doping

Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
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doping

Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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doping

Sinner doping case not helping tennis - Djokovic

24-time men's Grand Slam champion Novak Djokovic says Jannik Sinner's doping case "is not helping tennis at all". Sinner, the men's world number one, was cleared of any wrongdoing after twice testing positive for low levels of clostebol - a steroid that can be used to build muscle mass - during the Indian Wells tournament in March. The World Anti-Doping Agency have appealed against the decision which said Sinner bore 'no fault or negligence' for the substance being in his system.




doping

Sinner 'surprised' by World Anti-Doping Agency appeal

World number one Jannik Sinner says he is "surprised" by the World Anti-Doping Agency's appeal against the decision to clear him of blame after he twice tested positive for a banned substance.




doping

What happens next in Sinner doping case?

News that Jannik Sinner, the men's world number one, had failed two doping tests stunned tennis. BBC Sport examines the key questions at hand.




doping

Could a doping probe strip Salt Lake City of the 2034 Olympics? The IOC president says it's unlikely

In his first visit back to Utah since awarding Salt Lake City the 2034 Winter Games, the International Olympic Committee president sought to ease worries that the city could lose its second Olympics if organizers don't fulfill an agreement to play peacemaker between anti-doping authorities.




doping

Doping ban reduced for German hockey player who won Olympic silver medal

Yannic Seidenberg, who won the silver medal with the German men's hockey team at the 2018 Olympics, has had his doping ban cut by 18 months.




doping

Olympic medalist race walker Koki Ikeda of Japan suspended in doping investigation

Olympic silver medalist race walker Koki Ikeda of Japan has been provisionally banned for suspected blood doping, track and field's Athletics Integrity Unit said on Friday.




doping

Russian figure skating team falls under doping shadow

Alexei Zheleznyakov, who is part of the team of Russian figure skating coach Eteri Tutberidze, responded to recent reports about a suspicious doping test that one of the skaters of the Russian national team had at the Beijing Olympics. Zheleznyakov said that he did not believe that anyone from the Russian team could violate anti-doping rules. "The guys took samples before the Games, most likely when they arrived and after their performances. We were staying at the hotel without getting out, but now they suddenly found something, and it happened right after the gold medal,” Alexei Zheleznyakov, who choreographs the Russian figure skaters in Beijing wrote on his Facebook account.




doping

Kamila Valieva's doping test still remains a mystery to all

Kamila Valieva's doping test revealed the presence of three substances to improve the heart function, the US Anti-Doping Agency (USADA) said. According to The New York Times, these drugs can be aimed at increasing endurance, if used in combination. According to USADA's chief Travis Tygart, Kamila Valieva's doping test revealed the presence of trimetazidine, L-carnitine and hypoxen. Of these three drugs, it is only trimetazidine that is included in the list of drugs prohibited for athletes. "It's a trifecta of substances — two of which are allowed, and one that is not allowed. The benefits of such a combination "seem to be aimed at increasing endurance, reducing fatigue and promoting greater efficiency in using oxygen," Travis Tygart said.




doping

Kamila Valieva says she is emotionally exhausted because of doping scandal

Russian figure skater Kamila Valieva said that she was emotionally tired of the doping scandal, in which she found herself at the Beijing Olympics. "These days have been very hard for me, there are not enough emotions. I am happy, but I am emotionally tired. There are tears of happiness and grief a little. But, of course, I am happy to be at the Olympics. I will try to represent our country and I hope that I will be as motivated as possible to show a good result,” said Valieva. According to the athlete, she saw all the good wishes, and even banners in her support in the streets of Moscow.




doping

Investigations into the Concentrations and Metabolite Profiles of Doping Agents and Antidepressants in Human Seminal Fluid Using Liquid Chromatography-Mass Spectrometry [Articles]

Exogenous substances, including drugs and chemicals, can transfer into human seminal fluid and influence male fertility and reproduction. In addition, substances relevant in the context of sports drug testing programs, can be transferred into the urine of a female athlete (after unprotected sexual intercourse) and trigger a so-called adverse analytical finding. Here, the question arises as to whether it is possible to distinguish analytically between intentional doping offenses and unintentional contamination of urine by seminal fluid. To this end, 480 seminal fluids from nonathletes were analyzed to identify concentration ranges and metabolite profiles of therapeutic drugs that are also classified as doping agents. Therefore, a screening procedure was developed using liquid chromatography connected to a triple quadrupole mass spectrometer, and suspect samples (i.e., samples indicating the presence of relevant compounds) were further subjected to liquid chromatography-high-resolution accurate mass (tandem) mass spectrometry. The screening method yielded 90 findings (including aromatase inhibitors, selective estrogen receptor modulators, diuretics, stimulants, glucocorticoids, beta-blockers, antidepressants, and the nonapproved proliferator-activated receptor delta agonist GW1516) in a total of 81 samples, with 91% of these suspected cases being verified by the confirmation method. In addition to the intact drug, phase-I and -II metabolites were also occasionally observed in the seminal fluid. This study demonstrated that various drugs including those categorized as doping agents partition into seminal fluid. Monitoring substances and metabolites may contribute to a better understanding of the distribution and metabolism of exogenous substances in seminal fluid that may be responsible for the impairment of male fertility.

SIGNIFICANCE STATEMENT

This study demonstrates that doping agents as well as clinically relevant substances are transferred/eliminated into seminal fluid to a substantial extent and that knowledge about drug levels (and potential consequences for the male fertility and female exposure) is limited. The herein generated new dataset provides new insights into an important and yet little explored area of drug deposition and elimination, and hereby a basis for the assessment of contamination cases by seminal fluid in sports drug testing.




doping

Privacy commissioner launches investigation into World Anti-Doping Agency

Canada’s privacy commissioner has launched an investigation into the World Anti-Doping Agency (WADA) and “its handling of biological samples collected from athletes.”




doping

USADA’s stunning anti-doping swoop on Lesnar

BROCK Lesnar was allowed to dodge an anti-doping policy to make his megastar comeback at UFC 200 but what’s happened since is remarkable.




doping

Synergistic Fe,Ce doping of Ni3S2 for enhancing oxygen evolution reaction performance

Inorg. Chem. Front., 2024, 11,7623-7632
DOI: 10.1039/D4QI02187H, Research Article
Yu He, Kefan Shi, Xueqin Wang, Xingzi Zheng, Lanke Luo, Liu Lin, Zemin Sun, Genban Sun
Fe,Ce-Ni3S2@NF nanoneedle catalysts synthesised via a one-step hydrothermal route showed good OER performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Strontium doping RuO2 electrocatalyst with abundant oxygen vacancies for boosting OER performance

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02070G, Research Article
Bei An, Xiaoqian Li, Yuan Lin, Fanfan Shang, Huijie He, Hairui Cai, Xiaoxiao Zeng, Weitong Wang, Shengchun Yang, Bin Wang
Oxygen evolution reaction (OER) plays a crucial role as the anode reaction of electrolytic water in various applications. To date, it is still a great challenge to develop highly active...
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Aluminum and polyanion-doping to improve structural and moisture stability of Ni-rich layered oxides for lithium-ion batteries

RSC Adv., 2024, 14,12247-12254
DOI: 10.1039/D4RA00879K, Paper
Open Access
Yan Mo, Yingke Wu, Guohui Yuan, ZiKun Li, Meng Zhang
The substitution of Al3+ and PO34− in LiNi0.8Co0.1Mn0.1O2 material is favorable for stabilizing the layered structure against the undesired phase transition of H2 to H3 as well as the contamination of ambient air.
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doping

Influence of potassium doping on the structural, conduction mechanism, and dielectric properties of CaFe2O4

RSC Adv., 2024, 14,12464-12474
DOI: 10.1039/D4RA00260A, Paper
Open Access
Mohamed Mounir Bouzayani, Manel Ben Abdessalem, Ibtihel Soudani, Abderrazek Oueslati, Abdelhedi Aydi
The frequency and temperature-related dielectric relaxation and electrical conduction mechanisms in potassium-doped CaFe2O4 oxide ceramic were investigated in this study throughout a temperature range of 313–673 K.
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doping

Amplification of photocatalytic degradation of antibiotics (amoxicillin, ciprofloxacin) by sodium doping in nano-crystallite hydroxyapatite

RSC Adv., 2024, 14,12386-12396
DOI: 10.1039/D4RA00126E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sakabe Tarannum, Md. Sahadat Hossain, Muhammad Shahriar Bashar, Newaz Mohammed Bahadur, Samina Ahmed
Sodium-doped hydroxyapatite (Na_HAp) was synthesized for the enhanced photocatalytic degradation of amoxicillin and ciprofloxacin.
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doping

Enhanced photocatalytic performance of ZnO under visible light by co-doping of Ta and C using hydrothermal method

RSC Adv., 2024, 14,12954-12965
DOI: 10.1039/D4RA00579A, Paper
Open Access
Thi Viet Ha Luu, Hong Yen Xuan Nguyen, Quoc Thang Nguyen, Quang Bac Nguyen, Thi Ha Chi Nguyen, Ngoc Chuc Pham, Xuan Dung Nguyen, Trung Kien Nguyen, Ngoc Nhiem Dao
C, Ta-co-doped ZnO nanoparticles (Eg = 2.88 eV), prepared by hydrothermal method, were used as a photocatalyst under visible light to remove organic contaminants in aquatic environments.
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doping

Hole-states in Li doped NiO: doping dependence of Zhang-Rice spectral weight

Phys. Chem. Chem. Phys., 2024, 26,27735-27740
DOI: 10.1039/D4CP03373F, Paper
Suman Mandal, Krishnakumar S. R. Menon
The structural and spectroscopic evolution of Li-doped NiO, along with the behavior of doped hole states, are investigated using XRD and XAS.
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doping

Boosting the electrochemical performance of Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04275A, Communication
Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O...
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Impact of Cr doping on the structural and optoelectronic properties of a CsPbIBr2 perovskite solar cell

New J. Chem., 2024, 48,7205-7212
DOI: 10.1039/D4NJ00681J, Paper
M. I. Khan, Ali Mujtaba, Saddam Hussain, Asif Hussain, Dalil Bulayis N AlResheedi, Zainab Mufarreh Elqahtani, El Sayed Yousef, Norah Alwadai
The Cr–CsPbIBr2 device showed enhanced performance, with increased grain size, reduced energy band gap, and elevated efficiency from 9.64% to 12.06%.
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doping

Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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doping

Fabrication of BiVO4 submicron rods photoanodes through phase transition assisted by Mo doping

CrystEngComm, 2024, 26,2078-2086
DOI: 10.1039/D4CE00074A, Paper
Shuang Zhao, Haipeng Zhang, Zhaoqi Wang, Deifei Xiao, Xianbin Xu, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Ying Dai, Hefeng Cheng, Zeyan Wang, Baibiao Huang
Herein, Mo doping has been found to effectively lower the phase transition temperature from tetragonal zircon BiVO4 to monoclinic scheelite BiVO4. Our research introduces a novel method for the production of submicron rods BiVO4 photoanodes.
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doping

In situ P-doping induced Se vacancies enhance the supercapacitor performance of NiCo2Se4

CrystEngComm, 2024, 26,2197-2206
DOI: 10.1039/D4CE00048J, Paper
Miaomiao Wang, Weizhe Liu, Li Zhang, Huanli Liu, Xiao Yang
In this paper, we report the synthesis of P-doped NiCo2Sex nanomaterials with rich Se vacancies induced by P doping, which greatly improves the supercapacitor performance of electrode materials.
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doping

Cluster-doping in silicon nanocrystals

Nanoscale Horiz., 2024, 9,2042-2050
DOI: 10.1039/D4NH00235K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atta ul Haq, Marius Buerkle, Bruno Alessi, Vladimir Svrcek, Paul Maguire, Davide Mariotti
Sn-cluster doping of Si nanocrystals represents a new approach to property tuning, which results in a significant bandgap reduction and an atypical size-dependent behaviour, as confirmed by both experimental and theoretical studies.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Full-color peptide-based fluorescent nanomaterials assembled under the control of amino acid doping

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00400K, Communication
Yuhe Shen, Yulin Sun, Yaoyu Liang, Xiaojian Xu, Rongxin Su, Yuefei Wang, Wei Qi
Peptide-based biofluorescents are of great interest due to their controllability and biocompatibility, as well as their potential applications in biomedical imaging and biosensing.
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doping

Observation and enhancement through alkali metal doping of p-type conductivity in the layered oxyselenides Sr2ZnO2Cu2Se2 and Ba2Zn1−xO2−xCu2Se2

J. Mater. Chem. C, 2024, 12,17574-17586
DOI: 10.1039/D4TC02458C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zahida Malik, Sarah Broadley, Sebastian J. C. Herkelrath, Daniel W. Newbrook, Liam Kemp, George Rutt, Zoltán A. Gál, Jack N. Blandy, Joke Hadermann, Daniel W. Davies, Robert D. Smyth, David O. Scanlon, Ruomeng Huang, Simon J. Clarke, Geoffrey Hyett
The optoelectronic properties of two layered copper oxyselenide compounds, with nominal composition Sr2ZnO2Cu2Se2 and Ba2ZnO2Cu2Se2, have been investigated to determine their suitability as p-type conductors.
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doping

Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping

Chem. Soc. Rev., 2024, 53,10523-10574
DOI: 10.1039/D4CS00339J, Review Article
Open Access
Kanji Saito, Masashi Morita, Tomohiko Okada, Rattanawadee (Ploy) Wijitwongwan, Makoto Ogawa
The replacement of the main components with a small amount of heteroelements in a material affects its properties and imparts novel functions, similar to “wasabi” giving the important taste for “sushi”.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Sinner cleared of wrongdoing after failing anti-doping tests

Sinner provided an in-competition sample at the Indian Wells Masters on March 10, 2024 which contained the presence of a metabolite of clostebol at low levels, according to the ITIA




doping

Sinner fires trainer, physio amid doping furore

Sinner's case has created a storm considering other players who failed drugs tests usually get suspended during the course of the investigation.




doping

WADA appeals to CAS against Jannik Sinner doping verdict, seeks suspension

WADA said it would seek "a period of ineligibility of between one and two years" for Italy's Jannik Sinner




doping

Jannik Sinner ‘disappointed and surprised’ by WADA appeal over doping case

WADA made the appeal announcement as Sinner was on court at the China Open, where the defending champion fought back to beat 69th-ranked Russian Roman Safiullin 3-6, 6-2, 6-3 in Beijing




doping

Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00493K, Research Article
Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin Zhang
The co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.
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doping

Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide

Inorg. Chem. Front., 2024, 11,2272-2280
DOI: 10.1039/D4QI00344F, Research Article
Mengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang Zhu
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
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doping

High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping

Inorg. Chem. Front., 2024, 11,2339-2345
DOI: 10.1039/D4QI00310A, Research Article
Zhiqin Deng, Heng Liu, Huiyong Wang, Chaoqun Ma, Juan Du, Baozhan Zheng
B acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.
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doping

AFI to penalise coaches for athletes’ doping offence

The AFI chief said the athletes needed to declare their coaches’ names in dope control forms and all the coaches would have to be registered with the federation




doping

Curbing the doping scourge: Anju Bobby George, Ashwini Nachappa have their say

The two champion athletes agree on both the crux of the problem — incorrect or insufficient guidance — and the reasons for it — increased competition and desperation to succeed — but differ in how accountability should be apportioned




doping

Paul Pogba’s doping ban reduced from 4 years to 18 months

Four-year bans are standard under the world anti-doping code but can be reduced in cases where an athlete can prove their doping was not intentional, if the positive test was a result of contamination or if they provide “substantial assistance” to help investigators




doping

Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production

Dalton Trans., 2024, 53,17819-17828
DOI: 10.1039/D4DT01625D, Paper
Songhan Hu, Kai Wang, Xinxin Xu, Qiang Wang
Two Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Reducing carrier recombination loss by suppressing Sn loss and defect formation via Ag doping in Cu2ZnSn(S,Se)4 solar cells

Energy Environ. Sci., 2024, 17,8609-8620
DOI: 10.1039/D4EE02485K, Paper
SeongYeon Kim, Jaebaek Lee, Dae-Ho Son, Wook Hyun Kim, Shi-Joon Sung, Dae-Kue Hwang, Tae Ei Hong, Namuundari Otgontamir, Enkhjargal Enkhbayar, Tae-Hee Lee, Min-Yeong Kim, Ji-Soo Choi, Sang-Mo Koo, JunHo Kim, Jin-Kyu Kang, Dae-Hwan Kim, Kee-Jeong Yang
The position of Ag of the CZTSSe precursor significantly impacts the carrier recombination loss and overall efficiency, offering crucial insights for optimizing the CZTSSe solar cell design.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

High-entropy doping for high-performance zero-cobalt high-nickel layered cathode materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE05020G, Paper
Jiahui Zhou, Jiehui Hu, Xia Zhou, Zhen Shang, Yue Yang, Shengming Xu
Considering the high price and scarcity of cobalt resource, zero-cobalt, high-nickel layered cathode material (LNM) have been considered as the most promising material for next-generation high-energy-density lithium-ion batteries (LIBs). However,...
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Enhancing antioxidant properties of CeO2 nanoparticles with Nd3+ doping: structural, biological, and machine learning insights

Biomater. Sci., 2024, 12,2108-2120
DOI: 10.1039/D3BM02107F, Paper
Oscar Ceballos-Sanchez, Diego E. Navarro-López, Jorge L. Mejía-Méndez, Gildardo Sanchez-Ante, Vicente Rodríguez-González, Angélica Lizeth Sánchez-López, Araceli Sanchez-Martinez, Sergio M. Duron-Torres, Karla Juarez-Moreno, Naveen Tiwari, Edgar R. López-Mena
The antioxidant capabilities of nanoparticles are contingent upon various factors, including their shape, size, and chemical composition.
The content of this RSS Feed (c) The Royal Society of Chemistry




doping

Usain Bolt, Mo Farah and Jessica Ennis-Hill are clean athletes among a host of cheats, confirms leaked IAAF doping data

Usain Bolt and Mo Farah are among the athletes who are racing clean, along with Jessica Ennis-Hill, according to the avalanche of data reported this weekend.




doping

Toni Minichiello, coach of Jessica Ennis-Hill, demands Sebastian Coe reassigns medals from drug cheats after damning report on doping in Russian athletics 

Jessica Ennis-Hill's coach has told Sebastian Coe to immediately start drawing up a list of medals that should be taken from drug cheats and handed to the athletes they robbed.




doping

Jessica Ennis-Hill: Winning BBC Sports Personality of the Year would give athletics a lift in wake of doping scandal

INTERVIEW BY MARTHA KELNER: Jessica Ennis-Hill accepts that, through no fault of her own, some people might be deterred from voting for her because of the doping crisis engulfing athletics.




doping

Russia face new football scandal as WADA and FIFA uncover evidence of state-sponsored doping 

Fresh evidence that Russian footballers were helped to cheat during their nation's state-sponsored doping scandal will arrive at FIFA within weeks.




doping

Grasso, Three Others Enter Not Guilty Pleas; Feds Outline Volume Of Discovery In Doping Investigation

Four men arrested March 9 as part of the federal government's racehorse doping investigation pleaded not guilty on Tuesday in a telephonic arraignment conducted by District Court Judge P. Kevin Castel for the Southern District of New York. The defendants waived their right to physically appear in court because of the coronavirus (COVID-19) pandemic. Veterinarian […]

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