stereo

Regio- and stereo-selective synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QO02078A, Research Article
Yunqing Zhuang, Jin Zhang, Kai Yang, Gehua Bi, Xin Huang, Weimin Zhang
An efficient and novel method for the direct synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration has been developed.
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stereo

Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00358F, Research Article
Shan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui Shao
Chiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.
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stereo

Correction: Stereodivergent and enantioselective total syntheses of isochaetominines A–C and four pairs of isochaetominine C enantiomers: a six-step approach

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO90034K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang Huang
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stereo

Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis

Org. Chem. Front., 2024, 11,2171-2177
DOI: 10.1039/D3QO02029K, Research Article
Rong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo Han
An asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.
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stereo

NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00347K, Research Article
Zhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping Hui
A novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...
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stereo

Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00322E, Research Article
Zhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er Chen
An iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.
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stereo

OSCE Mission to Bosnia and Herzegovina’s youth summits challenge stereotypes and promote tolerance to counter violent extremism

Some 100 high school students, pedagogues and psychologists from across Bosnia and Herzegovina (BiH) took part in two youth summits in Teslić and Vogosća this week co-hosted by the OSCE Mission to BiH and the BiH Security Ministry ...




stereo

LXer: HiFiBerry DAC8x and Amp4 Pro for High-Quality Multi-Channel and Stereo Sound

Published at LXer: The HiFiBerry DAC8x and HiFiBerry Amp4 Pro are two significant upgrades for enhancing audio capabilities on the Raspberry Pi 5. These devices expand the audio options for users...



  • Syndicated Linux News

stereo

HendonCheapStereos

Cheap Car Stereo's




stereo

Animated Films Perpetuate Harmful Stereotypes About Eye Conditions




stereo

Stereotypes

Fr. Ted warns us against forming preconceived notions about people without getting to know them.




stereo

Focus on individual workers rather than generational stereotypes, management experts say

Washington — Instead of relying on generational labels such as “millennial” and “baby boomer” to help inform workforce management decisions – including those related to safety and communication – employers and managers should focus on workers’ individual situations and needs, concludes a recently published report from the National Academies of Sciences, Engineering, and Medicine.




stereo

Bangladesh defies stereotypes when it comes to health care. Let's keep it that way

Bangladesh defies the stereotypes. It was born in poverty but has risen up the income ladder and is a model of health progress. Will the current political upheaval take a toll on its impressive achievements?




stereo

Uncovering Unconscious Racial Bias - Lecture Examines Stereotypes and Their Impacts

We tend to think of the process of seeing as fairly objective — that our eyes are similar to cameras, neutrally taking in light and turning it into pictures. But research has shown that biases buried beneath our awareness can powerfully shape how we see.




stereo

Shattering stereotypes to shape the future of plumbing

US faces a shortage of 500k skilled plumbers, costing $33bn annually. Plumbing requires rigorous training, creative problem-solving, and meticulous execution. Valuing the critical role plumbers play can address the shortage and pave the way for a thriving water infrastructure.




stereo

Slurs, Smears, and Stereotypes: Rocky Election Road Ahead

When President Biden withdrew from the 2024 presidential campaign last month and endorsed Vice President Kamala Harris to be the Democratic Party’s nominee, the move resulted in several historical firsts. It also placed a swift focus on intersectionality and identity politics as tensions mount in the final stretch of the 2024 election cycle.

Littler Principal Cindy-Ann Thomas and her guests, University of North Carolina (Charlotte) Associate Chair of Communications Studies, Professor Debra C. Smith, and Littler Shareholder Bradford Kelley, explore:




stereo

[ P.811 (01/19) ] - Subjective test methodology for evaluating Speech oriented stereo communication systems over headphones

Subjective test methodology for evaluating Speech oriented stereo communication systems over headphones




stereo

[ P.1120 (03/17) ] - Super-wideband and fullband stereo hands-free communication in motor vehicles

Super-wideband and fullband stereo hands-free communication in motor vehicles




stereo

Estereotipos han generado barreras y son un desafío para el género: Laura

Laura Gallego habla sobre los estereotipos de género




stereo

Fracaso político, acuerdos de paz y Festival Estereo Picnic

La Luciérnaga se enciende para hablar de los  responsables del fracaso de la reforma política en el gobierno.  Además, sigue la polémica por la implementación de los acuerdos de paz. También, ¿cómo avanza el festival de música Estéreo Picnic?
La Luciérnaga, un espacio de humor, análisis y opinión de Caracol Radio que acompaña desde hace 30 años a sus oyentes en el regreso a casa.




stereo

Hiking, bike riding, breweries and pot. Do Denver residents live up to the stereotype?

Ask someone from another state what the typical Denverite likes, and you might get any number of answers. Skiing. Craft beer. Hiking. Cannabis. Goldendoodles.




stereo

Not your stereotypical missionary

From age 17, Ana Maria prayed to serve God in Switzerland. While she waited, she became a dance instructor with no idea dance would become her ministry.




stereo

Does 'the Achievement Gap' Evoke a Negative Stereotype? What the Research Says

What we call education inequality defines how—and even if—we solve it, write three researchers.




stereo

Jamie Oliver withdraws children’s book over ‘stereotyping’




stereo

to wire speakers to car stereo

to wire speakers to car stereo




stereo

to wire up a car stereo

to wire up a car stereo




stereo

Self-centred, spoiled and lonely? Examining the only child stereotype

More and more parents are choosing to only have one child. Here’s what the evidence says about how growing up without siblings affects their personality traits and well-being




stereo

Why Our Stereotypes of African Agriculture Are All Wrong

Calestous Juma (@calestous) will host a joint Twitter chat with the Elumelu Foundation on June 18, 2016, at 9:00 AM (EDT). Ask questions via #AskCJuma or #TEEPagricReport!

From newspaper editors to TV anchors to bloggers, the default symbol of African agriculture is an African woman holding a hand hoe. This imagery highlights the drudgery African women face in farming. But it also conflates family farming with the broader agricultural enterprise.




stereo

A Breezy Way for Car Stereo Installation

If you are a music lover, then a factory stereo system will not satisfy your music thirst. You might want to upgrade it or replace with a better one, and if you are hesitant about approaching a professional owing to cost, you might as well...




stereo

Stereotypes and stereotyping in early modern England : Puritans, papists and projectors [Electronic book] / ed. by Koji Yamamoto.

Manchester : Manchester University Press, [2022]




stereo

Three-dimensional porous rhodium–copper alloy nanoflowers stereoassembled on Ti3C2Tx MXene as highly-efficient methanol oxidation electrocatalysts

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article
Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti3C2Tx lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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stereo

Unusual solvent-regulated inversion of a metal stereocenter in an enantiopure Eu2L4 helicate: a new strategy for CPL inversion

Inorg. Chem. Front., 2024, 11,8093-8100
DOI: 10.1039/D4QI02276A, Research Article
Qing Ma, Sen Yin, Ziye Song, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng Li
The dinuclear helicate Eu2(LR)4 exhibits a solvent-regulated metal stereocenter Δ/Λ configurational inversion, independent of P/M helical conformational conversion. This reversal process is accompanied by an inversion of the CPL.
The content of this RSS Feed (c) The Royal Society of Chemistry




stereo

Versatile hybrid technique for passive straight micromixer manufacturing by combining pulsed laser ablation, stereolithographic 3D printing and computational fluid dynamics

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00009A, Paper
Open Access
Bastián Carnero, Yago Radziunas-Salinas, Bruno K. Rodiño-Janeiro, Sylvana Varela Ballesta, M. Teresa Flores-Arias
The proposed hybrid technique for passive straight micromixer manufacturing by combining pulsed laser ablation and stereolithographic 3D printing.
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stereo

Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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stereo

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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stereo

Diastereoselective synthesis of functionalized spiroindolines via intramolecular ipso-iodocyclization/nucleophile addition cascade reactions of indole-tethered ynones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00112E, Paper
Debojyoti Bag, Sanghapal D. Sawant
Herein, we describe a highly diastereoselective approach for synthesizing polyfunctionalized spiroindolines from indolyl-ynones involving an ipso-iodocyclization/nucleophile addition cascade.
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stereo

Stereoselective Synthesis of gem-Dihalopiperidines via Halo-Aza-Prins Cyclization Reaction: Access to Piperidin-4-ones and Pyridines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00338A, Paper
Anil Kumar Saikia, Surjya Kumar Bora, Subhamoy Biswas, Bipin Kumar Behera
An efficient methodology for the synthesis of 4,4-dihalopiperidine derivatives has been developed from N-(3-halobut-3-en-1-yl)-4-methylbenzenesulfonamide and aldehyde catalyzed by In(OTf)3 in excellent yields. The reaction involves an initial formation of six...
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stereo

Vinylogous and stereoselective domino synthesis of pyrano[2,3-c]pyrroles from alkylidene meldrum's acids

Org. Biomol. Chem., 2024, 22,2948-2952
DOI: 10.1039/D4OB00233D, Communication
Mariia Savchuk, Giang Vo-Thanh, Sylvain Oudeyer, Hélène Beucher, Jean-François Brière
An expeditious diatereoselective synthesis of pyrano[2,3-c]pyrroles thanks to a domino Vinylogous aza-Michael-Aldol-Cyclocondensation (aza-VMAC) reaction to alkylidene Meldrum's acid derivatives.
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stereo

Stereoselective synthesis of (R)- and (S)-1,2-diazetidine-3-carboxylic acid derivatives for peptidomimetics

Org. Biomol. Chem., 2024, 22,2974-2977
DOI: 10.1039/D4OB00278D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew Nutter, Henry Stone, Michael Shipman, Stefan Roesner
Stereoselective synthesis of both enantiomers of orthogonally protected 1,2-diazetidine-3-carboxylic acid (aAze) from homochiral glycidol and its application in peptidomimetics.
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stereo

Nickel-catalysed regio- and stereoselective hydrocyanation of alkynoates and its mechanistic insights proposed by DFT calculations

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00380B, Communication
Shigeru Arai, Koichi Nakazawa, Xiao-Fei Yang, Masaya Nakajima, Shinji Harada, Atsushi Nishida
This work discloses the origin of regio- and stereoselectivity of hydrocyanation of alkynoates.
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stereo

A Highly Diastereoselective One-Pot Ugi/Radical Spirocyclization/Aza-Michael Addition Sequence

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00610K, Communication
Chandra Volla, Salman Khan, Abhradeep Chatterjee, Akshay Murali Nair
We hereby report a highly diastereoselective synthesis of chalcogenated azaspirotricycles via a one-pot Ugi/spirocyclization/ aza-Michael addition sequence. The reaction proceeded via a key visible light mediated spirocyclization step under mild,...
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stereo

What is stereotactic radiation therapy for prostate cancer? How does it compare to other treatments?

Stereotactic radiotherapy uses high doses of radiation to target and kill cancer cells; it uses newer machines that can deliver very focused radiation beams




stereo

Enantioselective synthesis of molecules with multiple stereogenic elements

Chem. Soc. Rev., 2024, 53,11165-11206
DOI: 10.1039/D3CS00238A, Review Article
Open Access
Arthur Gaucherand, Expédite Yen-Pon, Antoine Domain, Alix Bourhis, Jean Rodriguez, Damien Bonne
This review explores the fascinating world of molecules featuring multiple stereogenic elements, unraveling the different strategies designed over the years for their enantioselective synthesis.
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stereo

Mechanism and stereoselectivity in metal and enzyme catalyzed carbene insertion into X–H and C(sp2)–H bonds

Chem. Soc. Rev., 2024, 53,11004-11044
DOI: 10.1039/D4CS00742E, Review Article
Reena Balhara, Ritwika Chatterjee, Garima Jindal
This review provides a mechanistic overview of asymmetric Fe, Cu, Pd, Rh, Au and heme-based enzymes catalyzed carbene insertion reactions to construct  C–X (X = O, N, S, etc.) and C–C bonds, focusing on the stereochemical models.
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stereo

Stereotypes and Politics [electronic journal].

National Bureau of Economic Research




stereo

Revealing Stereotypes: Evidence from Immigrants in Schools [electronic journal].

National Bureau of Economic Research




stereo

Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3 and BrO3 are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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stereo

Dribbling past gender stereotypes in rural Odisha

Odisha takes a lead in inspiring and training young tribal boys and girls to play mixed-gender football matches and drive social change in the State




stereo

Akira: breaks bones, but not stereotypes

'Akira' is yet another film in which being a strong woman essentially means having to suffer and sacrifice




stereo

An efficient approach to AviCys analogues via regio- and stereoselective hydrosulfuration of ynamides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01572J, Research Article
Zhenjia Zhang, Zhe Ding, Jinhua Yang, Yongli Zhao, Zhenguang Zhao, Can Liu, Norman Metanis, Junfeng Zhao
A novel synthetic strategy for the construction of AviCys analogues via a highly efficient regio- and stereoselective hydrosulfuration of ynamides was reported.
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