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Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A new versatile crystalline sponge for organic structural analysis without the need of activation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07946E, Paper
Jin chang Liu, Weiping Huang, Yuxin Tian, Wei Xu, Wen-Cai Ye, Ren-Wang Jiang
Crystalline sponges made “crystallography without crystals” and received current attentions, but were difficult to apply directly because of the tedious activation procedures. It was important to prepare crystalline sponges that...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
The content of this RSS Feed (c) The Royal Society of Chemistry




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NiFeCo–OH/NiTe nanoarrays with amorphous/crystalline interfaces for highly efficient oxygen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00772G, Paper
Jing Liu, Da Liu, Xiaoxiao Yan, Peifang Guo, Hongbin Xu, Peng Chen, Renbing Wu
One-dimensional heterostructured NiFeCo–OH/NiTe nanorod arrays with amorphous/crystalline interfaces have been rationally synthesized, exhibiting an excellent OER electrocatalytic performance.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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BSPC - Ständiger Ausschuss tagt unter neuer Leitung in Tallinn




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Korrektur: BSPC - Ständiger Ausschuss tagt unter neuer Leitung in Tallinn




tallin

Guide To Installing Fedora Core 6 On HP Pavilion dv2000 Series Laptops

This guide provides installation and configuration instructions for installing Fedora Core 6 on HP Pavilion dv2000 series laptops.




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Telia Estonia opens new service centre in Tallinn

(Telecompaper) Telia Estonia has opened its new shop and service centre in the commercial centre Viru Keskus in the city of Tallinn...




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Simple Session 18 - Tallinn, Estonia



Simple Session 18 - Tallinn, Estonia


The 18th edition of the annual Simple Session contest series, one of the world's most iconic action sports events will take on the heart of the notorious Nordic winter in 2018, taking place on February 3 –4, in Tallinn Estonia.

The world-renowned international contest will once again host 140 contestants from 30 countries and their newest show-stopping tricks at the cozy Saku Arena, the place that everyone has come to love through the series. As one of the most international action sports events out there, Simple Session 18 pits the globe’s best BMX riders and skateboarders against each other on it’s magnificent one-off contest course, so watch out for the ultimate show of progressive riding ever seen!

The contests will again be held in pro BMX street/park and Pro skateboarding street/park + additional shows/demos. The electrifying contest will be followed by non-stop after-parties and make up one unforgettable festival experience.

When:
Thursday 01.02.2018: Training Sessions
Friday 02.02.2018: Training Sessions
Saturday 03.02.2018: Qualification BMX Street and BMX Park
Sunday 04.02.2018: Finals BMX Street and BMX Park

Where: Saku Arena, Tallinn, Estonia

Infos: www.simplesession.net

Supported by: KellyBar, GoPro, Heimon, PRFOODS, Etnies, Subaru, Worm, Subway, kunstform BMX Shop, etnies, Vapiano, VisitEstonia, European Union

Tickets: Piletilevi.ee (25.90 EUR - 199.90 EUR)

We see us in Tallinn!

All the best

Your kunstform BMX Shop Team




tallin

Simple Session 18 - Tallinn, Estonia



Simple Session 19 - Tallinn, Estonia


The 19th edition of the annual Simple Session contest series, one of the world's most iconic action sports events will take on the heart of the notorious Nordic winter in 2019, in Tallinn Estonia.

The world-renowned international contest will once again host 140 contestants from 30 countries and their newest show-stopping tricks at the cozy Saku Arena, the place that everyone has come to love through the series. As one of the most international action sports events out there, Simple Session 19 pits the globe’s best BMX riders and skateboarders against each other on it’s magnificent one-off contest course, so watch out for the ultimate show of progressive riding ever seen!

The contests will again be held in pro BMX street/park and pro Skateboarding street/park + additional shows/demos. The electrifying contest will be followed by non-stop after-parties and make up one unforgettable festival experience.

When:
Thursday 31.01.2019: Training Sessions
Friday 01.02.2019: Training Sessions
Saturday 02.02.2019: Qualification BMX Street and BMX Park
Sunday 03.02.2019: Finals BMX Street and BMX Park

Where: Saku Arena, Tallinn, Estonia

Infos: www.session.ee

Supported by: LHV, GoPro, Kellybar.ee, Heimon Kala, Visit Estonia, Kunstform BMX Shop, etnies, Etnies Estonia, Curve Digital, Vapiano Eesti, Subway Eesti, Partner Yandex Taxi, Värska Originaal and Red Bull

Tickets: Piletilevi.ee (25.90 EUR - 199.90 EUR)

We see us in Tallinn!

All the best

Your kunstform BMX Shop Team




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kunstform BMX Team at the Simple Session 2019 in Tallinn




The 19th edition of the annual Simple Session contest series, one of the world's most iconic action sports events will take on the heart of the notorious Nordic winter in 2019, taking place on February 2 –3, in Tallinn Estonia. Over 140 riders from all over the world will participate at Simple Session 19


This year Felix Prangenberg, Miguel Smajli, Robin Kachfi, Felix Donat and Ricky Felchner will represent kunstform BMX Shop at the Simple Session 19 in category street and park.

Where: Saku Arena, Tallinn, Estonia

Infos: www.session.ee




tallin

Simple Session 20 - Tallinn, Estonia



Simple Session 20 - Tallinn, Estonia


The 20th edition of the annual Simple Session contest series, one of the world's most iconic action sports events will take on the heart of the notorious Nordic winter in 2020, in Tallinn Estonia.

The world-renowned international contest will once again host 140 contestants from 30 countries and their newest show-stopping tricks at the cozy Saku Arena, the place that everyone has come to love through the series. As one of the most international action sports events out there, Simple Session 20 pits the globe’s best BMX riders and skateboarders against each other on it’s magnificent one-off contest course, so watch out for the ultimate show of progressive riding ever seen!

The contests will again be held in pro BMX street/park and pro Skateboarding street/park + additional shows/demos. The electrifying contest will be followed by non-stop after-parties and make up one unforgettable festival experience.

When:
Friday 07.02.2020: Training Sessions
Saturday 08.02.2020: Qualification BMX Street and BMX Park
Sunday 09.02.2020: Finals BMX Street and BMX Park

Where: Saku Arena, Tallinn, Estonia

Infos: simple.session.ee

Tickets: from 38 EUR

We see us in Tallinn!

All the best

Your kunstform BMX Shop Team




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kunstform BMX Team at the Simple Session 2020 in Tallinn



The 20th edition of the annual Simple Session contest series, one of the world's most iconic action sports events will take on the heart of the notorious Nordic winter in 2019, taking place on February 8 –9, in Tallinn Estonia. Over 140 riders from all over the world will participate at Simple Session 20


This year Felix Prangenberg, Miguel Smajli, Robin Kachfi, Felix Donat, Justin Rudd and Lara Lessmann will represent kunstform BMX Shop at the Simple Session 19 in category street and park.

Where: Saku Arena, Tallinn, Estonia

Infos: www.session.ee




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Respirable crystalline silica

The health hazards of respirable crystalline silica have been in the spotlight in mining, manufacturing and other industries. So, what is it – and what can be done to reduce worker exposure?




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MSHA unveils long-awaited proposed rule on respirable crystalline silica

Washington — The Mine Safety and Health Administration has announced a proposed rule on worker exposure to respirable crystalline silica in an effort to better protect miners from associated health hazards.




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FACE Report: Worker electrocuted while installing lines for security cameras

A 48-year-old city electric maintenance worker was electrocuted while installing lines for security cameras in a residential area.




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On the Safe Side podcast Episode 44: Respirable crystalline silica and mental health at work

In Episode 44, the S+H team examines the October issue’s feature story on respirable crystalline silica. Also, Suzi Craig, vice president of workplace mental health at Mental Health America, joins the podcast to discuss normalizing conversations and attitudes around mental health in the “Five Questions With …” segment. 




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MSHA final rule on respirable crystalline silica under White House review

Washington — A long-anticipated Mine Safety and Health Administration final rule intended to reduce miners’ exposure to silica has been sent to the White House Office of Management and Budget for review.




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How to Ensure Your Walls are Plumb and Flat Before Installing Tile

Installing tile on walls can be more challenging than working on floors. Oscar Barradas, owner, OBF Tile, shares a couple of tips to ensure your walls are prepped properly. 




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A second crystalline modification of 2-{3-methyl-2-[(2Z)-pent-2-en-1-yl]cyclo­pent-2-en-1-yl­idene}hydrazinecarbo­thio­amide

A second crystalline modification of the title compound, C12H19N3S [common name: cis-jasmone thio­semicarbazone] was crystallized from tetra­hydro­furane at room temperature. There is one crystallographic independent mol­ecule in the asymmetric unit, showing disorder in the cis-jasmone chain [site-occupancy ratio = 0.590 (14):0.410 (14)]. The thio­semicarbazone entity is approximately planar, with the maximum deviation from the mean plane through the N/N/C/S/N atoms being 0.0463 (14) Å [r.m.s.d. = 0.0324 Å], while for the five-membered ring of the jasmone fragment, the maximum deviation from the mean plane through the carbon atoms amounts to 0.0465 (15) Å [r.m.s.d. = 0.0338 Å]. The mol­ecule is not planar due to the dihedral angle between these two fragments, which is 8.93 (1)°, and due to the sp3-hybridized carbon atoms in the jasmone fragment chain. In the crystal, the mol­ecules are connected by N—H⋯S and C—H⋯S inter­actions, with graph-set motifs R22(8) and R21(7), building mono-periodic hydrogen-bonded ribbons along [010]. A Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are H⋯H (67.8%), H⋯S/S⋯H (15.0%), H⋯C/C⋯H (8.5%) and H⋯N/N⋯H (5.6%) [only non-disordered atoms and those with the highest s.o.f. were considered]. This work reports the second crystalline modification of the cis-jasmone thio­semicarbazone structure, the first one being published recently [Orsoni et al. (2020). Int. J. Mol. Sci. 21, 8681–8697] with the crystals obtained in ethanol at 273 K.




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STEM SerialED: achieving high-resolution data for ab initio structure determination of beam-sensitive nanocrystalline materials

Serial electron diffraction (SerialED), which applies a snapshot data acquisition strategy for each crystal, was introduced to tackle the problem of radiation damage in the structure determination of beam-sensitive materials by three-dimensional electron diffraction (3DED). The snapshot data acquisition in SerialED can be realized using both transmission and scanning transmission electron microscopes (TEM/STEM). However, the current SerialED workflow based on STEM setups requires special external devices and software, which limits broader adoption. Here, we present a simplified experimental implementation of STEM-based SerialED on Thermo Fisher Scientific STEMs using common proprietary software interfaced through Python scripts to automate data collection. Specifically, we utilize TEM Imaging and Analysis (TIA) scripting and TEM scripting to access the STEM functionalities of the microscope, and DigitalMicrograph scripting to control the camera for snapshot data acquisition. Data analysis adapts the existing workflow using the software CrystFEL, which was developed for serial X-ray crystallography. Our workflow for STEM SerialED can be used on any Gatan or Thermo Fisher Scientific camera. We apply this workflow to collect high-resolution STEM SerialED data from two aluminosilicate zeolites, zeolite Y and ZSM-25. We demonstrate, for the first time, ab initio structure determination through direct methods using STEM SerialED data. Zeolite Y is relatively stable under the electron beam, and STEM SerialED data extend to 0.60 Å. We show that the structural model obtained using STEM SerialED data merged from 358 crystals is nearly identical to that using continuous rotation electron diffraction data from one crystal. This demonstrates that accurate structures can be obtained from STEM SerialED. Zeolite ZSM-25 is very beam-sensitive and has a complex structure. We show that STEM SerialED greatly improves the data resolution of ZSM-25, compared with serial rotation electron diffraction (SerialRED), from 1.50 to 0.90 Å. This allows, for the first time, the use of standard phasing methods, such as direct methods, for the ab initio structure determination of ZSM-25.




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Orientational analysis of atomic pair correlations in nanocrystalline indium oxide thin films

The application of grazing-incidence total X-ray scattering (GITXS) for pair distribution function (PDF) analysis using >50 keV X-rays from synchrotron light sources has created new opportunities for structural characterization of supported thin films with high resolution. Compared with grazing-incidence wide-angle X-ray scattering, which is only useful for highly ordered materials, GITXS/PDFs expand such analysis to largely disordered or nanostructured materials by examining the atomic pair correlations dependent on the direction relative to the surface of the supporting substrate. A characterization of nanocrystalline In2O3-derived thin films is presented here with in-plane-isotropic and out-of-plane-anisotropic orientational ordering of the atomic structure, each synthesized using different techniques. The atomic orientations of such films are known to vary based on the synthetic conditions. Here, an azimuthal orientational analysis of these films using GITXS with a single incident angle is shown to resolve the markedly different orientations of the atomic structures with respect to the planar support and the different degrees of long-range order, and hence, the terminal surface chemistries. It is anticipated that orientational analysis of GITXS/PDF data will offer opportunities to extend structural analyses of thin films by providing a means to qualitatively determine the major atomic orientation within nanocrystalline and, eventually, non-crystalline films.




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Statistical optimization of guest uptake in crystalline sponges: grading structural outcomes

Investigation of the analyte soaking conditions on the crystalline sponge {[(ZnI2)3(tpt)2·x(solvent)]n} method using a statistical design of experiments model has provided fundamental insights into the influence of experimental variables. This approach focuses on a single analyte tested via 60 experiments (20 unique conditions) to identify the main effects for success and overall guest structure quality. This is employed as a basis for the development of a novel molecular structure grading system that enables the quantification of guest exchange quality.




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Texture tomography, a versatile framework to study crystalline texture in 3D

Crystallographic texture is a key organization feature of many technical and biological materials. In these materials, especially hierarchically structured ones, the preferential alignment of the nano constituents heavily influences the macroscopic behavior of the material. To study local crystallographic texture with both high spatial and angular resolution, we developed Texture Tomography (TexTOM). This approach allows the user to model the diffraction data of polycrystalline materials using the full reciprocal space of the crystal ensemble and describe the texture in each voxel via an orientation distribution function, hence it provides 3D reconstructions of the local texture by measuring the probabilities of all crystal orientations. The TexTOM approach addresses limitations associated with existing models: it correlates the intensities from several Bragg reflections, thus reducing ambiguities resulting from symmetry. Further, it yields quantitative probability distributions of local real space crystal orientations without further assumptions about the sample structure. Finally, its efficient mathematical formulation enables reconstructions faster than the time scale of the experiment. This manuscript presents the mathematical model, the inversion strategy and its current experimental implementation. We show characterizations of simulated data as well as experimental data obtained from a synthetic, inorganic model sample: the silica–witherite biomorph. TexTOM provides a versatile framework to reconstruct 3D quantitative texture information for polycrystalline samples; it opens the door for unprecedented insights into the nanostructural makeup of natural and technical materials.




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Laue microdiffraction on polycrystalline samples above 1500 K achieved with the QMAX-µLaue furnace

X-ray Laue microdiffraction aims to characterize microstructural and mechanical fields in polycrystalline specimens at the sub-micrometre scale with a strain resolution of ∼10−4. Here, a new and unique Laue microdiffraction setup and alignment procedure is presented, allowing measurements at temperatures as high as 1500 K, with the objective to extend the technique for the study of crystalline phase transitions and associated strain-field evolution that occur at high temperatures. A method is provided to measure the real temperature encountered by the specimen, which can be critical for precise phase-transition studies, as well as a strategy to calibrate the setup geometry to account for the sample and furnace dilation using a standard α-alumina single crystal. A first application to phase transitions in a polycrystalline specimen of pure zirconia is provided as an illustrative example.




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Implications of size dispersion on X-ray scattering of crystalline nanoparticles: CeO2 as a case study

Controlling the shape and size dispersivity and crystallinity of nanoparticles (NPs) has been a challenge in identifying these parameters' role in the physical and chemical properties of NPs. The need for reliable quantitative tools for analyzing the dispersivity and crystallinity of NPs is a considerable problem in optimizing scalable synthesis routes capable of controlling NP properties. The most common tools are electron microscopy (EM) and X-ray scattering techniques. However, each technique has different susceptibility to these parameters, implying that more than one technique is necessary to characterize NP systems with maximum reliability. Wide-angle X-ray scattering (WAXS) is mandatory to access information on crystallinity. In contrast, EM or small-angle X-ray scattering (SAXS) is required to access information on whole NP sizes. EM provides average values on relatively small ensembles in contrast to the bulk values accessed by X-ray techniques. Besides the fact that the SAXS and WAXS techniques have different susceptibilities to size distributions, SAXS is easily affected by NP–NP interaction distances. Because of all the variables involved, there have yet to be proposed methodologies for cross-analyzing data from two techniques that can provide reliable quantitative results of dispersivity and crystallinity. In this work, a SAXS/WAXS-based methodology is proposed for simultaneously quantifying size distribution and degree of crystallinity of NPs. The most reliable easy-to-access size result for each technique is demonstrated by computer simulation. Strategies on how to compare these results and how to identify NP–NP interaction effects underneath the SAXS intensity curve are presented. Experimental results are shown for cubic-like CeO2 NPs. WAXS size results from two analytical procedures are compared, line-profile fitting of individual diffraction peaks in opposition to whole pattern fitting. The impact of shape dispersivity is also evaluated. Extension of the proposed methodology for cross-analyzing EM and WAXS data is possible.




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Operando pair distribution function analysis of nanocrystalline functional materials: the case of TiO2-bronze nanocrystals in Li-ion battery electrodes

Structural modelling of operando pair distribution function (PDF) data of complex functional materials can be highly challenging. To aid the understanding of complex operando PDF data, this article demonstrates a toolbox for PDF analysis. The tools include denoising using principal component analysis together with the structureMining, similarityMapping and nmfMapping apps available through the online service `PDF in the cloud' (PDFitc, https://pdfitc.org/). The toolbox is used for both ex situ and operando PDF data for 3 nm TiO2-bronze nanocrystals, which function as the active electrode material in a Li-ion battery. The tools enable structural modelling of the ex situ and operando PDF data, revealing two pristine TiO2 phases (bronze and anatase) and two lithiated LixTiO2 phases (lithiated versions of bronze and anatase), and the phase evolution during galvanostatic cycling is characterized.




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Tips for installing and servicing CPVC pipes

When installed properly and protected from incompatible chemicals, CPVC can deliver years of reliable service in even the most aggressive water conditions. Get tips on installing and servicing CPVC pipes.




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Contractor gains multiple benefits installing radiant in his own home

When Jason Gaspard, owner and project manager at Select Mechanical Services, was looking to finish the basement of his Maple Grove, Minnesota-based home, he knew he wanted radiant heating in the space.




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Ray Wohlfarth: Installing a trouble-free condensing boiler

On the older hydronic systems, replacing the existing boiler with a new one was pretty straightforward. The installer connected the new boiler to the existing flue, piping and electric. The newer high-efficiency boilers are much different and require some additional planning.





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Rocko's Plumbing Now Installing Mandatory Automatic Leak Detection for Insurance Renewals in Simi Valley, CA

Ensure Compliance and Protect Your Home with Rocko's State-of-the-Art Leak Detection Systems




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Installing Thermostatic Expansion Valves

As the old saying goes, an ounce of prevention is worth a pound of cure. This is especially true when a replacing a thermostatic expansion valve (TXV).




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9 Methods for Installing Residential and Commercial Radiant

With multiple methods offering their own unique advantages, it’s important to be familiarized with the relevant radiant installation method to ensure a job well done.




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Installing Sensors Incorrectly As a Mistake #2 In Instrumentation

Generally speaking, there are four ‘Poors’ that can lead to incorrectly installing instrumentation sensors: Poor placement Poor control Poor protection Poor grounding Each of above sensor ‘poors’ are described below, and by the way… have you read what is the mistake No.1... Read more

The post Installing Sensors Incorrectly As a Mistake #2 In Instrumentation appeared first on EEP - Electrical Engineering Portal.




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Installing Cisco ISE Evaluation VM for Labbing

This post describes how to install a Cisco ISE evaluation VM for labbing. The VM will run for 90 days, providing a full feature set for up to 100 endpoints. Start by downloading the software. I’ll be using an OVA




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Installing Certificate on ISE Lab Server

When ISE is installed, all the certificates used for different services such as EAP, Admin portal, etc., are self signed. Below is a short summary of the certificates that ISE uses: The certificates can be seen by going to Administration




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Contractor Pro Tip: Leave Installing and Disconnecting Lightning Protection to Specialists

Roofers face enough challenges; the importance of involving specialists for lightning protection systems to meet strict standards — and avoid potential issues with dissimilar metals and corrosion — is crucial for compliance.




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Starship Technologies: bringing autonomous food delivery to even more customers in Tallinn

 Starship Technologies and Bolt have announced the launch of a new food delivery service.





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Florida Coach, Wife Electrocuted While Installing Scoreboard

Officials say a high school baseball coach and his wife were electrocuted while installing a new scoreboard at a Florida baseball field to replace one that had been destroyed by Hurricane Michael.




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Naphthalene diimide-based crystalline hybrid photochromic materials: Structural types, photochromic mechanism, and applications

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article
Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal Node Exchange-Driven Ligand-Strain Modulation Strategy for One-Dimensional Crystalline Coordination Polymers

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02422B, Research Article
Gengxin Wu, Yong-Kang Zhu, Dongxia Li, Jia-Rui Wu, Yan Wang, Zhiquan Zhang, Ying-Wei Yang
Engineering ideal functional coordination polymers (CPs) via post-synthetic modification has emerged as a powerful synthetic strategy to achieve desirable functionalities and superior properties. In this work, we report a versatile...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Achieving controllable and reversible snap-through in pre-strained strips of liquid crystalline elastomers

Soft Matter, 2024, 20,3256-3270
DOI: 10.1039/D4SM00037D, Paper
Open Access
James T. Waters, Anna C. Balazs
Deformable, elastic materials that buckle in response to external stimuli can display “snap-through”, which involves a transition between different, stable buckled states.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thermally modified nanocrystalline snail shell adsorbent for methylene blue sequestration: equilibrium, kinetic, thermodynamic, artificial intelligence, and DFT studies

RSC Adv., 2024, 14,12703-12719
DOI: 10.1039/D4RA01074D, Paper
Open Access
Abisoye Abidemi Adaramaja, Abayomi Bamisaye, Shakirudeen Modupe Abati, Kayode Adesina Adegoke, Morenike Oluwabunmi Adesina, Ayodeji Rapheal Ige, Oluwatobi Adeleke, Mopelola Abidemi Idowu, Abel Kolawole Oyebamiji, Olugbenga Solomon Bello
The quest for an efficient and sustainable adsorbent material that can effectively remove harmful and hazardous dyes from industrial effluent has become more intense. Thermally modified nanocrystalline snail shell is a new biosorbent for removing methylene blue dye from contaminated wastewater.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Composition-dependent emission colors for biomass-based main-chain luminescent liquid crystalline copolyesters with excellent tensile properties

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00946K, Paper
Wei Wang, Jing Wang, Wenting Li, Guangjian Liao, Yuan Qiu, Guochuan Yin, Yonggui Liao, Xiaolin Xie
The emission colors of high-performance MCLCPs with biomass-based bifuran and AIE-active cyanostilbene units can be tuned by the composition from blue to cyan, and then to green. Upon UV exposure, the thin film can undergo an emission color change.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nanocrystalline alloy-mediated delivery of mosaic epitope peptides for universal influenza vaccine

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00742E, Paper
Hongyu Wang, Han Fu, Liyan Zhai, Jiaqing Le, Bohan Guo, Yuyang Zhou, Chenlin Ji, Dapeng Li, Yue Zhang
Mosaic influenza antimicrobial peptide-like epitopes (Ampitopes) co-crystalize with poly(I:C), a TLR3 agonist, into nanocrystalline vaccine, which boosts immunogenicity via multivalent toll like receptor 3 (TLR3) binding and immune activation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural Distortion Driven Polaronic Transport and Table-like Magnetocaloric Properties in Polycrystalline Tb0.7Sr0.3MnO3 compound

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03760J, Paper
Dipak Mazumdar, I. Das, Kalipada Das
This research mainly explores the structural, magnetic, magneto-transport, and magnetocaloric properties of the polycrystalline Tb0.7Sr0.3MnO3 compound. The results reveal a significant modification of the compound’s ground state with increasing the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Preparation of hydrogels with self-reinforced mechanical properties using ball-milled microcrystalline cellulose and regenerated cellulose from deep eutectic solvent

New J. Chem., 2024, 48,7405-7412
DOI: 10.1039/D4NJ00622D, Paper
Yi Zhang, Yingming Zhu, Kejing Wu, Yingying Liu, Houfang Lu, Bin Liang
Choline chloride–lactic acid deep eutectic solvent assisted by ball milling effectively dissolved microcrystalline cellulose. Regenerated cellulose was used to prepare novel cellulose hydrogel with self-reinforced mechanical properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly crystalline graphite nanofibers as an anode for high-performance potassium-ion batteries

New J. Chem., 2024, 48,7497-7502
DOI: 10.1039/D4NJ00662C, Paper
Kaixuan Sun, Kun Chang, Jinshuo Tan, Chuan-Fu Sun, Qin Liu
Graphite nanofibres with high crystallinity and low defect levels for potassium-ion batteries with high initial Coulombic efficiency and long cycling stability are reported in this study.
The content of this RSS Feed (c) The Royal Society of Chemistry