Tetra­kis(μ-acetato-κ2O:O')bis­{[1,3-bis­(2,6-diiso­propyl­phen­yl)imidazol-2-yl­idene-κC2]chromium(II)} tetra­hydro­furan disolvate, [Cr2(C2H3O2)4(C27H36N4)2]·2C4H8O or [Cr2(OAc)4(IDipp)2]·2C4H8O (1), and tetra­kis­(μ-acetato-κ2O:O')bis­{[1,3-bis­(2,4,6-tri­methyl­phen­yl)imidazol-2-yl­idene-κC2]chromium(II)}, {Cr2(C2H3O2)4(C21H24N2)2] or [Cr2(OAc)4(IMes)2] (2), were synthesized from anhydrous chromium(II) acetate [Cr2(OAc)4] and the corresponding NHC (NHC = N-heterocyclic carbene) in toluene as solvent. Both complexes crystallize in the triclinic system, space group Poverline{1}. The mol­ecular structures consist of Cr2(OAc)4 paddle-wheels that carry two terminal NHC ligands. This leads to a square-pyramidal coordination of the chromium atoms.

Clinical Study Results Show Nutrition 21's Chromax(R) Chromium Picolinate Improves Cognitive-Cerebral Function in Older

In the crystal structure of the title compound, (C5H6N)[Cr(NCS)4(C5H5N)2]·C5H5N, the CrIII ions are octa­hedrally coordinated by four N-bonding thio­cyanate anions and two pyridine ligands into discrete negatively charged complexes, with the CrIII ion, as well as the two pyridine ligands, located on crystallographic mirror planes. The mean planes of the two pyridine ligands are rotated with respect to each other by 90°. Charge balance is achieved by one protonated pyridine mol­ecule that is hydrogen bonded to one additional pyridine solvent mol­ecule, with both located on crystallographic mirror planes and again rotated by exactly 90°. The pyridinium H atom was refined as disordered between both pyridine N atoms in a 70:30 ratio, leading to a linear N—H⋯N hydrogen bond. In the crystal, discrete complexes are linked by weak C—H⋯S hydrogen bonds into chains that are connected by additional C—H⋯S hydrogen bonding via the pyridinium cations and solvent mol­ecules into layers and finally into a three-dimensional network.

The structure of the title compound, [CrCl2(C10H24N4)][Cr(HCONH2)2(C10H24N4)][ZnCl4]2 (C10H24N4 = 1,4,8,11-tetra­aza­cyclo­tetra­decane, cyclam; HCONH2 = formamide, fa), has been determined from synchrotron X-ray data. The asymmetric unit contains two independent halves of the [CrCl2(cyclam)]+ and [Cr(fa)(cyclam)]3+ cations, and one tetra­chlorido­zincate anion. In each complex cation, the CrIII ion is coordinated by the four N atoms of the cyclam ligand in the equatorial plane and two Cl ligands or two O-bonded formamide mol­ecules in a trans axial arrangement, displaying a distorted octa­hedral geometry with crystallographic inversion symmetry. The Cr—N(cyclam) bond lengths are in the range 2.061 (2) to 2.074 (2) Å, while the Cr—Cl and Cr—O(fa) bond distances are 2.3194 (7) and 1.9953 (19) Å, respectively. The macrocyclic cyclam moieties adopt the centrosymmetric trans-III conformation with six- and five-membered chelate rings in chair and gauche conformations. The crystal structure is stabilized by inter­molecular hydrogen bonds involving the NH or CH groups of cyclam and the NH2 group of coordinated formamide as donors, and Cl atoms of the ZnCl42− anion as acceptors.

A nickel-chromium-cobalt-molybdenum alloy includes (in weight %) Cr 21-23%, Fe 0.05-1.5%, C 0.05-0.08%, Mn≦0.5%, Si≦0.25%, Co 11-13%, Cu≦0.15%, Mo 8.0-10.0%, Ti 0.3-0.5%, Al 0.8-1.3%, P

Aqueous compositions useful as pretreatments prior to painting and to prevent the formation of white rust in the uncoated condition include an organopolyphosphonic acid or salt thereof, an organosilane, and a trivalent chromium compound. A method for treating a surface of a zinc-containing metal includes contacting the surface with an aqueous composition including an organopolyphosphonic acid or salt thereof, an organosilane, and a trivalent chromium compound. The composition may also include an agent for reducing hydrophilicity, such as a polyacrylic acid. The aqueous composition has been found to be particularly well-suited for treating a zinc-containing metal to passivate the surface, improve paint adhesion, and/or improve corrosion resistance.

In some embodiments, a solid oxide fuel system is provided. The solid oxide fuel cell system may include a chromium-getter material. The chromium-getter material may react with chromium to remove chromium species from chromium vapor. The solid oxide fuel cell system may also include an inert substrate. The chromium-getter material may be coated onto the inert substrate. The coated substrate may remove chromium species from chromium vapor before the chromium species can react with a cathode in the solid oxide fuel cell system.

(Ecole Polytechnique Fédérale de Lausanne) EPFL chemists have developed sponges to capture various target substances, like gold, mercury and lead, dissolved in solution. The sponges are actually porous crystals called metal organic frameworks, and now one exists for capturing toxic hexavalent chromium from water.

Guests Chris heilmann and Zohair Ali are developers for Microsoft working on the Edge project. Today they are talking about Edge on Chromium and the future of developer tools. Edge will now be built in Chromium rather than being its own engine, aligning it more with what is being used on the open web right now. The Edge team wanted to seize the opportunity to bring something into the Chromium project based on the needs of real users and contribute to the open source web. Edge on Chromium won’t be limited to Windows 10 either, but will be available on Mac, Windows 7, and Windows 8. This project is still in beta with no set release date, so the Edge team is looking for people to test it out on Mac and tell them how it works. 

Chris and Zohair talk about the different parts of a web browser and what distinguishes Chrome from Chromium.  Chromium is not just a platform, it’s an entire browser that you can install. Google adds a bunch of Google services to Chromium, such as being able to sign into your Google account,  and that’s how you get Google Chrome. Similarly, the new Edge adds its own features on top of Chromium, so you can sign into your Microsoft account. By now the browser engines are so similar to each other that the users are looking for the user experience, interface, and services around it, so it made more sense for the Edge team to contribute to Chromium than to maintain their own engine and help it improve.

Chris and Zohair talk about some of the features in Edge on Chromium. One service they’re particularly excited about is the Collections feature, where you can drag images, text, etc into Collections and export it to Excel or Word. Collections was inspired by what users need, and they talk about some of the different use cases for it. The new Edge on Chromium will also have an IE mode for products that still require IE 11. If you define what services need IE 11, Edge will open an IE 11 tab within the browser so you will not have to jump between browsers. Unfortunately, this feature is only available on Windows. Edge on Chromium will also offer an integration with VS Code, called Elements for VS Code, which takes part of the developer tools from Edge and puts it inside VS Code. Since the tools are based on Chromium, it stays in the same context all the time so you don’t have to jump back and forth, and you can see the changes live in your browser. This feature is in beta right now and they are looking for people to test it. 

The Edge team talks about their process for creating tools. They are working on putting their tools into other languages so that they are accessible to more people. They talk about how they want to avoid creating Edge specific tools as much as possible because they want to make it better for everybody. One of their biggest struggles is everybody demands developer tools, but nobody wants to contribute, so they don’t have as much feedback and not as much outside contribution. That’s why they keep calling for people to try out the new Edge on Chromium and give them feedback. They want to make that change more transparent so that they build things that people want. They will have to make some of their own tools, but they make sure that they don’t have any third party dependencies. They mention that all Chrome extensions are compatible with Edge, so if it’s available in the Chrome webstore, you can add it to Edge, you just have to be sure to allow it. They talk about some of the testing tools available. The show concludes with a discussion of the fate of Chakra Node. 

Panelists

• AJ O’Neal

• Aimee Knight

• Dan Shapir

• Steve Edwards

With special guests: Chris Heilmann and Zohair Ali

Sponsors

• Tidelift

• Sentry use the code “devchat” for 2 months free on Sentry’s small plan

• Views on Vue

Links

• Chromium

• Microsoft Edge Insider

• Microsoft Chakra Core

• Elements for VS Code

• MS Edge Driver

• Puppeteer 

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Picks

Aimee Knight:

• Cypress testing library

Steve Edwards: 

• CSS Tricks Screencast episode 174: Using Local Overrides in Devtools

Dan Shapir:

• The Chronicles of Amber

AJ O’Neal:

• The Legend of Zelda: Oracle of Ages

• Lover by Taylor Swift

Chris Heilmann:

• The Marvelous Mrs. Maisel

• TabNine

• doesthedogdie.com

Zohair Ali:

• Saga graphic novel series

I mentioned this the other day via Michelle Barker’s coverage, but here I’ll link to the official announcement. The main thing is that we’ll be getting gap with flexbox, which means:

.flex-parent {
  display: flex;
  gap: 1rem;
}
.flex-child {
  flex: 1;
}

That’s excellent, as putting space in between flex items has been tough in the past. We have justify-content: space-between, which is nice sometimes, but that doesn’t allow you to explicitly tell the flex container how … Read article “Chromium lands Flexbox gap”

The post Chromium lands Flexbox gap appeared first on CSS-Tricks.