été

Heterojunction lithiation engineering and diffusion-induced defect passivation for highly efficient Sb2(S,Se)3 solar cells

Energy Environ. Sci., 2024, 17,8402-8412
DOI: 10.1039/D4EE03135K, Paper
Cong Liu, Anweng Gong, Chen Zuo, Tao Liu, Xiaoyang Liang, Donglou Ren, Kai Shen, Jianzha Zheng, Qifan Xue, Zhiqiang Li, Ruud E. I. Schropp, Bingsuo Zou, Yaohua Mai
A heterojunction lithiation strategy has been developed to achieve a certified efficiency of 10.50%, which is the record efficiency for all of the Sb-based solar cells.
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été

Quantitatively detecting and characterizing metallic lithium in lithium-based batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article
Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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été

Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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été

Promoted thermoelectric performance in cubic-phase GeTe via grain-boundary phase elimination under phase diagram guidance

Energy Environ. Sci., 2024, 17,8691-8701
DOI: 10.1039/D4EE03090G, Paper
Fudong Zhang, Baopeng Ma, Yiyuan Luo, Lujun Zhu, Weishuai Wang, Yalin Shi, Beiquan Jia, Zhen-Hua Ge, Zupei Yang, Di Wu, Jiaqing He
The Ag8GeTe6 grain boundary phase gets eliminated in cubic-phase δ-TAGS as guided by a quaternary phase diagram.
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été

The Hindu webinar on diabetes management to be held on November 13




été

Development of an automated platform for monitoring microfluidic reactors through multi-reactor integration and online (chip-)LC/MS-detection

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00004H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hannes Westphal, Simon Schmidt, Sanjay Lama, Matthias Polack, Chris Weise, Toni Oestereich, Rico Warias, Tanja Gulder, Detlev Belder
Biocatalysis with packed-bed microreactors: a novel method combining microreactor technology, multi-reactor integration, and online (chip-)LC/MS analysis in a sequential automated workflow.
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été

Temperature effect on the steric and polar Taft substituent parameter values

React. Chem. Eng., 2024, 9,833-841
DOI: 10.1039/D3RE00500C, Paper
Sindi Baco, Marcel Klinksiek, Mélanie Mignot, Christoph Held, Julien Legros, Sébastien Leveneur
We investigate the influence of temperature by re-evaluating the substituent parameters of the Taft equation applied to the esterification of levulinic acid by methanol and ethanol, and the saponification of methyl and ethyl levulinates.
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été

Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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été

Determination of intermediates and products of the uranyl aerosol formation in UF6 hydrolysis in the gas phase

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian Mark Salvador, Jason M. Richards, Shannon M. Mahurin, Meng-Dawn Cheng, Joshua A. Hubbard
A graphical representation of the uranyl aerosol formation.
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été

Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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été

Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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été

The natural detergent

Soap nut berries and powder can be used for the washing machine and cut down on pollution. A look by S. Vishwanath




été

High-fat diet promotes type 2 diabetes mellitus by disrupting gut microbial rhythms and short-chain fatty acid synthesis

Food Funct., 2024, 15,10838-10852
DOI: 10.1039/D4FO02957G, Paper
Yangrui Wang, Fenfen Yan, Qingxue Chen, Fei Liu, Baofeng Xu, Yuanyuan Liu, Guicheng Huo, Jinsheng Xu, Bailiang Li, Song Wang
A schematic diagram of a high-fat diet promotes type 2 diabetes mellitus by disrupting gut microbial rhythms and short-chain fatty acid synthesis.
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Integrated transcriptomics and untargeted metabolomics reveal bone development and metabolism of newly weaned mice in response to dietary calcium and boron levels

Food Funct., 2024, 15,10853-10869
DOI: 10.1039/D4FO03657C, Paper
Shuo Li, Xuehai Cao, Tiande Zou, Zirui Wang, Xingping Chen, Jun Chen, Jinming You
Boron supplementation in diets with varying calcium levels modulates bone development and bone parameters in mice by regulating calcium signaling, lipid metabolism, and neural signaling and inflammatory signaling.
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été

1,393 farm fires detected in Punjab, 874 FIRs registered: Special DGP




été

Rajasthan’s seven Assembly bypolls present a test of credibility for veteran leaders

The BJP is trying to compensate for the loss of 11 seats in the 2024 Lok Sabha election in the State while the Congress-led INDIA bloc has fallen apart barely five months after the polls




été

Trump nominates Army veteran and Fox News host Pete Hegseth for defence secretary

Mr. Hegseth deployed to Iraq and Afghanistan and unsuccessfully ran for Senate in Minnesota in 2012 before joining Fox News.




été

What do the Atlantic Ocean hurricane forecasts foretell for India?

Climate models forecast cyclones indirectly, based on metrics that indicate cyclonic activity and its potential intensity




été

Ancient meteorite was 'giant fertiliser bomb' for life on earth

The meteorite would have delivered a large amount of phosphorous, a nutrient for microbes crucial for the molecules central to storing and conveying genetic information.




été

Happy Humbleteen Birthday

All about the fund-raising, 10k-running, humble teenager who wants a community-minded profile to get into college overseas



  • Life & Style

été

The eternal charm of Shakuntalam

Kavalam Narayana Panicker’s take of the classic play, ‘Abhijnana Shakuntalam’, with Manju Warrier in the lead, mesmerised the audience.




été

Veteran Marathi actor Nandu Pol passes away

He was extremely prolific, with a substantial body of work in television and appearing in popular advertisements as well.




été

Vardhman Concrete Limited - Board Meeting Intimation for Approval Of Standalone Un-Audited Financial Results For The Quarter Ended June 30, 2019




été

Hydrogenation of sulfoxides to sulfides mediated by incomplete cubane-type Mo3S4 clusters: synthetic applications and mechanistic insights

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper
Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo3S4 clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Graphdiyne (CnH2n−2) based copper(I) bromide dual S-scheme heterojunction with AX2O8 type compounds induced electron directional migration

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01031K, Paper
Xinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu Tsubaki
A fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.
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été

Improved charge carrier mobility in a copper oxide heterostructure enhances the photocatalytic partial oxidation of benzyl alcohol to benzaldehyde

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00889H, Paper
Hanggara Sudrajat, Dmytro Lisovytskiy, Juan Carlos Colmenares
The enhancement of the partial oxidation of an aromatic alcohol to its corresponding aldehyde through the coupling of Cu2O with CuO is comprehensively discussed.
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été

Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Enhancement mechanism of novel heterojunction Z-scheme-type composite BiOBr/ZnIn2S4 to degrade Congo red

Catal. Sci. Technol., 2024, 14,6363-6371
DOI: 10.1039/D4CY00912F, Paper
Junchao Huang, Borui Li, Jiaxing Yu, Zhan Shu, Ming Li
The Z-scheme three-dimensional flower-like shape BiOBr/ZnIn2S4 showed excellent efficiency to degrade Congo red.
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Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis

Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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Heterostructure engineered construction of N-doped CuO@Co3O4 for highly efficient electrocatalytic reduction of nitrate to ammonia

Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper
Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH3 can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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été

Investigation on heterogeneous Rh Catalysts for the Hydroformylation of 1,3-Butadiene to adipic aldehyde

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00745J, Paper
Lijin Gan, Zekun Liu, Lei Feng, Yi Duan, Guangyuan Xu, Si Chen, Huan Yan
Adipic aldehyde, as a precursor for polymers, has significant industrial applications, where the hydroformylation of 1,3-butadiene is a promising routine to fabricate adipic aldehyde. However, the heterogeneous hydroformylation of 1,3-butadiene...
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Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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Switching of selectivity from benzaldehyde to benzoic acid using MIL-100(V) as a heterogeneous catalyst in aerobic oxidation of benzyl alcohol

Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper
Open Access
Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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A negative photoconductivity photodetector based on two-dimensional Nb3Cl8

Nanoscale, 2024, 16,20312-20318
DOI: 10.1039/D4NR03376K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bom Lee, Xiaojie Zhang, Jinsu Kang, Byung Joo Jeong, Sooheon Cho, Kyung Hwan Choi, Jiho Jeon, Sang Hoon Lee, Dahoon Kim, Yeong Hyeop Kim, Ji-Hee Kim, Hak Ki Yu, Jae-Young Choi
We developed a Nb3Cl8-based photodetector with negative photoconductivity from 400 to 1050 nm, featuring high electron mobility, a strong Ion/Ioff ratio, and high responsivity, making it ideal for energy-efficient optoelectronic applications.
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été

N-Heterocyclic carbene-stabilized gold–copper nanoclusters: synthesis, bonding and mechanochromism

Nanoscale, 2024, 16,20228-20234
DOI: 10.1039/D4NR03320E, Paper
Dongjie Zuo, Huifang Guo, Qinghua Xu, Ayisha He, Zilin Li, Simin Li, Hui Shen
The first gold–copper alloy cluster protected by both NHC and alkyne ligands was reported. The cluster displays interesting mechanochromic properties, highlighting the bright future of NHC-functionalized metal nanoclusters in materials science.
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Nucleic acid detection with single-base specificity integrating isothermal amplification and light-up aptamer probes

Nanoscale, 2024, 16,20067-20072
DOI: 10.1039/D4NR01638F, Communication
Jaekyun Baek, Jihyun Park, Youngeun Kim
CLASSIC is a label-free DNA detection platform with single-nucleotide specificity and attomolar sensitivity. This assay offers rapid and sequence-specific DNA analysis through single-strand conversion and split light-up aptamer probes.
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Folic acid-targeted redox responsive polylactic acid-based nanoparticles co-delivering pirarubicin and salinomycin suppress breast cancer tumor growth in vivo

Nanoscale, 2024, 16,20131-20146
DOI: 10.1039/D4NR02365J, Paper
Priya Gupta, Ankushi Bansal, Harshdeep Kaur, Mohd Anees, Neetu Singh, Harpal Singh
Schematic illustration of design, administration, and mechanism of action of Pira/Sal dual-loaded FA-conjugated redox responsive [S-(PLA-b-PEG-CONH)]2 block copolymeric nanoparticles.
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Cr2TiC2Tx MXene as an Adsorbent Material in Ultrasonic-Assisted d-µ-Solid Phase Extraction for Trace Detection of Heavy Metals

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02556C, Paper
Saman Bagheri, Rashmeet Kaur Khurana, Md. Ibrahim Kholil, Michael J. Loes, Shengyuan Luo, Alexander Sinitskii
MXenes are a large family of two-dimensional transition metal carbides, nitrides, and carbonitrides. While MXenes have great potential for applications in analytical chemistry, most of the studies in this field...
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Interfacial coupling of NiSe in heterostructures promotes electrocatalytic hydrolysis of MoS2

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03180F, Paper
Feng Jiao, Jun Tang, Jinzhao Huang, Zehui Liu, Jing Xiao
NiSe@MoS2 was prepared using a hydrothermal method. Interfacial effects between the two phases lead to electronic restructuring of the interfacial region, resulting in more active sites.
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été

Tailored peptide nanomaterials for receptor targeted prostate cancer imaging

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03273J, Paper
Fátima Santillán, Carlie L. Charron, Betty C. Galarreta, Leonard G. Luyt
This study reports on a cancer targeted nanomaterial created from cyclic octapeptides that is tailored for the optical imaging of prostate cancer. The strategy focuses on the co-assembly of four specific templates into cyclic peptide nanotubes.
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été

A liposome-based assay for cancer biomarker detection: exploring the correlation between platelet-derived microvesicles and NSCLC-associated miRNAs

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03704A, Paper
Mohamed Aimene Benariba, Kanza Hannachi, Sha Zhu, Yuting Zhang, Xiaoli Wang, Nandi Zhou
This research reveals a significant correlation between PMVs and their associated miRNA. Additionally, the liposome-based assay demonstrates enhanced sensitivity with calcium-induced platelet activation.
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été

Recent Progress of Two-dimensional Bi2O2Se and its Heterostructures

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03769C, Review Article
Xiaoyu Hu, Wen He, Dongbo Wang, Lei Chen, Xiangqian Fan, Duoduo Ling, Yanghao Bi, Wei Wu, Shuai Ren, Ping Rong, Yinze Zhang, Yajie Han, Jinzhong Wang
Ever since the identification of graphene, the research on two-dimensional (2D) materials has garnered significant attention. As a typical layered bismuth oxyselenide, Bi2O2Se has attracted growing interest not only due...
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Electrode Informatics Accelerated Optimization for Catalyst Layer Key Parameters in Direct Methanol Fuel Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03026E, Paper
Lishou Ban, Danyang Huang, Yanyi Liu, Pengcheng Liu, Xihui Bian, Kaili Wang, Yifan Liu, Xijun Liu, Jia He
As the core component of direct methanol fuel cell, the catalyst layer plays the key role of material, proton and electron transport channels. However, due to the complexity of its...
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Shape-controlled, water-assisted synthesis of 2D luminescent CsPb2Br5 perovskite microcrystals for highly responsive UV detectors

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03021D, Paper
Dipayan Ray, Ankush Saini, Ankit Kumar, Sumit Kumar, Monojit Bag, Prasenjit Kar
Water-assisted, growth-controlled synthesis of CsPb2Br5 microcrystals for fast responsive UV-detectors.
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été

Bifunctional electrocatalytic hybrid heterostructures for polysulfide anchoring/conversion for a stable lithium–sulfur battery

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03190C, Paper
Sakthivel Kaliyaperumal, Karthik Kiran Sarigamala, Padmini Moorthy, Balaji Ramachandran, Narendhar Chandrasekar, Tim Albrecht
In situ phase engineering of transition metal dichalcogenides (TMDs) based hybrid heterostructures with controlled sulfur vacancies offers a promising strategy for superior-performance lithium–sulfur (Li–S) batteries.
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été

Quantifying the polar skyrmion motion barrier in an oxide heterostructure

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03686G, Paper
Lizhe Hu, Yuhui Huang, Yong Jun Wu, Zijian Hong
Exotic polar topologies such as polar skyrmions have been widely observed in the ferroelectric superlattice system. The dynamic motion of the polar skyrmion under external forces holds promise for applications...
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