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Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Properties and activity of Zn–Ta-TUD-1 in the Lebedev process

Green Chem., 2020, 22,2558-2574
DOI: 10.1039/D0GC00103A, Paper
Open Access
Guillaume Pomalaza, Pardis Simon, Ahmed Addad, Mickaël Capron, Franck Dumeignil
A zinc and tantalum-containing mesoporous silica catalyst highly active and selective in the Lebedev process has been prepared using the one-pot TUD-1 methodology. Characterization established a correlation between acidity and butadiene formation.
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Evaluating lignin valorization via pyrolysis and vapor-phase hydrodeoxygenation for production of aromatics and alkenes

Green Chem., 2020, 22,2513-2525
DOI: 10.1039/C9GC04245H, Paper
Open Access
Alireza Saraeian, Alvina Aui, Yu Gao, Mark M. Wright, Marcus Foston, Brent H. Shanks
Lignin valorization to chemicals is an important component of creating economically viable biofuels production from lignocellulosic biomass.
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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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Visible Light-Induced Aerobic Oxidation of Diarylalkynes to -Diketones Catalyzed by Copper-superoxo at Room Temperature

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00975J, Communication
Vaibhav Pramod Charpe, Arunachalam Sagadevan, Kuo Chu Hwang
We have developed the visible light induced simple copper(II) chloride catalyzed the oxidation of diarylacetylenes to -diketones by molecular oxygen at room temperature. The in-situ generated copper(II)-superoxo complex is a...
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Bio-based benzoxazine surfactant from amino acid

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00218F, Paper
Zheng Wang, Shu Yao, Kun Song, Xinjian Gong, Sujuan Zhang, Sheng Gao, Zaijun Lu
A novel bio-based benzoxazine (Ca-g) surfactant was synthesized via a Mannich reaction using renewable glycine and cardanol as raw materials. The structure of Ca-g was characterized by NMR, FT-IR, and...
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Chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols and alcohols catalyzed by nickel(II) and copper(II)-catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00520G, Paper
Rahul B. Sonawane, Swapnali R. Sonawane, Nishant K. Rasal, Sangeeta V. Jagtap
A crucial chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols, and alcohols in the presence of amines catalyzed by Ni(II) and Cu(II) complexes with 8-hydroxyquinoline in a homogeneous medium is achieved.
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Degradation of poly(ethylene terephthalate) catalyzed by metal-free choline-based ionic liquids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00327A, Paper
Yachan Liu, Xiaoqian Yao, Haoyu Yao, Qing Zhou, Jiayu Xin, Xingmei Lu, Suojiang Zhang
Glycolysis of PET is a prospective way for degradation of PET to its monomer bis(hydroxyethyl)terephthalate (BHET) which can be polymerized again to form new qualified PET materials, and hence provides possibilities for a permanent loop recycling.
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Nickel-catalyzed and Li-mediated regiospecific C–H arylation of benzothiophenes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00917B, Paper
Yorck Mohr, Gaëlle Hisler, Léonie Grousset, Yoann Roux, Elsje Alessandra Quadrelli, Florian M. Wisser, Jérôme Canivet
A sustainable nickel-catalyzed direct C–H arylation of benzothiophenes, benzofuran and selenophene is reported for the first time.
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Mechanochemical Cleavage of Lignin Models and lignin via Oxidation and Subsequent Base-Catalyzed Strategy

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00372G, Paper
Weike Su, Chen Sun, Lei Zheng, Wenhao Xu, Alexandr V. Dushkin
Mechanochemical cleavage of lignin dimer model compounds to phenolic monomers has been developed via a two-step strategy under milling conditions. In the first step of this process, the secondary benzylic...
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Tandem catalytic aromatization of volatile fatty acids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00964D, Paper
Open Access
Egor V. Fufachev, Bert M. Weckhuysen, Pieter C. A. Bruijnincx
The transition towards a circular economy requires closing the carbon loop, e.g. by the development of new synthesis routes to valuable intermediates and products from organic-rich waste streams.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00924E, Critical Review
Anping Wang, Putla Sudarsanam, Yufei Xu, Heng Zhang, Hu Li, Song Yang
This critical review introduces the preparation methods, structural and performance control, protection, and functionalization of magnetic nanoparticles as easily recyclable and efficient heterogeneous catalysts for biodiesel synthesis.
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A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01142H, Communication
Noémie Emmanuel, Pauline Bianchi, Julien Legros, Jean-Christophe M. Monbaliu
Intensified chemical neutralization of a chemical warfare agent simulant CEES with air and light under continuous flow conditions.
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Catalytic C–C coupling of diazo compounds with arylboronic acids: using surface modified sewage sludge as catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00317D, Paper
Zhipeng Zhang, Yang Yu, Yuxing Xie, Timothy Hughes, Jun Xu, Fei Huang, He Huang
A green, mild and efficient synthesis of diarylmethines using sewage sludge-derived carbonaceous materials (SW) by perchloric acid catalyzed coupling reactions between diazo compounds and arylboronic acids was developed.
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Cracking of squalene into isoprene as chemical utilization of algae oil

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00268B, Communication
Kazuya Kimura, Kazuma Shiraishi, Takahiro Kondo, Junji Nakamura, Tadahiro Fujitani
Thermal decomposition of squalene proceeds as a chain reaction to produce isoprene (C5H8) and C10 hydrocarbons.
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Photochemical strategies for C–N bond formation via metal catalyst-free (hetero) aryl C(sp2)–H functionalization

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01088J, Tutorial Review
Qing-Qing Kang, Wenfeng Wu, Qiang Li, Wen-Ting Wei
The development of efficient and mild methods to assemble C–N bonds represents an important and appealing goal in modern synthetic chemistry.
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Boosting the efficiency of solution-based CZTSSe solar cells by using supercritical carbon dioxide treatment

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01355B, Paper
Hai-Qin Xiao, Wen-Hui Zhou, Dongxing Kou, Zheng-Ji Zhou, Yue-Na Meng, Yafang Qi, Shengjie Yuan, Qingwen Tian, Si-Xin Wu
Cu2ZnSn(S,Se)4 (CZTSSe) solar cells are receiving considerable attention in recent years, owing to the low cost and toxicity as well as high abundance of their constituent elements. Solution-based (mainly precursor...
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Electrochemical Oxidative C(sp3)-H Azolation of Lactams Under Mild Conditions

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00687D, Communication
Zhaohua Wan, Dan Wang, Zixuan Yang, Heng Zhang, Shengchun Wang , Aiwen Lei
Lactam-containing structural compounds are ubiquitous in drugs and biomolecules. An electrochemical oxidative direct C(sp3)-H azolation of lactams has been reported under metal catalyst free and external oxidant free conditions. This...
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Photochemical Synthesis of Acetals utilizing Schreiner’s Thiourea as the Catalyst

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01135E, Paper
Open Access
Nikoleta Spiliopoulou, Nikolaos Nikitas, Christoforos G Kokotos
Acetalization of aldehydes is an area of great importance in Organic Chemistry for both synthetic and biological puproses. Herein, we report a mild, inexpensive and green photochemical protocol, where Schreiner’s...
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Catalyst-Free Photodecarbonylation of 2-Amine Benzaldehyde

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01256D, Communication
Jingwei Zhou, Lamei Li, Songping Wang, Ming Yan, Wentao Wei
It is almost a consensus that decarbonylation of aldehyde group (-CHO) need to not only be mediated by transition metal catalysts, but also react under severe reaction conditions (high temperature...
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Manufacturing of Pure Cellulose Films by Recycling Ionic Liquids as Plasticizers

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00046A, Paper
Longhui Li, Yun Zhang, Yanling Sun, Shuang Sun, Guancheng Shen, Peng Zhao, Jingqiang Cui, Haiyu Qiao, Yunming Wang, Huamin Zhou
Cellulose limited in insolubility and non-melting properties is hard to be directly applied to the manufacture of pure cellulose films (PCFs). Although existing progress in eco-friendly fabrication methods including chemical...
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Complete Service of Handbook of Assistance Programs for Non-Profit Organizations

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Handbook of Assistance Programs for non-profit organizations

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Antimicrobial resistance in bacteria from livestock and companion animals / editors: Stefan Schwarz, Lina Maria Cavaco, Jianzhong Shen, with Frank Møller Aarestrup




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So you want to teach clinical? : a guide for new clinical instructors / Laura A. Jaroneski and Lori A. Przymusinski

Jaroneski, Laura A., author




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An A-Z of symptoms and signs / Robyn Beirman & Roger Engel

Beirman, Robyn




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Pet-to-man travelling staphylococci : a world in progress / edited by Vincenzo Savini




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Atlas of hematopathology : morphology, immunophenotype, cytogenetics, and molecular approaches / Faramarz Naeim ... [et al.]




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Forensic psychology reconsidered : a critique of mental illness and the courts / David Polizzi, Matthew Draper

Polizzi, David, author




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Tietz textbook of clinical chemistry and molecular diagnostics / [edited by] Nader Rifai, PhD, (Professor of Pathology, Harvard Medical School, Louis Jospeh Gay-Lussac Chair of Laboratory Medicine, Director of Clinical Chemistry, Boston Children's Hos




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Gordis epidemiology / David D. Celentano, Moyses Szklo

Celentano, David D., author




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Tietz fundamentals of clinical chemistry and molecular diagnostics / Nader Rifai, Andrea Rita Horvath, Carl T. Wittwer

Rifai, Nader, author




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Hemoglobin : insights into protein structure, function, and evolution / Jay F. Storz (Professor, School of Biological Sciences, University of Nebraska)

Storz, Jay F., author




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Art therapy & the neuroscience of relationships, creativity, & resiliency : skills and practices / Noah Hass-Cohen, Joanna Clyde Findlay ; forewords by Louis J. Cozolino and Frances Kaplan

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The phlebotomy textbook / Susan King Strasinger, DA, MT(ASCP), Marjorie Schaub Di Lorenzo, MT(ASCP)SH

Strasinger, Susan King, author