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Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Two from Hyderabad, including government employee, lose ₹50 lakh in separate scams




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Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district




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‘Rahasyam Idham Jagath’ movie review: Earnest but far from engrossing

Director Komal R Bharadwaj’s Telugu indie ‘Rahasyam Idham Jagath’ is ambitious in using science, technology and stories from the Indian epics for an adventure drama, but falls short in its execution




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66% of gamers in India are from non-metro cities: Lumikai annual report

Average weekly time spent on gaming increased by 30% to 13 hours




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Wriddhiman Saha announces retirement from cricket after this year's Ranji Trophy

Veteran cricketer Wriddhiman Saha announces retirement, last season in Ranji Trophy, ending a cherished journey in cricket




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Ben Stokes missing from IPL’s list of 1,574 players ahead of mega auction

IPL mega auction list includes marquee Indian players like Pant, Iyer, and Rahul, with a total purse of ₹120 crore




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BCCI vs PCB spar on CT venue as Mohsin Naqvi denies receiving any official note from Indian board

The Hybrid Model was followed during 2023 Asia Cup where Pakistan played its matches at home but India played its matches in Sri Lanka.




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Stories from the heart

Writer Balakumaran talks to Suganthy Krishnamachari about the diverse subjects of his novels and the joy in capturing human emotions.



  • History & Culture

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Interfacial properties of a ZnO/PTFE composite from density functional tight-binding simulations

RSC Adv., 2024, 14,35097-35103
DOI: 10.1039/D4RA06790H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chol Ryu, Jun-Gi Ri, Yun-Sim Kim, Chung-Hyok Rim, Chung-Il Kim, Chol-Jun Yu
We performed density functional tight-binding simulations of a ZnO/amorphous PTFE superlattice to reveal the interlayer binding strength, charge redistribution and enhancement of mechanical strength of the ZnO-reinforced PTFE plastic composites.
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Clues from an ionic cocrystal structure: from catalysis to mechanochemistry

RSC Adv., 2024, 14,34843-34847
DOI: 10.1039/D4RA05652C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bandana Sar, Mollah Rohan Ahsan, Arijit Mukherjee
A crystal structure is no longer conceived as a static entity; rather, it often mirrors crystallization pathways, linking crystal structures with a solution scenario.
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Comparing diverse extraction methodologies to infer the performance of 1,8-cineole extraction from Eucalyptus cinerea: process optimization, kinetics, and interaction mechanisms

RSC Adv., 2024, 14,35529-35552
DOI: 10.1039/D4RA06050D, Paper
Open Access
Divya Baskaran, Madhumitha Sathiamoorthy, Ramasamy Govindarasu, Hun-Soo Byun
Different extraction techniques were used to extract 1,8-cineole from Eucalyptus cinerea leaves, and their performance efficiency was evaluated through optimization and kinetic studies.
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Syntheses of optically active monapterin, 7,8-dihydromonapterin, and 5,6,7,8-tetrahydromonapterin from L-xylose

RSC Adv., 2024, 14,35644-35649
DOI: 10.1039/D4RA07179D, Paper
Open Access
Arun K. Ghosh, Ashish Sharma, Satish Nagam, Clay Fuqua
Monapterin, 7,8-dihydromonapterin, and 5,6,7,8-tetrahydromonapterin are synthesized in optically active forms using L-xylose as the starting material.
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Review of iodine behavior from nuclear fuel dissolution to environmental release

RSC Adv., 2024, 14,35255-35274
DOI: 10.1039/D4RA06494A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chelsie L. Beck, Juan Cervantes, Steven Chiswell, Allison T. Greaney, Katherine R. Johnson, Tatiana G. Levitskaia, Leigh R. Martin, Gavin McDaniel, Stephen Noble, Jason M. Rakos, Brian J. Riley, Andrew Ritzmann, Joel M. Tingey
During nuclear fuel reprocessing, radioiodine, can be released.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and in vitro assessment of gold nanoparticles conjugated with extracts, sterols and pure compounds derived from marine sponges from the Indian and Pacific Oceans

RSC Adv., 2024, 14,36115-36131
DOI: 10.1039/D4RA04068F, Paper
Open Access
Avin Ramanjooloo, Devesh Bekah, Samson A. Adeyemi, Philemon Ubanako, Lindokuhle Ngema, Yahya E. Choonara, David E. Williams, Elena A. Polishchuk, Raymond J. Andersen, Archana Bhaw-Luximon
The synthesis of gold nanoparticles using extracts, sterols and pure compounds from marine sponges.
The content of this RSS Feed (c) The Royal Society of Chemistry




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From e-waste to eco-sensors: synthesis of reduced graphene oxide/ZnO from discarded batteries for a rapid electrochemical bisphenol A sensor

RSC Adv., 2024, 14,36073-36083
DOI: 10.1039/D4RA04046E, Paper
Open Access
Md Humayun Kabir, Md Yeasin Pabel, Nishat Tasnim Bristy, Md. Abdus Salam, Muhammad Shahriar Bashar, Sabina Yasmin
E-waste-derived reduced graphene oxide/ZnO forfast electrochemical detection of bisphenol A (BPA).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Upconversion nanoparticles incorporated with three-dimensional graphene composites for electrochemical sensing of baicalin from natural plants

RSC Adv., 2024, 14,36084-36092
DOI: 10.1039/D4RA06540A, Paper
Open Access
Na Zhang, Yilin Wu, Tian Liang, Yongxiang Su, Xusheng Xie, Tianren Zhang, Hongyan Wang, Keying Zhang, Rongli Jiang
The fabrication of UCNP-3DG and its application in electrochemical detection of Bn in natural plant samples.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
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Haryana Congress again urges Speaker to disqualify MLA Kiran Choudhry from State Assembly

Since the senior leader had joined the BJP, according to the Tenth Schedule of the Constitution, ‘any member of a House who voluntarily gives up their membership of a political party is liable to be disqualified,’ the Congress said




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Pune bar case: Police detain two people from Mumbai

The detention follows CM Shinde’s order to crackdown on illicit pubs for a ‘drug-free’ Pune




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10 Amarnath pilgrims injured after jumping out from moving bus in J&K’s Ramban

The incident happened when the passengers who wanted to get down were informed of the failure of the brakes.




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With four out of five NEET ‘solver gang’ arrests from the district, no easy answers in Nalanda

According to the police, the ‘solver gang’ is spread across Bihar, Jharkhand, Uttarakhand, Uttar Pradesh, and Gujarat




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13-year-old in Madhya Pradesh died trying to shoot hanging scene from tree, police find

While filming, the boy slipped from the wall and suffered a jerk in his neck. His friends did not realise this and assumed that he was still acting, official says




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Youth returning to Punjab from abroad, says CM; Akalis rubbish claim

CM Mann said the State Government has handed over appointment letters to 44,667 youth in various departments since it came to power




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Hindu man from Bangladesh becomes first person to get citizenship under CAA 

The Hindu man has been staying in Silchar town since 1988




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Thousands of decorative lights allegedly stolen from Ayodhya’s Ram Path and Bhakti Path

Complaint filed by contractor in charge of installation and maintenance said around 3,800 bamboo lights and 36 ‘gobo projector’ lights went missing in May




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Government working to increase Madhya Pradesh’s share in India’s economy to 5% from the current 4%: CM Mohan Yadav

In November, the State will launch the Yuva Shakti Mission for youth, the Nari Sashaktikaran Mission for women, the Kisan Kalyan Mission for farmers, and the Gareeb Kalyan Mission for the poor, the Chief Minister said in his Independence Day speech




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BJP has no leaders in Jharkhand, they ‘hire’ from other States to handle political scenario here: CM Hemant Soren

Without naming anyone, Mr. Soren said the Opposition is engaged in divisive politics and that there is no agenda or vision shown by them




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Not injured, withdrawal from Golden Spike meet a precautionary move, Neeraj Chopra clarifies

Neeraj Chopra said he would not want to risk injury in an Olympic year and hence decided to skip the prestigious meet.




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Stay calm, sleep well: PM Modi tells Paris-bound athletes; asks for mom-made ‘churma’ from Neeraj

The upcoming Games will be held from July 26 to August 11 and India would be hoping to better its best ever tally of seven medals, including Chopra's historic javelin throw gold, achieved in the Tokyo Games.




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Olympics-bound javelin thrower Kishore Jena says his father stopped him from quitting

Kishore Jena admitted that Neeraj Chopra's Tokyo Olympics gold medal motivated him to achieve more in his sport but he found it difficult to get the big throws and thought of quitting the sport in July last year




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From childhood restrictions to international glory, a septuagenarian’s remarkable athletic journey




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New guidelines for treatment of Type 2 diabetes from International Diabetes Federation soon

The guidelines are aimed at ensuring that while the science is not lost, they can be applied on to the environment in specific countries, by placing patients in the middle of the care model, said Peter Schwarz, president, IDF




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29th Climate Conference (COP) tracker | Key takeaways from U.N. chief’s speech and Day 1 discussions

Chetan Bhattacharji, who is at Baku for the first week of negotiations and The Hindu’s Jacob Koshy, will guide us through high-stakes conversations at COP29 at 5 p.m. on November 12




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Yemen's Houthi rebels are looking to gain from continuing conflict in Middle East

Recent Houthi attacks has again drawn attention to the Yemeni rebels and raised questions about their goals and strategies




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Multiple rocket launches identified from Lebanon since Yom Kippur fast began, says Israel

Israel shut down late on Friday afternoon for Yom Kippur, the Jewish Day of Atonement and the holiest day of the Jewish calendar




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Robot collects melted fuel from Fukushima nuclear reactor

Operated by Tokyo Electric Power Company Holdings, the robot collected a fragment measuring approximately 5 millimetres in size





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UEFA bans Barcelona fans from one Champions League game for Nazi-style flag

Barcelona was charged with “racism and/or other discriminatory conduct”




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Paul Pogba’s doping ban reduced from 4 years to 18 months

Four-year bans are standard under the world anti-doping code but can be reduced in cases where an athlete can prove their doping was not intentional, if the positive test was a result of contamination or if they provide “substantial assistance” to help investigators




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Mohun Bagan considered withdrawn from ACL 2: AFC

Mohun Bagan Super Giant had last month decided against travelling to Iran for the October 2 match owing to the volatile situation that prevailed in the west Asian nation at that time




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Cristiano Ronaldo misses late penalty as Al-Nassr eliminated from Saudi Cup

Ronaldo, who is yet to win a major trophy since signing for Al-Nassr, had converted all 18 of his previous penalties for the club but this time shot over the bar




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ISL: Majcen nets brace as Punjab come from behind to beat Chennaiyin

Luka Majcen, donning a mask after fracturing his jaw in its opening game versus Kerala Blasters, scored twice in three minutes while Asmir Suljic put the result beyond doubt with a third goal in the 70th minute




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ISL: Majcen nets brace as Punjab comes from behind to beat Chennaiyin




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Neymar picks up another injury in second game back from ACL tear

Neymar has time to recover before his next game, however, as he is not registered for the team’s matches in the Saudi Pro League and the next fixture in the AFC competition is on Nov. 25.




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Blasters keen to learn from negatives and move on




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Malabar Gold achieves 50% cost reduction from automation as gold prices go through the roof

The high prices may detract price-sensitive customers away, but he pins his hopes on the digital-savvy new generation to invest more in the gold



  • Gold & Silver

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RBI brings back 100 tonnes of gold reserves from UK vaults

Most countries keep their gold in the vaults of the Bank of England or some such location and pay a fee for the privileges



  • Gold & Silver

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After dipping 5% from peak, gold likely to decline further

The yellow metal set to lose its glitter on China pausing gold buys, US strong labour market



  • Gold & Silver

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India’s import of gold, silver from UAE rises 210% to $10.7 billion in 2023-24: GTRI

`Concessional customs duty under the India-UAE CEPA must be revised’