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Copy of IWMW 2008 Ning social network produced

Following changes to the terms and conditions of the Ning social networking service a copy of the IWMW 2008 Ning social network has been taken. [16 August 2008]




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USAF Eyes $100,000 Per Copy Munitions

The U.S. Air Force’s inventory of high-end munitions is sufficient, as the service moves to field lower-cost, $100,000 models in the coming years to bolster capacity to deter China and […]




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Symmetry-induced Modulation of Proton Conductivity in Y-doped Ba(Zr,Ce)O3: Insights from Raman Spectroscopy

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00415A, Paper
Yiming Yang, Jiachen Lu, Xinyu Zhang, Yanuo Shi, Peng Du, Xiao Ling, Nan Yang, Qianli Chen
Y-doped Ba(Zr,Ce)O3 (BZCY) proton conducting ceramics have attracted extensive attention for their promising applications as electrolytes for intermediate-temperature proton ceramic electrochemical cells. The proton conductivity of BZCY is governed by...
The content of this RSS Feed (c) The Royal Society of Chemistry




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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Textifi: How to OCR Hard Copy Printed Material Even in Airplane Mode

Textifi by Virtual Eye is a simple OCR app that doesn't require a data or wi-fi connection. The Play Store link is
https://play.google.com/store/apps/details?id=textifi.virtualeye.iohl=en_US

the interface is straight-forward. In the top right corner is a button for turning on the flashlight/torch, and across the bottom are buttons for detecting text, copying text to the clipboard, and reading the text out loud again. There is no menu icon, and there don’t seem to be any app settings.

To use Textifi, do the following:

• Turn on the flashlight (if necessary).
• Center your phone's viewfinder over the printed page.
• Tap the Detect Text button. Recognition is fairly quick. If nothing happens after a second or two, tap the screen again.

Once text is recognized, it is read automatically. If you want it to be repeated, tap the Speak Again button, and if you want to save it, tap the Copy button, then use TalkBack's editing menu to paste the text into a notepad app.

This app’s OCR results are great, but the key is to position your camera right. I was sitting in my office at school going through junk mail. If I positioned the camera by putting my elbow on the table next to the printed page and holding my hand up in the air, results were very good, almost as good as the Eye-D app by GingerMind Technologies. With Eye-D, recognition was pretty good even if I didn’t keep the camera level; with Textifi, recognition was great if I held the camera right, but results were bad if I wasn’t careful.

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Nexcopy announces new ultra-fast SD Card Duplicator solution based on USB 3.0 technology

Copy 1GB of data every 30 seconds with the all new 16 target SD Card Duplicator by Nexcopy. Improved copy speeds result in ultra-fast Secure Digital copier outperforming all other systems.




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DnD situation is a symptom of a larger problem: our insanely long copyright protection (life of the author + 70 years!)


(I posted this to the DnD subreddit also: link.)

The Open Gaming License fiasco with Dungeons & Dragons producer Wizards of the Coast is a symptom of a larger problem: our insane Intellectual Property system that currently protects material for the life of the author plus 70 years. As a comparison, patents generally only protect inventions for 20 years.

The purpose of intellectual property laws is to balance public and private interests. IP law is an agreement between society and creators: the creator is guaranteed an exclusive right to their creation for a period of time, and in exchange the public gets rights to the creation afterwards. It's intended to be a balance of interests, but the balance has gotten completely out of whack thanks to (obviously) lobbying throughout the 20th century by major copyright holders like Disney.

In my opinion, the current copyright term, life of the author plus 70 years, is grossly unfair to the public. I believe that the internet era has demonstrated that creators would be incentivized to create even without such a long period of exclusivity. Think about it: would you create less stuff if your great-grandkids didn't get exclusive rights? I doubt it.

Listen: creators should be able to make money from their work. I don't think copyright should go to zero, but why not bring it in line with patent protection with a 20-year term?

Disney, DnD, and many other creations are part of our generation's cultural legacy, part of a 10,000+ year inheritance that has been handed down through time to our grandparents, our parents, and now us. It's morally wrong for our ancestors and corporations to lock our inheritance away from us.

Copyright protections must be re-balanced to protect both creators and the public. This problem with WotC shouldn't be just about a license, it should be about the IP laws that grant them exclusive rights to creations that are over 50 years old. Our generation should re-open these negotiations and come up with a fair copyright term.



  • Law & Justice

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Duration/Term of Copyright

In the case of original literary, dramatic, musical and artistic works, the duration of copyright is the lifetime of the author or artist, and 60 years counted from the year following the death of the author.

In the case of cinematograph films, sound recordings, photographs, posthumous publications, anonymous and pseudonymous publications, works of government and works of international organizations are protected for a period of 60 years which is counted from the year following the date of publication.

www.mondaq.com




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Extension Copy 201103302445





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Incredible Black Dodge Challenger Muscle Car #2 - Copyright 2009 Jimmy Rocker Photography

Incredible Black Dodge Challenger Muscle Car #2 - Old School Joins with the New School - Copyright 2009 Jimmy Rocker Photography - Big, Bold, Black and Powerful. I'm Loving this Phat Azz American Muscle Car. Incredible Black Dodge Challenger Muscle Car #2 - Copyright 2009 Jimmy Rocker Photography




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Rich Brown Bubble Butt Beauty - Copyright 2009 JiMmY RocKeR PhoToGRaPhY

Rich Brown Bubble Butt Beauty - Copyright 2009 JiMmY RocKeR PhoToGRaPhY




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Green Burger Hill - Chlorophyll Maximum Density - Copyright 2oo9 JiMmY RocKeR PhoToGRaPhY

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Copy And Paste 1 Line Of Code For Chatbot-Driven Commissions Every Day!

Make anywhere from $48 to $995 per day by pasting one line of code on your website to deploy an A.I. chatbot that sucks in free traffic and converts leads into sales… Without writing a single line of code, or needing any techie skills whatsoever! Say goodbye to: • Hiring an expensive programmer to code […]



  • Website/WordPress Development
  • Chat Bot A.I.
  • chatbot

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RSS' Copyright Debate

RSS is commonly defined as really simple syndication. So, this means that any material contained in a feed is available for syndication, right? Well no, not exactly. It means that the content contained in an RSS feed is in a format that is syndication friendly, if the copyright holder allows for syndication. Offering a feed for syndication does not in fact grant any legal rights to anyone to reuse the feeds content beyond what the Copyright laws grant as Fair Use.

RSS' Copyright Debate




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Podcasts and Copyrights

Podcasting has a very low barrier to entry; all you need is audio recording software and a means of creating an RSS feed, be it through software or manual work. As a result, just about anyone can podcast, and the quality of podcasts is therefore highly variable; there are professional podcasts that rival professional broadcasts in quality, and there are amateur podcasts that can not even be heard clearly.

Podcasts and Copyights




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How To Write A Newsletter Toolkit: Copyright Free Articles, Newsletter Templates + 'How To' Manual

Stop Writing Newsletters The Hard Way! Here's How Anyone Can Turn Themselves Into An Award Winning Newsletter Editor! Discover How To Quickly and Easily Create Award Winning Newsletters In Less Than One Hour!




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DVD-Squeeze ::: DVD Copying Software

DVD Copy Program - DVD Squeeze, DVDX Copy, DVD XCopy. DVD Ripper using Dup DVD and DVD Wizard Pro!



  • Fun & Entertainment -- Music

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DVD Wizard Pro - DVD copy software, copy DVD to DVD/VCD/DIVX

DVD Wizard Pro -- a dvd copy software to copy DVD to DVD, copy dvd ripper to vcd, copy dvd ripper to divx avi file.



  • Fun & Entertainment -- Music

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EZ DVD Copy - burn, backup, copy any DVD movie, dvd copy software, ripper, DVD to DVD, VCD, SVCD, DivX

Copy any DVD to CD-R. No DVD burner required. EZDVDCopy is fastest and easiest way to burn copy backup rip any DVD.



  • Computing & Internet -- Programming

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Express Copy - 20% Off Your Postcard Marketing / Dir...

20% Off Your Postcard Marketing / Direct Mail Campaign




copy

RSS Copyright Debate

RSS is commonly defined as really simple syndication. So, this means that any material contained in a feed is available for syndication, right? Well no, not exactly. It means that the content contained in an RSS feed is in a format that is syndication friendly, if the copyright holder allows for syndication. Offering a feed for syndication does not in fact grant any legal rights to anyone to reuse the feeds content beyond what the Copyright laws grant as Fair Use.

RSS Copyright Debate




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Podcasts and Copyrights

Podcasting has a very low barrier to entry; all you need is audio recording software and a means of creating an RSS feed, be it through software or manual work. As a result, just about anyone can podcast, and the quality of podcasts is therefore highly variable; there are professional podcasts that rival professional broadcasts in quality, and there are amateur podcasts that can't even be heard clearly. For this reason, copyright infringement leeches, often unwittingly, into a number of podcasts. To produce a successful podcast, it is important to understand and respect Western copyright laws. To help ensure that these things are done, we have compiled some information about podcasts, music, and copyright law.

Podcasts and Copyrights




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Copyrights and Trademarks

Copyright is a type of intellectual property. A copyright is a set of exclusive rights granted by the government for a limited time to protect the particular form, way or manner in which an idea or information is expressed. Copyright is the legal protection given to artists or producers of creative work which protects them against unauthorized copying of their work.

All copyrighted material must be produced in a tangible medium (photo, paper, CD, or video). Concepts, processes and ideas can not be copy protected in the United States. If a statement is made yet not recorded or published it is not protected under the US copyright laws. In other words things must be recorded in a physical form in order to be protected under the copyright laws in the United States.

Copyrights and Trademarks




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Podcasts and Copyrights

Podcasting has a very low barrier to entry; all you need is audio recording software and a means of creating an RSS feed, be it through software or manual work. As a result, just about anyone can podcast, and the quality of podcasts is therefore highly variable; there are professional podcasts that rival professional broadcasts in quality, and there are amateur podcasts that can't even be heard clearly. For this reason, copyright infringement leeches, often unwittingly, into a number of podcasts. To produce a successful podcast, it is important to understand and respect Western copyright laws. To help ensure that these things are done, we have compiled some information about podcasts, music, and copyright law.

Podcasts and Copyrights




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Copywriting: the best side hustle for writers in 2023

Copywriting is the best side hustle for writers in 2023. Discover why it may be a good fit for you, plus how to get started.

The post Copywriting: the best side hustle for writers in 2023 appeared first on Coaching and training to scale your copywriting business, plus programs for new copywriters, startups, and marketers.





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Can I make money from copywriting? (Yes) A look at the possibilities

Not sure about making money from copywriting? This NEW post explores the possibilities of making good... heck, great... money from copywriting.

The post Can I make money from copywriting? (Yes) A look at the possibilities appeared first on Coaching and training to scale your copywriting business, plus programs for new copywriters, startups, and marketers.




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Copywriting for Startups: 7 Lessons To Drive Conversions

Effective copywriting is your secret weapon for driving conversions. With strategic word choice (based on voice of customer data) and a clear understanding of your target audience, you can craft copy that not only grabs attention but actively encourages action. Here's how...

The post Copywriting for Startups: 7 Lessons To Drive Conversions appeared first on Coaching and training to scale your copywriting business, plus programs for new copywriters, startups, and marketers.




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From Rookie to SaaS Copywriter Pro: A Newbie’s Blueprint

Becoming a SaaS copywriter is your ticket to being at the forefront of the tech industry, where your words have the power to turn interest into conversions. It's more than just writing. It's about understanding the pulse of the market and crafting messages that resonate with users on a personal level. You'll work with innovative brands, helping to shape messages that not only inform but also engage and inspire action. It's a dynamic, rewarding career path where your skill can directly contribute to a company's success, translating tech speak into language that connects, convinces, and converts.

The post From Rookie to SaaS Copywriter Pro: A Newbie’s Blueprint appeared first on Coaching and training to scale your copywriting business, plus programs for new copywriters, startups, and marketers.




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How To Write Emails: The Conversion Copywriter’s Approach

Conversion copywriters follow a simple 3-step process to get the ‘yes’ in email campaigns: First, they dive deep into understanding their audience, figuring out exactly what makes them tick. Then, they craft emails that are not just engaging but hit right at the heart of the reader's needs and desires. Every word is fine-tuned for clarity and impact. Finally, they test and tweak, ensuring the message not only resonates but also drives real action.

The post How To Write Emails: The Conversion Copywriter’s Approach appeared first on Coaching and training to scale your copywriting business, plus programs for new copywriters, startups, and marketers.




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How to drastically improve the copy on your site, even if you only have 5 minutes.

First, let me tell you a little story involving butterflies and bladders. I've spent the past few days at MicroConf. Just a phenomenal conference, full of like-minded folks, loaded with actionable content. Not to get too carried away, but it...




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How to calculate the return on investment (ROI) of expert copywriting

“A leader is one who knows the way, goes the way and shows the way,” - John C Maxwell, best-selling author, speaker and coach.

Genuine thought leadership is a powerful differentiator for any business.

Articles and reports that demonstrate true expertise, authority and insight stand apart from your competitors’ me-too blah-blah. They build trust, enhance your brand, help close deals and defend your margins.

High-quality content also avoids the Google penalties that come with spammy or AI-created content. Don’t take our word for that, here’s what Google has to say about creating helpful, reliable, people-first content. (See our take on AI in marketing too.)

What is high-quality content?

Thought-leadership copywriting provides unique insights, presents new research and uses data. It covers complex subjects in a new and engaging way. It is designed to expand readers’ understanding. It manages to be persuasive but not pushy.

Everyone can write, but not everyone is a writer. High-quality marketing content requires expert copywriters. (Read more about what a copywriter actually does.)

To get it right, writers require a deep understanding of their audiences, clients, products, the wider context of the industry, and the current shape of the market. For businesses embracing thought-leadership content, that’s where the true value lies.

But you have to invest time, money and marketing effort to realise this value. That can be challenging when business leaders and decision-makers can’t see the return on investment (ROI).

Let’s explore the ROI of copywriting and thought leadership to help you build a business case for their value.

What are the likely costs of copywriting and thought leadership?

The short answer? It depends. The long answer? There’s no one-size-fits-all cost and most writers will offer packages or tailored pricing. According to a study by Clutch, the average UK digital agency charges approximately £98.10 per hour. Research by DDIY suggests that a monthly content marketing retainer can cost between £1,805.78 and £23,551.50.

Of course, an hourly rate doesn’t tell you much about how long something will take or the required level of expertise needed to do an outstanding job.

That’s why, at Articulate, we charge for copywriting on a fixed price basis related to the length and complexity of the piece.

For maximum transparency and flexibility, we have a tariff—a kind of menu—of common writing deliverables such as case studies, white papers, or thought leadership articles. Our fixed prices include research, interviewing, writing, project management, editing, proofreading two rounds of revisions (if required), keyword optimisation, and, for blog articles, meta descriptions, a featured image and a couple of social posts.

Our marketing retainers start at £4,100 per month and one-off copywriting projects start at £5,000 for things like a case study library or a lead generation campaign centred around a flagship report or ebook.

We charge for website copywriting slightly differently, on a per-word basis, because of the additional complexity of integrating it with design, search engine optimisation and the rest of the development process. Also, in our experience, writing website copy for clients is like writing poetry and demands a high level of experience and client knowledge for your most important marketing asset.

Broadly speaking though, the cost of a content project will vary depending on the following factors: the who, the what, the when, the where and above all, the why.

The Who

Freelance copywriters and marketing agencies will charge different prices because, of course, their overheads and offerings are different. An agency may cost more but brings benefits such as editing, additional skills (e.g. SEO, research), better availability and turnaround times.

Then there are factors such as years of experience, location, specialisations and so on. You might also consider an in-house or staff writer who will require a competitive salary.

There are specific skills required to be a good marketing copywriter, including:

  • Marketing know-how
  • Business, sector and client knowledge
  • Interviewing skills
  • Research and analytical skills
  • Search engine optimisation, e.g. writing with keywords
  • Agility with tone of voice and messaging
  • Self- and pair-editing
  • Proofreading
  • Social media writing skills
  • Content planning and ideation

It’s helpful to put a good marketing copywriter with a reasonable level of skill and five or more years of experience in the same bracket as, say, a lawyer or an experienced, professional journalist writing for a trade magazine or reputable newspaper.

Typically, in an agency, they will work in teams that provide complementary skills and coverage for illness or holidays. All of this is hard to replicate in-house. (For more on this see our article: Should you hire a marketing person or a marketing agency.)

The What

The nature of your business and its content can impact how much copywriting will cost you. For technical or niche businesses, you’ll need to work with writers who understand your industry thoroughly or who have the skills and processes in place to learn about it efficiently.

You might not need to work with specialists if your company wants more generic content. But generic isn’t going to cut through the noise. Similarly, the length of your copy will affect the price, too. Some providers charge per project, others per word.

The When

How quickly and how often do you need copywriting and thought leadership content? Time-sensitive projects may incur additional costs to help you meet deadlines. And the more content you need, the more it will add up. A freelancer will struggle to produce tens of thousands of words in a short period of time but an agency can bring a whole team and a well-oiled production process to the challenge. You can, however, explore these helpful tips from the Articulate Marketing team on how to make every piece of content work harder for you.

The Where

Where are you posting, hosting or submitting the writing? The platform will impact the word count and, in turn, the price. A detailed report, an eBook or a long-form pillar page will set you back more than a 750-word blog post for your company website, for example. Similarly, copy for your home page might be short but it is very important and getting it right might take longer and cost more on a per-word basis than a more general piece.

The Why

Here’s where it gets interesting. You might know who you want to work with, what you want them to produce, when you need it and where it’s going. But do you know why you’re doing it? Have you considered who you want to read your thought-leadership content? And what you want them to do once they’ve read it?

From top-of-the-funnel content for brand awareness and lead generation to bottom-of-the-funnel content for conversions or customer retention, your copywriter needs to know what role your content plays in the context of your wider business.

In our opinion, the ‘why’ separates good writers from bad ones — and both kinds from the likes of ChatGPT. This is why we call our writers ‘marketing copywriters’ because they understand how to weave their work into broader marketing objectives.

So, what’s the ROI of copywriting and thought leadership?

Whether you choose to go external or in-house, there’s significant value in investing in the art of copywriting. Here’s why.

Demonstrate relevance and expertise

A study by Edelman and LinkedIn found that 73 percent of decision-makers say an organisation’s thought leadership content is more trustworthy for assessing its capabilities than its marketing materials.

The same study found that 80% of respondents want to see third-party data included in it, and 44% believe the highest-quality content helps them better understand a business's challenges and opportunities.

Decision-makers want to know why they should work with you. And your knowledge, experience, and expertise are your differentiators. The ROI? As many as 60 per cent of decision-makers say they’re willing to pay a premium to work with a business that produces good thought leadership.

Establish your brand and raise your profile

While thought-leadership and content marketing materials are busy showcasing your expertise, they’re also putting you on the map. Readers get to know your brand and tone of voice (TOV). Decision-makers may even share your content online, quote your research in their content, and reference your work conversationally.

The front of a buyer’s mind is a powerful place to be. Especially when we consider that 70 percent of C-suite executives said thought leadership content made them question their current B2B relationships — with 54 percent realizing other vendors might better understand their needs, according to a study by Edelman and LinkedIn.

Reach new audiences

A key part of establishing your brand with thought leadership is connecting with new audiences. Businesses often have a clear idea of who they want to work with and who wants to work with them. But growing your brand presence with thought leadership content means you’ll start to appear in new places online.

For example, when Basecamp founder Jason Fried tweeted about his company’s new ad, which called out Google’s paid ad strategy, he subsequently received over 1,000 backlinks to the company’s website. Depending on how you value backlinks, that could be worth up to $500,000 in SEO benefits.

This kind of thought-leadership content will help you rank for new search engine queries, generate more backlinks, appear in different social media feeds and so on. You might even find that your successful written content creates entirely new opportunities for you — podcast appearances, webinar invitations, the chance to speak at industry events and so on.

Build existing customer loyalty

Your written content doesn’t just serve the purpose of attracting new audiences. It’s a valuable tool for staying connected to your existing customers (and re-connecting with previous ones, too).

According to Accenture, 80 percent of businesses spend less than a third of their time and budget on customer-focused messaging. This presents a clear missed opportunity when considering loyal customers' ROI.

On average, a loyal customer is worth up to 10 times the value of their original purchase, according to the Office of Consumer Affairs. And, Bain and Co found that increasing customer retention by two percent has the same impact as reducing costs by 10 percent. Remember: the grass is greener where you water it!

Content is still king

Powerful, engaging, well-written thought leadership content has a functional role to play, too. Of course, establishing your brand, growing your audience, and giving your customers something to talk about are important. But high-quality written content is necessary to get discovered online. For example, brands that regularly update their blog get 67 percent more leads than those that don’t, according to Absurd Insights.

Similarly, search engines are starting to prioritise the quality of the content they promote to users, cracking down on misinformation, clickbait, spam, and AI-generated content. For example, Google looks for content showcasing experience, expertise, authority, and trustworthiness. This is called E-E-A-T content and thought leadership is precisely the kind of writing that reflects these crucial areas.

Recent Google updates penalise companies that fill up their site with cheap AI-generated SEO content. This tactic is just empty calories and now it’s creating marketing heart attacks for companies that tried it. The need for high-quality EEAT content has never been higher.

The final word

The ROI of thought leadership is going to take a lot of work to prove. That’s because it’s about more than just numbers. It’s about value. An AI-generated blog post will save you time and probably be fairly accurate. It may even generate a small amount of traffic (before Google recognises it as AI and penalises you for it, that is). But well-written thought leadership is a conversation starter. It’s the kind of content people are still thinking about after they’ve logged off. It makes potential customers think — and start questioning whether they’re working with the right providers. It’s full of insight, personality, colour and expertise. You can’t put a price on that.




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Big Brother is Watching But He Doesn’t Understand: Why Forced Filtering Technology on the Internet Isn’t the Solution to the Modern Copyright Dilemma

by Mitchell Longan[1] Introduction The European Parliament is currently considering a proposal to address problems of piracy and other forms of copyright infringement associated with the digital world.[2] Article 13 of the proposed Directive on Copyright in the Digital Single




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Multiplication complexity in education activities with fair use principle of copyright in Indonesia

Copying and duplicating papers for educational purposes is a violation form of copyright in Indonesia. The principle of fair use in education is a form of structured violation. Copying and duplicating the papers of the authors for educational purposes has provided commercial (business) benefits for libraries and universities. The research method is conducted using the observation method in libraries and universities that duplicate papers. The method also uses the normative juridical method that connects duplication of the papers in libraries and universities with the fair use principle. The results explain the authors' loss from copying and duplicating of papers in libraries and universities. Therefore, copying and duplicating the papers can only be done by implementing the responsibility system. Copying and duplicating the papers of the authors' in libraries and universities can be allowed if they fulfil the elements of copyright protection in the new concept.




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The Interface between Technological Protection Measures and the Exemptions to Copyright under Article 6 Paragraph 4 of the Infosoc Directive and Section 1201 of the Digital Millennium Copyright Act




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Judge In Absolute Bullshit Copyright Case Against Mariah Carey Signals She’s Leaning Carey’s Way

As the saying goes, the arc of morale judgment is long, but it does bend towards justice. And even if we accept such an optimistic worldview is relevant in this year of our lord, 2024, that certainly doesn’t mean we can’t bitch about how long that damned arc is. It’s been over two years since […]




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Plant Invasion and Imaging Spectroscopy




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Open exchange of scientific knowledge and European copyright: The case of biodiversity information




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Copyright and the Use of Images as Biodiversity Data




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U.S. Copyright Office: AI-Generated Art Can’t Be Copyrighted

Guest columnist James D. Berkeley details why a U.S. federal court dismissed an inventor’s attempt to copyright artwork produced by an image generator he designed.




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How to Write Copy That Converts Clients

Here are actionable tips and strategies for crafting compelling copy that attracts and converts clients in the ever-competitive security industry.




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Judge: Andy Warhol didn't violate Prince picture copyright

Andy Warhol transcended a photographer's copyright by transforming a picture of a vulnerable and uncomfortable Prince into an artwork that made the singer an "iconic, larger-than-life figure," a judge ruled Monday.




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A new copyright rule lets McDonald's fix its own broken ice cream machines

What would a McDonald’s be without its temperamental McFlurry machines? We may be closer to finding out.




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Density functional theory investigation of the phase transition, elastic and thermal characteristics for AuMTe2(M = Ga, In) chalcopyrite compounds

This study presents the first theoretical predictions of the phase transitions, elastic properties, and thermal behavior of AuMTe2 (M = Ga, In) chalcopyrite compounds. Using density functional theory and the quasi-harmonic Debye model, key mechanical and thermodynamic properties are analyzed, offering insights valuable for future experimental validation.




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Glucose-6-phosphate dehydrogenase and its 3D structures from crystallography and electron cryo-microscopy

Glucose-6-phosphate dehydrogenase (G6PD) is the first enzyme in the pentose phosphate pathway. It has been extensively studied by biochemical and structural techniques. 13 X-ray crystal structures and five electron cryo-microscopy structures in the PDB are focused on in this topical review. Two F420-dependent glucose-6-phosphate dehydrogenase (FGD) structures are also reported. The significant differences between human and parasite G6PDs can be exploited to find selective drugs against infections such as malaria and leishmaniasis. Furthermore, G6PD is a prognostic marker in several cancer types and is also considered to be a tumour target. On the other hand, FGD is considered to be a target against Mycobacterium tuberculosis and possesses a high biotechnological potential in biocatalysis and bioremediation.




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An alternative method to the Takagi–Taupin equations for studying dark-field X-ray microscopy of deformed crystals

This study introduces an alternative method to the Takagi–Taupin equations for investigating the dark-field X-ray microscopy (DFXM) of deformed crystals. In scenarios where dynamical diffraction cannot be disregarded, it is essential to assess the potential inaccuracies of data interpretation based on the kinematic diffraction theory. Unlike the Takagi–Taupin equations, this new method utilizes an exact dispersion relation, and a previously developed finite difference scheme with minor modifications is used for the numerical implementation. The numerical implementation has been validated by calculating the diffraction of a diamond crystal with three components, wherein dynamical diffraction is applicable to the first component and kinematic diffraction pertains to the remaining two. The numerical convergence is tested using diffraction intensities. In addition, the DFXM image of a diamond crystal containing a stacking fault is calculated using the new method and compared with the experimental result. The new method is also applied to calculate the DFXM image of a twisted diamond crystal, which clearly shows a result different from those obtained using the Takagi–Taupin equations.




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In situ characterization of stresses, deformation and fracture of thin films using transmission X-ray nanodiffraction microscopy

The use of hard X-ray transmission nano- and microdiffraction to perform in situ stress and strain measurements during deformation has recently been demonstrated and used to investigate many thin film systems. Here a newly commissioned sample environment based on a commercially available nanoindenter is presented, which is available at the NanoMAX beamline at the MAX IV synchrotron. Using X-ray nanoprobes of around 60–70 nm at 14–16 keV and a scanning step size of 100 nm, we map the strains, stresses, plastic deformation and fracture during nanoindentation of industrial coatings with thicknesses in the range of several micrometres, relatively strong texture and large grains. The successful measurements of such challenging samples illustrate broad applicability. The sample environment is openly accessible for NanoMAX beamline users through the MAX IV sample environment pool, and its capability can be further extended for specific purposes through additional available modules.




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Angle-resolved X-ray emission spectroscopy facility realized by an innovative spectrometer rotation mechanism at SPring-8 BL07LSU

The X-ray emission spectrometer at SPring-8 BL07LSU has recently been upgraded with advanced modifications that enable the rotation of the spectrometer with respect to the scattering angle. This major upgrade allows the scattering angle to be flexibly changed within the range of 45–135°, which considerably simplifies the measurement of angle-resolved X-ray emission spectroscopy. To accomplish the rotation system, a sophisticated sample chamber and a highly precise spectrometer rotation mechanism have been developed. The sample chamber has a specially designed combination of three rotary stages that can smoothly move the connection flange along the wide scattering angle without breaking the vacuum. In addition, the spectrometer is rotated by sliding on a flat metal surface, ensuring exceptionally high accuracy in rotation and eliminating the need for any further adjustments during rotation. A control system that integrates the sample chamber and rotation mechanism to automate the measurement of angle-resolved X-ray emission spectroscopy has also been developed. This automation substantially streamlines the process of measuring angle-resolved spectra, making it far easier than ever before. Furthermore, the upgraded X-ray emission spectrometer can now also be utilized in diffraction experiments, providing even greater versatility to our research capabilities.




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Open-source electrochemical cell for in situ X-ray absorption spectroscopy in transmission and fluorescence modes

X-ray spectroscopy is a valuable technique for the study of many materials systems. Characterizing reactions in situ and operando can reveal complex reaction kinetics, which is crucial to understanding active site composition and reaction mechanisms. In this project, the design, fabrication and testing of an open-source and easy-to-fabricate electrochemical cell for in situ electrochemistry compatible with X-ray absorption spectroscopy in both transmission and fluorescence modes are accomplished via windows with large opening angles on both the upstream and downstream sides of the cell. Using a hobbyist computer numerical control machine and free 3D CAD software, anyone can make a reliable electrochemical cell using this design. Onion-like carbon nanoparticles, with a 1:3 iron-to-cobalt ratio, were drop-coated onto carbon paper for testing in situ X-ray absorption spectroscopy. Cyclic voltammetry of the carbon paper showed the expected behavior, with no increased ohmic drop, even in sandwiched cells. Chronoamperometry was used to apply 0.4 V versus reversible hydrogen electrode, with and without 15 min of oxygen purging to ensure that the electrochemical cell does not provide any artefacts due to gas purging. The XANES and EXAFS spectra showed no differences with and without oxygen, as expected at 0.4 V, without any artefacts due to gas purging. The development of this open-source electrochemical cell design allows for improved collection of in situ X-ray absorption spectroscopy data and enables researchers to perform both transmission and fluorescence simultaneously. It additionally addresses key practical considerations including gas purging, reduced ionic resistance and leak prevention.