fluoride

Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00305E, Research Article
Chen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong Ma
Herein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.
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fluoride

RFK Jr. cues up clash by calling for the removal of fluoride from drinking water

Robert F. Kennedy Jr. is pushing President-elect Donald Trump to crack down on fluoride levels in drinking water, saying the mineral can lead to unintended medical problems -- and setting up a clash with medical experts who defend it as a proven way to fighting cavities.




fluoride

Board applauds EPA’s efforts to promote hydrogen fluoride safety

Washington — The Chemical Safety Board says it “appreciates” a recent Environmental Protection Agency initiative that emphasizes compliance at chemical facilities that use the toxic substance hydrogen fluoride.




fluoride

New ion radii for oxides and oxysalts, fluorides, chlorides and nitrides

Ion radii are derived here from the characteristic (grand mean) bond lengths for (i) 135 ions bonded to oxygen in 459 configurations (on the basis of coordination number) using 177 143 bond lengths extracted from 30 805 ordered coordination polyhedra from 9210 crystal structures; and (ii) 76 ions bonded to nitro­gen in 137 configurations using 4048 bond lengths extracted from 875 ordered coordination polyhedra from 434 crystal structures. There are two broad categories of use for ion radii: (1) those methods which use the relative sizes of cation and anion radii to predict local atomic arrangements; (2) those methods which compare the radii of different cations (or the radii of different anions) to predict local atomic arrangements. There is much uncertainty with regard to the relative sizes of cations and anions, giving rise to the common failure of type (1) methods, e.g. Pauling's first rule which purports to relate the coordination adopted by cations to the radius ratio of the constituent cation and anion. Conversely, type (2) methods, which involve comparing the sizes of different cations with each other (or different anions with each other), can give very accurate predictions of site occupancies, physical properties etc. Methods belonging to type (2) can equally well use the characteristic bond lengths themselves (from which the radii are derived) in place of radii to develop correlations and predict crystal properties. Extensive quantum-mechanical calculations of electron density in crystals in the literature indicate that the radii of both cations and anions are quite variable with local arrangement, suggesting significant problems with any use of ion radii. However, the dichotomy between the experimentally derived ion radii and the quantum-mechanical calculations of electron density in crystals is removed by the recognition that ion radii are pr­oxy variables for characteristic bond lengths in type (2) relations.




fluoride

EPA Standard for Fluoride in Drinking Water Is Not Protective - Tooth Enamel Loss, Bone Fractures of Concern at High Levels

The U.S. Environmental Protection Agencys standard for the maximum amount of fluoride allowed in drinking water -- 4 milligrams of fluoride per liter of water -- does not protect against adverse health effects.




fluoride

National Academies Completes Review of National Toxicology Program’s Draft Monograph on Fluoride and Neurodevelopmental and Cognitive Effects

Today the National Academies of Sciences, Engineering, and Medicine released its review of the National Toxicology Program’s (NTP) draft monograph Systematic Review of Fluoride Exposure and Neurodevelopmental and Cognitive Health Effects.




fluoride

National Academies Complete Review of National Toxicology Program’s Second Draft Monograph on Fluoride Exposure and Neurodevelopmental and Cognitive Effects

The National Academies of Sciences, Engineering, and Medicine released today a review of the National Toxicology Program’s (NTP) second draft of the monograph Systematic Review of Fluoride Exposure and Neurodevelopmental and Cognitive Health Effects.




fluoride

Membrane technologies for water treatment : removal of toxic trace elements with emphasis on arsenic, fluoride and uranium

Location: Engineering Library- TD442.5.M4586 2016




fluoride

Food, fluoride and funding: How a new Trump term might affect health in California

From family planning to hospital bills, the new Trump administration has the potential to affect a wide range of policies in the Golden State and beyond.




fluoride

Trump Embraces RFK Jr.’s Views on Vaccines, Fluoride

In the waning days of his campaign, former President Donald Trump has further embraced some of Robert F. Kennedy Jr.’s incorrect or controversial views on health, including vaccines and fluoride.

The post Trump Embraces RFK Jr.’s Views on Vaccines, Fluoride appeared first on FactCheck.org.




fluoride

Preparation of fatty acid methyl esters and dimethylacetals from lipids with boron fluoride--methanol

William R. Morrison
Oct 1, 1964; 5:600-608
Articles




fluoride

RFK Jr. wants to stop putting fluoride in drinking water. Here's what scientists say

On day one of Donald Trump's presidency, Robert F. Kennedy Jr. says he'll be advising Trump to take fluoride out of public water. The former presidential hopeful — and prominent proponent of debunked public health claims — has described fluoride as "industrial waste."




fluoride

How Fluoride Toothpaste Has Reduced the Need for Water Fluoridation

The benefits of medlinkfluoridating drinking water/medlink for dental health may be less than what was possible before the widespread use of medlinkfluoride toothpaste/medlink (!--ref1--).




fluoride

Equivalent cation-tuning to realize a new Ce(IV) fluoride with excellent comprehensive nonlinear optical performances

Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article
Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH4Ce3F13 is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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fluoride

Effects of Mixed Phases on Ionic Conductivities for (LaF3)1–x(PbF2)x Fast-Fluoride-Ion-Conducting Solid Electrolytes

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01063A, Paper
Ming Zhang, Yaowei Hao, Qiaojun Nie, Xiaocao Cao, Jiafan Zheng, Kai Zhang, Jun Zheng, Haodong Wang, Yafang Zhao, Jiayi Liu, Zhiguang Lin, Zhongrong Shen
The research on all-solid-state fluoride-ion batteries (FIBs) with a high theoretical energy density has attracted considerable attention due to their enhanced safety features and superior capacity. The selection of solid...
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fluoride

Polymer-confined synthesis of gram-scale high-entropy perovskite fluoride nanocubes for improved electrocatalytic reduction of nitrate to ammonia

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00341A, Communication
Open Access
Guohao Xue, Tianlu Wang, Hele Guo, Nan Zhang, Claire J. Carmalt, Johan Hofkens, Feili Lai, Tianxi Liu
A high-entropy perovskite fluoride with a well-defined nanocubic structure was successfully prepared via a polyvinylpyrrolidone-confined nucleation strategy, demonstrating excellent electrocatalytic activity for nitrate reduction.
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fluoride

Tailoring electromagnetic interference shielding, electrical and thermal properties of poly(vinylidene fluoride) based hybrid nanocomposites with carbon nanofiber and magnetite nanoparticles

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC02880E, Paper
Aleena Sabu, Sabarish Narayanan B. B, Pratheep Kumar Annamalai, Ramanujam Brahmadesam Thoopul Srinivasa Raghava
Flexible polymer nanocomposite films hold great potential for microwave absorption applications and their electromagnetic interference shielding effectiveness (EMI SE) can be tailored by optimising the electrical properties such as conductivity....
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fluoride

Hydrophobic fouling-resistant electrospun nanofiber membranes from poly(vinylidene fluoride)/polyampholyte blends

Soft Matter, 2024, 20,8654-8662
DOI: 10.1039/D4SM00817K, Paper
Anuja S. Jayasekara, Luca Mazzaferro, Ryan O’Hara, Ayse Asatekin, Peggy Cebe
This study reports the fabrication of non-woven fibrous membranes from electrospinning blended solutions of PVDF with a random polyampholyte amphiphilic copolymer (r-PAC) in N,N-dimethylformamide and methanol.
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fluoride

Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01870B, Research Article
Lijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng Yu
We developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.
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fluoride

A fluoride gradient, Zn-salt-rich hydrophobic interphase formed by a zincophilic, hydrophobic, anion-philic polymer “skin” for an anode-free solid Zn battery

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE01978D, Paper
Xinpeng Han, Jinpeng Han, Kang Ma, Jiaqi Wen, Lianpeng Li, Daliang Han, Jie Sun
A Zn2+·OC group-derived contact ion pair (CIP)/aggregate (AGG)-rich electrolyte is fabricated to generate a fluoride gradient, Zn-salt-rich hydrophobic solid electrolyte interface (SEI) layer with ultrahigh mechanical properties.
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fluoride

Exploration of the synergistic regulatory mechanism of hydroxide and fluoride modification on the photocatalytic activity of 2D g-C3N4

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00971A, Paper
Qianqian Shang, Hongbing Wang, Changjie Kan, Rui Ding, Yankai Li, Shiva Pandeya, Ziliang Li, Mahesh Kumar Joshi
Exfoliation and hetero-element doping are common procedures for band gap engineering and enhancing the photocatalytic properties of g-C3N4.
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fluoride

Fetching fluoride with hydrogen bonding

Catalyst spurs insoluble salts into action as nucleophiles for enantioselective reactions




fluoride

EPA Standard for Fluoride in Drinking Water Is Not Protective - Tooth Enamel Loss, Bone Fractures of Concern at High Levels

The U.S. Environmental Protection Agencys standard for the maximum amount of fluoride allowed in drinking water -- 4 milligrams of fluoride per liter of water -- does not protect against adverse health effects.




fluoride

National Academies Completes Review of National Toxicology Program’s Draft Monograph on Fluoride and Neurodevelopmental and Cognitive Effects

Today the National Academies of Sciences, Engineering, and Medicine released its review of the National Toxicology Program’s (NTP) draft monograph Systematic Review of Fluoride Exposure and Neurodevelopmental and Cognitive Health Effects.




fluoride

Fluoride, prefab and Sudden Valley's finest [Weekend link clump]

This weekend: Model homes have a moment (thanks, Netflix!) and Portland maintains its status as the nation's largest fluoride-free city.




fluoride

Processes for separation of fluoroolefins from hydrogen fluoride by azeotropic distillation

The present disclosure relates to a process for separating a fluoroolefin from a mixture comprising hydrogen fluoride and fluoroolefin, comprising azeotropic distillation both with and without an entrainer. In particular are disclosed processes for separating any of HFC-1225ye, HFC-1234ze, HFC-1234yf or HFC-1243zf from HF.




fluoride

Gaseous compositions comprising hydrogen fluoride and an alkylated ammonia derivative

A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.




fluoride

Processes for producing phosphorus pentafluoride and phosphate hexafluoride

An object the invention is to provide a phosphorus pentafluoride producing process wherein phosphorus pentafluoride is separated/extracted from a pentavalent phosphorus compound or a solution thereof, or a composition obtained by allowing the pentavalent phosphorus compound or the solution thereof to react with hydrogen fluoride, thereby producing phosphorus pentafluoride; and a phosphate hexafluoride producing process wherein the resultant phosphorus pentafluoride is used as raw material to produce a phosphate hexafluoride high in purity. The present invention relates to a process for producing phosphorus pentafluoride, wherein a carrier gas is brought into contact with either of the following one: a pentavalent phosphorus compound, a solution thereof, or a solution in which a composition obtained by allowing the pentavalent phosphorus compound or the solution thereof to react with hydrogen fluoride is dissolved, thereby a phosphorus pentafluoride is extracted into the career gas.




fluoride

PROCESS FOR THE PRODUCTION OF MAGNESIUM FLUORIDE SOL SOLUTIONS FROM ALKOXIDES COMPRISING ADDITION OF CARBON DIOXIDE

The invention relates to a method for obtaining a magnesium fluoride (MgF2) sol solution, comprising the steps of providing a magnesium alkoxide precursor in a non-aqueous solvent and adding 1.85 to 2.05 molar equivalents of non-aqueous hydrofluoric acid to said magnesium precursor, characterized in that the reaction proceeds in the presence of carbon dioxide. The invention further relates to sol solutions, method of applying the sol solutions of the invention to surfaces as a coating, and to antireflective coatings obtained thereby.




fluoride

Anti-fluoride campaign now needs to focus on stopping child tooth decay

The end to the fluoride saga in the Southampton city region will put a big hole in the correspondence bag for this paper’s daily letters page.




fluoride

Preparation of fatty acid methyl esters and dimethylacetals from lipids with boron fluoride--methanol

William R. Morrison
Oct 1, 1964; 5:600-608
Articles




fluoride

Study: Evidence does not support classifying fluoride as cognitive neurodevelopmental hazard

The National Academies of Sciences, Engineering, and Medicine announced March 5 that it does not find that the National Toxicology Program adequately supported its conclusion that fluoride is “presumed” to be a cognitive neurodevelopmental hazard to humans.




fluoride

U.S. Lowers Recommended Fluoride Levels in Drinking Water

Title: U.S. Lowers Recommended Fluoride Levels in Drinking Water
Category: Health News
Created: 4/27/2015 12:00:00 AM
Last Editorial Review: 4/28/2015 12:00:00 AM




fluoride

Comparative efficacy of a hydroxyapatite and a fluoride toothpaste for prevention and remineralization of dental caries in children




fluoride

Fluoride varnish and dental caries in preschoolers: a systematic review and meta-analysis




fluoride

Calgary city councillors discuss returning fluoride to water supply

One study and a pile of anecdotal evidence has shown that perhaps the decision to remove fluoride in 2011 wasn't such a great idea.




fluoride

Excess Fluoride Causes Tooth Enamel Defects

In the cells forming tooth enamel, excessive fluoride exposure was found to alter calcium signaling, mitochondrial function, and gene expression, stated




fluoride

[ASAP] Controlling the Phase Behavior of Low and Negative Thermal Expansion ReO<sub>3</sub>-Type Fluorides using Interstitial Anions: Sc<sub>1–<italic toggle="yes"><italic toggle="yes">x</italic><

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.0c00629




fluoride

Novel nitro substituted formazan derivatives: Selective ratiometric and colorimetric chemosensors for fluoride anion sensing detectable by the naked eye

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01860K, Paper
Gulsen Turkoglu
Novel two formazan derivatives FNB and FDNB were synthesized from their corresponding phenylhydrazone and characterized by various spectroscopic methods. The sensing ability of these formazan sensors towards different anions was...
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fluoride

Lanthanide doped bismuth-based fluoride nanoparticles: controlled synthesis and ratiometric temperature sensing

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00435A, Paper
Pengpeng Lei, Ran An, Chengyu Li, Jing Feng, Hongjie Zhang
Bismuth-based nanoparticles, especially NaBiF4, have attracted extensive attention as hosts of lanthanides (Ln3+) ions and other luminescent ions in recent years. However, controllable synthesis of NaBiF4 nanoparticles remains a challenge....
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fluoride

Near-IR absorption and photocurrent generation using a first-of-its-kind boron difluoride formazanate non-fullerene acceptor

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00109K, Research Article
Josh D. B. Koenig, Mahmoud E. Farahat, Jasveer S. Dhindsa, Joe B. Gilroy, Gregory C. Welch
We report the synthesis and characterization of the first non-fullerene acceptor containing a boron difluoride formazanate core end-capped with N-annulated perylene diimides.
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fluoride

[ASAP] Flexible, Lead-Free Nanogenerators Using Poly(vinylidene fluoride) Nanocomposites

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c01143




fluoride

[ASAP] Addition to “Selective Methylation of Amides, <italic toggle="yes">N</italic>-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride”

Organic Letters
DOI: 10.1021/acs.orglett.0c01524




fluoride

Enhanced dielectric performance in flexible MWCNT/poly(vinylidene fluoride-co-hexafluoropropene)-based nanocomposites by designing a tri-layered structure

J. Mater. Chem. C, 2020, 8,5950-5957
DOI: 10.1039/D0TC00148A, Paper
Jie Chen, Yifei Wang, Jiufeng Dong, Yujuan Niu, Weixing Chen, Hong Wang
Tri-layered films are capable of excellent capacitive stability over straight bending (i.e. 20 000 cycles) and winding (i.e. 120 hours) tests.
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fluoride

[ASAP] Investigation of Plausible Mechanism of the Synthesized Inorganic Polymeric Coagulant and Its Application toward Fluoride Removal from Drinking Water

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00760




fluoride

Improving the determination of celecoxib in body fluids and pharmaceuticals using a new selective and thermosensitive molecularly imprinted poly(vinylidene fluoride) membrane

Anal. Methods, 2020, 12,2185-2195
DOI: 10.1039/D0AY00237B, Paper
Negin Yazdanian, Behrouz Akbari-Adergani, Maryam Kazemipour, Homayon Ahmad Panahi, Mehran Javanbakht
Molecularly imprinted membranes that demonstrated high selectivity for celecoxib were synthesized using N-vinylcaprolactam and 2-hydroxyethyl methacrylate.
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fluoride

Bridging the immiscibility of an all-fluoride fire extinguishant with highly-fluorinated electrolyte toward safe sodium metal batteries

Energy Environ. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0EE00694G, Paper
Xueying Zheng, Zhen-Yi Gu, Xuyang Liu, Zhongqiang Wang, Jiayun Wen, Xing-Long Wu, Wei Luo, Yunhui Huang
Room-temperature sodium metal batteries with metallic Na anode and flammable organic solvent-based electrolyte are breeding severe safety concerns. Herein, by introducing non-flammable, highly-fluorinated ethers as the bridge solvents, we enable...
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fluoride

[ASAP] Revealing the Dissolution Mechanism of Polyvinylidene Fluoride of Spent Lithium-Ion Batteries in Waste Oil-Based Methyl Ester Solvent

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c02072




fluoride

[ASAP] Copper(I) Diphosphine Bifluoride Complexes as Efficient Preactivated Catalysts for Nucleophilic Addition on Unsaturated Functional Groups

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00443




fluoride

Hydrogen fluoride method development for the Ogawa Passive Sampling Device