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13-year-old in Madhya Pradesh died trying to shoot hanging scene from tree, police find

While filming, the boy slipped from the wall and suffered a jerk in his neck. His friends did not realise this and assumed that he was still acting, official says




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Why Himalayan towns need a different kind of development | Explained

Do cities along the Indian Himalayan Range have adequate funds and resources to manage civic issues?




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Two coaches of passenger train derail in Madhya Pradesh

The train movement on the track remained hindered for nearly three hours




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Madhya Pradesh Government orders colleges to buy set of 88 books, most of which are written by authors with links to RSS

Colleges have also been asked to set up ‘Bharatiya gyaan parampara’ cells




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Multiple wagons of goods train derailed in Madhya Pradesh




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Thousands of decorative lights allegedly stolen from Ayodhya’s Ram Path and Bhakti Path

Complaint filed by contractor in charge of installation and maintenance said around 3,800 bamboo lights and 36 ‘gobo projector’ lights went missing in May




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Government working to increase Madhya Pradesh’s share in India’s economy to 5% from the current 4%: CM Mohan Yadav

In November, the State will launch the Yuva Shakti Mission for youth, the Nari Sashaktikaran Mission for women, the Kisan Kalyan Mission for farmers, and the Gareeb Kalyan Mission for the poor, the Chief Minister said in his Independence Day speech




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Madhya Pradesh Cabinet meets in tribal queen’s capital on her 500th birth anniversary

The Cabinet has approved additional assistance of up to ₹3,900 per hectare to farmers under the Rani Durgavati Shri Anna Protsahan Yojana, over the minimum purchase price




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Jeswin Aldrin, Ankita Dhyani make Olympics cut, Indian athletics team strength rises to 30

The Indian athletics team will now have 30 members; the track and field competitions will begin on August 1




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Annu Rani wins women’s javelin; Lalu Prasad and Nithya emerge 100m winners




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Food companies sell products that are less healthy in poorer countries, says report

Products sold by companies including Nestle, Pepsico and Unilever were assessed as part of a global index published by the Access to Nutrition Initiative




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Is there a scientific reason why online phishing fraudsters target senior citizens?

A research paper documents the fact that older people tend to underestimate their cognitive decline and this could affect their finances; experts say senior citizens could be more vulnerable to cyber scamsters and to financial abuse from their own families




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AAPI Chief Dr Kathula suggests fast-track green cards for Indian physicians in the US

Voices concerns that there are many physicians who are still on H-1B work visas even after staying in the US for over 15-20 years.




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Vice President Harris is in ‘excellent health,’ physician says

Her most recent physical exam in April was “unremarkable,” Simmons added




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US and India can work together on mental health, says US Surgeon General Vivek Murthy

US Surgeon General Murthy says it is time to prioritise and accelerate the work on mental health, because the consequences have been too high




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India-Germany sign multiple MoUs on green hydrogen, technology & trade

Prime Minister Narendra Modi meeting with German Chancellor Olaf Scholz follows signing of multiple treaties, agreements on Mutual Legal Assistance Treaty in Criminal Matters and Indo-German Green Hydrogen Road Map




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Trump wins Pennsylvania, leaving him 3 electoral votes shy of clinching White House

Pennsylvania was carried by Trump when he first won the White House in 2016 and then flipped back to Democrats in 2020. Trump also took Georgia, which had voted for Democrats four years ago




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Punjab FC meets Hyderabad FC, hopes to make it three wins in a row




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ISL | Punjab downs Hyderabad, continues in its merry way

The home team’s 2-0 win takes it to the top of the table with three victories from three outings; Singto’s men, languishing at the bottom with two losses in as many games, have their task cut out; HFC’s D’Cunha gets ejected for a second yellow




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Messi scores twice for Inter Miami to win his 46th career trophy —MLS Supporters Shield

Lionel Messi and Inter Miami have another trophy, along with home-field advantage throughout the Major League Soccer playoffs




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The purity paradox: Why gold’s fineness matters in your investment 

The precious metal’s brilliance lies not just in its physical form, but also in its adaptability to diverse investment strategies



  • Gold & Silver

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Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02496F, Paper
Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena Shubina
Octahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
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Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02901A, Paper
Maxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia Spitsyna
The hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...
The content of this RSS Feed (c) The Royal Society of Chemistry




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The Bonding Situations in Ruthenium Chalcogenonitrosyl Compounds: A Physical Reasoning

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02680B, Paper
Richard Fragnani Cardoso, Vinícius Acir Glitz, Renato Luis Tame Parreira, Giovanni Finoto Caramori, Luis Henrique Silveira Lacerda
This research presents, for the first time, a comprehensive and rigorous investigation of ruthenium(II) chalcogenonitrosyl bonding situations in two sets of coordination compounds: [Ru(NE)Cl2(L_{OEt})] (1a-4a) and [Ru(NE)Cl2(L_{OEt})]- (1b-4b), where E...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Indium-Catalyzed Hydrosilylation of Nitroarenes to Aromatic Amines

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02861A, Paper
Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda
Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures...
The content of this RSS Feed (c) The Royal Society of Chemistry




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The preparation of CuM/SiO2 (M=Bi, Mg, Mn) catalysts applied in ethynylation of formaldehyde for 1,4‑butynediol synthesis: the positive interface effect of CuO and Bi2O3

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02616K, Paper
Jiali Chen, Guihua Yang, Feng Gao, Rui Wang
The ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why do we succumb to pressure?




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Permeating partiarchy

It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family




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Physics in 2018

Physics World journalists discuss what excites them about the year ahead




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Handbook of art therapy [electronic resource] / edited by Cathy A. Malchiodi.

New York : Guilford Press, 2012.




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Why people smoke [electronic resource] : an innovative approach to treating tobacco dependence / Frank T. Leone and Sarah Evers-Casey ; with illustrations by Joey Leone.

Philadelphia : University of Pennsylvania Press, [2023]




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Ranji Trophy | Denish and Purkayastha give Assam the first-innings lead against TN

The captain’s 173-run association with Sibsankar for the fourth wicket turns the tide the hosts’ way; Pradosh picks up three wickets




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ICC Champions Trophy: Team India not to play in Pakistan, declares BCCI

BCCI decision comes despite Pakistan Cricket Board offering special security arrangements, choice of venue; India favours having its matches outside Pakistan under hybrid model




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Ranji Trophy | Jagadeesan tons up again as TN battles to a draw against Assam

Pradosh chips in with a half-century as the team reaches 217 for two in its second essay; the host clinches three points for its first-innings lead while the visitor gains a point




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Ranji Trophy | Mulani scalps memorable five in outing against Odisha

His 15th five-wicket haul results in Mumbai earning a bonus point following an innings win; Himanshu picks four as Swain, Biswal contributions go in vain




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Ranji Trophy | Sudip’s unbeaten ton, the silver-lining in Karnataka-Bengal stalemate

Saha’s fifty quashes hopes of a comeback by the hosts; Smaran, Shreyas and Manish take their side to safety after a shaky start; Mayank puts the onus on the batters to iron out their flaws