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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

By pubs.rsc.org
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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The millet makeover: Nutrihub, ICAR-IIMR’s technology business incubator for millet start-ups is a game changer

By www.thehindu.com
Published On :: Thu, 15 Jun 2023 15:09:23 +0530

Scientists at the Indian Institute of Millet Research are helping start-ups create products, from icecream to beer, with the grain at Nutrihub


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Divine incarnations

By www.thehindu.com
Published On :: Wed, 19 Oct 2016 00:01:56 +0530


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Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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Structural optimization of icaritin for advanced cancer: novel carbamates via oral administration

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05723B, Paper
Fengxiao Li, Weiping Wang, Jiaqi Fan, Yixiu Zhai, Jiaming Zhang, Tianhong Zhang, Qikun Jiang
Carbamates of icaritin (3N-Me and 3N-Et) are synthesized first to overcome the challenge of the phase II metabolism of ICT. 3N-Me has potential as a novel advanced cancer treatment agent via oral administration in the future.
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Boric acid-grafted biochar (BoAB) for the direct amidation of carboxylic acids and amines

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00745J, Paper
Adhish Singh, Mohit Kapoor
Boric acid grafted biochar was developed and explored for its potential in the amidation of unactivated carboxylic acids and amines under mild conditions.
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A boron nitride–carbon composite derived from ammonia borane and ZIF-8 with promises for the adsorption of carbon dioxide

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00643G, Paper
Open Access
Carlos A. Castilla-Martinez, Christophe Charmette, Jim Cartier, Umit B. Demirci
In the present study, we report the synthesis, characterization and assessment of the carbon dioxide adsorption capacity of a composite made of boron nitride and carbon.
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Peptide-linked perylenebisimide and ferrocene dicarboxylic acid conjugates with tunable optoelectronic properties

By pubs.rsc.org
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New J. Chem., 2024, 48,7225-7234
DOI: 10.1039/D3NJ05809C, Paper
Biswanath Hansda, Soumyajit Hazra, Niladri Hazra, Purnadas Ghosh, Arindam Banerjee
Peptide linked perylenebisimide and ferrocene dicarboxylic acid conjugates display wonderful and tunable optoelectronic properties.
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Mesoporous carbon hollow spheres loaded with Fe/Fe3C as efficient solar vapour generation materials

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New J. Chem., 2024, 48,7168-7175
DOI: 10.1039/D4NJ00424H, Paper
Jianfeng Gao, Hui Zhang, Zhaoshun Zhang, Changcheng Lin, Qun Yang, Shiwei Shi, Xueqin Zuo, Shaowei Jin, Guang Li
An evaporator has two major advantages: excellent interfacial evaporation efficiency and organic pollution treatment capacity.
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Adsorption behavior of chloramphenicol on an activated carbon from pomelo peel using KHCO3 activator

By pubs.rsc.org
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New J. Chem., 2024, 48,7081-7091
DOI: 10.1039/D3NJ05838G, Paper
Haixia Li, Hai Zhu, Junqiang Qiu, Danning Zheng, Lifang Gao, Dan Zhou, Dan Xu
The pomelo peel-based activated carbon as a high-performance adsorbent for chloramphenicol is synthesized by KHCO3 activator through a solid pyrolysis method.
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Gram-scale synthesis of aggregation-caused quenching-resistant red-emissive carbon dots for potential applications

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New J. Chem., 2024, 48,7265-7276
DOI: 10.1039/D4NJ00321G, Paper
Ashok Kumar, Kanchan Negi, Sumanta Kumar Sahu
This work describes the gram-scale synthesis of N/S-doped carbon dots for red emissive properties. The developed carbon dots can be used in WLEDs, fingerprinting, bioimaging, fluorescent ink, and room-temperature phosphorescence.
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Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

By pubs.rsc.org
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New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
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Effective synthesis of diethyl carbonate over Mg–Y composite oxides via alcoholysis of ethyl carbamate

By pubs.rsc.org
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New J. Chem., 2024, 48,7489-7496
DOI: 10.1039/D3NJ05757G, Paper
Peixue Wang, Shimin Liu, Xinjiang Cui, Yang Wu, Feng Shi
Effective synthesis of diethyl carbonate from ethyl carbamate and ethanol using Mg–Y composite oxides.
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Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors

By pubs.rsc.org
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New J. Chem., 2024, 48,7244-7255
DOI: 10.1039/D4NJ01100G, Paper
Jesús A. Lara-Cerón, Roberto Flores-Moreno, José A. Flores-Ramos, Gururaj K. Jayaprakash
Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors.
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Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

By pubs.rsc.org
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New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper
Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00555D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomohito Shinozuka, Daiki Shimizu, Kenji Matsuda
Radical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.
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KOH-mediated synthesis of amides from azides and 1,3-dicarbonyl compounds

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05813A, Paper
Zhuoran Yang, Yao Xu, Xiaoming Liao, Wenjun Wang, Chang Lyu, Xiaoxiang Zhang
Aryl amides were prepared through KOH-mediated [3+2] cycloaddition/Wolff rearrangement from organic azides and 1,3-dicarbonyl compounds.
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Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
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A robust dual-network hydrogel electrolyte coupled with a porous carbon material for flexible quasi-solid-state zinc ion hybrid supercapacitors

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00310A, Paper
Chenchen Ji, Xinhong Lin, Yang Hong, Junfeng Liu, Aoteng Liu, Yijia Yao, Sicheng Liu, Hongyu Mi
A hydrogel electrolyte was designed by constructing a multi-crosslinked network. The quasi-solid-state ZHSC based on the hydrogel electrolyte and HSSPC delivers a high specific capacity, high energy/power densities, and good cycle stability.
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Effect of Functionalized Multiwalled Carbon Nanotubes on Mechanical, Swelling and Viscoelastic Properties on Gum ghatti-cl-poly(NIPAm) Hydrogels

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01677G, Paper
Pragnesh N Dave, Pradip Macwan
The present work involves the Gum ghatti-cl-poly(NIPAm)/-o-MWCNT (GGNIPACNT) hydrogels via free radical polymerization technique. The synthesized hydrogels were characterized by FTIR analysis which suggested the successful binding of -o-MWCNT in...
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Sulfonic groups modified carbon nanotubes: the decorative strategy for enhancing the performance of lithium-sulfur batteries

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00927D, Communication
Chensong Yang, Yakun Tang, Yue Zhang, Xingyan Zeng, Mengyao Dai, Lang Liu
Porous carbon nanotubes can not only provide a large surface area for anchoring sulfur and restraining polysulfides, but also provide continuous conductive networks to facilitate ion transport in lithium-sulfur batteries...
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Selenium nanomaterials promoted ferredoxin and iron–sulfur protein synthesis and acetyl CoA carboxylase activity to improve the photosynthesis and fatty-acid synthesis in soybean

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00978E, Paper
Lian Zhang, Xiaona Li, Le Yue, Xuesong Cao, Bingxu Cheng, Chuanxi Wang, Zhenyu Wang
Herein, the effect of selenium engineered nanomaterials (Se ENMs) on soybean photosynthesis and fatty-acid synthesis by regulating ferredoxin (Fd) and iron–sulfur (Fe/S) protein synthesis and acetyl CoA carboxylase (ACC) activity was explored.
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The pulmonary effects of nickel-containing nanoparticles: cytotoxicity, genotoxicity, carcinogenicity, and their underlying mechanisms

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00929G, Critical Review
Yiqun Mo, Yue Zhang, Qunwei Zhang
This review summarized the cytotoxic, genotoxic, and carcinogenic effects of Ni-containing NPs on humans, lung cells in vitro, and rodent lungs in vivo, and the underlying mechanisms. Their extra-pulmonary effects were also briefly mentioned.
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Carbon nanotubes as a nanocatalyst and nanoreactor for the efficient treatment of pharmaceutical wastewater via CaSO3 activation

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00026A, Paper
Haoqi Wang, Xiaohong Liu, Yanlan Wang, Yiqun Tian, Yingping Huang, Di Huang, Xiang Liu
Herein, carbon nanotubes (CNTs) are reported as an efficient catalyst and nanoreactor for activating CaSO3 for water decontamination.
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Impact of CeO2 nanoparticles on the microbiota of the S. flos-cuculi L. (Caryophyllaceae) rhizosphere

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00479A, Paper
Open Access
M. Civilini, A. Colautti, A. Brunello, N. Saccomanno, L. Marchiol, A. Foscari, L. Iacumin
Influence of cerium oxide nanoparticles (nCeO2) on root bacterial composition and the associated substrate (root zone soil) of Silene flos-cuculi (L.) by metabarcoding.
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Carbon NPs seize the accumulation of storage proteins and check the generation advancement of polyphagous insect pest tobacco cutworm Spodoptera litura (Fabricius)

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00939D, Paper
Manisha Mishra, Rashmi Pandey, Ranjana Chauhan, Sharad Saurabh, Anoop Shukla, Sheelendra Pratap Singh, Pradhyumna Kumar Singh, Farrukh Jamal
Spodoptera litura (Lepidoptera: Noctuidae) is considered one of the most important agricultural pests, globally. It is a highly prevalent and very damaging insect pest to several vegetables and crops like...
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Carbon dot-embedded hydrogels promote maize germination and growth under drought stress

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00070F, Paper
Yuying Ren, Xiaona Li, Bingxu Cheng, Le Yue, Xuesong Cao, Chuanxi Wang, Zhenyu Wang
Tannic acid derived carbon dot (TACD)-embedded gelatin hydrogels (GTACDs) were formed by hydrogen bonding and electrostatic interactions, which as seed coating were applied to drought soil to enhance crop drought resistance and growth.
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Characterization of black carbon and silica nanoparticle interactions with human plasma proteins

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00773A, Communication
Si-si Chen, Hong-juan Chen, Xue-wen Guo, Wei-juan Zheng, Hong-zhen Lian
Black carbon and silica nanoparticles, modeling different sources of PM, differ in protein corona composition and effects on protein structure.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Fe–carbon nanofiber-modified Mo-MOF for the controlled release and translocation of micronutrients in plants

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1597-1611
DOI: 10.1039/D3EN00833A, Paper
Komal Pandey, Rishabh Anand Omar, Nishith Verma, Govind Gupta
Fe-CNF/Mo-MOF releases Mo and Fe in soil upon degradation by resident rhizobacteria and translocates the micronutrients to plant roots, shoots, and leaves.
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Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
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Nanoscale control over water-film thickness using temperature modulation: tuning mineral carbonation reactivity

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1412-1416
DOI: 10.1039/D3EN00884C, Communication
Open Access
Christopher J. Thompson, Sebastian T. Mergelsberg, Bavan P. Rajan, Paul F. Martin, Sebastien N. Kerisit, John S. Loring
Temperature modulation was demonstrated as a novel way to control water partitioning during the reaction of silicate minerals with water-saturated supercritical carbon dioxide.
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Recycling and repurposing of waste carbon nanofiber polymers: a critical review

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1394-1411
DOI: 10.1039/D3EN00784G, Critical Review
Zhihao Liu, Zhijie Chen, Zimin Wang, Daijun Zhang, Bing-Jie Ni
Carbon nanofibers are a class of lightweight, high-performance composite materials.
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Rational construction of micro-plate-like iron oxide/aluminium oxide-fabricated screen-printed carbon electrode for the electrochemical detection of the antiandrogen drug

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1521-1532
DOI: 10.1039/D3EN00808H, Paper
Sivakumar Musuvadhi Babulal, Nandini Nataraj, Tse-Wei Chen, Shen Ming Chen, Bih-Show Lou, Arshad Mehmood Abbasi, Amal M. Al-Mohaimeed, Mohamed Soliman Elshikh, Jaysan Yu
An improved electrochemical sensing platform with a vital strategy for NTM antiandrogen drug detection in real environmental and biofluid samples.
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Sulfur-doped porous carbon sheets embedded with rich iron sites for 1O2 dominated peroxymonosulfate activation

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00971H, Paper
Yadan Song, Yalong Liu, Yangju Li, Haipeng Hu, Kexin Huang, Zhe Zhang, Zhongxian Li, Wanning Cao, Kai Jiang, Dapeng Wu
Porous carbon films co-doped with iron, nitrogen, and sulfur were synthesized via a one-step pyrolysis process, which have multiple active sites and can produce bulk 1O2 through PMS activation, which is effective in phenol degradation.
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Consequences of twisting of the flexible arms of imidazole-derived urea in zinc-dicarboxylate coordination polymers

By pubs.rsc.org
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CrystEngComm, 2024, 26,1976-1985
DOI: 10.1039/D4CE00005F, Paper
Satyendra Verma, Rinki Brahma, Jubaraj B. Baruah
A semi-flexible imidazole-based urea ligand, 1-(3-(1H-imidazol-1-yl)propyl)-3-phenylurea, and three zinc-dicarboxylate coordination polymers possessing the ligand were synthesized and characterized.
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Construction of CsPbBr3/carboxyl-modified rGO heterostructures for efficient photocatalytic reduction of CO2 to methanol

By pubs.rsc.org
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CrystEngComm, 2024, 26,1994-2002
DOI: 10.1039/D4CE00036F, Paper
Meng Li, Jingtao Xu, Yang Song, Yuanyuan Li, Jin Wang, Feiyong Chen
Construction of monodispersed CsPbBr3 NCs and carboxyl-modified rGO composites led to the production of CO and CH3OH with an Relectron of 359 μmol g−1 h−1 by photocatalytic CO2 reduction.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

By pubs.rsc.org
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CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Musk says Twitter is losing cash because advertising is down; company is carrying heavy debt

By www.thehindubusinessline.com
Published On :: Sun, 16 Jul 2023 09:02:02 +0530

Need to reach positive cash flow before we have the luxury of anything else: Elon Musk


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Two-quarters of no disruptions will help revive entry-level bike and cars segments: FADA chief  

By www.thehindubusinessline.com
Published On :: Fri, 12 Aug 2022 16:53:35 +0530

The EV segment needs to deliver good quality products, said Vinkesh Gulati


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Car sales declined by 7% in December

By www.thehindubusinessline.com
Published On :: Fri, 13 Jan 2023 19:58:24 +0530

But utility vehicle segment grew 23% year-on-year: SIAM data


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30BestBarsIndia announces its list: Sidecar wins the title for the best bar in the country

By www.thehindu.com
Published On :: Wed, 18 Jan 2023 14:30:17 +0530

On the night before 30BestBarsIndia announced its list, nominees partied hard in Delhi, in a joyful chaos of cocktails and reunions. 


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  • Life & Style
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Car accident: pedestrian awarded ₹92 lakh compensation

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 19:41:49 +0530

Highest compensation awarded in Kerala to those rendered bedridden by accidents


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Card is king; small eateries struggle to retain clients

By www.thehindu.com
Published On :: Wed, 16 Nov 2016 07:48:20 +0530


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Used car sales in slow lane

By www.thehindu.com
Published On :: Fri, 18 Nov 2016 09:29:56 +0530

What effect has the demonetisation decision had on our lives? The Hindu’s reporters fan out across neighbourhoods, professions and industries to find out. Today, we look at how transactions are at a standstill for used cars sellers and buyers


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The central bank's dilemma [electronic resource] : look through supply shocks or control inflation expectations? / Paul Beaudry, Thomas J. Carter, Amartya Lahiri

By darius.uleth.ca
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Cambridge, MA. : National Bureau of Economic Research, 2023


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