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A safe and new strategy for N-arylation of 2,4-thiazolidinediones via microwave irradiation using base catalyst K2CO3 in DMF

React. Chem. Eng., 2024, 9,842-848
DOI: 10.1039/D3RE00641G, Paper
Ragini C. Patil, Nita M. Khiratkar, Sumeer Ahmed, Joazaizulfazli Jamalis, Aso Hameed Hasan, Malika Berredjem, Sarkar M. A. Kawsar, Ajmal R. Bhat
Green efforts as an alternative to existing conventional methods for providing new tools, knowledge and design of organic synthesis, will contribute to the economy and protecting the environment and health.
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Encapsulation of TixFeyLamOz nanoparticles into NH2-MIL-125(Ti) to fabricate a promising photocatalyst for the C–N coupling reaction

React. Chem. Eng., 2024, 9,849-860
DOI: 10.1039/D3RE00457K, Paper
Yahya Absalan, Mohammad Rafsanjani Dehghazi, Reza Samavati, Kambiz Souri, Mostafa Gholizadeh
An array of organic compounds and natural products can be synthesized through carbon–nitrogen coupling reactions.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption

React. Chem. Eng., 2024, 9,816-824
DOI: 10.1039/D3RE00513E, Paper
Pariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta Chareonpanich
In this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.
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Understanding the effects of forced and bubble-induced convection in transport-limited organic electrosynthesis

React. Chem. Eng., 2024, 9,930-939
DOI: 10.1039/D3RE00579H, Paper
Casey K. Bloomquist, Melisa Dogan, James S. Harris, Benjamin D. Herzog, William J. Tenn III, Eray S. Aydil, Miguel A. Modestino
Insights from data-driven surrogate models reveal that the Sherwood number characterizes mass transport conditions independent of the convection method, offering design guidelines for scaling up organic electrosynthesis.
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Continuous flow synthesis of the ionizable lipid ALC-0315

React. Chem. Eng., 2024, 9,959-966
DOI: 10.1039/D3RE00630A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakob B. Wolf, Ju Weon Lee, Matthew B. Plutschack, Dario Cambié, Andreas Seidel-Morgenstern, Peter H. Seeberger
The ionizable lipid ALC-0315 is the major component of the lipid nanoparticles used to encapsulate the mRNA in the Biontech–Pfizer COVID-19 vaccine.
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Interaction of SO2 with a Cu–Mn oxide oxygen carrier during chemical looping with oxygen uncoupling

React. Chem. Eng., 2024, 9,888-900
DOI: 10.1039/D3RE00498H, Paper
Turna Barua, Bihter Padak
During chemical looping combustion with oxygen uncoupling (CLOU) fuel-sulfur species impact the reactivity of Cu–Mn oxide oxygen carrier with CH4. SO2 oxidation to SO3 competes with fuel for available O2 and lowers CH4 conversion.
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From microkinetic model to process: understanding the role of the boron nitride surface and gas phase chemistry in the oxidative dehydrogenation of propane

React. Chem. Eng., 2024, 9,795-802
DOI: 10.1039/D3RE00600J, Paper
Unni Kurumbail, William P. McDermott, Edgard A. Lebrón-Rodríguez, Ive Hermans
In the oxidative dehydrogenation of propane over boron nitride, propylene selectivity is lost due to unselective gas-phase chemistry.
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Biomass-based graphene aerogel for the removal of emerging pollutants from wastewater

React. Chem. Eng., 2024, 9,753-776
DOI: 10.1039/D3RE00526G, Review Article
Vijayendra Kumar Tripathi, Manish Shrivastava, Jaya Dwivedi, Raju Kumar Gupta, Lokesh Kumar Jangir, Kumud Malika Tripathi
This review article provides a detailed overview of the synthesis techniques of biomass-based graphene aerogels and highlights the influence of fabrication parameters on the performance of the resulting aerogels for wastewater treatment applications.
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Digital Pareto-front mapping of homogeneous catalytic reactions

React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Surface treatment of magnetite nanoparticle thin films with potassium phosphate for calcium phosphate precipitation

React. Chem. Eng., 2024, 9,782-786
DOI: 10.1039/D4RE00048J, Communication
Reo Kimura, Kazuto Sugimoto, Iori Yamada, Motohiro Tagaya
The treatment of magnetite nanoparticle thin films with potassium phosphate and their surface reaction with simulated body fluid were in situ monitored by the QCM-D technique, which is suitable for the precipitation of calcium phosphate.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Determination of intermediates and products of the uranyl aerosol formation in UF6 hydrolysis in the gas phase

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian Mark Salvador, Jason M. Richards, Shannon M. Mahurin, Meng-Dawn Cheng, Joshua A. Hubbard
A graphical representation of the uranyl aerosol formation.
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Comprehensive Study of Lumped Kinetic Models and Bio-Oil Characterization in Microwave-Assisted Pyrolysis of Sargassum sp.

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00674C, Paper
Teta Fathya Widawati, Muhammad Fuad Refki, Rochmadi Rochmadi, Arief Budiman
Indonesia, renowned for its tropical marine environments, boasts a rich diversity of macroalgae, with Sargassum being a major contributor. Currently, Sargassum's primary application revolves around alginate extraction, prompting a systematic...
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Automated kinetic model identification via cloud services using model-based design of experiments

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00047A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emmanuel Agunloye, Panagiotis Petsagkourakis, Muhammad Yusuf, Ricardo Labes, Thomas Chamberlain, Frans L. Muller, Richard A. Bourne, Federico Galvanin
Industry 4.0 has birthed a new era for the chemical manufacturing sector, transforming reactor design and integrating digital twin into process control.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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On a seamlessly replicable circular photoreactor for lab-scale continuous flow applications

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00109E, Paper
Yi-Hsuan Tsai, Martin Cattoen, Guillaume Masson, Gabrielle Christen, Lisa Traber, Morgan Donnard, Frederic R. Leroux, Guillaume Bentzinger, Sylvain Guizzetti, Jean-Christophe M. Monbaliu
A cost effective and replicable continuous flow circular photoreactor system is introduced. All body parts of the reactor are 3D-printed and the electronics are purchased from various mainstream suppliers. The...
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Scaling-up continuous production of mesoporous silica particles at kg scale: design & operational strategies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00707C, Paper
Rajashri B. Jundale, Jayesh R. Sonawane, Anil V. Palghadmal, Hemant Kumar Jaiswal, Hital S. Deore, Amol A. Kulkarni
This paper demonstrates a continuous flow pilot-scale production of highly porous mesoporous silica particles (MSPs) via a soft template based technique.
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Hydrothermal liquefaction of plastics: a survey of the effect of reaction conditions on the reaction efficiency

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D2RE00510G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthijs Justin Boel, Hongqi Wang, Ahmad AL Farra, Laura Megido, José Manuel González-LaFuente, N. Raveendran Shiju
Plastic waste is a major global issue and hydrothermal liquefaction is a promising technique for the chemical recycling of waste plastics. This review summarises the effect of reaction conditions on the liquefaction efficiency.
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Correction: Applying quantum mechanics to deconvolute benchtop 1H NMR reaction data

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90015D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiayu Zhang, Tristan Maschmeyer, Ben Shapiro, Sunil Babu Paudel, Matthew C. Leclerc, Jason E. Hein
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Synthesis and kinetic study of 1,3,2-dioxathiolane 2,2-dioxide in microreactors

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00123K, Paper
Ting Wang, Junnan Wang, Chengxiang He, Zhongdong Wang, Yating Li, Chunying Zhu, Youguang Ma, Taotao Fu
1,3,2-dioxathiolane 2,2-dioxide (DTD) is an essential intermediate in organic synthesis and plays a vital role in improving the performance and service life of lithium-ion batteries. A large amount of heat...
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Generation of nitrogen by means of electrochemical oxygen depletion

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00104D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Sachse, Basil Noha Chelachottil, Andreas Glüsen, Martin Müller, Uwe Rau, Ralf Peters
Electrochemical oxygen reduction enables a high depletion of the oxygen content with very high Faraday efficiency at the same time.
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Efficient removal of dibutyl phthalate from aqueous solutions: recent advances in adsorption and oxidation approaches

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00055B, Review Article
Yaqi Wang, Jiawei Wu, Wenju Zhang, Linyun Zhong, Dan Zhang, Siqi Yan, Junyou Shi
Dibutyl phthalate (DBP), a recognized endocrine-disrupting contaminant, poses substantial environmental challenges due to its persistence, resistance to degradation, and potential for bioaccumulation.
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Experimental Investigation of Mass Transfer in NH3 SCR Over Self-Supporting Cu-ZSM-5 Foam

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00533J, Paper
Risha Raju, Kuruvilla Joseph, K. Prabhakaran, A. Salih
Selective catalytic reduction of NOx by NH3 is an emerging technology for emission control applications worldwide. The development of structured catalysts for process intensification is of growing interest in catalytic...
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Bridgestone invests $85 million to boost premium tire production and development in India

Investment to focus on Bridgestone’s Pune and Indore manufacturing plants, with production capacity at the Pune plant set to increase by 1.1 million tires annually by 2029




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Shoppers Stop aims to scale up beauty distribution, bring more international brands to India

Shoppers Stop expects Global SS Beauty to end this fiscal with revenues to the tune of ₹220-250 crore




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Inteva Products to expand manufacturing facility in Pune with $3.3 million investment

Inteva Products’ expansion project to increase the plant’s production space by 70 per cent, to a total of 85,000 square feet




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Ola Electric sees 5% y-o-y loss reduction to ₹495 crore for Q2FY25

Revenue for the quarter under review increased by 38.5 per cent y-o-y to ₹1,240 crore from ₹896 crore in the year-ago period




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SIS Ltd eyes strategic acquisitions in India

Plans listing of cash logistics joint venture




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Tesla market value hits $1 trillion as Trump win fans optimism for Elon Musk’s companies

Musk’s companies are expected to get favourable treatment in the Trump regime, for the support he extended to the Trump campaign




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UnifyApps raises $20 million in Series A funding to deliver AI agents across enterprise

Iconiq Growth has invested in companies like Airbnb, Uber and Snowflake. ICONIQ Growth General Partner Matt Jacobson has joined UnifyApps’ board of directors as part of the new funding




io

PFC turns down $2.4 billion debt to Shapoorji

With the latest move, the company may have to find new ways to raise money




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HUL, fintech SRO raise concerns over Trai’s new rules for transactional messages

The Telecom Regulatory Authority of India, in a consultation paper issued in September, has suggested that users will have the option to opt out of receiving transactional messages




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Singapore Airlines to invest additional ₹3,195 crore in Air India post-Vistara merger

The merger will result in Singapore Airlines having a 25.1% stake in the enlarged Air India




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Debt at Vedanta Resources cut by $4.7 billion: Anil Agarwal

Vedanta’s Agarwal says the company has delivered its highest-ever EBITDA of ₹Rs 20,639 crore in the first half of the current fiscal year




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Zomato launches Food Rescue initiative to prevent wastage due to cancellations

The platform said that every month, about four lakh food orders are cancelled, posing a serious challenge




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Bhanzu secures $16.5M Series B led by Epiq Capital; poised for US expansion

Bhanzu CEO: The U.S. math education market has significant potential, but it is dominated by large, billion-dollar companies that have not innovated their curricula or effectively embraced technology




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KFC, Pizza Hut operator Devyani International posts net loss of ₹4.92 crore, revenues up 49%

The company also announced that it has secured Exclusive Master Franchise rights for three new QSR brands which include TeaLive, New York Fries and Sanook Kitchen




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India’s gaming industry soars to $3.8 billion, set to reach $9.2 billion by FY29: Report

The report, developed in collaboration with Google and Deloitte, shows that India is the world’s second-largest mobile gaming market, recording 15.2 billion downloads




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Post US President elections, China may look at reducing steel exports: Tata Steel MD

oOur projects are moving at the right pace, says TV Narendran




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Raghu Vamsi Group acquires UK-based PMC Group for 7.7 million pounds

It will also invest 2 million pounds towards working capital.




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Hindalco Q2 net up 78% on lower cost, better realisation

The revenue of Hindalco increased seven per cent to Rs ₹58,203 crore (Rs ₹54,169 crore)




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Wheelocity secures $15 million to transform e-commerce in semi-urban India 

Originally a B2B platform, Wheelocity has transitioned to a B2C model, now serving over 1 million households across 3,500 towns and villages




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A riot of colours

Wild ornamentals like daffodils, primroses and violets can transform your garden into a haven during springtime, says R. Pauline Deborah