science and technology

Microplastics promote cloud formation, with likely effects on weather and climate

Scientists show that microplastic particles can have the same effects, producing ice crystals at temperatures 5 to 10 degrees Celsius warmer than droplets without microplastics.




science and technology

Team at Kolkata institute engineers bacteria to solve maths problems

In a groundbreaking experiment, Saha Institute scientists have built bacterial computers that behave like artificial neural networks




science and technology

Unveiling the Cosmic Mystery: Why Is Space Dark?

Explore why space appears dark despite the countless stars in the universe. Learn about the inverse square law of light and the vast distances between stars that cause the darkness of space.




science and technology

Sunita Williams Bids Adieu To Boeing's Starliner; Spacecraft Left Space Station For Earth

Boeing's Starliner spacecraft has left the International Space Station (ISS) and is on its way back to Earth. 




science and technology

Elon Musk-Led Space X Aims For First Uncrewed Starship Mission To Mars Within 2 Years

Elon Musk-led SpaceX recently launched the third test flight of its 400-foot-tall Starship rocket, along with the Heavy booster. 




science and technology

Indian Space Startup Pixxel Bags NASA Contract To Support Earth Science Research

The satellites can help detect, monitor, and predict critical global phenomena across agriculture, oil and gas, mining, environment, and other sectors in up to 50 times richer detail. 




science and technology

Elon Musk's SpaceX Sent Three Civilians To Spacewalk On Polaris Dawn - Who Are They?

It lifted off atop a SpaceX Falcon 9 rocket today at after 5:23 a.m. EDT (2:54 PM IST) from historic Launch Complex-39A at NASA's Kennedy Space Center (KSC).




science and technology

Explained: Why Earth Vibrated For 9 Days Continuously In 2023? Know About Greenland Landslide Mega Tsunami

Due to climate change and rising global temperatures, the glaciers had been gradually thinning. When the glacier finally gave way, it sent a colossal amount of debris tumbling into the fjord, displacing enough material to fill around 10,000 Olympic-sized pools.




science and technology

'All Preparatory Steps For Manned Mission To Moon Approved': Minister Ashwini Vaishnaw As Cabinet Approves Chandrayaan-4 Mission

Union Cabinet today approved the 'Chandrayaan-4' mission, aimed at developing and demonstrating the technologies required for landing Indian astronauts on the moon and ensuring their safe return to Earth. 




science and technology

Bharatiya Anthariksh Station: India To Have Its Space Station, Announces PM Modi

The Union Cabinet today approved the first step towards the Bharatiya Antariksh Station.




science and technology

Water On The Moon: Surprising New Discovery Reveals The Moon Has More Water Than Expected!

New research reveals that the Moon contains far more water than previously thought, surprising scientists and reshaping future lunar exploration plans!




science and technology

NASA Astronaut Sunita Williams In Poor Health? Doctor Shares How Extended Space Stay Can Take A Toll

While concerns have been raised repeatedly about the health of the astronauts stuck in space, recent photos have stirred the discussion. Williams appears gaunt, which experts say might indicate nutritional deficiencies 




science and technology

Shining a light on methane dry reforming – exploring the impact of visible light on carbon formation over Co/xCeO2–Al2O3

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper
George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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science and technology

Exploring anodic oxidation reactions in hybrid water electrolysis: special emphasis on substrate choice

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00907J, Review Article
Baghendra Singh, Neetu Verma
Anodic oxidation reactions have been assessed focusing on essential parameters for the substrate choice.
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science and technology

Tuneable, in situ-generated nickel-hydride alkene isomerisation catalyst

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00974F, Paper
Melanie A. Kascoutas, Alison Sy-min Chang, Kiana E. Kawamura, Gabriela M. Bailey, Parker T. Morris, Elizabeth A. Borst, Lilliana H. Granados, Amanda K. Cook
A modular Ni(0)/silane E-selective alkene isomerization system has been developed with air-tolerant reagents.
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science and technology

MOF-derived N-doped CoNi@C as bifunctional catalysts for efficient water splitting

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00924J, Paper
Xihui Yang, Zekun Li, Zikun Yang, Dapeng Meng, Zhao Wang
CoNi@C core–shell catalysts from ZIF-67 were synthesized for efficient water splitting. The hydrophilic carbon shell inhibits metal oxidation. The CoNi alloy serves as the active site, while nitrogen doping promotes the electrocatalytic performance.
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science and technology

Synergy of Ag and Pd in bimetallic catalysts for the selective oxidation of 5-(hydroxymethyl)furfural

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01028K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Neukum, Maya Eyleen Ludwig, Georgios Uzunidis, Ajai Raj Lakshmi Nilayam, Baerbel Krause, Silke Behrens, Jan-Dierk Grunwaldt, Erisa Saraçi
The synthesis of renewable bio-based monomers, like 2,5-furandicarboxylic acid (FDCA), is of high interest in the shift toward a circular economy. Bimetallic catalysts offer the variation of different properties, enabling...
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science and technology

Ultrasmall RuO2/CoFe2O4 nanoparticles with robust interfacial interactions for the enhanced acidic oxygen evolution reaction

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper
Open Access
Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO2/CoFe2O4 nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO2 and CoFe2O4.
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science and technology

Hydrogenation of sulfoxides to sulfides mediated by incomplete cubane-type Mo3S4 clusters: synthetic applications and mechanistic insights

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper
Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo3S4 clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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science and technology

Exploration of the synergistic regulatory mechanism of hydroxide and fluoride modification on the photocatalytic activity of 2D g-C3N4

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00971A, Paper
Qianqian Shang, Hongbing Wang, Changjie Kan, Rui Ding, Yankai Li, Shiva Pandeya, Ziliang Li, Mahesh Kumar Joshi
Exfoliation and hetero-element doping are common procedures for band gap engineering and enhancing the photocatalytic properties of g-C3N4.
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science and technology

Graphdiyne (CnH2n−2) based copper(I) bromide dual S-scheme heterojunction with AX2O8 type compounds induced electron directional migration

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01031K, Paper
Xinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu Tsubaki
A fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.
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science and technology

DFT calculation-aided optimisation of a chiral phosphoric acid catalyst: case study of kinetic resolution of racemic secondary alcohols through lactonisation

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01029A, Paper
Haiting Ye, Takuma Sato, Taishi Nakanishi, Shigetomo Ito, Shigenobu Umemiya, Masahiro Terada
Chiral phosphoric acid catalysts were screened rationally and efficiently through the theoretical prediction model of the kinetic resolution of racemic γ-hydroxybutyrate without performing an exhaustive search for plausible lactonisation pathways.
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science and technology

Mechanistic insights into the oxidative coupling of methane over a Li/MgO catalyst: an experimental and microkinetic modeling study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper
Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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science and technology

Solar-Driven Tripus Photocatalytic Action of Defective S-doped g-C3N4 for 1,4 NADH Regeneration and Simultaneous Benzylamine Conversion along with CO2 Fixation into HCOOH

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00825A, Paper
Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Satyam Singh, Shaifali Mishra, Rehana Shahin, Atul Pratap Singh, Chandani Singh, Navneet Kumar Gupta, Jin-Ook Baeg, Hwanhui Yun, Hyeongjoong Kim
Incorporating defects through intrinsic defect engineering has emerged as a versatile strategy for finely tuning key properties of materials, particularly the redox capacity. Defects are fundamentally important in enhancement of...
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science and technology

Improved charge carrier mobility in a copper oxide heterostructure enhances the photocatalytic partial oxidation of benzyl alcohol to benzaldehyde

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00889H, Paper
Hanggara Sudrajat, Dmytro Lisovytskiy, Juan Carlos Colmenares
The enhancement of the partial oxidation of an aromatic alcohol to its corresponding aldehyde through the coupling of Cu2O with CuO is comprehensively discussed.
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science and technology

Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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science and technology

Exploring catalytic oxidation pathways of furfural and 5-hydroxymethyl furfural into carboxylic acids using Au, Pt, and Pd catalysts: a comprehensive review

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00821A, Review Article
Toyese Oyegoke, Franck Dumeignil, Baba E.-Yakubu Jibril, Carine Michel, Robert Wojcieszak
This review explores the mechanisms and factors influencing the selective oxidation of HMF and furfural into valuable products using gold, platinum, and palladium catalysts.
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science and technology

Mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds: a DFT study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper
Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
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science and technology

Vibrational frequencies utilized for the assessment of exchange–correlation functionals in the description of metal–adsorbate systems: C2H2 and C2H4 on transition-metal surfaces

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper
Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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science and technology

NiFe2O4: harnessing catalytic potential in water splitting

Catal. Sci. Technol., 2024, 14,6155-6175
DOI: 10.1039/D4CY00627E, Review Article
A. Anantha Krishnan, Sreehari Harikumar, M. A. Aneesh Kumar, Revathy B. Nair, Sajith Kurian, M. Ameen Sha, P. S. Arun
NiFe2O4 is a potential catalyst for energy conversion and storage, owing to their electrical conductivity, catalytic activity, and stability.
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science and technology

Advancing catalysis research through FAIR data principles implemented in a local data infrastructure – a case study of an automated test reactor

Catal. Sci. Technol., 2024, 14,6186-6197
DOI: 10.1039/D4CY00693C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Abdulrhman Moshantaf, Michael Wesemann, Simeon Beinlich, Heinz Junkes, Julia Schumann, Baris Alkan, Pierre Kube, Clara Patricia Marshall, Nils Pfister, Annette Trunschke
Digitalisation in experimental catalysis research: we are introducing machine-readable standard operating procedures combined with automated data acquisition, storage and sharing to improve research efficiency and reproducibility.
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science and technology

First-principles investigation of an efficient non-noble single-atom catalyst Fe1/Ti2CO2 for formaldehyde oxidation

Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper
Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe1/Ti2CO2 is an efficient catalyst that can remove indoor formaldehyde.
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science and technology

Cycloaddition of CO2 with epoxides into cyclic carbonates catalyzed by a binary organocatalyst under mild conditions

Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper
Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO2 into cyclic carbonates from flue gas under atmospheric pressure.
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science and technology

New insights into influences of initial oxidization states on dynamic reconstruction of Cu catalysts and C–C coupling in CO2 reduction

Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper
Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO2 reduction, resulting in the dynamic evolution of i-CuOx species. The in situ formed i-CuOx plays decisive roles in promoting C–C coupling.
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science and technology

Reducing meso-lactide formation from racemic lactic acid using shape-selective H-Beta zeolite

Catal. Sci. Technol., 2024, 14,6331-6337
DOI: 10.1039/D4CY01046A, Paper
Ling Ding, Lou Gao, Di Pan, Ke Du, Jiayu Yu, Wanyi Li, Yahong Zhang, Yi Tang
Efficiently reduce the formation of meso-lactide from racemic lactic acid by utilizing H-Beta zeolite shape selectivity towards lactic acid dimers.
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science and technology

Directed evolution of C-methyltransferase PsmD for enantioselective pyrroloindole derivative production

Catal. Sci. Technol., 2024, 14,6298-6306
DOI: 10.1039/D4CY00657G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Diana A. Amariei, Julia Tenhaef, Thomas Classen, Benoit David, Tobias M. Rosch, Holger Gohlke, Stephan Noack, Jörg Pietruszka
The engineering of stereoselective C-methyltransferase PsmD through saturation mutagenesis led to improved activity for larger substrates. An automated process was designed and successfully applied for the mutant library production and screening.
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science and technology

Influence of redox treatments on the low-temperature water gas shift reaction over Pt/CeO2 catalysts

Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper
Open Access
Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H2 reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO2 catalysts by increasing the number of active Pt0 NPs. A 12 h oxidative post-treatment at 500 °C which forms PtOx species easily activated also leads to improvement.
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science and technology

Theoretical insights into Pt–Rh alloy nanoparticles: stability, elemental distribution, and catalytic mechanisms for NO + CO reactions

Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper
Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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science and technology

Ag co-catalyst prepared by ultrasonic reduction method for efficient photocatalytic conversion of CO2 with H2O using ZnTa2O6 photocatalyst

Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper
Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO2 with H2O—known as artificial photosynthesis—is important.
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science and technology

A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
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science and technology

An overview: dinuclear palladium complexes for organic synthesis

Catal. Sci. Technol., 2024, 14,6112-6154
DOI: 10.1039/D4CY00425F, Review Article
Sarita Yadav, Sangeeta Yadav, Mookan Natarajan, Kamal Kishore Pant, Ravi Tomar
From materials science and polymer chemistry to organic synthesis and medicinal chemistry, cross-coupling has influenced many scientific fields.
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science and technology

Accelerated design of nickel-cobalt based catalysts for CO2 hydrogenation with human-in-the-loop active machine learning

Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO2 methanation and is extendable to other catalytic processes.
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science and technology

Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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science and technology

Enhancement mechanism of novel heterojunction Z-scheme-type composite BiOBr/ZnIn2S4 to degrade Congo red

Catal. Sci. Technol., 2024, 14,6363-6371
DOI: 10.1039/D4CY00912F, Paper
Junchao Huang, Borui Li, Jiaxing Yu, Zhan Shu, Ming Li
The Z-scheme three-dimensional flower-like shape BiOBr/ZnIn2S4 showed excellent efficiency to degrade Congo red.
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science and technology

Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis

Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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science and technology

Construction of a flow-through catalytic reactor employing O3–Fe/TiO2 for efficient catalytic ozonation disinfection

Catal. Sci. Technol., 2024, 14,6351-6362
DOI: 10.1039/D4CY00893F, Paper
Jiaxuan Li, Xin Chen, Siyu Li, Kunrong Mei, Lequan Liu, Jinhua Ye
An O3–Fe/TiO2 reactor is designed for efficient air disinfection by catalytically converting ozone into reactive oxygen species (ROS).
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science and technology

Single-step in situ synthesis of bimetallic catalysts via a gas-phase route: the case of PdZn–ZnO

Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper
Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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science and technology

Multiscale modelling of CO2 hydrogenation of TiO2-supported Ni8 clusters: on the influence of anatase and rutile polymorphs

Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO2 phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO2 hydrogenation to methane.
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science and technology

Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
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science and technology

Heterostructure engineered construction of N-doped CuO@Co3O4 for highly efficient electrocatalytic reduction of nitrate to ammonia

Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper
Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH3 can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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