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Physically crosslinked polyacrylates by quadruple hydrogen bonding side chains

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01702A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jente Verjans, Alexis André, Tomáš Sedlačík, Resat Aksakal, Evelyne van Ruymbeke, Richard Hoogenboom
Dynamic polymer materials with improved mechanical properties can be obtained by introducing supramolecular interactions between the polymer chains as demonstrated here by introducing ureidopyrimidinone quadruple hydrogen bonding units in the side chains of polyacrylates.
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Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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Multimodal layer-by-layer nanoparticles: a breakthrough in gene and drug delivery for osteosarcoma

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01541J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Eugenia Crisafulli, Annachiara Scalzone, Chiara Tonda-Turo, Joel Girón-Hernández, Piergiorgio Gentile
This study explored biodegradable nanoparticles for treating osteosarcoma. Co-delivery of miRNA-34a, doxorubicin, and resveratrol by LbL nanocoating enhanced apoptosis and cell disruption with promise to improve efficacy and reduce drug resistance.
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Unravelling the molecular mechanobiology by DNA-Based fluorogenic tension sensor

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01858C, Review Article
Kaushik Pal
Investigation of the biological system reveals many underlying principles that govern the regular life processes. Recently, the analysis of tiny mechanical forces associated with many biological processes revels their significance...
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'Not my responsibility to babysit anyone on Bigg Boss 10'

Karan Mehra is happy to get out of Bigg Boss 10.





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Meet Karan Mehra-Nisha Rawal's baby boy

Check out these adorable pictures!






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Bigg Boss 16: Is Sumbul A Cry Baby?

Sumbul Touqeer has turned out to be quite the cry baby of Bigg Boss 16. It's a pity, since she had made quite an impression on Salman Khan when she first entered the house.




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Sunny-Bobby's Revelation: The Men They Called For Help

From talking about their highs and lows to discussing their father Dharmendra's much-talked-about kiss in KJo's Rocky Aur Rani Kii Prem Kahaani, the Deol brothers were a laugh riot on the show.




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Get inspired by our rich past

Basking in a life of comfort and convenience, have we forgotten the wisdom of the tribal communities and the role they played in ensuring our survival?




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At K Sureshkumar’s pedagogical laboratory in Thiruvananthapuram students understand basic concepts of Physics by doing experiments on their own

National award-winning science teacher K Sureshkumar’s pedagogical laboratory in Thiruvananthapuram enables students of high school to conduct experiments in Physics and learn the concepts themselves



  • Life & Style


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Thousands Say Goodbye To Sinead O'Connor

Thousands of fans and well-wishers lined up the streets of Bray in Ireland to say their last goodbyes to Sinead O'Connor on August 8.




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'We are crushed by Matthew's death'

'He would love that the world is talking about how talented he was. And he really was very talented.'




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Rapid quantification of disaccharide isomers by derivatization in combination with ion mobility spectrometry in beer and milk

Analyst, 2024, 149,5298-5305
DOI: 10.1039/D4AN00995A, Paper
Keqi Ye, Jiacheng Ye, Yinghua Yan, Chuan-Fan Ding
This work introduces rapid quantification of disaccharide isomers by derivatization in combination with ion mobility spectrometry in beer and milk.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reference-free quantitative mass spectrometry in the presence of nonlinear distortion caused by in situ chemical reactions among constituents

Analyst, 2024, 149,5320-5328
DOI: 10.1039/D4AN00961D, Paper
Yusuke Hibi
Nonlinear reference-free analysis in pyrolysis-MS enables accurate compositional analysis even in reactive and interactive systems.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Surface-enhanced Raman spectroscopy with single cell manipulation by microfluidic dielectrophoresis

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN00983E, Paper
Kwanhwi Ko, Hajun Yoo, Sangheon Han, Won Seok Chang, Donghyun Kim
The combination of dielectrophoresis and surface-enhanced Raman spectroscopy provides an effective method for analyzing the Raman characteristics and the dielectrophoretic behavior of polystyrene beads and U-87MG cells in a microfluidic environment.
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Hyperpolarised [2-13C]-pyruvate by 13C SABRE in an acetone/water mixture

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01005A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Oksana A. Bondar, Gamal A. I. Moustafa, Thomas B. R. Robertson
The NMR hyperpolarisation technique SABRE has been used to hyperpolarise 13C labelled pyruvate in a predominantly aqueous solution which has then been measured by benchtop NMR.
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In situ study of the interactions between metal surfaces and cationic surfactant corrosion inhibitors by surface-enhanced Raman spectroscopy coupled with visible spectroscopy

Analyst, 2024, 149,5372-5380
DOI: 10.1039/D4AN00861H, Paper
Open Access
Felix Frank, Daniela Tomasetig, Peter Nahringbauer, Wolfgang Ipsmiller, Gerd Mauschitz, Karin Wieland, Bernhard Lendl
Coupling Raman and VIS spectroscopy enables the study of AgNP aggregations induced by surfactants.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Differentiation of oligosaccharide isomers by direct infusion multidimensional mass spectrometry

Analyst, 2024, 149,5504-5517
DOI: 10.1039/D4AN01142B, Paper
Open Access
Enoch Amoah, Taghi Sahraeian, Ayesha Seth, Abraham K. Badu-Tawiah
Halide adduction enables the generation of diagnostic fragments ions for oligosaccharide isomers enabling multi-dimensional mass spectrometry analysis without prior separation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Evaluating protocols for reproducible targeted metabolomics by NMR

Analyst, 2024, 149,5423-5432
DOI: 10.1039/D4AN01015A, Paper
Darcy Cochran, Panteleimon G. Takis, James L. Alexander, Benjamin H. Mullish, Nick Powell, Julian R. Marchesi, Robert Powers
Evaluating how sample preparation methods and data analysis platforms impact measured metabolite concentrations underscores the need for a universal consensus in the followed approaches for metabolomics data analysis.
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Evaluation of extracellular vesicle aggregation by single vesicle analysis

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01112K, Paper
Johan Yi, Suyeon Kim, Chungmin Han, Jaesung Park
A TIRF microscopy-based method for single vesicle aggregation analysis enables precise assessment of EV aggregation under various conditions, enhancing EV characterization and functional analysis.
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Exploring gunshot residue detection in fingerprints by functionalized particle-coupled matrix-assisted laser desorption/ionization mass spectrometry

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01260G, Paper
Sunil S. Adav, Yan Wen Crystal Tan, Choon Teck Low, Song Wei Loo, Ridhwan Yusoff, Archana Gautam, Yuk Lin Yong, Chiew Yung Yang, Chin Chin Lim, Kee Woei Ng
In firearm forensic investigations, detecting gunshot residue (GSR) is crucial for linking firearms to suspects and determining firing distance for forensic reconstruction.
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Densification of sodium and magnesium aluminosilicate glasses at ambient temperature: structural investigations by solid-state nuclear magnetic resonance and molecular dynamics simulations

Phys. Chem. Chem. Phys., 2024, 26,27348-27362
DOI: 10.1039/D4CP02431A, Paper
Millena Logrado, Yara Hellen Firmo Gomes, Tomiki Inoue, Shingo Nakane, Yoshinari Kato, Hiroki Yamazaki, Akihiro Yamada, Hellmut Eckert
Superposition of 17O triple-quantum magic-angle spinning NMR spectra of 20MgO–20Al2O3–60SiO2 (MAS**) and 20Na2O–20Al2O3–60SiO2 (NAS**) glasses prepared at ambient pressure (AP) and pressurized and decompressed at 25 GPa at room temperature (HP(25)).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrogen bond network structures of protonated 2,2,2-trifluoroethanol/ethanol mixed clusters probed by infrared spectroscopy combined with a deep-learning structure sampling approach: the origin of the linear type network preference in protonated fluoroal

Phys. Chem. Chem. Phys., 2024, 26,27751-27762
DOI: 10.1039/D4CP03534H, Paper
Po-Jen Hsu, Atsuya Mizuide, Jer-Lai Kuo, Asuka Fujii
Infrared spectroscopy combined with a deep-learning structure sampling approach reveals the origin of the unusual structure preference in protonated fluorinated alcohol clusters.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dynamics of ionic liquids by means of nuclear magnetic resonance relaxation – overview of theoretical approaches

Phys. Chem. Chem. Phys., 2024, 26,27248-27259
DOI: 10.1039/D4CP03183K, Review Article
Danuta Kruk, Elzbieta Masiewicz, Roksana Markiewicz, Rajendra Kumar Singh
Nuclear magnetic resonance relaxometry probes the translational and rotational dynamics of ionic liquids. To take advantage of this unique experimental potential, appropriate theoretical models are needed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A theoretical investigation on the OER and ORR activity of graphene-based TM–N3 and TM–N2X (X = B, C, O, P) single atom catalysts by density functional theory calculations

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03779K, Paper
Jiaxiang Wu, Erjun Kan, Cheng Zhan
Promising ORR/OER single atom catalysts have been designed in the form of TM–N2X via DFT simulation.
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Experimental and simulation study of reverse micelles formed by aerosol-OT and water in non-polar solvents

Phys. Chem. Chem. Phys., 2024, 26,27772-27782
DOI: 10.1039/D4CP03389B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angie Mat'usová, Georgina Moody, Peter J. Dowding, Julian Eastoe, Philip J. Camp
Small-angle neutron scattering and molecular dynamics simulations are used to characterise aerosol-OT reverse micelles. Simulations capture spontaneous self-assembly, compare favourably with experiments, and give microscopic information.
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Lattice thermal conductivity reduction in Ca3AlSb3 and Ca5Al2Sb6 by manipulating the covalent tetrahedral chain

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03574G, Paper
Chi Zhang, Wenya Zhai, Jingyu Li, Jianbo Zhu, Zengfu Ou, Lanwei Li, Peng-Fei Liu, Xiaobing Liu, Yuli Yan, Yongsheng Zhang
Exploring the origins of low thermal conductivity in Ca–Al–Sb compounds reveals structural interactions that enhance phonon scattering. Strategies involve substituting heavier atoms to disrupt covalent chains, thereby reducing thermal conductivity.
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Improved perovskite crystallization by antisolvent engineering in tin-perovskite photovoltaics

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02655A, Paper
Xin Zhang, Yu Liu, Xinyao Chen, Chunqian Zhang, Jigang Wang, Jin Cheng, Junming Li
By adding an appropriate proportion of DMS to the anti-solvent, the DMSO remaining in the tin-based perovskite films can be effectively extracted, resulting in films with better crystallography, and the devices have lower trap densities.
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Extraction mechanism of phenolic compounds by deep eutectic solvents: DFT and molecular dynamics studies

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03453H, Paper
Lan Yi, Jinwen Wang, Jixing Liu, Hao Luo, Xiaoqin Wu, Wen-Ying Li
The mechanism of a deep eutectic solvent consisting of choline chloride and glycerol (ChCl/GLY) for extracting phenolic compounds from coal tar was theoretically studied using density functional theory and molecular...
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Breaking barriers: Display by neurodiverse artists at Salar Jung Museum in Hyderabad

The Art Sanctuary presents a curated art show created by neurodiverse individuals, for the first time in Hyderabad




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Chennai | Memories and mothers are the centre of this exhibition-performance by Nimi Ravindran

Nimi Ravindran decides to open her Pandora’s box to mediate on memories and mothers at this exhibition-performance 




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Dark and disturbing: ‘Killer Joe’ by Tracy Letss to be staged in Hyderabad

Directed by Sandeep Tadi, the play is a collaboration between Storyboard Productions and Preksha Theatre Company




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High triboelectrification and charge collection efficiency of direct current triboelectric nanogenerator achieved by tri-synergistic enhancement strategy

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03784G, Paper
Shuyan Xu, Jian Wang, Chuncai Shan, Kaixian Li, Huiyuan Wu, Gui Li, Shaoke Fu, Qionghua Zhao, Yi Xi, Chenguo Hu
Direct current triboelectric nanogenerator (DC-TENG) utilized air-breakdown effect to collect triboelectrification charges from dielectric tribo-layers, providing a new type of mechanical energy harvesting mode for TENGs, which has demonstrated its...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00889D, Review Article
Mikhail O. Zubkov, Alexander D. Dilman
The review summarizes advances in the radical chemistry of polyfluorinated arenes under photocatalytic conditions. The fluoroaryl fragment serves as enabling motif for the reaction design and efficient generation of reactive intermediates.
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Layer-by-layer thinning of two-dimensional materials

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00817G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Phuong V. Pham, The-Hung Mai, Huy-Binh Do, M. Vasundhara, Van-Huy Nguyen, Trieu Nguyen, Hao Van Bui, Van-Duong Dao, Ram K. Gupta, Vinoth Kumar Ponnusamy, Jin-Hong Park
Etching technology – one of the representative modern semiconductor device makers – serves as a broad descriptor for the process of removing material from the surfaces of various materials, whether partially or entirely.
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Ferrari buoyed by pace after Australian GP practice

Leclerc's team mate Carlos Sainz was third quickest in FP2 on his return to racing two weeks after appendicitis surgery




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Lando Norris earns 1st career F1 victory by ending Verstappen's dominance at Miami

Lando Norris needed 110 starts and a mistake by Max Verstappen to earn his first ever Formula 1 race and end Verstappen’s dominance at the Miami Grand Prix




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Unfazed by fire in McLaren’s facility, Norris edges Verstappen for pole at Spanish GP

Lando Norris has snatched pole position from Max Verstappen during qualifying for the Spanish Grand Prix




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Daniel Ricciardo released by Red Bull F1 team; replaced by Liam Lawson for rest of 2024 season

The 35-year-old Ricciardo knew at the Singapore Grand Prix it was likely his final F1 race




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Everything you need to know about the all-new BYD eMAX 7

BYD India, a subsidiary of the global New Energy Vehicles (NEV) giant, has introduced the country’s first electric Multi-Purpose Vehicle (MPV) in six and seven-seater configurations




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Astronomy for curious kids : an illustrated introduction to the Solar System, our galaxy, space travel--and more! / [Giles Sparrow ; illustrated by Nik Neves]

Sparrow, Giles, 1970- author




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Biindigen! : Amik says welcome / Nancy Cooper ; illustrated by Joshua Mangeshig Pawis-Steckley

Cooper, Nancy, 1967- author




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Biogeology / by Christina Earley

Earley, Christina, author




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The boy who harnessed the wind / William Kamkwamba and Bryan Mealer ; pictures by Elizabeth Zunon

Kamkwamba, William, 1987- author




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Change is in the air : carbon, climate, Earth, and us / Debbie Levy ; illustrated by Alex Boersma

Levy, Debbie, author




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Climate / by Christina Earley

Earley, Christina, author