ca Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca BODIPY dyes for optical limiting applications on the nanosecond timescale By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17766-17771DOI: 10.1039/D4DT02505A, FrontierJohn Mack, Gugu Kubheka, Aviwe May, Bokolombe P. Ngoy, Tebello NyokongRecent research at the Institute for Nanotechnology Innovation at Rhodes University exploring the utility of BODIPY and azaBODIPY dyes for optical limiting of incident nanosecond laser pulses in the visible region is described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17963-17975DOI: 10.1039/D4DT02014F, PaperMorigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin ZhaoConstruction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Fluorescent molecular systems based on carborane-perylenediimide conjugates By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17841-17851DOI: 10.1039/D4DT02477J, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ruben Rodriguez-Madrid, Sohini Sinha, Laura Parejo, Jordi Hernando, Rosario Núñezo-Carborane–perylenediimide conjugates exhibit exceptional fluorescence properties in solution, while red-light excimer emission is observed in their aggregated forms and in dispersible nanoparticles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17864-17879DOI: 10.1039/D4DT02425G, PaperJie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu XuanAn asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17880-17892DOI: 10.1039/D4DT02544J, PaperZhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing CuiThree novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18047-18053DOI: 10.1039/D4DT02567A, PaperHui Li, He ZhengInsights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18037-18046DOI: 10.1039/D4DT02755H, PaperJingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. ColebatchA new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17989-18002DOI: 10.1039/D4DT02195A, PaperJie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng FangA series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18013-18020DOI: 10.1039/D4DT02533D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. NolanDespite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17976-17988DOI: 10.1039/D4DT02355B, PaperThe Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang TranVarious 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02627F, PaperWenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie DingCage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02781G, PaperRuopei Sun, Erwan Dupuis, Jean Aupiais, Pascal ReillerThe formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit By Published On :: Wednesday, March 30, 2022, 13:23 +0530 The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam. Full Article
ca Unfurling a mythological gem By www.thehindubusinessline.com Published On :: Sun, 30 Jun 2013 01:46:01 +0530 Full Article S Madhavan
ca Of coruscating celluloid By www.thehindu.com Published On :: Sun, 18 Aug 2024 01:45:00 +0530 The cameras back then captured raw, real, and unadulterated images Full Article Open Page
ca Shedding light on local history By www.thehindu.com Published On :: Sun, 15 Sep 2024 00:40:34 +0530 It’s the lifeblood of community identities and is vital for preserving cultural heritage Full Article Open Page
ca Confessions of an impractical person By www.thehindu.com Published On :: Sun, 15 Sep 2024 00:52:29 +0530 How one ignored the imperfection of life by finding solace in the perfection of art Full Article Open Page
ca When influencers call the shots By www.thehindu.com Published On :: Sun, 15 Sep 2024 01:31:00 +0530 They act as symbols of beauty, success, and happiness, and their posts, stories, and videos are vehicles of meaning for the audiences Full Article Open Page
ca A case for a welfare economy By www.thehindu.com Published On :: Sun, 06 Oct 2024 02:25:41 +0530 More human development means more purchasing power and more demand for products Full Article Open Page
ca Self-care is the best healing By www.thehindu.com Published On :: Sun, 20 Oct 2024 02:35:00 +0530 Work on building your network, wear a smile and genuinely thank those who assist in your daily work Full Article Open Page
ca On the wrong call By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:20:00 +0530 Talking on the mobile phone while driving is tempting fate Full Article Open Page
ca A case for public transport By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:53:00 +0530 Aspirational India likes to flaunt snazzy cars, unmindful of the cost to environment Full Article Open Page
ca NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy By physicsworld.com Published On :: 2018-01-19T14:46:48Z Register now: 8 March 2018 A webinar sponsored by HORIBA Scientific Full Article
ca Developing the world's first full-body PET scanner By physicsworld.com Published On :: 2018-02-07T14:41:25Z Simon Cherry explains why the EXPLORER project will revolutionize medical imaging Full Article
ca D’Cunha report on COVID ‘scam’ adds more heat to bypoll campaign By www.thehindu.com Published On :: Sat, 09 Nov 2024 23:45:20 +0530 While Yediyurappa denied the allegation and called it ‘politically motivated’, Chief Minister Siddaramaiah, quoting The Hindu report, said it vindicated their earlier stand Full Article Karnataka
ca Karnataka makes online applications mandatory for private aided school teacher recruitment By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:03:16 +0530 DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently Full Article Karnataka
ca Art camp in support of cancer patients in Mysuru soon By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:59:54 +0530 Full Article Karnataka
ca CCB cracks down on fake degree certificate racket By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:33:12 +0530 Full Article Karnataka
ca Public campaigning for bypolls to end on November 11 By www.thehindu.com Published On :: Mon, 11 Nov 2024 03:52:34 +0530 The final day of public canvassing will see the Chief Minister and the Deputy Chief Minister besides top leaders of JD(S) and BJP seeking votes in Channapatna Full Article Karnataka
ca Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’ By www.thehindu.com Published On :: Mon, 11 Nov 2024 04:25:28 +0530 After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy Full Article Karnataka
ca Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ca Tunga Aarati held in Shivamogga as part of campaign to clean river Tungabhadra By www.thehindu.com Published On :: Mon, 11 Nov 2024 13:23:18 +0530 Shivamogga MLA S.N. Channabasappa appreciated the efforts of people and students involved in the padayatra from Sringeri to Harihar as part of a campaign to keep the river clean Full Article Karnataka
ca BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:33:09 +0530 Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event Full Article Karnataka
ca All roads lead to Channapatna on last day of public campaign By www.thehindu.com Published On :: Mon, 11 Nov 2024 22:29:29 +0530 Full Article Karnataka
ca HMT forest land denotification: Forest Department issues notice to former and current officers By www.thehindu.com Published On :: Mon, 11 Nov 2024 23:58:06 +0530 Full Article Karnataka
ca Karnataka’s KSRTC introduces UPI payments for cashless ticketing By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:07:00 +0530 As part of this initiative, KSRTC has equipped its buses with advanced Electronic Ticketing Machines, which are designed to accept UPI payments, along with debit and credit cards, making transactions quick and convenien Full Article Karnataka
