bili Disability Inclusion in Development Efforts: Analyzing the United States Agency for International Development’s Funding Solicitations for Evidence of Inclusive Practices By ifp.nyu.edu Published On :: Tue, 05 Nov 2024 02:28:36 +0000 Journal of Disability Policy Studies, Ahead of Print. In 1997, the United States Agency for International Development established a policy focused on including people with disabilities in its development efforts. For the past two decades, this initiative has been echoed globally, yet research on its effectiveness remains limited. This study revisits a previous 2015 analysis […] The post Disability Inclusion in Development Efforts: Analyzing the United States Agency for International Development’s Funding Solicitations for Evidence of Inclusive Practices was curated by information for practice. Full Article Journal Article Abstracts
bili These Playful 3D-Printed Lamps Take Sustainability Seriously By design-milk.com Published On :: Fri, 08 Nov 2024 15:00:07 +0000 With their unique forms, these 3D-printed lamps made from recycled plastic by Emil Robbrecht bring a playful element to your home. Full Article Home Furnishings Main 3D printed 3D printing Emil Robbrecht home furnishings lamp lamps lighting table lamp table lamps
bili For many with disabilities, 'Let It Go' is an anthem of acceptance By minnesota.publicradio.orghttps Published On :: Tue, 22 Jan 2019 06:16:04 -0600 The breakout song from Disney's "Frozen" has inspired many marginalized groups -- but its message of rejecting stigma holds special resonance for disabled people and their families. Full Article
bili Twin Cities stands out nationally for ‘job accessibility’ By www.mprnews.org Published On :: Fri, 08 Nov 2024 21:00:00 +0000 If you feel like your drive to work has gotten longer recently, it’s not just you. New research shows that the return of traffic has led to fewer jobs being reachable within 30 minutes by car. Full Article
bili Jack Graham says pastors urging congregations not to vote 'have lost all credibility' By www.christianpost.com Published On :: Tue, 05 Nov 2024 16:02:57 -0500 A social media post from a well-known Evangelical pastor has sparked debate about Christians' engagement in politics and what pastors should advise their congregations. Full Article
bili Health Care Provider Boot Camp Day 3: Health Care Provider Roles and Responsibilities By www.tdi.texas.gov Published On :: Tue, 11 Feb 2025 18:00:00 GMT Health Care Provider Boot Camp Day 3: Health Care Provider Roles and Responsibilities Full Article
bili Speed, accuracy and traceability By www.retailtechnologyreview.com Published On :: Mobile Computing/AIDC (Data capture) Technology ReportRetail Technology Review spoke with leading representatives from the analyst and vendor communities about many of the current key talking points and areas of innovation taking place within the world automatic identification and data capture (AIDC)/mobile computing solutions. Full Article Data Capture Voice Mobile Computers Critical Issues
bili Out of the data jungle: More interoperability for resilient supply chains By www.retailtechnologyreview.com Published On :: Fri, 13 Nov 7840 17:29:58 +0000 By Philipp Pfister, Chief Customer Experience Officer at Transporeon (a Trimble company)There’s no denying that the transport sector is a prominent cog across most global industries. As the saying goes, “There is no production without procurement logistics, and no trade without delivery traffic.” Full Article Retail Supply Chain Critical Issues
bili Customer adoption of Bitsight cloud monitoring grows 170% amid increased demand for Visibility Across digital infrastructure By www.retailtechnologyreview.com Published On :: Bitsight, the cyber risk management solutions provider, has introduced new asset mapping capabilities to help companies better manage vulnerabilities across their extended attack surface. Full Article Surveillance and Security Cloud Computing
bili Paper packaging sales stabilising, as decline slows from 17% in Q1 to 12% in Q2, and to 9% in August By www.retailtechnologyreview.com Published On :: Fri, 13 Nov 8240 17:28:37 +0000 New data from Demica, the fintech, reveals that the paper packaging sector in key markets across Europe and North America is showing signs of stabilisation. Full Article Internet Retailing Critical Issues
bili Divido bolsters merchant capabilities to supercharge checkout finance experience ahead of the Golden Quarter By www.retailtechnologyreview.com Published On :: Checkout finance provider, Divido, has launched two new product capabilities ‘Divido Analytics’ and ‘Split Capability’, allowing merchants to have greater understanding and flexibility over their checkout finance experience. Full Article EPoS Systems Data Capture
bili Brother UK named as leader in sustainability programs and services in new report By www.retailtechnologyreview.com Published On :: Brother UK has been named as a 'leader' in sustainability programs and services in the most recent IDC Sustainability MarketScape assessment. Full Article Print and Label
bili Digitisation, sustainability and the cloud – The printing and labelling evolution continues By www.retailtechnologyreview.com Published On :: Printing and Labelling Technology ReportRetailTechnologyReview.com spoke with leading analysts, vendors and associations about current developments within the printing and labelling technology marketplace about recent developments and what to look out for over the next year or two. Full Article Critical Issues Print and Label Cloud Computing
bili ISTA European Packaging Symposium will bring together global transport packaging leaders to focus on e-commerce, sustainability and more By www.retailtechnologyreview.com Published On :: The International Safe Transit Association (ISTA), the industry developer of pre-shipment performance testing standards for packaged products, has announced programming for its annual European Packaging Symposium, which will be held 8-9 October at the Le Méridien Frankfurt in Frankfurt, Germany. Full Article Internet Retailing Exhibitions and Events
bili Elon Musk's Starlink satellite Internet raises Russian combat capability dramatically By english.pravda.ru Published On :: Tue, 12 Nov 2024 20:02:00 +0300 Russian military correspondent Alexander Kots said that the Russian Armed Forces use Elon Musk's technology in military actions. According to Kots, the Russian military use Starlink satellites in the special military operation zone. "The troops actively use Starlink in the SVO (SVO is a Russian abbreviation for special military operation — ed.). We use it, among other things, for broadcast to command posts, to get images from reconnaissance UAVs,” the military correspondent said. This has significantly raised the level of Russian intelligence, the military correspondent added. Full Article Incidents
bili N. Korean Leader's Sister Declares to Continue Bolstering Nuclear Capabilities By world.kbs.co.kr Published On :: Sat, 02 Nov 2024 14:06:21 +0900 [Inter-Korea] : Kim Yo-jong, the powerful sister of North Korean leader Kim Jong-un, declared that the regime will continue to bolster its nuclear capabilities in protest of criticisms from the international community. In a statement carried by the North's Korean Central News Agency(KCNA) on Saturday, Kim ...[more...] Full Article Inter-Korea
bili Emotional Cancer Meets Free-Spirited Aquarius: Compatibility Breakdown By entertainment.howstuffworks.com Published On :: Fri, 08 Nov 2024 05:30:03 -0500 Discover the compatibility between Cancer and Aquarius in love, friendship, and relationships. Learn how their emotional and intellectual traits align or clash. Full Article
bili Leo and Pisces Compatibility: Why Their Relationship Is Complex but Worth It By entertainment.howstuffworks.com Published On :: Sat, 09 Nov 2024 05:00:05 -0500 Explore Leo and Pisces compatibility, uncovering their strengths, weaknesses, and whether these zodiac signs can make their relationship work. Full Article
bili Is Taurus and Virgo Compatibility a Perfect Match? Exploring Their Bond By entertainment.howstuffworks.com Published On :: Sun, 10 Nov 2024 05:00:04 -0500 Discover Taurus and Virgo compatibility in love, relationships, and friendship. Explore how these earth signs align in values, trust, and practical connections. Full Article
bili Is Virgo and Capricorn Compatibility Solid? Discover the Strengths and Challenges By entertainment.howstuffworks.com Published On :: Sun, 10 Nov 2024 05:15:02 -0500 s Virgo and Capricorn compatibility strong? Discover how these earth signs connect in love, friendship, and marriage with shared values, loyalty, and mutual support. Full Article
bili The Pros and Cons of Aries and Sagittarius Compatibility By entertainment.howstuffworks.com Published On :: Mon, 11 Nov 2024 05:30:04 -0500 Discover Aries and Sagittarius compatibility in love, friendship, and beyond. Learn how these two fire signs create a dynamic, passionate bond full of excitement and adventure. Full Article
bili What Reversed Compatibility Reveals About Pisces and Cancer Pairing By entertainment.howstuffworks.com Published On :: Tue, 12 Nov 2024 05:30:03 -0500 Explore reversed Pisces and Cancer compatibility! Learn how these water signs bond emotionally, support each other deeply, and thrive together in relationships. Full Article
bili Exploring the Deep Connection of Cancer and Taurus Compatibility By entertainment.howstuffworks.com Published On :: Wed, 13 Nov 2024 05:15:02 -0500 Explore Cancer and Taurus compatibility, where stability meets sensitivity. Learn how these signs create lasting love through trust, loyalty, and mutual understanding. Full Article
bili BGS collaborates with Icelandic colleagues to assess windfarm suitability - British Geological Survey By news.google.com Published On :: Thu, 03 Oct 2024 07:00:00 GMT BGS collaborates with Icelandic colleagues to assess windfarm suitability British Geological Survey Full Article
bili Structural transformations and stability of benzo[a]pyrene under high pressure By journals.iucr.org Published On :: This study explores the high-pressure behavior of benzo[a]pyrene, revealing two previously unknown polymorphs at 4.8 and 7.1 GPa. These findings enhance our understanding of the structural dynamics and stability of polycyclic aromatic hydrocarbons under extreme conditions. Full Article text
bili Crystal structure and compressibility of magnesium chloride heptahydrate found under high pressure By journals.iucr.org Published On :: In-situ diffraction measurements reveal that magnesium chloride forms a unique high-pressure phase, a heptahydrate, above 2 GPa. The hydrogen-bonding structure appears to contain orientational disorder. Full Article text
bili Coordination geometry flexibility driving supramolecular isomerism of Cu/Mo pillared-layer hybrid networks By journals.iucr.org Published On :: The hydrothermal synthesis and structural characterization of four novel 3D pillared-layer metal–organic frameworks are studied, revealing how the malleability of copper coordination geometries drives diverse supramolecular isomerism. The findings provide new insights into designing advanced hybrid materials with tailored properties, emphasizing the significant role of reaction conditions and metal ion flexibility in determining network topologies. Full Article text
bili Variable stoichiometry and salt-cocrystal intermediate in the multicomponents of flucytosine: structural elucidation and its impact on stability By journals.iucr.org Published On :: Five multicomponent solid forms of an antifungal drug flucytosine are reported with a hygroscopic stability study. A detailed CSD search on the cocrystal/salts of flucytosine is evaluated and correlated the structures based on bond angles and bond distances. Full Article text
bili Crystal structure and compressibility of magnesium chloride heptahydrate found under high pressure By journals.iucr.org Published On :: 2024-10-21 The odd hydration number has so far been missing in the water-rich magnesium chloride hydrate series (MgCl2·nH2O). In this study, magnesium chloride heptahydrate, MgCl2·7H2O (or MgCl2·7D2O), which forms at high pressures above 2 GPa and high temperatures above 300 K, has been identified. Its structure has been determined by a combination of in-situ single-crystal X-ray diffraction at 2.5 GPa and 298 K and powder neutron diffraction at 3.1 GPa and 300 K. The single-crystal specimen was grown by mixing alcohols to prevent nucleation of undesired crystalline phases. The results show orientational disorder of water molecules, which was also examined using density functional theory calculations. The disorder involves the reconnection of hydrogen bonds, which differs from those in water ice phases and known disordered salt hydrates. Shrinkage by compression occurs mainly in one direction. In the plane perpendicular to this most compressible direction, oxygen and chlorine atoms are in a hexagonal-like arrangement. Full Article text
bili Grazing-incidence small-angle neutron scattering at high pressure (HP-GISANS): a soft matter feasibility study on grafted brush films By journals.iucr.org Published On :: We present a demonstration of high-pressure grazing-incidence small-angle neutron scattering for soft matter thin films. The results suggest changes in water reorganization at different pressures. Full Article text
bili Improving the reliability of small- and wide-angle X-ray scattering measurements of anisotropic precipitates in metallic alloys using sample rotation By journals.iucr.org Published On :: Rotations of small- and wide-angle X-ray scattering samples during acquisition are shown to give a drastic improvement in the reliability of the characterization of anisotropic precipitates in metallic alloys. Full Article text
bili Real-time analysis of liquid-jet sample-delivery stability for an X-ray free-electron laser using machine vision By journals.iucr.org Published On :: This paper describes real-time statistical analysis of liquid jet images for SFX experiments at the European XFEL. This analysis forms one part of the automated jet re-alignment system for SFX experiments at the SPB/SFX instrument of European XFEL. Full Article text
bili Grazing-incidence small-angle neutron scattering at high pressure (HP-GISANS): a soft matter feasibility study on grafted brush films By journals.iucr.org Published On :: 2024-11-04 Grazing-incidence small-angle neutron scattering (GISANS) under pressure (HP-GISANS) at the solid (Si)–liquid (D2O) interface is demonstrated for the pressure-induced lateral morphological characterization of the nanostructure in thin (<100 nm) soft matter films. We demonstrate feasibility by investigating a hydrophobic {poly[(2,2,3,3,4,4,5,5-octafluoro)pentyl methacrylate]} (POFPMA)–hydrophilic {poly[2-(dimethylamino)ethyl methacrylate]} (PDMAEMA) brush mixture of strong incompatibility between the homopolymers, anchored on Si, at T = 45°C for two pressures, P = 1 bar and P = 800 bar. Our GISANS results reveal nanostructural rearrangements with increasing P, underlining P-induced effects in tethered polymer brush layers swollen with bulk solvent. Full Article text
bili Improving the reliability of small- and wide-angle X-ray scattering measurements of anisotropic precipitates in metallic alloys using sample rotation By journals.iucr.org Published On :: 2024-11-04 Nanometric precipitates in metallic alloys often have highly anisotropic shapes. Given the large grain size and non-random texture typical of these alloys, performing small- and wide-angle X-ray scattering (SAXS/WAXS) measurements on such samples for determining their characteristics (typically size and volume fraction) results in highly anisotropic and irreproducible data. Rotations of flat samples during SAXS/WAXS acquisitions are presented here as a solution to these anisotropy issues. Two aluminium alloys containing anisotropic precipitates are used as examples to validate the approach with a −45°/45° angular range. Clear improvements can be seen on the SAXS I(q) fitting and the consistency between the different SAXS/WAXS measurements. This methodology results in more reliable measurements of the precipitate's characteristics, and thus allows for time- and space-resolved measurements with higher accuracy. Full Article text
bili Stability of inorganic ionic structures: the uniformity approach By journals.iucr.org Published On :: 2024-10-14 The crystal structure uniformity is numerically estimated as the standard deviation of the crystal space quantizer 〈G3〉. This criterion has been applied to explore the uniformity of ionic sublattices in 21465 crystal structures of inorganic ionic compounds. In most cases, at least one kind of sublattice (whole ionic lattice, cationic or anionic sublattice) was found to be highly uniform with a small 〈G3〉 value. Non-uniform structures appeared to be either erroneous or essentially non-ionic. As a result, a set of uniformity criteria is proposed for the estimation of the stability of ionic crystal structures. Full Article text
bili ProSPyX: software for post-processing images of X-ray ptychography with spectral capabilities By journals.iucr.org Published On :: 2024-02-09 X-ray ptychography is a coherent diffraction imaging technique based on acquiring multiple diffraction patterns obtained through the illumination of the sample at different partially overlapping probe positions. The diffraction patterns collected are used to retrieve the complex transmittivity function of the sample and the probe using a phase retrieval algorithm. Absorption or phase contrast images of the sample as well as the real and imaginary parts of the probe function can be obtained. Furthermore, X-ray ptychography can also provide spectral information of the sample from absorption or phase shift images by capturing multiple ptychographic projections at varying energies around the resonant energy of the element of interest. However, post-processing of the images is required to extract the spectra. To facilitate this, ProSPyX, a Python package that offers the analysis tools and a graphical user interface required to process spectral ptychography datasets, is presented. Using the PyQt5 Python open-source module for development and design, the software facilitates extraction of absorption and phase spectral information from spectral ptychographic datasets. It also saves the spectra in file formats compatible with other X-ray absorption spectroscopy data analysis software tools, streamlining integration into existing spectroscopic data analysis pipelines. To illustrate its capabilities, ProSPyX was applied to process the spectral ptychography dataset recently acquired on a nickel wire at the SWING beamline of the SOLEIL synchrotron. Full Article text
bili Grazing-incidence synchrotron radiation diffraction studies on irradiated Ce-doped and pristine Y-stabilized ZrO2 at the Rossendorf beamline By journals.iucr.org Published On :: 2024-02-16 In this work, Ce-doped yttria-stabilized zirconia (YSZ) and pure YSZ phases were subjected to irradiation with 14 MeV Au ions. Irradiation studies were performed to simulate long-term structural and microstructural damage due to self-irradiation in YSZ phases hosting alpha-active radioactive species. It was found that both the Ce-doped YSZ and the YSZ phases had a reasonable tolerance to irradiation at high ion fluences and the bulk crystallinity was well preserved. Nevertheless, local microstrain increased in all compounds under study after irradiation, with the Ce-doped phases being less affected than pure YSZ. Doping with cerium ions increased the microstructural stability of YSZ phases through a possible reduction in the mobility of oxygen atoms, which limits the formation of structural defects. Doping of YSZ with tetravalent actinide elements is expected to have a similar effect. Thus, YSZ phases are promising for the safe long-term storage of radioactive elements. Using synchrotron radiation diffraction, measurements of the thin irradiated layers of the Ce-YSZ and YSZ samples were performed in grazing incidence (GI) mode. A corresponding module for measurements in GI mode was developed at the Rossendorf Beamline and relevant technical details for sample alignment and data collection are also presented. Full Article text
bili Vibrational stability improvement of a mirror system using active mass damping By journals.iucr.org Published On :: 2024-08-08 Addressing the demand for high stability of beamline instruments at the SHINE facility, a high stability mirror regulating mechanism has been developed for mirror adjustments. Active mass damping was adopted to attenuate pitch angle vibrations of mirrors caused by structural vibrations. An internal absolute velocity feedback was used to reduce the negative impact of spillover effects and to improve performance. The experiment was conducted on a prototype structure of a mirror regulating mechanism, and results showed that the vibration RMS of the pitch angle was effectively attenuated from 47 nrad to 27 nrad above 1 Hz. Full Article text
bili Structural flexibility of Toscana virus nucleoprotein in the presence of a single-chain camelid antibody By journals.iucr.org Published On :: 2024-01-24 Phenuiviridae nucleoprotein is the main structural and functional component of the viral cycle, protecting the viral RNA and mediating the essential replication/transcription processes. The nucleoprotein (N) binds the RNA using its globular core and polymerizes through the N-terminus, which is presented as a highly flexible arm, as demonstrated in this article. The nucleoprotein exists in an `open' or a `closed' conformation. In the case of the closed conformation the flexible N-terminal arm folds over the RNA-binding cleft, preventing RNA adsorption. In the open conformation the arm is extended in such a way that both RNA adsorption and N polymerization are possible. In this article, single-crystal X-ray diffraction and small-angle X-ray scattering were used to study the N protein of Toscana virus complexed with a single-chain camelid antibody (VHH) and it is shown that in the presence of the antibody the nucleoprotein is unable to achieve a functional assembly to form a ribonucleoprotein complex. Full Article text
bili Structure and stability of an apo thermophilic esterase that hydrolyzes polyhydroxybutyrate By journals.iucr.org Published On :: 2024-10-23 Pollution from plastics is a global problem that threatens the biosphere for a host of reasons, including the time scale that it takes for most plastics to degrade. Biodegradation is an ideal solution for remediating bioplastic waste as it does not require the high temperatures necessary for thermal degradation and does not introduce additional pollutants into the environment. Numerous organisms can scavenge for bioplastics, such as polylactic acid (PLA) or poly-(R)-hydroxybutyrate (PHB), which they can use as an energy source. Recently, a promiscuous PHBase from the thermophilic soil bacterium Lihuaxuella thermophila (LtPHBase) was identified. LtPHBase can accommodate many substrates, including PHB granules and films and PHB block copolymers, as well as the unrelated polymers polylactic acid (PLA) and polycaprolactone (PCL). LtPHBase uses the expected Ser–His–Asp catalytic triad for hydrolysis at an optimal enzyme activity near 70°C. Here, the 1.75 Å resolution crystal structure of apo LtPHBase is presented and its chemical stability is profiled. Knowledge of its substrate preferences was extended to different-sized PHB granules. It is shown that LtPHBase is highly resistant to unfolding, with barriers typical for thermophilic enzymes, and shows a preference for low-molecular-mass PHB granules. These insights have implications for the long-term potential of LtPHBase as an industrial PHB hydrolase and shed light on the evolutionary role that this enzyme plays in bacterial metabolism. Full Article text
bili The interoperability of crystallographic data and databases By journals.iucr.org Published On :: 2024-01-01 Interoperability of crystallographic data with other disciplines is essential for the smooth and rapid progress of structure-based science in the computer age. Within crystallography and closely related subject areas, there is already a high level of conformance to the generally accepted FAIR principles (that data be findable, accessible, interoperable and reusable) through the adoption of common information exchange protocols by databases, publishers, instrument vendors, experimental facilities and software authors. Driven by the success within these domains, the IUCr has worked closely with CODATA (the Committee on Data of the International Science Council) to help develop the latter's commitment to cross-domain integration of discipline-specific data. The IUCr has, in particular, emphasized the need for standards relating to data quality and completeness as an adjunct to the FAIR data landscape. This can ensure definitive reusable data, which in turn can aid interoperability across domains. A microsymposium at the IUCr 2023 Congress provided an up-to-date survey of data interoperability within and outside of crystallography, expounded using a broad range of examples. Full Article text
bili Ab initio crystal structures and relative phase stabilities for the aleksite series, PbnBi4Te4Sn+2 By journals.iucr.org Published On :: 2023-11-01 Density functional theory methods are applied to crystal structures and stabilities of phases from the aleksite homologous series, PbnBi4Te4Sn+2 (n = homologue number). The seven phases investigated correspond to n = 0 (tetradymite), 2 (aleksite-21R and -42R), 4 (saddlebackite-9H and -18H), 6 (unnamed Pb6Bi4Te4S8), 8 (unnamed Pb8Bi4Te4S10), 10 (hitachiite) and 12 (unnamed Pb12Bi4Te4S14). These seven phases correspond to nine single- or double-module structures, each comprising an odd number of atom layers, 5, 7, (5.9), 9, (7.11), 11, 13, 15 and 17, expressed by the formula: S(MpXp+1)·L(Mp+1Xp+2), where M = Pb, Bi and X = Te, S, p ≥ 2, and S and L = number of short and long modules, respectively. Relaxed structures show a and c values within 1.5% of experimental data; a and the interlayer distance dsub decrease with increasing PbS content. Variable Pb—S bond lengths contrast with constant Pb—S bond lengths in galena. All phases are n-fold superstructures of a rhombohedral subcell with c/3 = dsub*. Electron diffraction patterns show two brightest reflections at the centre of dsub*, described by the modulation vector qF = (i/N) · dsub*, i = S + L. A second modulation vector, q = γ · csub*, shows a decrease in γ, from 1.8 to 1.588, across the n = 0 to n = 12 interval. The linear relationship between γ and dsub allows the prediction of any theoretical phases beyond the studied compositional range. The upper PbS-rich limit of the series is postulated as n = 398 (Pb398Bi4Te4S400), a phase with dsub (1.726 Å) identical to that of trigonal PbS within experimental error. The aleksite series is a prime example of mixed layer compounds built with accretional homology principles. Full Article text
bili K0.72Na1.71Ca5.79Si6O19 – the first oligosilicate based on [Si6O19]-hexamers and its stability compared to cyclosilicates By journals.iucr.org Published On :: 2024-08-30 Synthesis experiments were conducted in the quaternary system K2O–Na2O–CaO–SiO2, resulting in the formation of a previously unknown compound with the composition K0.72Na1.71Ca5.79Si6O19. Single crystals of sufficient size and quality were recovered from a starting mixture with a K2O:Na2O:CaO:SiO2 molar ratio of 1.5:0.5:2:3. The mixture was confined in a closed platinum tube and slowly cooled from 1150°C at a rate of 0.1°C min−1 to 700°C before being finally quenched in air. The structure has tetragonal symmetry and belongs to space group P4122 (No. 91), with a = 7.3659 (2), c = 32.2318 (18) Å, V = 1748.78 (12) Å3, and Z = 4. The silicate anion consists of highly puckered, unbranched six-membered oligomers with the composition [Si6O19] and point group symmetry 2 (C2). Although several thousands of natural and synthetic oxosilicates have been structurally characterized, this compound is the first representative of a catena-hexasilicate anion, to the best of our knowledge. Structural investigations were completed using Raman spectroscopy. The spectroscopic data was interpreted and the bands were assigned to certain vibrational species with the support of density functional theory at the HSEsol level of theory. To determine the stability properties of the novel oligosilicate compared to those of the chemically and structurally similar cyclosilicate combeite, we calculated the electronegativity of the respective structures using the electronegativity equalization method. The results showed that the molecular electronegativity of the cyclosilicate was significantly higher than that of the oligostructure due to the different connectivities of the oxygen atoms within the molecular units. Full Article text
bili JUAMI, the joint undertaking for an African materials institute: building materials science research collaborations and capabilities between continents By journals.iucr.org Published On :: 2024-01-26 JUAMI, the joint undertaking for an African materials institute, is a project to build collaborations and materials research capabilities between PhD researchers in Africa, the United States, and the world. Focusing on research-active universities in the East African countries of Kenya, Ethiopia, Tanzania and Uganda, the effort has run a series of schools focused on materials for sustainable energy and materials for sustainable development. These bring together early-career researchers from Africa, the US, and beyond, for two weeks in a close-knit environment. The program includes lectures on cutting-edge research from internationally renowned speakers, highly interactive tutorial lectures on the science behind the research, also from internationally known researchers, and hands-on practicals and team-building exercises that culminate in group proposals from self-formed student teams. The schools have benefited more than 300 early-career students and led to proposals that have received funding and have led to research collaborations and educational non-profits. JUAMI continues and has an ongoing community of alumni who share resources and expertise, and is open to like-minded people who want to join and develop contacts and collaborations internationally. Full Article text
bili Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)potassium-μ-oxalato-triphenylstannate(IV), the first reported 18-crown-6-stabilized potassium salt of triphenyloxalatostannate By journals.iucr.org Published On :: 2024-08-13 The title complex, (1,4,7,10,13,16-hexaoxacyclooctadecane-1κ6O)(μ-oxalato-1κ2O1,O2:2κ2O1',O2')triphenyl-2κ3C-potassium(I)tin(IV), [KSn(C6H5)3(C2O4)(C12H24O6)] or K[18-Crown-6][(C6H5)3SnO4C2], was synthesized. The complex consists of a potassium cation coordinated to the six oxygen atoms of a crown ether molecule and the two oxygen atoms of the oxalatotriphenylstannate anion. It crystallizes in the monoclinic crystal system within the space group P21. The tin atom is coordinated by one chelating oxalate ligand and three phenyl groups, forming a cis-trigonal–bipyramidal geometry around the tin atom. The cations and anions form ion pairs, linked through carbonyl coordination to the potassium atoms. The crystal structure features C—H⋯O hydrogen bonds between the oxygen atoms of the oxalate group and the hydrogen atoms of the phenyl groups, resulting in an infinite chain structure extending along a-axis direction. The primary inter-chain interactions are van der Waals forces. Full Article text
bili A note on the Hendrickson–Lattman phase probability distribution and its equivalence to the generalized von Mises distribution By journals.iucr.org Published On :: 2024-02-16 Hendrickson & Lattman [Acta Cryst. (1970), B26, 136–143] introduced a method for representing crystallographic phase probabilities defined on the unit circle. Their approach could model the bimodal phase probability distributions that can result from experimental phase determination procedures. It also provided simple and highly effective means to combine independent sources of phase information. The present work discusses the equivalence of the Hendrickson–Lattman distribution and the generalized von Mises distribution of order two, which has been studied in the statistical literature. Recognizing this connection allows the Hendrickson–Lattman distribution to be expressed in an alternative form which is easier to interpret, as it involves the location and concentration parameters of the component von Mises distributions. It also allows clarification of the conditions for bimodality and access to a simplified analytical method for evaluating the trigonometric moments of the distribution, the first of which is required for computing the best Fourier synthesis in the presence of phase, but not amplitude, uncertainty. Full Article text
bili On the feasibility of time-resolved X-ray powder diffraction of macromolecules using laser-driven ultrafast X-ray sources By journals.iucr.org Published On :: 2024-07-29 With the emergence of ultrafast X-ray sources, interest in following fast processes in small molecules and macromolecules has increased. Most of the current research into ultrafast structural dynamics of macromolecules uses X-ray free-electron lasers. In parallel, small-scale laboratory-based laser-driven ultrafast X-ray sources are emerging. Continuous development of these sources is underway, and as a result many exciting applications are being reported. However, because of their low flux, such sources are not commonly used to study the structural dynamics of macromolecules. This article examines the feasibility of time-resolved powder diffraction of macromolecular microcrystals using a laboratory-scale laser-driven ultrafast X-ray source. Full Article text
bili In situ/operando method for energy stability measurement of synchrotron radiation By journals.iucr.org Published On :: 2024-10-15 A novel in situ/operando method is introduced to measure the photon beam stability of synchrotron radiation based on orthogonal diffraction imaging of a Laue crystal/analyzer, which can decouple the energy/wavelength and Bragg angle of the photon beam using the dispersion effect in the diffraction process. The method was used to measure the energy jitter and drift of the photon beam on BL09B and BL16U at the Shanghai Synchrotron Radiation Facility. The experimental results show that this method can provide a fast way to measure the beam stability of different light sources including bending magnet and undulator with meV-level energy resolution and ms-level time response. Full Article text
bili Towards Seamless Payment Interoperability – Thunes Report By thepaypers.com Published On :: Fri, 11 Oct 2024 09:24:00 +0100 ‘The Road Ahead: Towards Seamless Payments Interoperability’, an eBook from Thunes, Visa, and The Paypers, explores how payments interoperability is reshaping the future of cross-border transactions. Full Article
bili TerraPay partners with Suyool to boost financial accessibility in Lebanon By thepaypers.com Published On :: Wed, 06 Nov 2024 15:27:00 +0100 TerraPay, a global money movement company,... Full Article