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A melange of genres

Rang-Sangam brought different forms of dance and music on one stage.




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‘One should not take liberty in the name of novelty’

In a freewheeling conversation, Vidushi Ashwini Bhide Deshpande tells Manjari Sinha what makes her performance an emotional experience.




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Amidst the heights of melody...

The 3rd Shimla Classical Music Festival saw some of the finest musicians showcasing commendable execution of intricate compositions.




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Deliberations on dhrupad

Arijit Mahalanabis’s workshop dealt with order and presentation in Hindustani music.




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On a different wavelength

Jayateerth Mevundi and M. Narmada tried to establish a voice-violin connect.




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Mahindra Kabira Festival: Celebrating diversity by the banks of the Ganga

The sixth edition of the Mahindra Kabira Festival underlined the relevance of Kabir in modern times




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Music on the streets of Mylapore: Why Carnatic vocalist Saketharaman is celebrating an age-old tradition

How Carnatic vocalist Saketharaman is taking the veedhi bhajan tradition to the younger generation




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Market capitalization of privately listed companies surged 6.4 times, PSUs grew 5 times over last 10 years: Motilal Oswal




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Political stability boosts India's apparel appeal for exports




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Union Finance Minister Nirmala Sitharaman meets AIIB Board of Directors in Delhi




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Japan to push for biofuel-compatible new cars by 2030s




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Truly insightful: Gautam Adani hosts envoys from EU, Belgium, Denmark and Germany




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Bears on prowl! Sensex tanks 820 points, Nifty below 24,000




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Enhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures

Chem. Sci., 2024, 15,18060-18066
DOI: 10.1039/D4SC05442C, Edge Article
Open Access
Zheng-Xiao Tang, Bin Wang, Zhi-Rui Li, Zhuo Huang, Hai-Xia Zhao, La-Sheng Long, Lan-Sun Zheng
A molecule-based ferroelectric [(CH3)3NCH2CH2Br][GaBr4] (1), with a d33 value of 331 pC N−1, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm−2.
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Spotting d-band centers of single-atom catalysts by oxygen intermediate-boosted electrochemiluminescence

Chem. Sci., 2024, 15,18085-18092
DOI: 10.1039/D4SC03763D, Edge Article
Open Access
Ruyu Xie, Kaitao Li, Rui Tian, Chao Lu
We have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.
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Recent advances in hydrogel-based flexible strain sensors for harsh environment applications

Chem. Sci., 2024, 15,17799-17822
DOI: 10.1039/D4SC05295A, Review Article
Open Access
Miaoyu Li, Jie Pu, Qinghe Cao, Wenbo Zhao, Yong Gao, Ting Meng, Jipeng Chen, Cao Guan
The application of hydrogel-based flexible strain sensors in harsh environments, including extreme temperatures, humidity, high mechanical strain, and strong corrosion, is investigated.
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Automated electrosynthesis reaction mining with multimodal large language models (MLLMs)

Chem. Sci., 2024, 15,17881-17891
DOI: 10.1039/D4SC04630G, Edge Article
Open Access
Shi Xuan Leong, Sergio Pablo-García, Zijian Zhang, Alán Aspuru-Guzik
Leveraging multimodal large language models (MLLMs) to process multimodal data inputs and complex inter-modality data dependencies for automated (electro)chemical data mining from scientific literature.
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A facile self-saturation process enabling the stable cycling of a small molecule menaquinone cathode in aqueous zinc batteries

Chem. Sci., 2024, 15,17971-17978
DOI: 10.1039/D4SC04685D, Edge Article
Open Access
Shuo Li, Guoli Zhang, Qianrui Li, Tianshun He, Xiaoqi Sun
A facile self-saturation strategy, realized by the introduction of a hydrophobic methyl group on naphthoquinone, is demonstrated to suppress the dissolution of small molecule cathode materials and achieve stable cycling in aqueous zinc cells.
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MR-TADF liquid crystals: towards self assembling host–guest mixtures showing narrowband emission from the mesophase

Chem. Sci., 2024, 15,18022-18030
DOI: 10.1039/D4SC04429K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Julius A. Knöller, Franziska Müller, Tomas Matulaitis, John M. dos Santos, Abhishek Kumar Gupta, Eli Zysman-Colman, Sabine Laschat
We developed a MR-TADF based, columnar liquid crystalline host system and doped it with a MR-TADF guest. Efficient FRET allowed us to construct the first columnar liquid crystal with narrowband MR-TADF from the strongly aggregated mesophase.
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Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors

Chem. Sci., 2024, 15,18111-18126
DOI: 10.1039/D4SC04852K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. Ofial
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.
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FragGen: towards 3D geometry reliable fragment-based molecular generation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04620J, Edge Article
Open Access
Odin Zhang, Yufei Huang, Shichen Cheng, Mengyao Yu, Xujun Zhang, Haitao Lin, Yundian Zeng, Mingyang Wang, Zhenxing Wu, Huifeng Zhao, Zaixi Zhang, Chenqing Hua, Yu Kang, Sunliang Cui, Peichen Pan, Chang-Yu Hsieh, Tingjun Hou
FragGen introduces a novel fragment-based AI-based molecular design method. It proposes the geometry handling protocol to improve the generation quality and has been applied to design highly bioactive type II kinase inhibitors.
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Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05998K, Edge Article
Open Access
Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.
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Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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The Effect of gem-Difluorination on the Conformation and Properties of a Model Macrocyclic System

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05424E, Edge Article
Open Access
Laurent Knerr, Thomas Cogswell, Marie. Ahlqvist, Richard James Lewis, Anneli Nordqvist, Christian Sköld
Conformational control of drug candidates to engineer improved potency and ADME properties is an ongoing area of research. Macrocyclic rings tend to offer a greater degree of rigidity than non-cyclised...
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Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC90219J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang Xu
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The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04767B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lucie Pedussaut, Nolwenn Mahieu, Camille Chartier, Thayalan Rajeshkumar, Maxime Tricoire, Iskander Douair, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Grégory Nocton
Reversible light isomerization in organometallic complexes of lanthanides: the low-energy wavelengths favor the cis isomer, and the high-energy wavelengths favor the trans isomer.
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The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05736H, Review Article
Open Access
Ritu Gupta, Anujit Balo, Rabia Garg, Amit Kumar Mondal, Koyel Banerjee Ghosh, Prakash Chandra Mondal
This review highlights recent experimental findings related to the chirality-induced spin selectivity effect. This effect is demonstrated to explain asymmetric electron's spin transport in chiral molecules for various technological applications.
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Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06820C, Review Article
Open Access
Seungwon Sun, Jisu Choe, Jaeheung Cho
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...
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Pd(II)-Catalyzed Enantioselective C-H Olefination and Photoregulation of Sterically-Hindered Diarylethenes

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05375C, Edge Article
Open Access
Guanlun Zhang, Xu Wu, Shiyu Mao, Mengqi Li, Honglong Hu, Bing-Feng Shi, Weihong Zhu
Sterically-hindered diarylethenes with intrinsic chirality have shown great potential in chiral signal regulation, light-controlled liquid crystals (LCs), etc. Their unique enantiospecific phototransformation between axial chirality of ring-open isomer and central...
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Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC03942D, Edge Article
Open Access
Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-Kostal
Cleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...
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Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05788K, Edge Article
Open Access
Utsav Dey Sarkar, Mahima Rana, Harinath Chakrapani
A new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.
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PharmacoNet: deep learning-guided pharmacophore modeling for ultra-large-scale virtual screening

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04854G, Edge Article
Open Access
Seonghwan Seo, Woo Youn Kim
PharmacoNet is developed for virtual screening, including deep learning-guided protein-based pharmacophore modeling, a parameterized analytical scoring function, and coarse-grained pose alignment. It is extremely fast yet reasonably accurate.
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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article
Open Access
Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06324D, Edge Article
Open Access
Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. Reek
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
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Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05014B, Edge Article
Open Access
Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei He
Modulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.
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Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05482B, Edge Article
Open Access
Gongming Yang, Shangde Liu, Shujie Ji, Xingsen Wu, Jian Wang
The unprecedented non-enzymatically atroposelective synthesis of planar-chiral macrocycles via a Pd/NHC sequential catalytic intermolecular macrocyclization is reported.
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Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05286B, Edge Article
Open Access
Lu-Lu Ma, Pavel N. Zolotarev, Kang Zhou, Xin Zhou, Jiaqi Liu, Jiafeng Miao, Shenfang Li, Guo-Ping Yang, Yao-Yu Wang, Davide M. Proserpio, Jing Li, Hao Wang
Regulated adsorptive separation of alkane/alkenes has been achieved through engineering the coordinated water arrays in MOF channels.
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Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05873A, Edge Article
Open Access
Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou Zhai
A novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta2O5 nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.
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Regioselectivity switches between anthraquinone precursor fissions involved in bioactive xanthone biosynthesis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06369D, Edge Article
Open Access
Xiao Jing Lv, Chun Zhi Ai, Li Rong Zhang, Xiu Xiu Ma, Juan Juan Zhang, Jia Peng Zhu, Ren Xiang Tan
BruN and BTG13 cleave chrysophanol hydroquinone into monodictyphenone and cephalanone F, respectively, with the regioselectivities found tunable via the key amino acid (AA) substitution strategy.
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Dynamic satellite–parent liposome networks for quantitative microreactions

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04925J, Edge Article
Open Access
Jia-Qi Tian, Nan-Nan Deng
A dynamic satellite–parent liposome network was developed to explore molecular transfer and quantitative microreactions through environmental stimuli, offering a platform to mimic multicellular systems in vitro.
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Resonance Plasmonic Coupling: Selective Enhancement of Band Edge Emission over Trap State Emission of CdSe Quantum Dots

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04960H, Edge Article
Open Access
Livin Paul, Elizabeth Mariam Thomas, Akshaya Chemmangat, Stephen Gray, K. George Thomas
The photoluminescence properties of quantum dots (QDs) are often enhanced by eliminating surface trap states through chemical methods. Alternatively, a physical approach is presented here for improving photoluminescence purity in...
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Ligand Cross-Links as a Design Element in Oligo- and PolyMOFs

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06109H, Edge Article
Open Access
Debobroto Sensharma, Seth M Cohen
Metal-Organic Frameworks (MOFs) constructed using cross-linked oligomeric or polymeric ligands (OligoMOFs and PolyMOFs respectively) have so far relied on a handful of canonical structural blueprints, in which the cross-links have...
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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
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Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06227B, Edge Article
Open Access
Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin Jiang
Water–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.
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Delocalization error poisons the density-functional many-body expansion

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05955G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dustin R. Broderick, John M. Herbert
Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06403H, Edge Article
Open Access
Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang Kong
Successful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.
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Allosteric release of cucurbit[6]uril from a rotaxane using a molecular signal

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC03970J, Edge Article
Open Access
Aneta Závodná, Petr Janovský, Václav Kolařík, Jas S. Ward, Zdeňka Prucková, Michal Rouchal, Kari Rissanen, Robert Vícha
Repulsions between portals of cucurbit[n]urils are sufficiently strong to unlock the rotaxane structure.
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Bipolar electrochemiluminescence at the water/organic interface

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06103A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuheng Fu, Bingbing Xie, Miaoxia Liu, Shaojuan Hou, Qunyan Zhu, Alexander Kuhn, Lin Zhang, Wensheng Yang, Neso Sojic
A novel bipolar electrochemistry approach for wireless dual-color ECL emission at the water/organic interface is developed. This system overcomes spatial limitations of conventional methods, enabling imaging of complex multiphase environments.
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Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05977H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei Li
Ischemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...
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