The refugee advantage [electronic resource] : English-language attainment in the early twentieth century / Ran Abramitzky, Leah Platt Boustan, Peter Catron, Dylan Connor, Rob Voigt

Cambridge, MA. : National Bureau of Economic Research, 2023




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Trade integration, industry reallocation, and welfare in Colombia [electronic resource] / George A. Alessandria, Oscar I. Avila-Montealegre

Cambridge, MA. : National Bureau of Economic Research, 2023




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Treatment for mental health and substance use [electronic resource] : spillovers to police safety / Monica Deza, Thanh Lu, Johanna Catherine Maclean, Alberto Ortega

Cambridge, MA.: National Bureau of Economic Research, 2024




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Youth labor force participation, education, and human capital in Asia, by gender, 1990-2019 [electronic resource] / Barbara M. Fraumeni

Cambridge, Mass. : National Bureau of Economic Research, 2023




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Advocates seek clarification from Maharashtra Election Commission

They ask the poll body whether promising reservation amounts to appeasement or whether it will amount to a breach of Model Code of Conduct




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ED raids eight locations linked to illegal betting and broadcast of IPL

The searches were conducted as part of a probe into Fairplay, which was involved in illegal broadcasting of cricket, IPL matches, and online betting.




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Maharashtra Assembly elections 2024: Uddhav's Sena (UBT) releases manifesto; promises to scrap Dharavi project, provide free education

The party leader unveils Maharashtra Assembly polls manifesto with promises of free education, stable prices for essential items, and scrapping Dharavi project




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Jacqueline's Dreamy Beach Vacation

What's a vacation if you don't post some super hot pictures on your social media feed soon after?






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Clean facts about desertification and land degradation 

Severe land degradation is now affecting 168 countries across the world 




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Researchers discover alternate method to study changes during DNA replication process




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INST scientists develop anti-counterfeiting ink to curb document duplication




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Living Library Event: Celebrating International Education | Nov. 21

Link to Notice




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Rain fury: 600 families in Bengaluru asked to relocate for 8 days




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T'gana to constitute dedicated panel for survey on Backward Class quota




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Nominated posts filled after screening 30,000 applications: Chandrababu Naidu




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Gujarat govt allocates Rs 100 crore for flood relief, 75 pc to Vadodara




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No energy for outdoor vacations




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Delta sues CrowdStrike over ‘catastrophic’ software glitch

Delta says the faulty update cost the airline at least $500 million in out-of-pocket losses — in addition to “severe harm to its reputation and goodwill,” according to the complaint, filed Friday in state court in Georgia




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Ericsson expects network densification to drive next phase of growth in India

Ericsson estimates that the data traffic in India will grow from 29 GB per smartphone user per month to 68 GB per smartphone user per month by 2029




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Cat of nine lives

Every afternoon, come hell or high water, the cat would come knocking...




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Siloxane-containing phosphine (oxide) ligands for enhanced catalytic activity of cobalt complexes for hydrosilylation reactions

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00333K, Paper
Peng Liu, Jiajian Peng, Ying Bai, Jiayun Li
A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized.
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Catalytic asymmetric construction of helicenes via transformation of biaryls

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00012A, Review Article
Peiling Fan, Lun Li, Deyun Qian
Chiral helicenes can be built by catalytic asymmetric transformation of pre-existing, easily accessible biaryl precursors using conceptually novel strategies such as olefin metathesis, alkyne hydroarylation, C–X coupling, and C–H functionalization.
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Kinetic resolution of 1,1'-binaphthyl-2,2'-diamine derivatives by chiral calcium phosphate-catalyzed acylation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00355A, Paper
Tatsuhiro Uchikura, Yuki Kanno, Yukino Fukuda, Mikoto Sato, Takahiko Akiyama
Chiral calcium phosphate-catalyzed kinetic resolution of BINAM derivatives.
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Copper catalyzed dehydrogenative cyclization, alkenylation towards dihydroquinolinones

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00134F, Paper
Pari Keerthana, Fazlur-Rahman Nawaz Khan
An efficient copper-catalysized one-pot sequential synthesis of alkenylated quinolinyldihydroquinolinones is reported utilizing ketones, 1,3-cyclohexanediones, and benzyl alcohols via dehydrogenative cyclisation, followed by alkenylation. This highly straightforward method provides a mild...
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A rhodium-catalyzed cascade C–H activation/annulation strategy for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00193A, Paper
Yinsong Wu, Guanghao Shi, Yanan Liu, Yangzilin Kong, Mengdi Wu, Demao Wang, Xiaobing Wu, Yongjia Shang, Xinwei He
We have developed a cascade annulation strategy triggered by rhodium(III)-catalyzed C–H activation for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines from free NH-sulfoximines with maleimides under mild conditions.
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Photoinduced decatungstate-catalyzed C(sp3)–H thioetherification by sulfinate salts

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00394B, Paper
Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang, Wujiong Xia
A visible light photoinduced decatungstate-catalyzed C(sp3)–H thioetherification of hydrocarbons by sodium sulfite is herein reported.
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A copper-catalyzed asymmetric Friedel–Crafts hydroxyalkylation of pyrazole-4,5-diones with 5-aminoisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00322E, Communication
Siyu Gao, Xiang Sun, Sijie Peng, Zhenggen Zha, Qi Sun, Zhiyong Wang
An asymmetric Friede-Crafts hydroxyalkylation reaction was developed under the catalysis of chiral copper complexes. A variety of pyrazolone derivatives were obtained with excellent yields and enantioselectivities.
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Copper-catalyzed ortho-thiocyanation of aromatic amines

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00137K, Communication
Monak Patel, Nitish Kumar, Hussain Bhukya, Bharatkumar Z. Dholakiya, Togati Naveen
Here, we described an efficient ortho- C(sp2)-H thiocyanation of anilines for the synthesis of aryl thiocyanates. This protocol tolerates a variety of aromatic amines to provide the desired products in good to excellent yields.
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Chemoenzymatic total synthesis of rotigotine via IRED-catalyzed reductive amination

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00072B, Communication
Dongyu Tang, Yaqing Ma, Jinping Bao, Shushan Gao, Shuli Man, Chengsen Cui
An engineered imine reductase (IRED) was developed specifically for 2-tetralone substrate, and utilized in the total synthesis of rotigotine.
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Rh(III)-catalysed C-H annulation of cis-stilbene acids with 2-diazo-1,3-diketones: A facile access to 6,7-dihydrobenzofuran-4(5H)-one and α-pyrone scaffolds

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00151F, Paper
Shankaraiah Nagula, Mary Sravani Galla, Nandini B. Kale, Akshay Kumawat, Darshana Bora
An efficient Rh(III)-catalysed C-H functionalization, tandem annulation of cis-stilbene acids using 2-diazo-1,3-diketones was devised. The protocol has solely afforded 6,7-dihydrobenzofuran-4(5H)-ones using alicyclic diazocarbonyls via decarbonylation and α-pyrones with aliphatic diazo...
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The synthesis of alk-2-ynl Weinreb amides via Pd/Cu-catalysed oxidative carbonylation of terminal alkynes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00290C, Paper
Bharati Mourya, Sandip T. Gadge, Bhalchandra M. Bhanage
Synthesis of alk-2-ynl-Weinreb amides via Pd-catalyzed oxidative carbonylation of terminal alkynes and N,O-dimethylhydroxylamine hydrochloride at room temperature under low CO/O2 pressure is reported for the first time.
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DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00383G, Paper
Debasish Bera, Rajib Sarkar, Tiyasa Dhar, Pinaki Saha, Prasanta Ghosh, Chhanda Mukhopadhyay
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C–N coupling and C–O coupling under oxidant-free conditions are outlined.
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DFT investigation of the DDQ-catalytic mechanism for constructing C–O bonds

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00346B, Paper
Xiu-Fang Zheng, Da-Gang Zhou, Li-Jun Yang
The DDQ-catalytic mechanisms for constructing C–O bonds via H2O and CH3OH as oxygen sources have been investigated with DFT.
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Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00442F, Communication
Fuxin Li, Hui Liu, Wanyu Xing, Qingju Zhang, Liming Wang
Here we report an efficient electrochemical nickel-catalyzed cross-coupling reaction for the synthesis of S-glycosides from preactivated phenols and ketones.
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Catalyst- and base-free visible light-enabled radical relay trihalomethylation/functional group-migration/carbonylation with CX3SO2Cl

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00292J, Paper
Jinkai Hu, Chenglei Yang, Xiaotao Qin, Hui Liu, Tongtong Ma, Ao-tong Shi, Qing-Long Lv, Xingman Liu, Jinhui Yang, Dianjun Li
A visible light-enabled photocatalyst-free radical trihalomethylation/cyano (or benzo[d]thiazol-2-yl) 1,4-migration/carbonylation reaction of 2-hydroxy-2-hex-5-enenitrile (or (benzo[d]thiazol-2-yl)-pent-4-enol) with CX3SO2Cl (X = F, Cl) is reported.
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Reduction of sulfoxides catalyzed by the commercially available manganese complex MnBr(CO)5

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00204K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Leal Lourenço, Ana Cristina Fernandes
A new methodology for the reduction of a wide variety of aliphatic and aromatic sulfoxides catalyzed by the air-stable, cheap and commercially available manganese catalyst MnBr(CO)5 with excellent yields is...
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Recent advances in spirocyclization of maleimides via transition-metal catalyzed C–H activation

Org. Biomol. Chem., 2024, 22,2916-2947
DOI: 10.1039/D3OB01904G, Review Article
Swadhin Swaraj Acharya, Sagarika Patra, Rojalini Maharana, Manaswini Dash, Liza Mama Barad, Bibhuti Bhusan Parida
In recent years, the maleimide scaffold has received a great deal of attention in C–H activation.
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2-Azabicyclo[3.2.1]octane scaffold: synthesis and applications

Org. Biomol. Chem., 2024, 22,2902-2915
DOI: 10.1039/D4OB00199K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mariana Crespo Monteiro, João Rafael Vale, Filipa Siopa
This review focuses on the preparation and applications in total synthesis of 2-azabicyclo[3.2.1]octane structures, a class of natural and synthetic compounds with a range of biological activities.
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