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Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials

Inorg. Chem. Front., 2024, 11,2471-2478
DOI: 10.1039/D4QI00233D, Research Article
Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
An efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor

Inorg. Chem. Front., 2024, 11,2436-2441
DOI: 10.1039/D3QI02685J, Research Article
Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
D–J phase perovskite (BDA)MA2Pb3Br10 reveals excellent photo-responsivity antifatigue merits and remarkable switching stability.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
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Dual-drive acoustic micromixer for rapid nucleation and ultrafast growth of perovskite nanoparticles

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00721B, Paper
Zhifang Liu, Yuwen Lu, Wei Tan, Guorui Zhu
An acoustic micromixer driven by bubbles and sharp edges, controlling the nucleation and growth of perovskite nanoparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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kit

KITE gives technological edge to coverage of State school sports meet




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Design and fabrication of La-based perovskites incorporated with functionalized carbon nanofibers for the electrochemical detection of roxarsone in water and food samples

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00264D, Paper
Mariya Antony John Felix, Santhiyagu Sahayaraj Rex Shanlee, Shen-Ming Chen, Sundaresan Ruspika, Ramachandran Balaji, Narendhar Chandrasekar, Periyanayagam Arockia Doss
Fabrication of potent electrocatalyst, La-based perovskites coupled with functionalized carbon nanofibers (LMO/f-CNF) for ultrasensitive electrochemical detection of roxarsone in edible and water samples.
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kit

598: Jen Simmons on Interop, WebKit Releases, and New CSS Features in Safari

Jen Simmons, Apple Evangelist on the Web Developer Experience team for Safari & Webkit, stops by to talk about what Interop is, and a look ahead at new CSS features in Webkit and Safari such as JPEG XL, masks, a round function, JavaScript improvements, styling form controls, content unblocks, masonry, and more!




kit

Taking roots in Tirupati, ‘Konark’ set to reach the kitchens of Odisha and Bengal




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Kitsch and tell

A burst of colours, quirky motifs and all things India-inspired... A. SHRIKUMAR hands out tips on how to embrace this trend




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Kerala School Sports & Games 2024: KITE beams 100 hours of live feed and uploads whopping 5,000 images during week-long event

The challenge was met impressively thanks to efforts of 70 technical staff from KITE and 300 members of Little KITES, IT clubs from 31 schools in Ernakulam district




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Pulkit TMT introduces innovative ‘Lab on Wheels’ for quality testing in Kerala 

The initiative aims to raise awareness about the significance of using high-quality TMT bars in construction projects and empower consumers, builders, and dealers to make informed decisions about their steel choices.




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Kitsch kitsch hota hai

Sixty five years after Independence, we are learning to be less apologetic about ourselves. Indian designers are embracing street culture with a vengeance.



  • Life & Style

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Delhi International Kite Festival 2012

Delhi Tourism hosted the second edition of its International Kite Festival.




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Mamallapuram to host Tamil Nadu International Kite Festival for the first time

The maiden edition of Tamil Nadu Kite Festival is set to see custom kites, brought in by professionals from USA, Thailand, Malaysia and India, take flight



  • Life & Style

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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Investigation of variable range hopping and dielectric relaxation in GdCrO3 orthochromite perovskites

RSC Adv., 2024, 14,36161-36172
DOI: 10.1039/D4RA06104G, Paper
Open Access
Mohamed Youssef Gneber, Imen Elhamdi, Jalel Messoudi, Radhia Dhahri, Foudil Sahnoune, Mosbah Jemmali, Magdy Hussein, Essebti Dhahri, Benilde Faria Oliveira Costa
This study investigates the structural, electrical, and dielectric properties of GdCrO3 (GCO) compounds. X-ray diffraction analysis confirmed the formation of the perovskite phase of GCO, crystallizing with the Pbnm space group.
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Cs2ZnCl4: a lead-free all-inorganic perovskite with a large dielectric permittivity

RSC Adv., 2024, 14,36253-36263
DOI: 10.1039/D4RA04755A, Paper
Open Access
Imen Romdhane, Asma Ajmi, Mohamed Ben Bechir, Regis Barille, Abdallah Ben Rhaiem
In recent years, inorganic perovskite materials based on metallic halides have attracted significant attention due to their non-toxicity and ease of synthesis, making them suitable for various applications.
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Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
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Jeswin Aldrin, Ankita Dhyani make Olympics cut, Indian athletics team strength rises to 30

The Indian athletics team will now have 30 members; the track and field competitions will begin on August 1




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PIX: NZ in control after India are skittled out for 46

IMAGES from Day 2 of the 1st Test played between India and New Zealand in Bengaluru, on Thursday.




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A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Irani Cup: Anureet and Ankit in Rest of India team




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India’s forex kitty drops by $3.71 billion to $701.176 billion

In the previous reporting week, the reserves had jumped by $12.588 billion to an all-time high of $704.885 billion.




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Revealing degradation mechanisms in 3D/2D perovskite solar cells under photothermal accelerated ageing

Energy Environ. Sci., 2024, 17,8313-8324
DOI: 10.1039/D4EE03869J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zijian Peng, Andrej Vincze, Fabian Streller, Vincent M. Le Corre, Kaicheng Zhang, Chaohui Li, Jingjing Tian, Chao Liu, Junsheng Luo, Yicheng Zhao, Andreas Späth, Rainer Fink, Thomas Heumüller, Andres Osvet, Ning Li, Martin Stolterfoht, Larry Lüer, Christoph J. Brabec
Three-dimensional/two-dimensional (3D/2D) heterojunctions in perovskite solar cells exhibit excellent optoelectronic properties and enhanced stability under mild ageing conditions.
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De-templated crystallization in 2D perovskites for enhanced photovoltaic efficiency

Energy Environ. Sci., 2024, 17,8284-8292
DOI: 10.1039/D4EE03272A, Paper
Fang Zeng, Zhenhuang Su, Weiyu Kong, Feng Li, Yuhang Liang, Xingmo Zhang, Tao Wang, Lin Zhang, Yuze Lvtao, Runkai Liu, Xingyu Gao, Jun Huang, Xudong Yang, Rongkun Zheng
A de-templated crystallization strategy using a stable intermediate to promote out-of-plane crystallization of layered 2D perovskites was proposed, in favor of highly efficient and stable perovskite solar cells.
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Synergistic enhancement of charge extraction and heat dissipation in inverted perovskite solar cells via n-doped top interlayers

Energy Environ. Sci., 2024, 17,8304-8312
DOI: 10.1039/D4EE02836H, Paper
Sangmi Park, Sang Young Jeong, Jaehoon Kim, Heunjeong Lee, Hye Seung Kim, Young Wook Noh, Ye In Kim, Shinuk Cho, Joon Sang Kang, Han Young Woo, Myoung Hoon Song
n-Doping the fullerene-based interlayer in perovskite solar cells enhances heat dissipation and charge extraction by improving thermal/electrical conductivity, and energy level alignment, which boosts photovoltaic performance and stability.
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Efficient 1.77 eV-bandgap perovskite and all-perovskite tandem solar cells enabled by long-alkyl phosphonic acid

Energy Environ. Sci., 2024, 17,8219-8227
DOI: 10.1039/D4EE02483D, Paper
Hongling Guan, Shiqiang Fu, Guojun Zeng, Weiqing Chen, Chen Wang, Hongsen Cui, Dexin Pu, Peng Jia, Weiwei Meng, Guojia Fang, Weijun Ke
Incorporating dodecylphosphonic acid additives into 1.77 eV-bandgap perovskites enabled single-junction solar cells to achieve a PCE of 20.2%. Tandem cells further reached impressive PCEs of 27.41% (two-terminal) and 28.65% (four-terminal).
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Perspectives for sustainability analysis of scalable perovskite photovoltaics

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03956D, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xueyu Tian, Samuel D. Stranks, Jinsong Huang, Vasilis M. Fthenakis, Yang Yang, Fengqi You
We propose a multi-scale analytics and modeling framework to fill the gap in integrating circular solar economy principles with ecosystem and climate commitments, enabling a holistic sustainability analysis of perovskite PVs.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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Stress regulation via surface micro-etching and reconstruction for enhancing triple-cation perovskite solar cells with an efficiency of 25.54%

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04248D, Paper
Yang Ding, Erming Feng, Siyuan Lu, Jianhui Chang, Caoyu Long, Sichao Tong, Hengyue Li, Junliang Yang
A surface micro-etching and reconstruction strategy is developed to regulate the stresses in a perovskite film, achieving a benign transition from tensile stress to compressive stress.
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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Metastable interphase induced pre-strain compensation enables efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03801K, Paper
Hongyu Xu, Yun Xiao, Karim A Elmestekawy, Pietro Caprioglio, Qiuyang Li, Qixuan Zhong, Yongqiang Ji, Tianyu Huang, Haoming Yan, Yingguo Yang, Laura M Herz, Qihuang Gong, Henry Snaith, Rui Zhu, Lichen Zhao
High-efficiency metal halide perovskite solar cells (PSCs) include the rigid substrates with low thermal-expansion coefficients (TECs), resulting in a significant TEC mismatch with the perovskites with high TECs at the...
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Depressing charge recombination in hybrid perovskites by introducing a dynamic electron/energy relay couple towards enhanced photocatalytic hydrogen production

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03864A, Paper
Jiaqi Liu, Yuxin Xie, Yongxin Jiao, Hefeng Zhang, Junhui Wang, Yuying Gao, Xu Zong
Extraordinary photocatalytic hydrogen evolution is achieved on methylammonium lead iodide perovskites by introducing a dynamic Cu/(CuI2) couple as the electron/energy relay station and the Pt co-catalyst as the charge/energy-releasing promotor.
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Decoupling light- and oxygen-induced degradation mechanisms of Sn–Pb perovskites in all perovskite tandem solar cells

Energy Environ. Sci., 2024, 17,8557-8569
DOI: 10.1039/D4EE02427C, Paper
Open Access
Yang Bai, Ruijia Tian, Kexuan Sun, Chang Liu, Xiting Lang, Ming Yang, Yuanyuan Meng, Chuanxiao Xiao, Yaohua Wang, Xiaoyi Lu, Jingnan Wang, Haibin Pan, Zhenhua Song, Shujing Zhou, Ziyi Ge
This study showed PEHCl-CN can enhance the strength of Sn–I, resulting in good light stability. The subsequent doping of MBI resulted in good air stability. This enables the integrated 2T all-perovskite device to achieve an efficiency of 27.9%.
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Trimming defective perovskite layer surfaces for high-performance solar cells

Energy Environ. Sci., 2024, 17,8582-8592
DOI: 10.1039/D4EE03585B, Paper
Chanhyeok Kim, Kihoon Kim, Youngmin Kim, Nikolai Tsvetkov, Nam Joong Jeon, Bong Joo Kang, Hanul Min
The defect density on the top surface of the perovskite thin film was significantly higher than that in the bulk. A trimming solvent treatment removed the defective top surface, substantially reducing the defect concentration and strain.
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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
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An energy-efficient tellurium electrode enabled by a Cs2TeI6 perovskite structure for durable aqueous Zn–Te batteries

Energy Environ. Sci., 2024, 17,8633-8642
DOI: 10.1039/D4EE02916J, Paper
Jinye Li, Chengjun Lei, Pengjie Jiang, Chen Xu, Tingting Liu, Xiao Liang
CsI in 2 M ZnSO4 aqueous electrolyte facilitates the formation of Cs2TeI6 perovskite phase for Te electrode, effectively suppressing Te4+ hydrolysis and sustaining fast redox kinetics in multi-electron transfer Zn–Te aqueous batteries.
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Water-induced spinodal decomposition of mixed halide perovskite captured by real-time liquid TEM imaging

Energy Environ. Sci., 2024, 17,8745-8755
DOI: 10.1039/D4EE03381G, Paper
Nicolas Folastre, Mohammad Ali Akhavan Kazemi, Kirill Cherednichneko, Arash Jamali, Jean Rousset, Frédéric Sauvage, Arnaud Demortière
Segmented images showing the live degradation of CsMAFA particles in contact with water molecules. The formed particles are CsPb2Br5 and PbI2 resulting from the spinodal decomposition of perovskite before dissolution/recrystallization process.
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Suppressed Surface Lattice Vacancies and Distortion Through Lattice Anchoring for Efficient FAPbI3 Perovskite Quantum Dot Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04112G, Paper
Mingxu Zhang, Xinyi Mei, Guoliang Wang, Junming Qiu, Zhimei Sun, Xiaoliang Zhang
Formamidinium lead triiodide perovskite quantum dots (FAPbI3 PQDs) exhibit outstanding optoelectronic characteristics for new-generation solar cells. However, the PQD seriously suffers from surface lattice vacancies and lattice distortion, resulting in...
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Surface-deprotonated ultra-small SnO2 quantum dots for high-performance perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03193H, Paper
Wuchen Xiang, Yiheng Gao, Bobo Yuan, Shuping Xiao, Rui Wu, Yiran Wan, Zhiqiang Liu, Liang Ma, Xiang-Bai Chen, Weijun Ke, Guojia Fang, Pingli Qin
SnO2 electron transport layers (ETLs) have improved perovskite solar cell (PSC) efficiencies but face issues with surface protonation, leading to energy loss and instability. We developed ultra-small (2.5 nm) SnO2...
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Minimizing defect states through multidentate coordination and morphology regulation for enhancing the performance of inverted perovskite solar cells

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03140G, Paper
Himangshu Baishya, Mayur Jagdishbhai Patel, Ramkrishna Das Adhikari, Deepak Yadav, Parameswar Krishnan Iyer
The interaction between CO and Pb2+ regulated grain growth, enhanced crystallinity that effectively passivated non-radiative recombination centres and CF3 group stabilizes the perovskite structure by interacting with FA and Pb cationic defects.
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Retarding anion exchanges in lead halide perovskite nanocrystals by ligand immobilization

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03241A, Paper
Gauri Sharma, Radha Rathod, Pralay K. Santra
Plasma treatment causes the crosslinking of passivating molecules around CsPbX3 (X = Cl, Br, I) perovskite nanocrystals (PNCs), which retards the anion exchanges.
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Facile Approach for Fabricating Efficient and Stable Perovskite Solar Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03705G, Paper
Sajid Sajid, Salem Alzahmi, Nouar Tabet, Mohammad Y. Al-Haik, Saleh T. Mahmoud, Yousef Haik, Ahmed Mourtada Elseman, Ihab M Obaidat
Perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs) can be produced using a variety of methods, such as different fabrication methods, device layout modification, and ingredients and interfaces...
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Conduction band photonic trapping via band gap reversal of brookite quantum dots using controlled graphitization for tuning a multi-exciton photoswitchable high-performance semiconductor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper
Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
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Shape-controlled, water-assisted synthesis of 2D luminescent CsPb2Br5 perovskite microcrystals for highly responsive UV detectors

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03021D, Paper
Dipayan Ray, Ankush Saini, Ankit Kumar, Sumit Kumar, Monojit Bag, Prasenjit Kar
Water-assisted, growth-controlled synthesis of CsPb2Br5 microcrystals for fast responsive UV-detectors.
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Factors influencing the chiral imprinting in perovskite nanoparticles

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03329A, Minireview
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nazifa Tabassum, Brian P. Bloom, Gouranga H. Debnath, David H. Waldeck
This work discusses the imprinting of optoelectronic chirality on hybrid-organic inorganic perovskites, which are a new class of chiral nanomaterials for manipulation and control of spin polarized current and circularly polarized light.
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By Hand from the Heart brings custom apparel, teak furniture, and DIY art kits 

The upcoming edition of By Hand from the Heart promises custom apparel, DIY stationery, and more




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Lakme Fashion Week 2024: Designer Aneeth Arora on Péro’s collaboration with Hello Kitty

At Lakme Fashion Week SS 25, the fashion brand’s biggest collab yet with Hello Kitty channeled ‘Cottagecore Kawaii’