ni

Cleaning composition

Provided is an aqueous cleaning composition comprising at least one surfactant, xanthan gum, and a carbonate salt, wherein the composition has a turbidity of less than 16 NTU. Also provided is a method of cleaning a substrate by applying the cleaning composition to the substrate.




ni

Solid fast draining/drying rinse aid for high total dissolved solid water conditions

The present invention is a solid rinse aid composition and methods of making and using the same. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes an short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.




ni

Metal conservation with stripper solutions containing resorcinol

Resist stripping agents useful for fabricating circuits and/or forming electrodes on semiconductor devices for semiconductor integrated circuits and/or liquid crystals with reduced metal and metal alloy etch rates (particularly copper etch rates and TiW etch rates), are provided with methods for their use. The preferred stripping agents contain low concentrations of resorcinol or a resorcinol derivative, with or without an added copper salt, and with or without an added amine to improve solubility of the copper salt. Further provided are integrated circuit devices and electronic interconnect structures prepared according to these methods.




ni

Combination of crosslinked cationic and ampholytic polymers for personal and household applications

A cleansing composition for cosmetic or household use may include an ampholytic polymer; a crosslinked cationic polymer; a surfactant component selected from the group consisting of anionic surfactants, amphoteric surfactants, cationic surfactants, nonionic surfactants, and zwitterionic surfactants; and an aqueous and/or organic carrier.




ni

Cleansing composition with cationic surfactants

Disclosed is a cleansing composition containing from about 6% to about 20% of at least one nonionic surfactant; from about 3% to about 10% of at least one amphoteric surfactant; from about 2% to about 8% of at least one anionic surfactant; and from about 0.1% to about 5% of at least one cationic conditioning surfactant, cationic conditioning amine, or a mixture thereof; wherein the amount of nonionic surfactant present in the final composition is greater than the amount of the amphoteric surfactant, and the ratio of the nonionic surfactant (a) to anionic surfactant (c) is at least about 1.9 as much as the anionic surfactant, based on the weight percent of each surfactant in the final composition.




ni

Thickener containing a cationic polymer and softening composition containing said thickener, in particular for textiles

A method for softening laundry employs a softening composition, which includes at least one thickener containing a cationic polymer obtained by polymerization: of a cationic monomer;of a monomer with a hydrophobic nature, of formula (I): wherein R1=H or CH3 R2=alkyl chain having at least 16 carbon atomsX═O, m≧5, y=z=0, orX═NH, m≧z≧5, y=0, orX═NH, m≧y≧5, z=0, of a nonionic monomer.




ni

Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts

Methods employing detergent compositions effective for reducing soil redeposition and accumulation on hard surfaces are disclosed. The detergent compositions employ phosphinosuccinic acid adducts in combination with an alkalinity source and gluconic acid or salts thereof, copolymers of acrylic acid and maleic acids or salts thereof, sodium hypochlorite, sodium dichloroisocyanurate or combinations thereof.




ni

Gemini surfactants, process of manufacture and use as multifunctional corrosion inhibitors

Gemini surfactants of bis-N-alkyl polyether, bis-N-alkenyl polyether, bis-N-cycloalkyl polyether, bis-N-aryl polyether bis-beta or alpha-amino acids or their salts, are produced for use as multifunctional corrosion inhibitors, which protect and prevent corrosion of ferrous metals exposed to acidic, basic and neutral liquids when transporting or storing crude oil and liquid fuels. The surfactants are also used to inhibit corrosion of equipment and pipes used in cooling systems in petroleum and petrochemical equipment. The Gemini surfactants have the structural formula:




ni

Structured detergent or cleaning agent

The invention describes a stable liquid washing agent or liquid cleaning agent having a yield point and very good dispersing properties. The agents contain anionic and nonionic surfactants as well as inorganic salt and cosurfactant. The invention also relates to the use of the liquid washing agent or liquid cleaning agent, and to a method for manufacturing it.




ni

Low foam media cleaning detergent

A chemical composition for cleaning a medium is provided. For some embodiments, the chemical composition comprises a nonionic surfactant, an inorganic salt, a glycol compound, a chelating agent, and deionized water. For example, the chemical composition may comprise between about 1% and 5% of nonionic surfactant, between about 2% and 6% by weight of an inorganic salt, between about 5% and 10% by weight of a glycol compound, between about 5% and 10% by weight of a chelating agent, and deionized water.




ni

Enzyme composition comprising enzyme containing polymer particles

The present invention relates to an enzyme composition comprising enzyme containing polymer particles, which is useful for detergent compositions, in particular for liquid detergent compositions. In these enzyme containing particles, the particles comprise i) at least one enzyme, and ii) at least one polymer P, which is selected from homo- and copolymers having a C—C-backbone, wherein the C—C-backbone carries carboxylgroups, which may be present in the acidic form or in the neutralized form, and wherein the C—C-backbone comprises hydrophobic repeating units.




ni

Compositions for cleaning applicators for hair removal compositions

A non-aqueous liquid cleaning composition for applicators used for applying non-aqueous hair removal compositions to the skin. The composition includes a solubilizing oil effective for solubilizing the non-aqueous hair removal composition, e.g., mineral oil, and an effective antibacterial amount of an antibacterial agent, e.g., triclosan. The composition may also include fragrances and additional bacteriocides, e.g., phenoxyethanol. When the applicator is contacted with the heated cleaning composition any hair removal composition and bacteria on the applicator are removed therefrom and the applicator is ready for reuse. It is preferred to use surgical stainless steel applicators. Also provided are methods of using these compositions and kits containing, among other items, such compositions and applicators.




ni

Acidic viscoelastic surfactant based cleaning compositions comprising glutamic acid diacetate

Acidic viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in acidic cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide enhanced viscoelasticity and cleaning.




ni

Compressed gas aerosol composition comprising a non-ionic surfactant in a steel can

An aqueous compressed gas aerosol formulation in combination with a lined steel can, which may also optionally be tin plated, to provide corrosion stability, fragrance stability and color stability. An aerosol formulation of particular advantage for use is an air and/or fabric treatment formulation. The combination provides a compatibility which allows for the ability to use a broader fragrance pallet for the air and/or fabric treatment formulation which is aqueous based in major proportion. The formulation includes, in addition to an aqueous carrier, a fragrance, nonionic surfactant(s) or a blend of nonionic surfactant(s) and cationic surfactant(s), a compressed gas propellant(s), pH adjuster(s), and corrosion inhibitor(s). The formulation has a pH of about 8 to less than 10. The corrosion inhibitor(s) is (are) mild in strength and used in a minor amount.




ni

Granulated foam control composition comprising a polyol ester and cationic polymer

A granulated foam control composition comprises a foam control agent based on a polydiorganosiloxane fluid, an organic additive of melting point 45″17C to 100° C. comprising a polyol ester, a water-soluble particulate inorganic carrier and a polymer having a net cationic charge. The mean number of carbon atoms in the organo groups of the polydiorganosiloxane fluid is at least 1.3. The foam control agent includes a hydrophobic filler dispersed in the polydiorganosiloxane fluid, and optionally an organosilicone resin. The polyol ester is miscible with the polydiorganosiloxane fluid.




ni

Method for minimizing the diameter of a urea solution, urea solution and use of a surfactant in urea solution

A mixture of surfactants from alkylene oxide adducts with different degrees of alkoxylation is used in a urea solution to be added to an exhaust stream for reduction of nitrous gases.




ni

Method and apparatus for applying uniaxial compression stresses to a moving wire

An apparatus and method for moving a wire along its own axis against a high resistance to its motion causing a substantial uniaxial compression stress in the wire without allowing it to buckle. The apparatus consists of a wire gripping and moving drive wheel and guide rollers for transporting the moving wire away from the drive wheel. Wire is pressed into a peripheral groove in a relatively large diameter, rotating drive wheel by a set of small diameter rollers arranged along part of the periphery causing the wire to be gripped by the groove.




ni

Techniques for protecting a superconducting (SC) tape

Techniques for protecting a superconducting (SC) article are disclosed. The techniques may be realized as an apparatus for protecting a superconducting (SC) article. The apparatus may comprise a porous sleeve configured to fit around the superconducting (SC) article. The porous sleeve may be made of non-conductive, dielectric material.




ni

Intermediate connection unit of superconducting cables

In an intermediate connecting unit 50 of superconducting cables, by forming the connecting superconducting wires 101 in a trapezoid shape tapered in the direction of the electric insulating layer 113 (the superconducting shield layers 114) sides from the large radius section 213a side of the reinforcement insulating layer 213, the inclined surface sections 213b can be covered without spaces and without the plurality of connecting superconducting wires overlapping. The plurality of connecting superconducting wires 101 cover the inclined surface sections 213b of the reinforcement insulating layer 213 formed thicker than the radius of the cable cores 11 of the superconducting cables 10. The connecting superconducting wires 101 further connects the superconducting wires 10 arranged on the outer periphery of the large radius section 213a of the reinforcement insulating layer 213 and the superconducting wires 100 constituting the superconducting shield layers 114.




ni

Email administration for rendering email on a digital audio player

Methods, systems, and computer program products are provided for email administration for rendering email on a digital audio player. Embodiments include retrieving an email message; extracting text from the email message; creating a media file; and storing the extracted text of the email message as metadata associated with the media file. Embodiments may also include storing the media file on a digital audio player and displaying the metadata describing the media file, the metadata containing the extracted text of the email message.




ni

Automated communication integrator

An apparatus includes a plurality of applications and an integrator having a voice recognition module configured to identify at least one voice command from a user. The integrator is configured to integrate information from a remote source into at least one of the plurality of applications based on the identified voice command. A method includes analyzing speech from a first user of a first mobile device having a plurality of applications, identifying a voice command based on the analyzed speech using a voice recognition module, and incorporating information from the remote source into at least one of a plurality of applications based on the identified voice command.




ni

Script compliance and quality assurance based on speech recognition and duration of interaction

Apparatus and methods are provided for using automatic speech recognition to analyze a voice interaction and verify compliance of an agent reading a script to a client during the voice interaction. In one aspect of the invention, a communications system includes a user interface, a communications network, and a call center having an automatic speech recognition component. In other aspects of the invention, a script compliance method includes the steps of conducting a voice interaction between an agent and a client and evaluating the voice interaction with an automatic speech recognition component adapted to analyze the voice interaction and determine whether the agent has adequately followed the script. In yet still further aspects of the invention, the duration of a given interaction can be analyzed, either apart from or in combination with the script compliance analysis above, to seek to identify instances of agent non-compliance, of fraud, or of quality-analysis issues.




ni

Method and system for facilitating communications for a user transaction

Current human-to-machine interfaces enable users to interact with a company's database and enter into a series of transactions (e.g., purchasing products/services and paying bills). Each transaction may require several operations or stages requiring user input or interaction. Some systems enable a user to enter a voice input parameter providing multiple operations of instruction (e.g., single natural language command). However, users of such a system do not know what types of commands the system is capable of accepting. Embodiments of the present invention facilitate communications for user transactions by determining a user's goal transaction and presenting a visual representation of a voice input parameter for the goal transaction. The use of visual representations notifies the user of the system's capability of accepting single natural language commands and the types of commands the system is capable of accepting, thereby enabling a user to complete a transaction in a shorter period of time.




ni

Using a physical phenomenon detector to control operation of a speech recognition engine

A device may include a physical phenomenon detector. The physical phenomenon detector may detect a physical phenomenon related to the device. In response to detecting the physical phenomenon, the device may record audio data that includes speech. The speech may be transcribed with a speech recognition engine. The speech recognition engine may be included in the device, or may be included with a remote computing device with which the device may communicate.




ni

Speaker recognition from telephone calls

The present invention relates to a method for speaker recognition, comprising the steps of obtaining and storing speaker information for at least one target speaker; obtaining a plurality of speech samples from a plurality of telephone calls from at least one unknown speaker; classifying the speech samples according to the at least one unknown speaker thereby providing speaker-dependent classes of speech samples; extracting speaker information for the speech samples of each of the speaker-dependent classes of speech samples; combining the extracted speaker information for each of the speaker-dependent classes of speech samples; comparing the combined extracted speaker information for each of the speaker-dependent classes of speech samples with the stored speaker information for the at least one target speaker to obtain at least one comparison result; and determining whether one of the at least one unknown speakers is identical with the at least one target speaker based on the at least one comparison result.




ni

System, method and program product for providing automatic speech recognition (ASR) in a shared resource environment

A speech recognition system, method of recognizing speech and a computer program product therefor. A client device identified with a context for an associated user selectively streams audio to a provider computer, e.g., a cloud computer. Speech recognition receives streaming audio, maps utterances to specific textual candidates and determines a likelihood of a correct match for each mapped textual candidate. A context model selectively winnows candidate to resolve recognition ambiguity according to context whenever multiple textual candidates are recognized as potential matches for the same mapped utterance. Matches are used to update the context model, which may be used for multiple users in the same context.




ni

Speech recognition and synthesis utilizing context dependent acoustic models containing decision trees

A speech recognition method including the steps of receiving a speech input from a known speaker of a sequence of observations and determining the likelihood of a sequence of words arising from the sequence of observations using an acoustic model. The acoustic model has a plurality of model parameters describing probability distributions which relate a word or part thereof to an observation and has been trained using first training data and adapted using second training data to said speaker. The speech recognition method also determines the likelihood of a sequence of observations occurring in a given language using a language model and combines the likelihoods determined by the acoustic model and the language model and outputs a sequence of words identified from said speech input signal. The acoustic model is context based for the speaker, the context based information being contained in the model using a plurality of decision trees and the structure of the decision trees is based on second training data.




ni

Image-based character recognition

Various embodiments enable a device to perform tasks such as processing an image to recognize and locate text in the image, and providing the recognized text an application executing on the device for performing a function (e.g., calling a number, opening an internet browser, etc.) associated with the recognized text. In at least one embodiment, processing the image includes substantially simultaneously or concurrently processing the image with at least two recognition engines, such as at least two optical character recognition (OCR) engines, running in a multithreaded mode. In at least one embodiment, the recognition engines can be tuned so that their respective processing speeds are roughly the same. Utilizing multiple recognition engines enables processing latency to be close to that of using only one recognition engine.




ni

Multilingual electronic transfer dictionary containing topical codes and method of use

A multilingual electronic transfer dictionary provides for automatic topic disambiguation by including one or more topic codes in definitions contained the dictionary. Automatic topic disambiguation is accomplished by determining the frequencies of topic codes within a block of text. Dictionary entries having more frequently occurring topic codes are preferentially selected over those having less frequently occurring topic codes. When the topic codes are members of a hierarchical topical coding system, such as the International Patent Classification system, an iterative method can be used with starts with a coarser level of the coding system and is repeated at finer levels until an ambiguity is resolved. The dictionary is advantageously used for machine translation, e.g. between Japanese and English.




ni

Method, system, and computer readable medium for creating clusters of text in an electronic document

Disclosed herein are systems and methods for navigating electronic texts. According to an aspect, a method may include determining text subgroups within an electronic text. The method may also include selecting a text seed within one of the text subgroups. Further, the method may include determining a similarity relationship between the text seed and one or more adjacent text subgroups that do not include the selected text seed. The method may also include associating the text seed with the one or more adjacent text subgroups based on the similarity relationship to create a text cluster.




ni

Electronic device and method for providing menu using the same

An electronic device and a method for providing a menu are disclosed. The electronic device displays a plurality of words on the screen, detects a first action specifying selection of at least one of the displayed words, searches an option item related to the word selected by the first action, generates at least one menu item based on the selected word and the searched option item, and displays the generated menu item in a first area of the screen.




ni

Vehicular manipulation apparatus

A remote manipulation apparatus includes a main body and a manipulating handle manipulated by a user to move to cover all the orientations from a manipulation basis position defined on a basis of the main body. Movement of the manipulating handle relative to the manipulation basis position corresponds to movement of a pointer image relative to a screen basis position on a screen of a display apparatus. An auxiliary navigational display window includes a specified button image assigned with pointer-pulling information. When the auxiliary navigational display window appears on the screen, the manipulating handle is automatically driven to a position that corresponds to a position of the specified button image on the screen so that the pointer image is moved onto the specified button image that is assigned with the pointer-pulling information.




ni

Visualization techniques for imprecise statement completion

When a user enters text into an application, the application can utilize an auto-complete feature to provide the user with estimations as to a complete term a user is attempting to enter into the application. Visualization can be provided along with an estimation to disclose the likelihood the estimation is what the user intends to enter. Furthermore, a rationale can be provided to the user for the reason an estimation was provided to the user.




ni

Detecting automated identities in computer user communities

A computer-implemented method of detecting automated identities, including. The method includes, using one or more computing devices, providing for display to a user a first representation of a first profile for a first identity and a second representation of a second profile for a second identity, providing for display to the user a choice indication mechanism for indicating a judgment about the first representation of the first profile for the first identity and the second representation of the second profile for the second identity, receiving an indication of the judgment from the user about the first representation of the first profile for the first identity and the second representation of the second profile for the second identity, and determining whether at least one of the first identity, the second identity, or the user is more or less likely to be automated, based at least in part on the received indication.




ni

Handheld electronic device and method for performing spell checking during text entry and for providing a spell-check learning feature

A handheld electronic device includes a reduced QWERTY keyboard and is enabled with a disambiguation routine that is operable to disambiguate text input. In addition to identifying and outputting representations of language objects that are stored in the memory and that correspond with a text input, the device is able to perform a spell check routine during input of a text entry and to learn and automatically correct mistakes typically made by the particular user.




ni

Controlling the rendering of supplemental content related to electronic books

Architectures and techniques are provided to control the rendering of supplemental content associated with electronic books. For example, electronic books may be associated with content that is in addition to the content originally provided to an individual acquiring the electronic book, such as annotations, social networking site information, media outlet information, and the like. Individuals may control the supplemental electronic book content that is rendered via their client devices via actuation of a physical input device or a representation of an input device shown via a touch sensitive display. The amount of supplemental content that is rendered may correspond to information associated with a specified number of categories of supplemental electronic book content based on a supplemental content rendering level. In other implementations, the amount of supplemental electronic book content that is rendered may correspond to an amount of supplemental content to be rendered for each category of supplemental content.




ni

Minimizing and maximizing between portrait dual display and portrait single display

Methods and devices for minimizing and maximizing displayed output associated with applications are provided. More particularly, an application presented as two or more pages in a portrait mode can be minimized to present one of the two or more pages following a minimization operation. The page that continues to be displayed can comprise a primary or preferred page, while the page that is dismissed can comprise a secondary or ancillary page. With respect to a maximization operation received with respect to a page of an application results in the display of an additional page associated with that application. Maximization can include controlling the respective screens on which first and second pages of the maximized application are displayed.




ni

Method and apparatus for annotating an electronic document

A method and apparatus to mark-up an electronic document (i.e., a second electronic document) that is superimposed on a first electronic document keeping the first electronic document unchanged. The second electronic document is optionally viewed concurrently with the first electronic document. The second electronic document is capable of being viewed or modified using different application programs so long as the different application programs process the format used by the second electronic document. The second electronic document is saved as a separate document independent of the first electronic document.




ni

Synthesis of and curing additives for phthalonitriles

A composition having a mixture of the below compounds having a mole ratio of at least 1:20. Ar1 and Ar2 are independently selected aromatic groups. A composition comprising phthalonitrile compounds that comprise at least 5 mol % of the first compound below. A method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; a dihydroxyaromatic compound or anion thereof; an organic transition metal complex or a transition metal salt; an alkaline hydroxide base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form a dimetallic salt of an aromatic ether oligomer. The molar ratio of the dihydroxyaromatic compound to the dichloroaromatic compound is greater than 2:1. Water formed during the heating is concurrently distilled from the solution.




ni

Process of producing phosphinothricin employing nitrilases

The present invention generally relates to processes for the enzymatic production of a phosphinothricin product or precursor thereof from a nitrile-containing substrate.




ni

Point of use generation of amyl nitrite

The present disclosure relates to devices and methods for the preparation of amyl nitrite formulations at a point of use location from relatively shelf-stable reagents employing acidic cationic exchange resins.




ni

Phosphazene compound having vinyl group, resin composition containing the same, and circuit board manufactured from the same

A phosphazene compound having a vinyl group is manufactured by a reaction between a vinyl compound and a phosphazene compound having a hydroxyl group and added to a resin composition for manufacturing a prepreg or a resin film so as to be applicable to copper-clad laminates and printed circuit boards to thereby achieve satisfactory circuit laminate properties, namely low coefficient of thermal expansion, low dielectric properties, heat resistant, fire resistant, and halogen-free.




ni

Process for the preparation of 2-cyanophenylboronic acid and esters thereof

The present invention relates to a process for the synthesis of 2-cyanophenylboronic acid and the esters and salts thereof of formula (II), which are intermediates of the synthesis of active pharmaceutical ingredients such as Perampanel or E2040. formula (II): (II).




ni

Method for producing silica-supported catalyst, and method for producing unsaturated carboxylic acid or unsaturated nitrile

A method for producing a silica-supported catalyst comprising Mo, V. Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of proprane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water;(II) obtaining a dry powder by drying the raw material mixture solution; and(III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.




ni

Nitrate esters and their use for the treatment of muscle and muscle related diseases

Alkyl nitrate ester compounds are provided for the delivery of nitric oxide to targeted muscle tissues, and in particular, to normal and dystrophic muscles. In one aspect, nitrate ester compounds are provided having the following formula: wherein, R1 is ONO2, CH2ONO2, CnH2n+1OH, CnH2n+1OH, or CH2CH2CH3, or H;R2 is ONO2, CH2ONO2, Cn'H2n'+1OH, Cn'H2n'+1OH, CH2CH2CH3 or H; andR3 is ONO2, CH2ONO2, Cn'″H2n″+1OH, Cn″H2n″+1OH, CH2CH2CH3 or H; wherein n is an integer from 0 to 9, n' is an integer from 0 to 9, and n″ is an integer from 0 to 9, and n+n'+n″≦9, and wherein at least one of R1, R2, and R3 is an ester nitrate selected from the group consisting of ONO2, CH2ONO2, and combinations thereof.




ni

Crystalline form of 3-methylsulfonylpropionitrile

The present invention relates to processes for preparing 3-methylsulfonylpropionitrile. The processes provide a good yield and a good purity of the final product and provide a controllable reaction. The present invention also relates to a crystalline form of 3-methylsulfonylpropionitrile having X-ray diffraction peaks at 13.9±0.1, 19.2±0.1, 20.0±0.1, 22.5±0.1, 23.2±0.1, 25.7±0.1, 28.1±0.1, 29.9±0.1, and 30.6±0.1 degrees 2θ, and wherein the most intense peak is the peak at 13.9±0.1 degrees 2θ.




ni

Halo active aromatic sulfonamide organic compounds and uses therefor

Aromatic N-halosulfonamide organic compounds have been known for over one hundred years. The ability of these compounds to release active halogen ions has been utilized in a range of biocidal and fungicidal applications. This disclosure deals with the use of halo active aromatic sulfonamide organic compounds as odor control and/or biocidal agents in a cleaning solution for use with bovines and other dairy animals.




ni

Process for making nitriles

An improved multi-reaction zone process provides for improved nitrile product quality and yield. In a first reaction zone, 1,3-butadiene is reacted with hydrogen cyanide in the presence of a catalyst to produce pentenenitriles comprising 3-pentenenitrile and 2-methyl-3-butenenitrile. In a second reaction zone, 2-methyl-3-butenenitrile, recovered from the first reaction zone, is isomerized to 3-pentenenitrile. In an optional third reaction zone, 3-pentenenitrile recovered from the first and second reaction zones is reacted with hydrogen cyanide in the presence of a catalyst and a Lewis acid to produce adiponitrile. A portion of the first catalyst is purified and recycled. Zero valent nickel is added to the purified first catalyst before it is recycled.




ni

Process for making nitriles

Adiponitrile is made by reacting 3-pentenenitrile with hydrogen cyanide. The 3-pentenenitrile is made by reacting 1,3-butadiene with hydrogen cyanide and by isomerizing 2-methyl-3-butenenitrile. The reaction of 1,3-butadiene with hydrogen cyanide to produce 3-pentenenitrile also produces small amounts of dinitrile compounds, including adiponitrile (ADN) and methylglutaronitrile (MGN). Methylglutaronitrile is removed to provide an adiponitrile-enriched stream, which is used in a catalyst purification step.




ni

Process for making nitriles

The present invention relates to a process for hydrocyanating 3-pentenenitrile. The process can include feeding 3-pentenenitrile and HCN to a hydrocyanation reaction zone that includes a Lewis acid promoter, nickel, and a phosphorus-containing ligand. In various embodiments, the process can also include controlling water concentration within the hydrocyanation reaction zone sufficient to maintain a high activity of the ligand catalyst complex while recycling at least a portion of the ligand catalyst complex.