dyes

Isostructural behaviour in ammonium and potassium salt forms of sulfonated azo dyes

The structures of five ammonium salt forms of mono­sulfonated azo dyes, derivatives of 4-(2-phenyldiazen-1-yl)benzenesulfonate, with the general formula [NH4][O3S(C6H4)NN(C6H3)RR']·XH2O [R = OH, NH2 or N(C2H4OH)2; R' = H or OH] are presented. All form simple layered structures with alternating hydro­phobic (organic) and hydro­philic (cation, solvent and polar groups) layers. To assess for isostructural behaviour of the ammonium cation with M+ ions, the packing of these structures is compared with literature examples. To aid this comparison, the corresponding structures of four potassium salt forms of the mono­sulfonated azo dyes are also presented herein. Of the five ammonium salts it is found that three have isostructural equivalents. In two cases this equivalent is a potassium salt form and in one case it is a rubidium salt form. The isostructurality of ion packing and of unit-cell symmetry and dimensions tolerates cases where the ammonium ions form somewhat different inter­action types with coformer species than do the potassium or rubidium ions. No sodium salt forms are found to be isostructural with any ammonium equivalent. However, similarities in the anion packing within a single hydro­phobic layer are found for a group that consists of the ammonium and rubidium salt forms of one azo anion species and the sodium and silver salt forms of a different azo species.




dyes

Surfactant-induced alterations in optoelectronic properties of perylene diimide dyes: modulating sensing responses in the aqueous environment

Soft Matter, 2024, 20,3044-3052
DOI: 10.1039/D3SM01694C, Paper
Animesh Pal, Nilanjan Dey
The compartmentalization effect of microheterogeneous systems, like surfactant aggregates, showcases altered optoelectronic properties of a perylene diimide-based chromogenic dye (PDI-Ala) compared to bulk water.
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dyes

Correction: Photocatalytic degradation of drugs and dyes using a machine learning approach

RSC Adv., 2024, 14,12983-12983
DOI: 10.1039/D4RA90045F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ganesan Anandhi, M. Iyapparaja
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dyes

3-Perfluoroalkylated fluorescent coumarin dyes: rational molecular design and photophysical properties

Mol. Syst. Des. Eng., 2024, 9,332-344
DOI: 10.1039/D4ME00006D, Paper
Ayano Ikemura, Yukiko Karuo, Yuki Uehashi, Tomohiro Agou, Masahiro Ebihara, Yasuhiro Kubota, Toshiyasu Inuzuka, Masaaki Omote, Kazumasa Funabiki
The photochemical properties of a coumarin derivative with a promising electron-withdrawing fluoroalkyl group at the 3-position in solution and in the crystal were investigated in detail.
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dyes

Tuning the photophysical properties of ESIPT active unsymmetrical azine dyes by the change in the substituent and solvent: TD-PBE0 and TD-CAM-B3LYP studies

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00039K, Paper
Hossein Roohi, Tahereh Pouryahya
The photophysical properties of the designed ESIPT active as well as donor–acceptor structured unsymmetrical azine dyes L1L5 were investigated at PBE0/6-31++G(d,p) and CAM-B3LYP/6-31++G(d,p) levels of theory in the gas phase and solvent media.
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dyes

Exchange of free and capsule conjugated cyanine dyes between cells

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01874E, Paper
Zhanna V. Kozyreva, Polina A. Demina, Olga I. Gusliakova, Gleb B. Sukhorukov, Olga A. Sindeeva
Cells readily exchange free cyanine dyes when their membranes are in close contact. Photoconvertible capsules based on cyanine dyes are internalized into the cytoplasm with a low degree of exchange, allowing individual cell labeling and tracking.
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dyes

Mitochondria-targeted BODIPY dyes for small molecule recognition, bio-imaging and photodynamic therapy

Chem. Soc. Rev., 2024, 53,3976-4019
DOI: 10.1039/D3CS00456B, Review Article
Sisi Wang, Lizhi Gai, Yuncong Chen, Xiaobo Ji, Hua Lu, Zijian Guo
This review focuses on the design strategy, spectroscopic characteristics, and functionalization of mitochondrion-targeted BODIPY dyes, providing an overview of these dyes for mitochondrion-targeted bioimaging and photodynamic therapy.
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dyes

From byproducts to NLO-active dyes: catalyst-free transfer hydrogenation in the modular synthesis of merocyanines

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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dyes

New 2-pyridone-based donor–acceptor dyes: the effect of the donor group position, type of π-linker and acid–base characteristics of the medium on the photophysical properties

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00177J, Paper
Saveliy P. Sorokin, Mikhail Yu. Ievlev, Oleg V. Ershov
Synthesis of a series of new donor–acceptor dyes based on 2-pyridone and the study of the effect of the position of the donor group, the type of π-linker and the acid–base characteristics of the medium on their photophysical properties.
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dyes

Design, synthesis, and biological application of A–D–A-type boranil fluorescent dyes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00297K, Paper
Wei Luo, Yiling Li, Liang Wang, Yanhua Qin, Qiao Cheng, Guochang Hu, Chaoyi Yao, Xiangzhi Song
Acceptor–donor–acceptor boranil fluorescent dyes, CSU-BF-R (R = H, CH3, and OCH3), were developed with strong red fluorescence and large Stokes shifts. CSU-BF-OCH3 could selectively sense intracellular hypochlorous acid in living cells and zebrafish.
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dyes

Correction: Charge transfer properties of novel linear carbon chain-based dyes

J. Mater. Chem. C, 2024, 12,17704-17704
DOI: 10.1039/D4TC90100B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giuseppe Consiglio, Adam Gorczyński, Salvatore Petralia, Giuseppe Forte
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dyes

Intermediate diradical character and thermal cis–trans isomerization of near-infrared absorbing thionated squaraine dyes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01722F, Research Article
Open Access
Taishi Oka, Takeshi Maeda, Daisuke Sakamaki, Naoya Suzuki, Shigeyuki Yagi, Shintaro Kodama, Hideki Fujiwara
Near-infrared absorbing squaraine dyes incorporating 4-membered thionated oxocarbon and chalcogenopyrylium moieties exhibit intermediate diradical character, which impacts thermal cis–trans isomerization.
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dyes

Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01848F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tobias B. Tischer, Zulema Fernandez, Lorenz Borsdorf, Constantin Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo Fernandez
Supramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...
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dyes

Investigation and development of novel synthetic approaches for synthesis of euxanthone and derived dyes

RSC Adv., 2024, 14,35601-35609
DOI: 10.1039/D4RA06475E, Paper
Open Access
M. Mustafa Cetin
This work explores new synthetic methods for euxanthone and its derived dye Indian yellow through euxanthic acid formation, confirming structures with analytical techniques and proposing a mechanism for the euxanthone synthesis.
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dyes

Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
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dyes

BODIPY dyes for optical limiting applications on the nanosecond timescale

Dalton Trans., 2024, 53,17766-17771
DOI: 10.1039/D4DT02505A, Frontier
John Mack, Gugu Kubheka, Aviwe May, Bokolombe P. Ngoy, Tebello Nyokong
Recent research at the Institute for Nanotechnology Innovation at Rhodes University exploring the utility of BODIPY and azaBODIPY dyes for optical limiting of incident nanosecond laser pulses in the visible region is described.
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dyes

PILI raises funds for biotech textile dyes




dyes

Colorful hair dyes from blackcurrants

Semipermanent color from anthocyanins in fruit skins are a natural alternative to petroleum-derived dyes




dyes

The benefits of using natural hair dyes

Blackcurrant, indigo and henna can color and strengthen your hair naturally and avoid some of the controversial ingredients in traditional dyes.



  • Fitness & Well-Being

dyes

Sulfonamide derivatives of polycyclic dyes used for analytical applications

The invention concerns the production of quinoline compounds containing sulfonic acid groups, the said quinoline compounds and their conversion into dyes containing sulfonic acid groups. The dyes according to the invention are used especially to label analytes, for example to label biomolecules.




dyes

Polymer-bonded perylene dyes and compositions containing same

A method of increasing the solubility and/or dispersibility of a perylene dye in a liquid medium. The method comprises binding the perylene dye to a polymer which is soluble in the liquid medium. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.




dyes

Fluorescent dyes with large stokes shifts

Herein are disclosed fluorescent dyes based around a framework for a ligand comprising a pyridyl group linked to a diaryl anilido unit. A variety of ligands based on this framework are disclosed. The ligands chelate to a BF2 center to produce the fluorescent dye. The disclosed dyes combine longer Stokes shifts (approximately 100 nm) with increased quantum yields. They are also photostable in aqueous and organic solutions for several hours. These dyes may be used in the labeling of biomolecules for bioimaging and assays. Also disclosed are methods for the synthesis of these dyes.




dyes

Black disazo dyes, their preparation and use

Black disazo dyes of general formula (V) wherein A is a moiety of formula (VI) or of formula (VII) and B is a moiety of formula (VII) or of formula (IX) and wherein M, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23, and R24, are as defined in the specification, are excellent black dyes for dying and printing cellulose containing materials and textile materials and, in particular, for preparation of recording liquids for ink jet printing and for writing utensils.




dyes

Thiophene azo dyes and laundry care compositions containing the same

This application relates to thiophene azo dyes for use as hueing agents, laundry care compositions comprising such thiophene azo dyes, processes for making such thiophene azo dyes, and laundry care compositions and methods of using the same. The thiophene azo dyes contain a formally charged moiety and are generally comprised of at least two components: at least one chromophore component and at least one polymeric component. Suitable chromophore components generally fluoresce blue, red, violet, or purple color when exposed to ultraviolet light, or they may absorb light to reflect these same shades. These thiophene azo dyes are advantageous in providing a hueing effect, for example, a whitening effect to fabrics, while not building up over time and causing undesirable blue discoloration to the treated fabrics. The thiophene azo dyes are also generally stable to bleaching agents used in laundry care compositions.




dyes

Metal free acid dyes, methods for the production thereof and their use

The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.




dyes

Disulfide dyes

Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2). A-(X1)p—(Csat)r—S—S—(Csat)q—(X2)p-D (1)




dyes

Azo dyes

The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.




dyes

How to make all-natural Easter egg dyes

Who needs an overpriced kit with synthetic color tablets when you've already got colorful ingredients in your kitchen?




dyes

American kids need to be weaned off synthetic food dyes

These questionable additives are found in nearly half of all foods marketed to kids.




dyes

Canada Exports of Dyes and Pigments Petrochemic

Exports of (bop) - Dyes and Pigments, Petrochemic in Canada decreased to 263.60 CAD Million in March from 266.30 CAD Million in February of 2020. Exports of (bop) - Dyes and Pigments, Petrochemic in Canada averaged 211.17 CAD Million from 1988 until 2020, reaching an all time high of 455.80 CAD Million in July of 2008 and a record low of 46 CAD Million in June of 1992. This page includes a chart with historical data for Canada Exports of (bop) - Dyes And Pigments, Petrochemic.




dyes

Alexandra Mardell showcases her VERY bold new do' as she dyes her locks purple

Alexandra Mardell was almost unrecognisable in a snap shared on Saturday after the actress dyed her hair purple in lockdown.




dyes

Kylie Jenner removes waist-length hair extensions and dyes her roots... before eating nachos

It's been less than a month since the 22-year-old reality star originally lightened her short raven bob




dyes

Kylie Jenner removes waist-length hair extensions and dyes her roots... before eating nachos

It's been less than a month since the 22-year-old reality star originally lightened her short raven bob




dyes

Celebrity Apprentice star Aubrey O'Day dyes her dogs rainbow colours to match her newly hued hairdo

She's recently gone from blonde to cherry red, and now Aubrey O'Day has gone one step further by dying her dogs' hair, as well.




dyes

Gas-phase Förster resonance energy transfer in mass-selected ions with methylene or peptide linkers between two dyes: a concerted dance of charges

Phys. Chem. Chem. Phys., 2020, Advance Article
DOI: 10.1039/D0CP01287D, Paper
Christina Kjær, Ying Zhao, Mark H. Stockett, Li Chen, Klavs Hansen, Steen Brøndsted Nielsen
Emission from gaseous rhodamine 640 is redshifted when the dye is tethered to rhodamine 575 due to internal Coulomb interaction.
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dyes

[ASAP] Palladium-Catalyzed C-4 Selective Coupling of 2,4-Dichloropyridines and Synthesis of Pyridine-Based Dyes for Live-Cell Imaging

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00449




dyes

[ASAP] Pyridine-Embedded Phenothiazinium Dyes as Lysosome-Targeted Photosensitizers for Highly Efficient Photodynamic Antitumor Therapy

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00280




dyes

Multifunctional polymers with interpenetrating structures: luminescent sensing, ECL behaviors, selective detection of Fe3+ ion and rapid removal of anionic dyes

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01066A, Paper
Lingshu Meng, Lun Zhao, Guanlin Guo, Xin Liu
Three novel 3D coordination polymers (CPs), {[Cd(L)(bimb)](H2O)4}n (1), {[Zn(L)(bibp)](H2O)(DMF)}n (2) and {[Zn(L)(bif)](H2O)4}n (3) (bimb= 1,4-bis(imidazoly-1-yl)benzene, bibp= 4,4'-bis(imidazol-1-yl)biphenyl, bif= 2,7-bis(1-imidazoly)fluorene, H2L=1-(4-carbxoylphenyl)piperidine-4-caboylic acid) have been synthesized under solvothermal conditions. Compound 1 featured...
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dyes

POM-based dyes featured rigidified bithiophene π linkers: Potential high-efficient dyes for dye-sensitized solar cells

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01150A, Paper
Yu Gao, Li-Kai Yan, Wei Guan, Yanhong Xu
A series of POM-based dyes with triphenylamine electron donor group, cyanoacrylic acid electron acceptor group and different π linkers of thiophene derivatives are systematically investigated to analyze the influence of...
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dyes

New trends in natural dyes for textiles / Padma Shree Vankar, Dhara Shukla

Online Resource




dyes

Recent advances in decolorization and degradation of dyes in textile effluent by biological approaches / Ram Lakhan Singh, Pradeep Kumar Singh and Rajat Pratap Singh

Online Resource




dyes

Cobalt–carbon/silica nanocomposites prepared by pyrolysis of a cobalt 2,2'-bipyridine terephthalate complex for remediation of cationic dyes

RSC Adv., 2020, 10,17660-17672
DOI: 10.1039/D0RA02752A, Paper
Open Access
Nusaybah Alotaibi, Hassan H. Hammud, Ranjith Kumar Karnati, Syed Ghazanfar Hussain, Javed Mazher, Thirumurugan Prakasam
A cobalt–carbon@silica nanocomposite was synthesized from a cobalt 2,2'-bipyridine terephthalate complex and its adsorption behavior towards crystal violet dye was tested using batch and column techniques.
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dyes

Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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dyes

Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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dyes

Cancer risk studies raise questions about the safety of long-lasting hair dyes

Long-lasting hair dyes are popular, and their safety has been well researched. But new epidemiology studies show their use correlates with increased risk of breast cancer




dyes

Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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dyes

PILI raises funds for biotech textile dyes




dyes

Colorful hair dyes from blackcurrants

Semipermanent color from anthocyanins in fruit skins are a natural alternative to petroleum-derived dyes