io Folding of a dynamic macrocyclic system to stabilize its cation radical state By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01566E, Research ArticleArnab Dutta, Krzysztof Dzieszkowski, Marco Farinone, Łukasz Orzeł, Krzysztof Kruczała, Monika Kijewska, Miłosz PawlickiA precisely designed π-extended system responds to different stimuli by folding the structure, which prevents overoxidation and stabilizes the cation radical.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01600A, Research ArticleYongfeng Wang, Ruijun Chu, Yanxiao Wang, Mengyuan Zhou, Yuan Chen, Cheng Xu, Jingyu Sun, Guodong YinA novel class of heterocyclic AIEgens has been synthesized via a multicomponent reaction of isatins, 2,3-diaryl cyclopropenones, and alkyl bromides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Recent advances in carbon atom addition for ring-expanding single-atom skeletal editing By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01806K, Review ArticleTing Yuan, Lei ShiThis review focuses on recent advances in carbon atom addition for ring-expanding single-atom skeletal editing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io A Stereoselective Organocatalyzed C-Glycosylation of Indole: Implications of Acceptor-Catalyst-Donor Interaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01873G, Research ArticleLihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa XuA stereoselective pyridinium hexafluorophosphate-catalyzed C-glycosylation of indole is presented, featuring the plausible formation of a catalyst-acceptor complex and a crucial H-bond between the indole N-H and the oxygen at C6...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01963F, HighlightYingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie WuAs the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Thiocyanoalkylation of Alkenes via Dual Photoredox and Copper Catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01864H, Research ArticleXu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua ZhangOrganic thiocyanates are commonly used as an essential organic synthesis intermediate and widely present in various drug molecules and bioactive molecules. Herein, a copper and photoredox catalyzed thiocyanoalkylation reaction of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01627K, Research ArticleBo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long ZhuWe report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Integrating electrocatalysis with biocatalysis for asymmetric synthesis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01899K, HighlightYuqi Lin, Jiage Yu, Ke-Yin YeThis highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01832J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh HariharanAchieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00984C, Research ArticleGuolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming MaChiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01870B, Research ArticleLijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng YuWe developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01877J, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cintya Pinilla, Mario García-Zarza, Ana C. AlbénizThe mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01573H, Research ArticleZhaolin Quan, Yubo Duan, Zhengkai ChenA straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01831A, Research ArticleJiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang LiA method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01714E, Research ArticleKe Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang SunTransition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01810A, Research ArticleÁngel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-CastellsCyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01589D, Research ArticleXinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah HamzeThe well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01879F, Research ArticleYuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin FanOxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01592D, Research ArticleBin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao HeThe development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01734J, Research ArticleYuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing LiTransition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01913J, Research ArticleXue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang ShenAlkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:06:15 +0530 Full Article Telangana
io Mahabubnagar District Education Officer in ACB net By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:16:55 +0530 Full Article Telangana
io TGSRTC Karimnagar region to operate special buses to Arunachala Hill in Tamil Nadu on November 13 By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:04:23 +0530 Full Article Telangana
io Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district By www.thehindu.com Published On :: Thu, 07 Nov 2024 23:19:05 +0530 Full Article Telangana
io Nampally court takes cognisance of ED’s prosecution complaint against AgriGold By www.thehindu.com Published On :: Fri, 08 Nov 2024 03:03:10 +0530 Full Article Telangana
io No more parties without permission: Telangana Excise Dept. to farmhouse owners By www.thehindu.com Published On :: Fri, 08 Nov 2024 19:42:15 +0530 Full Article Telangana
io Cockroach infestation found at CCMB canteen; hygiene violations flagged at Nacharam restaurants By www.thehindu.com Published On :: Sat, 09 Nov 2024 18:01:58 +0530 Full Article Hyderabad
io U.S. doctors explore institutional collaboration with NIMS By www.thehindu.com Published On :: Sat, 09 Nov 2024 19:38:44 +0530 Full Article Hyderabad
io Commotion at BRS dharna in Huzurabad, vehicular traffic disrupted on highway By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:29:37 +0530 Full Article Telangana
io District Consumer Commission dismisses complaint against Google Pay due to lack of evidence By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:36:08 +0530 Full Article Telangana
io Mental health and resilience in higher education institutions as a mission By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:10:51 +0530 A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing Full Article Telangana
io Apprehensions aplenty in Hyderabad about caste survey By www.thehindu.com Published On :: Sat, 09 Nov 2024 23:51:46 +0530 Many residents refuse to share details, with some regarding questions too intrusive and some wary about data privacy and identity of enumerators in the backdrop of rising scams; officials face public ire over unfulfilled government promises and outcome of ‘Praja Palana’ applications Full Article Telangana
io Man, friend killed in car-bus collision after attending sister’s wedding reception By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:10:31 +0530 Full Article Telangana
io Telangana delegation to embark on 3-day study tour in Karnataka for fisheries development By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:30:13 +0530 Full Article Telangana
io Guru Nanak’s 555th birth anniversary celebrations to begin in Hyderabad on November 11 By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:48:15 +0530 Full Article Telangana
io Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:40:20 +0530 Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice Full Article Telangana
io Explosion at restaurant injures four in Hyderabad’s Jubilee Hills By www.thehindu.com Published On :: Sun, 10 Nov 2024 22:49:03 +0530 Full Article Telangana
io Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana By www.thehindu.com Published On :: Sun, 10 Nov 2024 23:47:20 +0530 Full Article Telangana
io Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief By www.thehindu.com Published On :: Mon, 11 Nov 2024 11:34:20 +0530 He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore Full Article Telangana
io Hyderabad-based Raghu Vamsi Group acquires British precision machining firm PMC Group By www.thehindu.com Published On :: Mon, 11 Nov 2024 14:55:02 +0530 The Hyderabad-based MSME, Raghu Vamsi Group, has completed the acquisition of British precision machining firm PMC GGroup, that traces its roots to over 100 years Full Article Hyderabad
io Modi’s parivar stands for division of people and Gandhi parivar works for country’s unity: Telangana CM Revanth By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:51:35 +0530 Referring to the lack of minority representation in his Cabinet, the Chief Minister attributed it to the absence of a Muslim MLA in Telangana Full Article Telangana
io Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:05:04 +0530 The new order comes into effect from November 11 until further notice, said the commissioner Full Article Hyderabad
io Watch: ‘I am prepared to face political repercussions’: Revanth Reddy on HYDRAA By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:54:00 +0530 Telangana Chief Minister A. Revanth Reddy made it clear that the government is not going to spare encroachers and that HYDRAA has been given full powers Full Article Videos
io Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:48:38 +0530 Full Article Telangana
io Cyberabad police impose restrictions near exam centres on November 17 and 18 By www.thehindu.com Published On :: Tue, 12 Nov 2024 11:42:16 +0530 Full Article Hyderabad
