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Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

Chem. Sci., 2020, 11,4287-4296
DOI: 10.1039/C9SC06006E, Minireview
Open Access
Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. Engle
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Liberating praxis : Paulo Freire's legacy for radical education and politics / by Peter Mayo (University of Malta)

Mayo, Peter, 1955- author




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Trends in biomedical research Mieczyslaw Pokorski, editor

Online Resource




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Statistical modeling in biomedical research: contemporary topics and voices in the field / Yichuan Zhao, Ding-Geng (Din) Chen, editors

Online Resource




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Victorian Women Writiers, Radical Grandmothers, and the Gendering of God / Gail Turley Houston

Online Resource




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Shifting interests [electronic resource] : the medical discourse on abortion in English Canada, 1850-1969 / by Tracy Penny Light

Waterloo, Ont. : University of Waterloo, 2003




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Karnataka may rope in private medical colleges if Covid-19 cases surge post lock-down

The government will provide doctors with a checklist to follow regarding treatment. We will also be applying to ICMR to seek permission to conduct lung biopsies after the death of patients and for clinical autopsies. This will help in providing critical patients with more effective care and bring down mortality rates, Health and Family Welfare Commissioner Pankaj Kumar Pandey said.




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As senior GPs, doctors of private hospitals sit at home, medical students run the Covid show in Mumbai

Resident doctors, MBBS students and those serving their bond are at the frontline in the fight against Covid-19 in the city as senior clinicians stay away from their duty, leaving the young team of medical professionals firefighting the crisis on their own.




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A polio outbreak threatens global eradication plans, and what happened to America’s first dogs

Wild polio has been hunted to near extinction in a decades-old global eradication program. Now, a vaccine-derived outbreak in the Democratic Republic of the Congo (DRC) is threatening to seriously extend the polio eradication endgame. Deputy News Editor Leslie Roberts joins host Sarah Crespi to talk about the tough choices experts face in the fight against this disease in the DRC. Sarah also talks with Online News Editor David Grimm about when dogs first came to the Americas. New DNA and archaeological evidence suggest these pups did not arise from North American wolves but came over thousands of years after the first people did. Now that we know where they came from, the question is: Where did they go? Read the research. This week’s episode was edited by Podigy. Download a transcript of this episode (PDF) Listen to previous podcasts. About the Science Podcast [Image: Polio virus/David Goodsell/RCSB PDB; Music: Jeffrey Cook]




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Will a radical open-access proposal catch on, and quantifying the most deadly period of the Holocaust

Plan S, an initiative that requires participating research funders to immediately publish research in an open-access journal or repository, was announced in September 2018 by Science Europe with 11 participating agencies. Several others have signed on since the launch, but other funders and journal publishers have reservations. Host Meagan Cantwell speaks with Contributing Correspondent Tania Rabesandratana about those reservations and how Plan S is trying to change publishing practices and research culture at large. Some 1.7 million Jewish people were murdered by the Nazis in the 22 months of Operation Reinhard (1942–43) which aimed to eliminate all Jews in occupied Poland. But until now, the speed and totality of these murders were poorly understood. It turns out that about one-quarter of all Jews killed during the Holocaust were murdered in the autumn of 1942, during this operation. Meagan talks with Lewi Stone, a professor of biomathematics at Tel Aviv University in Israel and mathematical science at RMIT University in Melbourne, Australia, about this shocking kill rate, and why researchers are taking a quantitative approach to characterizing genocides. This week’s episode was edited by Podigy. Download the transcript (PDF) Listen to previous podcasts. About the Science Podcast [Image: Michael Beckwith; Music: Jeffrey Cook]




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Bio-assay of non-amidated progastrin-derived peptide (G17-Gly) using Tailor-made recombinant antibody fragment and phages display method: A biomedical analysis

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00627K, Paper
Deniz Sadighbayan, Mohammad Reza Tohid-kia, Tayebeh Mehdipour, Mohammad Hasanzadeh, Ahmad Yari Khosroushahi
In this research, four novel and sensitive immunosensor for electrochemical determination of G17-Gly were designed based on signal amplification and tailor-made recombinant antibody technology. Anti-G17-Glyantibody fragments (i.e. scFv and VL...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Colorimetric indicators for volatile amines based on succinic anhydride (SAh)-grafted poly (lactic acid) (PLA)

Anal. Methods, 2020, Advance Article
DOI: 10.1039/D0AY00550A, Paper
Adrian Lopera-Valle, Anastasia Elias
Smart materials that can undergo changes in color upon the detection of amines have the potential to provide information on the freshness of fish and meat.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A nation on the line: call centers as postcolonial predicaments in the Philippines / Fan M. Padios

Barker Library - HE8789.P6 P33 2018




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The people want : a radical exploration of the Arab uprising / Gilbert Achcar ; translated from the French by G.M. Goshgarian

Achcar, Gilbert




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[ASAP] Method for Structural Determination of Lipid-Derived Radicals

Analytical Chemistry
DOI: 10.1021/acs.analchem.0c00053




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[ASAP] <italic toggle="yes">Ab Initio</italic> Kinetics of Methylamine Radical Thermal Decomposition and H-Abstraction from Monomethylhydrazine by H-Atom

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.0c02389




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Positive Findings from Year 2 of the Centers for Medicare &amp; Medicaid Services’ Million Hearts&#174; Cardiovascular Disease Risk Reduction Model

Mathematica has released positive evaluation findings from Year 2 of the Million Hearts® model, just in time for American Heart Month this February.




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Inventory of State-Level Medicaid Policies, Programs, and Initiatives to Improve Maternity Care and Outcomes

Mathematica was contracted by Medicaid and CHIP Payment and Access Commission (MACPAC) to create an updated inventory of state- and territory-level Medicaid policies, programs, or initiatives that are designed to improve the access to, quality of, and outcomes of maternity care services.




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Effects of Medicaid Expansion on Access, Treatment, and Outcomes for Patients with Acute Myocardial Infarction

Uninsured patients have decreased access to care, lower rates of percutaneous coronary intervention (PCI), and worse outcomes after acute myocardial infarction (AMI).




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Mathematica to Lead Transitional Program Office to Expand Graduate Medical Education in California

The California Health Care Foundation is funding a transitional graduate medical education program office in California to help address physician shortages.




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Medically important plant biomes: source of secondary metabolites / Dilfuza Egamberdieva, Antonio Tiezzi, editors

Online Resource




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Green heroes: from Buddha to Leonardo DiCaprio / László Erdős

Online Resource





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Extreme reactions: radical right mobilization in Eastern Europe / Lenka Bustikova, Arizona State University

Dewey Library - JC573.2.E852 B88 2020





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Yellow power, yellow soul [electronic resource] : the radical art of Fred Ho / edited by Roger N. Buckley and Tamara Roberts




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Zapatistas [electronic resource] : the Chiapas revolt and what it means for radical politics / Mihalis Mentinis

Mentinis, Mihalis




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A Woman in Her 20s With Chest Pain and Arm Claudication

This case report describes bilateral calcified coronary aneurysms with a significant proximal left anterior descending and right coronary artery stenoses immediately distal to the aneurysms.




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Performance indicators for water supply services / Helena Alegre, Jaime Melo Baptista, Enrique Cabrera Jr., Francisco Cubillo, Patrícia Duarte, Wolfram Hirner, Wolf Merkel, Renato Parena

Alegre, Helena, author




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HC suspends decision to surrender medical PG diploma courses

This is not the way to treat govt. doctors, observes bench




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Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N,N'-(1,2-phenylene)bisamides and 2-amidophenols

Org. Chem. Front., 2020, 7,1095-1106
DOI: 10.1039/C9QO01508F, Research Article
Damoder Reddy Motati, Dilipkumar Uredi, Amarender Goud Burra, J. Phillip Bowen, Frank R. Fronczek, Clint R. Smith, E. Blake Watkins
A highly efficient, site-selective, visible light-accelerated, remote C–H halogenation of unsymmetrical aromatic bisamides/amidoesters has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Insights into N-heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of α,β-unsaturated aldehyde with 1,3-dicarbonyl compounds

Org. Chem. Front., 2020, 7,1113-1121
DOI: 10.1039/D0QO00091D, Research Article
Xinghua Wang, Yang Wang, Jinshuai Song, Donghui Wei
N-Heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of 1,3-dicarbonyl compounds have been systematically studied in theory.
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Measurement of the Proton Affinities of a Series of Mono- and Biradicals of Pyridine

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c00202




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[ASAP] Too Persistent to Give Up: Aromaticity in Boron Clusters Survives Radical Structural Changes

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c02228




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[ASAP] Copper-Catalyzed Asymmetric Radical 1,2-Carboalkynylation of Alkenes with Alkyl Halides and Terminal Alkynes

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03130




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[ASAP] 1,<italic toggle="yes">n</italic>-Bisborylalkanes via Radical Boron Migration

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03058




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[ASAP] Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03125




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Polymer-based additive manufacturing: biomedical applications / Declan M. Devine, editor

Online Resource




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Selective modification of Ti6Al4V surfaces for biomedical applications

RSC Adv., 2020, 10,17642-17652
DOI: 10.1039/C9RA11000C, Paper
Open Access
Gabriela Melo Rodriguez, James Bowen, Mischa Zelzer, Artemis Stamboulis
The surface of a medical implant is required to interact favourably with ions, biomolecules and cells in vivo, commonly resulting in the formation of the extracellular matrix.
The content of this RSS Feed (c) The Royal Society of Chemistry




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No fees for medical screening, Maharashtra tells HC

Court wants decision on levying costs for transport of migrant workers





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JAMA Internal Medicine : Analysis of Proposed Medicare Reforms on Prescription Drug Total Spending and Patient Cost-Sharing

Interview with Aaron Kesselheim, author of Analysis of Proposed Medicare Part B to Part D Shift With Associated Changes in Total Spending and Patient Cost-Sharing for Prescription Drugs, and Francis J. Crosson, M.D., author of Managing the Cost of Medicare Part B Drugs: Implications for the Program and Beneficiaries







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Indian American therapist found guilty of medicare fraud



  • DO NOT USE Indians Abroad
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