If the dilute and dispose approach for disposing of the surplus plutonium in the Waste Isolation Pilot Plant (WIPP) is fully implemented, the U.S. Department of Energy (DOE) should use two independent review teams to develop public trust in and improve its decisions, says a new interim report by the National Academies of Sciences, Engineering, and Medicine.

The U.S. Department of Energy’s plan to dilute and dispose of 34 metric tons of surplus plutonium in the Waste Isolation Pilot Plant (WIPP) in New Mexico is technically viable, provided that the plan’s implementation challenges and system vulnerabilities are resolved.

Jordan Trimble of Skyharbour Resources lays out the reasons why the uranium bear market is coming to an end, and why his company is poised to take advantage of the upturn, in this conversation with Maurice Jackson of Proven and Probable.

With the supply/demand balance moving in favor of miners, the outlook for uranium stocks is the brightest it has been in years, according to McAlinden Research Partners.

Jordan Trimble of Skyharbour Resources lays out the reasons why the uranium bear market is coming to an end, and why his company is poised to take advantage of the upturn, in this conversation with Maurice Jackson of Proven and Probable.

With the supply/demand balance moving in favor of miners, the outlook for uranium stocks is the brightest it has been in years, according to McAlinden Research Partners.

Globally, up to 27% of all steel and 33% of all aluminium could potentially be reused, according to research. Significant barriers to reuse, such as component incompatibility between products and metal corrosion, must first be addressed if these reuse figures are to be achieved.

The potential of recycling aluminium scrap in Austria has been modelled in a new study. A surplus of mixed aluminium scrap is expected by 2045 if no advanced sorting technologies are applied. Increased demand for wrought aluminium alloys could mean this surplus occurs sooner. New methods to intensively sort aluminium could prevent this excess and contribute towards REACH1 recycling and climate targets.

Adding nanoparticles to water in solar collectors, which are used to capture the sun’s energy, can considerably improve their performance, a recent study on nanofluids has found. The energy efficiency of the collector can be increased by up to 76.6% when using water containing 0.1% by volume of titanium dioxide nanoparticles, compared with water alone.

Nanoparticles (NPs) have unique physical and chemical properties, but their increasing use in technological innovations has raised concerns about possible risks to the environment and human health. A new Chinese study has assessed the effects of NPs on plants and ecosystems. The findings indicated that NPs restrict wheat growth and damage soil ecosystems, which may have implications for the environment, agricultural productivity and human health.

Titanium dioxide nanoparticles are entering the environment in ever greater quantities as a result of their widespread use in consumer products and as a disinfectant of sewage. Researchers have recently discovered that titanium dioxide nanoparticles have a toxic effect on marine phytoplankton when exposed to normal levels of ultraviolet light found in natural sunlight.

Emissions of the greenhouse gases (GHGs) tetrafluoromethane (TFM) and hexafluoroethane (HFE) reported by industry accounted for only around half actual levels measured in the atmosphere between 2002 and 2010, new research reveals. The semiconductor and aluminium production industries, the two main sources of these gases, have reported success in their voluntary efforts to control these emissions. However, this does not match ‘top-down’ atmospheric monitoring, the researchers say.

Colorado's debate over uranium mines isn't that different from other energy debates around the nation.

The Artificial Inorganic Leaf (AIL) may unlock the secrets to producing cheap, clean hydrogen by mimicking the photosynthetic structure of the leaf.

Built atop a parking garage, this iconic park is considered the world's largest rooftop garden. It's also the place for kids and curious adults to go.

Are you buying a men's titanium ring as a gift? Are you thinking of getting titanium rings for wedding? Do you know the true meanings behind the metal as jewelry? Here is some general information for making such a decision.

The MSI Wealth Management Fund specializes in lucrative real estate acquisitions in the Washington, DC metropolitan area. We are committed to identifying, analyzing and implementing strategies that result in consistent, above-average returns.

What You Need to Know About Forced Telecom Access in the State of Illinois

Attorneys Michael S. Bender, Jeffrey A. Rembaum, Peter C. Mollengarden and Lisa A. Magill join a prestigious list of attorneys

The Ground-Up Property Offers the Highly Coveted 421 Tax Abatement

The National Park Service and the Department of the Interior are coordinating with federal and state agencies to investigate and address concerns of exposure to uranium rock samples previously stored at Grand Canyon National Park's Museum Collection building. https://www.nps.gov/grca/learn/news/national-park-service-reviews-uranium-exposure-at-grand-canyon.htm

Preliminary findings of an interagency safety review conducted last week at Grand Canyon National Park indicate no current exposure concerns for park employees and visitors from uranium ore samples previously stored in buckets at the park's Museum Collection building. https://www.nps.gov/grca/learn/news/preliminary-findings-indicate-no-current-uranium-ore-exposure.htm

The National Park Service (NPS) and the Department of the Interior (DOI) completed an interagency safety review finding no radiation exposure health risk to employees or visitors from uranium ore samples at Grand Canyon National Park. https://www.nps.gov/orgs/1207/final-report-concludes-no-radiation-exposure-from-uranium-ore-at-grand-canyon-national-park.htm

A method for preparation of an aryl poly(oxalkyl) quaternary ammonium compound is provided, said method comprising steps of: 1) reacting a phenol with a dihalopolyalkylene ether under the action of a phase transfer catalyst, to obtain an arylpoly(oxalkyl) halide; 2) reacting said arylpoly(oxalkyl) halide with an amination reagent under the action of a phase transfer catalyst, to obtain an arylpoly(oxalkyl) amine; 3) reacting said arylpoly(oxalkyl) amine with an alkylation reagent, to obtain an aryl poly(oxalkyl) quaternary ammonium compound; wherein R1 is H or a C1 to C16 alkyl group, located in the ortho, meta or para position; n is an integer of 2 to 6; R2 is H or a C1 to C16 alkyl group; R3 is H or a C1 to C16 alkyl group; R4 is a C1 to C16 alkyl group; X1 is Br or Cl; X is Cl, Br, or I. The preparation method according to the present invention requires low temperature and low pressure, the reaction time is short, and an overall yield can reach 75%. The operation is simple, the cost is low, and the product can be separated easily and have a purity of pharmaceutical grade, thereby facilitating the large-scale production.

Provided are an anti-static and anti-microbial surface treatment agent including a quaternary ammonium salt compound as an active ingredient and a method of preventing a polymer fiber from developing static electricity by using the surface treatment agent. The quaternary ammonium salt compound has excellent anti-static and anti-microbial effects for the prevention or improvement of static electricity in a polymer fiber. Accordingly, the quaternary ammonium salt compound is suitable for use as a fabric softener, or an anti-static agent, and also, provides anti-microbial effects to a polymer fiber.

The invention relates to the use of a composition of A) at least one quaternary ammonia compound comprising at least one organic radical bonded to the ammonia nitrogen atom and optionally comprising heteroatoms and having 1 to 36 carbon atoms, and B) at least one amine alkoxylate ester of formula (1) or a salt thereof, where A, B are, independently of each other, a C2- through C5-alkylene radical R1, a C8- through C24-alkyl radical or alkenyl radical R2, R3, R4 independent of each other, H, or a C8- through C24-acyl radical, with the stipulation that at least one of the radicals R2, R3 or R4 stands for a C8- through C24-acyl radical, and x, y, z, independently of each other, stand for a whole number from 0 through 50, with the stipulation that x+y+z is a whole number from 1 through 100, in quantities of 10 through 5000 g/tonne of ore as a collector in silicate floation.

A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8, and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 starts with NH2 and is diazotized followed by a polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 is a carbon in the aromatic ring, Rx and Ry represent any combination of CH3, C2H5, and hydrogen, except that Rx and Ry cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100, preferably from 2 to 20 is described. The polymeric phenazonium compound is usable as an additive in a metal plating bath comprising copper. The method includes the steps of a) dissolving an effective amount of an amino compound in a formic acid solution; b) adding a nitrite salt to diazotize the amino compound; and c) adding sulfamic acid to neutralize any excess nitrous acid that may be formed in step b), whereby a polymeric phenazonium compound is produced with a smaller quantity of unreacted monomer remaining in the end product than those produced using methods of the prior art.

A glycerol derivative which is effective to reduce blood pressure and has the formula: ##STR1## wherein R1 is an alkyl group having 10-22 carbon atoms, R2 is a lower acyl group or benzoyl, each of R3 and R4 independently is hydrogen or a straight or branched chain alkyl group having 1-6 carbon atoms; each of R5, R6 and R7 independently is hydrogen, a straight or branched chain alkyl group having 1-6 carbon atoms, an aryl group or an aralkyl group; and each of m and n independently is 0 or a positive integer under the condition of m+n=2-8.

This invention relates to a process for polymerizing ethylene comprising contacting ethylene and optional comonomers with a catalyst system comprising an activator and a transition metal compound represented by the formula: ##STR1## Wherein R1 and R2 are independently hydrogen or a group having up to 100 carbon atoms, Cp1 is a bulky ligand; Cp2 is a bulky ligand or a heteroatom optionally bound to a C1 to C50 hydrocarbyl group, n is the valence state of the transition metal, Tm is a Group 3 to 10 metal, and each X is independently an anionic leaving group.

A process for producing an alkali metal cyclopentadienylide is disclosed which comprises reacting in a solvent an alkali metal hydride with a disubstituted or trisubstituted 1,3-cyclopentadiene. Further, a process for producing a dihalobis(η-substituted-cyclopentadienyl)zirconium is disclosed which comprises reacting a zirconium halide with the above alkali metal cyclopentadienylide. The former process enables performing the reaction between the disubstituted or trisubstituted 1,3-cyclopentadiene and the alkali metal hydride at an easily controllable temperature of room temperature to about 150° C. and also enables obtaining the alkali metal cyclopentadienylide in high yield. The latter process enables obtaining the dihalobis(η-substituted-cyclopentadienyl)zirconium in high yield.

An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality: where: R1 represents a halogen, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, C3-8 heteroaryl, linear, branched, or cyclic C1-8 alkoxy, or C7-16 aralkyl;R21 each independently represents hydrogen, halogen, nitro, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, linear, branched, or cyclic C1-8 alkoxy, or a C7-16 aralkyl;R3 represents hydrogen, or an optionally substituted: C6-14 aryl, a C3-8 heteroaryl, or a C7-16 aralkyl; andY2 represents a halogen, or an optionally substituted: C1-8 alkylsulfonyloxy, C6-14 arylsulfonyloxy, or C7-16 aralkylsulfonyloxy.

Disclosed are: a diaryliodonium salt mixture which is a precursor of a BF4 salt or the like of a diaryliodonium compound, can be produced in the form of crystals at ambient temperature, can be purified in a simple manner, can be produced with high efficiency, and can be induced into a BF4 salt or the like salt that has excellent solubility in a monomer or the like; and a process for producing the diaryliodonium salt mixture. Also disclosed is a production process which can achieve good yield and can produce reduced amounts of byproducts, and is therefore applicable to the industrial mass production of a diaryliodonium compound. The diaryliodonium salt mixture is characterized by containing at least two specific diaryliodonium salts.

An ammonium hydroxyfluoroalkanesulfinate is obtained by using an organic base while sulfinating a bromofluoroalcohol with a sulfinating agent. An ammonium hydroxyfluoroalkanesulfonate is obtained by oxidizing the ammonium hydroxyfluoroalkanesulfinate. An onium fluoroalkanesulfonate is obtained by converting the ammonium hydroxyfluoroalkanesulfonate into an onium salt through esterification. This onium fluoroalkanesulfonate is useful as a photoacid generator in chemically amplified resists and the like.

Isocyanates are produced in the gas phase and by-products such as ammonium halides are selectively separated from the gas phase by desublimation.

Provided by the present invention is a method for efficient oxidation of alcohols by using, as a catalyst for dehydrogenation oxidation, a ruthenium complex which can be easily produced and easily handled and is obtainable at a relatively low cost. The invention relates to a method of producing a compound having a carbonyl group by dehydrogenation oxidation of alcohols by using as a catalyst the ruthenium carbonyl complex represented by the following general formula (1) RuXY(CO)(L) (1) (in the general formula (1), X and Y may be the same or different from each other and represent an anionic ligand, and L represents a tridentate aminodiphosphine ligand).

Disclosed are novel ruthenium compounds of formula (Ia) and (Ib): wherein R1 and the moiety are defined herein. Also disclosed is a process for using these novel ruthenium compounds as catalysts for asymmetric hydrogenation and transfer hydrogenation of ketones with high reactivities and excellent selectivities.

In various embodiments, the present disclosure provides a method of fixing nitrogen. An amount of titania catalyst is provided and contacted with a feed stream that includes nitrogen. The titania catalyst is heated. The heated titania catalyst fixes nitrogen in the feed stream to form nitrogen products, such as nitrates. The nitrogen products are then removed from the titania catalyst. In some examples, the titania catalyst is treated with a base. In further examples, the catalytic process is carried out in the absence of light for photochemically activating the titania catalyst.

Complexes of heterocyclic radionuclides are prepared based upon ligands having substituted pyridyl and imidazolyl groups. The ligands are bifunctional, having amino acid residues that may act as a linker to a bioactive molecu le, and a tridentate chelator that may complex the radionuclide. The bioactive molecule may be a peptide or somatostatin.

The present invention relates to a process to dissolve plutonium or a plutonium alloy, by placing it in contact with an aqueous dissolution mixture, wherein said dissolution mixture comprises nitric acid, a carboxylic acid with complexing properties with respect to plutonium, and a compound comprising at least one —NH2 radical such as urea. The invention also relates to a process to convert plutonium or a plutonium alloy into plutonium oxide and to manufacture nuclear fuel from said oxide.The invention particularly applies to the dismantling of plutonium contained in nuclear weapons with a view to its use in civilian nuclear reactors, particularly in the form of MOX fuel.

The invention provides a method of separating uranium from at least fission products in irradiated nuclear fuel, said method comprising reacting said irradiated nuclear fuel with a solution of ammonium fluoride in hydrogen fluoride fluorinating said reacted irradiated nuclear fuel to form a volatile uranium fluoride compound and separating said volatile uranium fluoride compound from involatile fission products. The invention thus provides a reprocessing scheme for irradiated nuclear fuel. The method is also capable of reacting, and breaking down Zircaloy cladding and stainless steel assembly components. Thus, whole fuel elements may be dissolved as one thereby simplifying procedures over conventional Purex processes.

Alloys and methods for preparing the same are provided. The alloys are represented by the general formula of (ZraAlbCucNid)100-e-fYeMf, wherein a, b, c, and d are atomic fractions, in which: 0.472≦a≦0.568; 0.09≦b≦0.11; 0.27≦c≦0.33; 0.072≦d≦0.088; the sum of a, b, c, and d equals 1; e and f are atomic numbers of elements Y and M respectively, in which 0≦e≦5 and 0.01≦f≦5; and M is selected from the group consisting of Nb, Ta, Sc, and combinations thereof.

A zirconium alloy nuclear reactor cylindrical cladding has an inner Zr substrate surface (10), an outer volume of protective material (22), and an integrated middle volume (20) of zirconium oxide, zirconium and protective material, where the protective material is applied by impaction at a velocity greater than 340 meters/second to provide the integrated middle volume (20) resulting in structural integrity for the cladding.

Disclosed is a zirconium alloy material having high corrosion resistance regardless of thermal history during its manufacturing process. The zirconium alloy material is obtained by providing a zirconium alloy containing on the mass basis: 0.001% to 1.9% of Sn, 0.01% to 0.3% of Fe, 0.01% to 0.3% of Cr, 0.001% to 0.3% of Ni, 0.001% to 3.0% of Nb, 0.027% or less of C, 0.025% or less of N, 4.5% or less of Hf and 0.16% or less of O with the remainder being inevitable impurities and zirconium, being formed of a bulk alloy and a surface layer, in which the surface layer has a plastic strain of 3 or more or a Vickers hardness of 260 HV or more and an arithmetic mean surface roughness Ra of 0.2 μm or less.

UO2 nuclear fuel pellets are fabricated by adding additive powder comprising Mn compound and Al compound into UO2 powder.

Graphite and/or carbon surfaces are coated with a titanium nitride coating by exposing the substrate to electric arc thermal spray process wherein titanium wire as the source of titanium and nitrogen is used as the propelling (atomizing) gas.

The invention relates to a process for the milling-drying of a raw mixture containing aluminum trihydroxide having an average particle size D50 in the range from 50 to 130 μm and a specific BET surface area in the range from 0.01 to 0.5 m2/g and containing from 0.1 to 20% by weight of water, based on the raw mixture, which including the steps i) introduction of the raw mixture into a milling-drying apparatus,ii) introduction of a hot air stream having a temperature in the range from 20 to 100° C. into the milling-drying apparatus so as to flow through the milling-drying apparatus andiii) comminution of the aluminum trihydroxide present in the raw mixture in the milling-drying apparatus.

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H2, CH4, CO, CO2, ammonia and hydrogen sulfide.

Provided is a method of preparing a nanocrystalline titanium alloy at low strain to have better strength. The present invention is characterized in that an initial microstructure is induced as martensites having a fine layered structure, and then a nanocrystalline titanium alloy is prepared at low strain by optimizing process variables through observation of the effects of strain, strain rate, and deformation temperature on the changes in the microstructure.

The present invention is a method for manufacturing a titanium ingot (30), the method being characterized by comprising: a step of melting a titanium alloy for a predetermined time by cold crucible induction melting (CCIM); a step of supplying molten titanium (6) to a cold hearth (10), and separating high density inclusions (HDIs) (8) by precipitation in the cold hearth (10) while spraying a plasma jet or an electron beam onto the bath surface of the molten titanium (6); and a step of supplying a molten titanium starting material from which the HDIs (8) are separated by precipitation to a mold (20) to obtain the titanium ingot.