el Jewellery retailers fear a lacklustre Akshaya Tritiya this year due to soaring gold prices By www.thehindubusinessline.com Published On :: Fri, 12 Apr 2024 20:55:10 +0530 Akshaya Tritiya, which falls on May 10 this year, is considered auspicious to buy gold Full Article Gold & Silver
el Quick commerce firms Swiggy Instamart and Zepto to deliver gold and silver coins in 10 minutes By www.thehindubusinessline.com Published On :: Fri, 10 May 2024 18:08:19 +0530 Tata Digital’s Bigbasket has partnered with Tanishq and MMTC-PAMP to offer gold and silver coins and bars Full Article Gold & Silver
el Gold prices surge on Iran-Israel tension and US rate cut hopes By www.thehindubusinessline.com Published On :: Tue, 21 May 2024 19:16:16 +0530 Analysts anticipate continued volatility in gold prices, fluctuating between ₹71,000 and ₹75,000 in the near term Full Article Gold & Silver
el Silver likely to rule at higher levels this year on supply deficit By www.thehindubusinessline.com Published On :: Thu, 23 May 2024 09:00:00 +0530 Supply shortage forecast to increase by 17% even as industrial demand is projected to rise 9% Full Article Gold & Silver
el Gold prices likely to hit ₹81,000 per 10 grams as global market eyes $2,650 By www.thehindubusinessline.com Published On :: Thu, 30 May 2024 08:52:06 +0530 MOFSL recommends “buy on dips” approach on gold when prices were hovering at ₹69,000 and $2,250 in the international market Full Article Gold & Silver
el Bullion Cues: Prices likely to drop By www.thehindubusinessline.com Published On :: Sat, 01 Jun 2024 19:18:08 +0530 But traders can go long on dips Full Article Derivatives
el Gold steadies after slide below key $2,300 level By www.thehindubusinessline.com Published On :: Mon, 10 Jun 2024 09:53:22 +0530 Spot gold was up 0.2% at $2,396.69 per ounce, as of 0146 GMT. U.S. gold futures fell 0.5% to $2,313.60 Full Article Gold & Silver
el After dipping 5% from peak, gold likely to decline further By www.thehindubusinessline.com Published On :: Tue, 11 Jun 2024 18:45:11 +0530 The yellow metal set to lose its glitter on China pausing gold buys, US strong labour market Full Article Gold & Silver
el Tamil Nadu’s mineral exploration projects for gold, rare-earth elements approved By www.thehindubusinessline.com Published On :: Fri, 21 Jun 2024 18:57:39 +0530 The state has seen an increase in mineral revenue, with plans to explore new deposits through agencies like the Geological Survey of India. Full Article Gold & Silver
el Will ‘one nation, one gold rate’ add to the yellow metal’s sheen? By www.thehindubusinessline.com Published On :: Tue, 16 Jul 2024 20:45:12 +0530 Industry moots policy to bring transparency that can boost customer confidence Full Article Gold & Silver
el Budget 2024: Duty cut to lower gold prices. How will it impact jewellery stocks? By www.thehindubusinessline.com Published On :: Tue, 23 Jul 2024 20:14:59 +0530 A drop in gold price can lead to increased jewellery demand, improving their revenue and profits Market experts believe the price of yellow metal could drop between ₹300 and ₹500 per gram going ahead Full Article Gold & Silver
el Gold industry forms self-regulatory body to ensure transparency, boost trust By www.thehindubusinessline.com Published On :: Tue, 06 Aug 2024 19:28:37 +0530 The Association for Gold Excellence and Standards will frame good practices to be followed by the entire value chain of the industry, including bullion, jewellery manufacturers and retailers Full Article Gold & Silver
el As prices soften, festival period triggers buying interest in gold jewellery By www.thehindubusinessline.com Published On :: Mon, 09 Sep 2024 19:12:05 +0530 Sales up 20% during Ganesh Chathurthi, wedding demand could buoy demand for the precious metal further Full Article Gold & Silver
el Gold hits near record levels, silver follows suit amidst rising demand By www.thehindubusinessline.com Published On :: Fri, 11 Oct 2024 19:41:01 +0530 Gold prices surged by ₹1,150 to ₹78,500 per 10 grams, while silver prices rose by ₹1,500 to reach ₹93,000 per kg Full Article Gold & Silver
el Amid soaring gold prices, jewellers boost sales with sparkling innovations By www.thehindubusinessline.com Published On :: Sun, 20 Oct 2024 18:43:47 +0530 Jewellery brands in India are devising newer strategies and refining their existing approaches to alleviate the impact of soaring gold prices Full Article Gold & Silver
el Godrej & Boyce launches ISI-certified lockers for jewellers and pawnbrokers By www.thehindubusinessline.com Published On :: Tue, 22 Oct 2024 19:22:07 +0530 To improve security standards and ensure compliance with government regulations, all high-security safes are now mandated to carry an ISI mark Full Article Companies
el Jewellers woo Dhanteras buyers with attractive offers By www.thehindubusinessline.com Published On :: Tue, 29 Oct 2024 22:18:54 +0530 Gold prices have been hovering above Rs ₹78,600 per 10 gm-level consistently despite weak demand due to ongoing global geopolitical turmoil in West Asia and Russia-Ukraine Full Article News
el How to Help a Tree in Distress By www.berkshirepublishing.com Published On :: Fri, 21 Jan 2022 16:48:45 +0000 Karin Vaneker, a writer and activist in the Netherlands, has been helping me by tackling subjects that haven’t yet attracted much scholarly research for the second edition of the Encyclopedia of Sustainability. She’s written, for example, on including composting and community gardens - important, relevant, and yet somehow a little too close to home The post How to Help a Tree in Distress appeared first on Berkshire Publishing. Full Article Berkshire Blog Karen's Letter
el Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9] By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02698E, PaperZhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua ZhangNon-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02619E, PaperChunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao NieLithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02714K, PaperAna Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva MaiaThe diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02303J, PaperTao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan WangNi/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02659D, PaperSunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua SunThe coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02469A, PaperZhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei QinHeteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02467B, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank VanhaeckeThis study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02310B, PaperCai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui WenThe automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02734E, PaperHui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang TangA biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02606C, PaperIan DanceI describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02645D, PaperKetan Maru, Sarita Kalla, Ritambhara JangirThe study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02871F, PaperYuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing LiThe reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02514H, PaperKhalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique LorcyMultinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT03006K, CommunicationReiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu YinRod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02756F, PaperXiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing WanHerein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02940B, PaperThi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek DereńThe increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me] By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT01863J, PaperRodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn PillingerFor inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02440K, PaperRebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig AndrewsFive complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17819-17828DOI: 10.1039/D4DT01625D, PaperSonghan Hu, Kai Wang, Xinxin Xu, Qiang WangTwo Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17803-17818DOI: 10.1039/D4DT01490A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. VilaThe study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC50 values.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17756-17765DOI: 10.1039/D4DT01868K, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozary, Claude PiguetEfficient and easy lanthanide(III)-based luminescence reading of iron(II) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17742-17755DOI: 10.1039/D4DT01727G, PerspectiveEduarda Andrade, Filipe A. Almeida Paz, Flávio FigueiraMOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Single-ion magnetism in novel Btp-based cobalt complexes of different charge By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02338B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez LópezBy deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Price pooling mantra: Wake up to expensive electricity By www.thehindubusinessline.com Published On :: Tue, 02 Apr 2013 13:15:05 +0530 Full Article Siddhartha P Saikia
