In a process for producing polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition in at least one hydrocarbon. The catalyst composition comprises a Group 4 metal complex of a phenolate ether ligand and the slurry includes from about 5 to less than 40 ppm per liter of a compound effective to increase the conductivity of said at least one hydrocarbon.

Polyolefin production using an improved catalyst system and, in particular, a method for production of a polyolefin is disclosed. One or more monomers are contacted with a catalyst system. The catalyst system includes titanium tetrachloride as a catalyst precursor and magnesium ethylate as a support for the catalyst precursor. The catalyst system also includes a hydrocarbyl aluminum cocatalyst represented by the formula R3Al, where R is an alkyl radical having 1 to 14 carbon atoms, and where the molar ratio of the hydrocarbyl aluminum cocatalyst to the titanium tetrachloride catalyst precursor ranges from 50:1 to 400:1. The catalyst system also includes a halogenated hydrocarbon as a promoter, where the molar ratio of the halogenated hydrocarbon promoter to the titanium tetrachloride catalyst precursor ranges from 0.001:1 to 300:1.

The present invention provides a diene polymer in which a polar functional group is introduced into an end by radical polymerization, and its production method; a polymer emulsion and a rubber composition each containing the diene polymer; and a pneumatic tire containing the rubber composition. The present invention relates to a diene polymer, which is obtained by radical polymerization of at least one radical polymerizable monomer in the presence of at least one polar functional group-containing thiol compound, and has a polar functional group at at least one end: The polar functional group-containing thiol compound is preferably represented by formula (1): X—R1—SH (1) wherein X represents an ester group, a hydroxyl group, a carboxyl group, an amino group, or an alkoxysilyl group, and R1 represents an alkylene or arylene group which may have a substituent.

The invention relates to free-radical polymerization and free-radical cross-linking and more particularly provides a process of free-radical polymerization or cross-linking wherein at least one polymerizable monomer or at least one compound to be cross-linked is contacted in the presence of at least one selected organic peroxides, characterized in that the organic peroxide is prepared continuously by an ex situ process with the aid of a closed plate exchanger. In the process according to the invention, it's possible to introduce the above selected organic peroxide continuously during the polymerization or cross-linking reaction.

A magnetic particle-polymer hybrid material can include: a substance having a structure of Formula 1 or derivative or salt thereof:Z(Y-Triazole-CH2—X—CH2—(FP)n)m (Formula 1), wherein Z is a magnetic particle smaller than 1 mm; n and m are independently integers; Y includes a first linker having an alkyl and/or aryl linked to the magnetic particle; X is CH2 or a heteroatom; FP is a functionalized polymer having: a first structure derived from a first norbornene compound linked to the magnetic particle through the Y-Triazole-CH2—X—CH2 linker; and one or more monomeric units each including a second structure derived from a second norbornene compound, where one of the monomeric units is linked to the first structure through a saturated or unsaturated alkyl, each monomeric unit includes a functional group capable of binding with another substance.

The present description relates to an olefin block copolymer preferably useful to form nonslip pads due to excellences in elasticity and heat resistance, and a sheet-shaped molded body comprising the olefin block copolymer The olefin block copolymer includes a plurality of blocks or segments, each of which includes an ethylene or propylene repeating unit and an α-olefin repeating unit at different weight fractions. The olefin block copolymer satisfies a defined relationship when a load of 5 to 10 kg is applied to a sheet-shaped molded body of the block copolymer for 12 hours or longer at a temperature of 60° C. or higher, and then removed.

A strap comprising a propylene and 1-hexene copolymer containing from 0.3 wt % to less than 5 wt % of 1-hexene derived units said copolymer having a melt flow rate (MFR) determined according to ISO method 1133 (230° C., 2.16 kg ranging from 0.3 to less than 11 g/10 min.

The present application relates to novel monomers comprising polycarbosiloxane monomers useful in certain specific embodiments in the manufacture of devices. More particularly, the present application relates to certain ethylenically unsaturated free radical polymerizable monomers comprising polycarbosiloxane monomers. Even more particularly, the present application pertains to monomers comprising polycarbosiloxane monomers which further comprise at least two ethylenically unsaturated free radical polymerizable groups.

An ion conducting membrane for fuel cells involves coupling a compound having a sulfonic acid group with a polymeric backbone. Each of the compounds having a sulfonic acid group and the polymeric backbone are first functionalized with a halogen.

The present invention relates to a polymer composition comprising polylactide and, based on the weight of this polymer, from 17 to 25 wt % of a chain modifier, from 30 to 55 wt % of an elastomeric polymer and from 20 to 45 wt % of a plasticizer. The invention also relates to the method of preparing said composition as well as to the method of manufacturing an article starting from said composition and the article per se.

To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.

The present invention relates to a process for preparing a diene elastomer. The invention especially applies to the production of a polybutadiene with a high level of cis-1,4 linkages that has at the same time a Mooney viscosity ML (1+4) greater than or equal to 40, a polydispersity index less than 2.1 and a reduced cold flow and of a polyisoprene. The process according to the invention comprises a reaction of a catalyst system with at least one conjugated diene monomer, this catalyst system being based on at least: one conjugated diene;one organic phosphoric acid salt of one or more rare-earth metals, said salt being in suspension and in at least one saturated and aliphatic or alicyclic, and inert hydrocarbon-based solvent;one alkylating agent composed of an alkyl aluminum for formula AlR3 or HAlR2 anda halogen donor belonging to the family of alkylaluminium halides, with the exclusion of alkylaluminium sesquihalides. This process comprises a separate bringing together of the monomer(s) to be polymerized with at least one alkylaluminium compound of formula AlR3 or HAlR2 which is identical or not to the alkylating agent of said catalyst system, said amount being chosen as a function of the characteristics of the polymerization medium and/or the polymerization conditions and/or said elastomer to be obtained.

A method for preparing a catalyst system for heterogenous catalysis of an isobutylene polymerization reaction includes the steps of forming an alumina support in which the alumina support has pores formed therein, and reacting BF3/methanol catalyst complex with the alumina support. The ratio of methanol to BF3 in the catalyst complex ranges from 0.5 moles to 2 moles of methanol per mole of BF3. The alumina support is formed so as to have pores each having a diameter of greater than twenty nanometers. The alumina support can be in the form of beads or extrudates having a length significantly greater than a diameter. The extrudate can also have a tri-lobe configuration.

A true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils. Articles made from the expandable copolymer may include tapes, membranes, films, fibers, and are suitable in a variety of end applications, including medical devices.

The present invention relates to a polymer composition that includes a polymer having at least one polymer segment represented by the following Formula (I), With reference to Formula (I): M independently for each w is a residue of a monomer; φ is a residue of a mechanochromic compound having at least two reactive groups that are each independently bonded to one monomer residue M; w, independently for each z, is an integer of at least 1; and z is an integer of at least 2. The mechanochromic compound is selected from at least one of the following, (a) a spirooxazine compound represented by the following Formula (II), and (b) an indenonaphthopyran represented by the following Formula (III),

The invention relates to a method for preparation of platinum siloxane compounds containing at least one CO ligand molecule (Pt carbonyl siloxanes). The method comprises reacting gaseous carbon monoxide (CO) with a platinum siloxane compound, preferably a platinum vinyl-cyclosiloxane compound, in solution with an organic solvent. The method is straightforward and applicable to industrial scale. With this method, specific isomers of platinum carbonyl vinylcyclosiloxanes are prepared, in which the two η-2-ethenyl groups coordinated to the Pt atom are bonded in trans-configuration relative to the cyclosiloxane backbone. The Pt compounds obtained by the method are used as catalysts for hydrosilylation and for crosslinking and curing of siloxanes and silanes.

A road safety barrier having a plurality of ropes supported by posts rigidly mounted on or in the ground is described. Each rope is held in tension against the posts and supported in a notch or groove in a side of the posts. The ropes are released from a post and the post is not pulled from the ground when a vertical force is exerted on the rope. The ropes when weaved are tensioned against the posts and this gives use to a combined frictional resistance to displacement of the ropes relative to each post along the length of the safety barrier. The structure of at least some of the posts and/or their mounting with respect to the ground defines a minimum bending yield strength in a direction along the length of the barrier. This minimum bending yield strength is greater than the bending moment resulting from the combined frictional resistance forces acting on the post.

A form-fitting connection between two components (5 and 14) has a break-away function in one direction. At least one connection element, designed as a shear bolt (6), is formfittingly connected to the first component (5) to be connected. The end of the shear bolt (6) is formfittingly and functionally connected to a second component (14) via an attached component (17) that is resilient in the direction of the formfitting connection.

An automatic pitch control system for riding power trowels enables a user to control and automatically adjust trowel blade pitch and height for concrete finishing. The disclosed system provides for blade pitch of separate rotor assemblies to be adjusted independently of one another or synchronously. The disclosed system also provides for a mode of operation that allows the user to completely flatten trowel blades for panning.

A vehicle access control system includes an elongate, generally hollow, generally planar base platform having a first and a second distal end. A generally hollow enclosure is atop the base platform. A first lift gate is intermediate the enclosure and the first distal end of the base platform, while a second lift gate is intermediate the enclosure the second distal end of the base platform. A first lift arm is pivotally coupled to the first lift gate and extends generally perpendicularly away from a longitudinal axis of the base platform. Likewise, a second, opposing lift arm is pivotally coupled to the second lift gate and extends generally perpendicularly away from the longitudinal axis of the base platform. The base platform is configured for direct contact with a mounting surface. In addition, the vehicle access control system is transportable as a unit.

A package for two liquid personal care compositions, including an applicator, a first reservoir, and a second reservoir. The applicator is non-removably connected at and extends away from the first cavity. The first and second reservoirs each hold a quantity of a liquid composition therein. The first reservoir includes an open end sized for independent insertion and removal of the applicator therethrough. The first reservoir is removable and protectively encases the applicator. The second reservoir includes a closed end an opposing open end, through which a liquid composition can be dispensed.

A powered, spray cleaning device that can be operated in an inverted orientation is provided. The cleaning device includes a cleaning head and an elongated handle configured to be grasped by a user. A container of cleaning solution is removably received by the handle, and when received by the handle, fluid from the container fills a fluid accumulator. Fluid in the fluid accumulator is prevented from flowing back into the container when the device is inverted, thus allowing the device to spray fluid when inverted.

The present invention relates to an applicator for applying a composition to keratinous fibers, in particular the eyelashes or the eyebrows, the applicator including a stem having a longitudinal axis and including at least one elastically-deformable flexible portion that is suitable for flexing during application and/or wiping; and an applicator element that is fastened to the stem and that includes a twisted wire core and bristles that extend transversally to the longitudinal axis of the stem.

A mobile wireless communications device may include a portable housing, a circuit board carried by the portable housing, a wireless communications circuit carried by the circuit board, and an audio circuit carried by the circuit board. The mobile wireless communications device may further include an antenna assembly including an antenna carrier frame coupled to the circuit board and defining a cavity therein, and an antenna element carried on the antenna carrier frame and having a plurality of spaced apart signal feed points coupled to the wireless communications circuit. In addition, an audio transducer may be carried within the cavity of the antenna carrier frame and coupled to the audio circuit.

A wireless communication device is configured for performing uplink transmission power control. The wireless communication device includes a processor and instructions stored in memory. The wireless communication device performs uplink transmission power control for multiple regulated frequency bands or component carriers. The wireless communication device determines a total transmission power for at least one component carrier and allocates transmission power to at least one antenna.

A method and system are provided for controlling uplink transmission power in a wireless communication system. At least one of a plurality of downlink carriers and a plurality of uplink carriers are aggregated, and the plurality of downlink carriers and the plurality of uplink carriers are mapped between a User Equipment (UE) and a network in the wireless communication system. A message relating to uplink carrier transmission power is received at the UE from the network via a downlink carrier. Uplink transmission power of one or more uplink carriers is controlled in accordance with the message and aggregation and mapping of at least one of the downlink carrier and the one or more uplink carriers.

The invention concerns a method for optimizing antenna pattern assignment for a first wireless communication device forming a wireless network with at least one second wireless communication device, each of said communication device being equipped with a multi-sector antenna, an antenna pattern being a combination of said antenna sectors, said communication devices being adapted for sending a request and for receiving a response using a current antenna pattern assignment, said method comprising a step of: evaluating by said first communication device a first value;sending by said first communication device to said second communication device a broadcast request comprising said valuereceiving by said first communication device, a response to said broadcast request, said response being sent by said second communication device, said response depending on a second value evaluated by said second device;Switching or not, by said first communication device, to a new antenna sector assignment depending on said response; According to the invention the first value is evaluated by minimizing a first local function according to the received signal strength received by said first communication device having said current antenna pattern assignment and the second value is evaluated by minimizing a second local function according to the received signal strength received by said second communication device for its own current antenna pattern assignment.

A cabinet structure for a switchgear assembly. The cabinet structure includes a cabinet having upper and lower vents and a breaker cradle for holding a circuit breaker having primary disconnects for connecting the circuit breaker to bus bars. The cabinet further includes an air passageway located between the upper and lower vents, wherein the air passageway extends vertically through the primary disconnects and the cabinet. Further, the cabinet includes a fan module having at least one fan for drawing outside air through the lower vent, the air passageway and the primary disconnects for cooling the primary disconnects.

A saddle type vehicle provided with a headlight stay for permitting a harness laying operation to be easily carried out. A motorcycle is provided with the headlight stay which is supported on a head pipe and extends toward the vehicle front side from the head pipe. A headlight unit is attached to the headlight stay. The headlight stay includes a first stay extending forward from the head pipe, in a side view of the vehicle and a second stay which is supported in a cantilever manner by a front portion of the first stay and extends rearwardly and upwardly. The headlight unit is partly disposed on the front side of the second stay and is disposed so as to overlap with the first stay.

The present invention relates to an aluminum extrusion heat sink structure and a corresponding backlight module. The aluminum extrusion heat sink structure comprises a light source connecting portion, a back plate connecting portion and a light guide plate support portion. The manufacture cost of the aluminum extrusion heat sink structure is lower, and the heat dissipation effect is better, so as to solve the technology problem that the volume of a traditional aluminum extrusion heat sink structure is larger caused the cost of the aluminum extrusion heat sink structure and the corresponding backlight module is higher.

A lead-free conductive paste composition contains a source of an electrically conductive metal, a fusible material, an optional additive, and an organic vehicle. An article such as a high-efficiency photovoltaic cell is formed by a process of deposition of the lead-free paste composition on a semiconductor substrate (e.g., by screen printing) and firing the paste to remove the organic vehicle and sinter the metal and fusible material.

An emergency system for a vehicle integrates many disparate equipment into single housing, including the power supply for the equipment. In one embodiment of the invention, the emergency system is a light bar. The light bar houses a power source comprising solar cell panels, a Lithium-Ion battery pack and a connection to an external supply such as the vehicle's electrical power. Energy for operating the light bar is provided by one or more of the power sources, depending on operating conditions of the light bar and each of the power sources.

The present invention provides a method of deploying a medical filter within a channel in a patient's body and filter systems which can be used in such a method. Such a filter may include a radially expandable body 52 having an opening 56 in a proximal length thereof. In one method, the filter is urged along a length of the channel with the filter body in a radially reduced configuration. This body is expanded to substantially fill the lumen of the vessel and orient the opening in the body proximally. Body fluid is permitted to enter the filter body through the proximally oriented opening and pass distally through the distal length of the body so that the distal length of the body filters from the body fluid particulate material entrained therein. The proximal length of the body can be drawn into the retrieval catheter, thereby effectively closing the proximally oriented opening within the catheter to retain the particulate material within the enclosure. In a preferred embodiment, the filter body 52 is formed of a porous, resilient fabric having pores therein and the proximal opening 56 is at least five times the size of such pores.

Disclosed is a method and apparatus for regulating tourniquet cuff pressure based on a personalized tourniquet pressure (PTP) to facilitate safe performance of a surgical procedure. The apparatus includes a dual-purpose tourniquet cuff adapted to encircle a region of a patient limb to provide both a sensor during a pre-surgical time period and an effector during a surgical time period. An effector module communicates pneumatically with an inflatable bladder of the cuff for maintaining pressure in the bladder near a PTP during the surgical time period to safely stop penetration of arterial blood past the cuff. A pulsation sensor that communicates pneumatically with the inflatable bladder during the pre-surgical time period senses and characterizes pressure pulsations that are indicative of penetration of arterial blood into the region of the limb encircled by the cuff. A PTP estimator is responsive to the pulsation sensor for producing an estimate of the PTP, such that the estimate of the PTP is a function of the sensed pulsations.

A system for occluding a physical anomaly. One embodiment comprises a shape memory material body wherein the shape memory material body fits within the physical anomaly occluding the physical anomaly. The shape memory material body has a primary shape for occluding the physical anomaly and a secondary shape for being positioned in the physical anomaly.

Devices, systems and methods for dynamically stabilizing the spine are provided. The devices include an expandable spacer having an undeployed configuration and a deployed configuration, wherein the spacer has axial and radial dimensions for positioning between the spinous processes of adjacent vertebrae. The systems include one or more spacers and a mechanical actuation means for delivering and deploying the spacer. The methods involve the implantation of one or more spacers within the interspinous space.

An intervertebral fusion cage that is adapted to contain an inserter within its inner volume during insertion of the cage.

This disclosure relates to a method of preparing polyamide particles. The method include spray drying a solution containing a polyamide to form polyamide particles having an average diameter of between about 0.5 μm and about 10 μm and at least about 85% of the polyamide particles having a diameter distribution of no more than about 1.5 μm.

The invention relates to a method for producing implants and components by direct shaping. The method includes the steps of producing a mold for the implants or components to be produced, making allowances for changes in geometry occurring during after-treatment after the implants or components are removed from the mold, and, providing partial areas of the mold with a structured surface for transferring this structure to the surfaces of the implants or components. In the method, raw material is introduced into the mold and, after remaining in the mold for a certain period of time, the hardened raw material is then removed from the mold to allow the implants or components to take on the structured surface of the mold as well as its geometry. The demolded implants or components are finally subjected to any after-treatment that may be necessary.

In accordance with this invention a binder composition for treating particulate material to form a solid aggregate matrix is prepared by providing a urea formaldehyde precondensate; a polar solvent; additional urea; an acid or salt thereof, the acid or salt thereof being selected such as to render the pH of the binder composition to a value from 2.0 to 5.3; providing a sugar; providing a binding promoter for enhancing the binding between the binder composition and the particulate material; and mixing the above so as to form a binder composition. The binder composition is mixed with particulate material and allowed to set into a solid aggregate matrix over a period of longer than 30 minutes from being mixed with the said particulate material.

Disclosed herein is a method for preparing a near infrared shielding fiber. The method includes the steps of preparing and compounding a composition, then pelletizing the compounded composition to obtain the near-infrared shielding masterbatch, and melt spinning the near-infrared shielding masterbatch into the near-infrared shielding fiber. The composition includes at least one metallic ionic compound powder in an amount of about 1-25 wt %, a cross-linking agent in an amount of about 0.1-2 wt %, a thermoplastic polymer in an amount of about 67-98.7 wt %, a cross-linking initiator in an amount of about 0.1-1 wt %, and a dispersing agent in an amount of about 0.1-2 wt %.

Provided is a method for manufacturing a sheet for a solar cell encapsulant which has stability against yellowing after a crosslinking process and thus good appearance with improved productivity in the sheet manufacture process, specifically to a method for manufacturing a sheet for a solar cell encapsulant characterized by melt-mixing a resin composition with an organic peroxide, a co-crosslinking agent and a silane coupling agent at the degradation temperature of the organic peroxide or less, wherein the resin composition is obtained by melt-mixing EVA resin with an antioxidant, an UV absorber and a light stabilizer at 80-220° C., and forming a sheet from the obtained melt-mixed resin composition.

There is provided solid imaging methods and apparatus for making three-dimensional objects from solid imaging material. A tray with a film bottom is provided to hold solid imaging material that is selectively cured into cross-sections of the three-dimensional object being built. A coater bar is moved back and forth over the film to remove any uncured solid imaging material from a previous layer and to apply a new layer of solid imaging material. A sensor is provided to measure the amount of resin in the tray to determine the appropriate amount of solid imaging material to be added, from a cartridge, for the next layer. A shuttle, which covers the tray when the exterior door to the solid imaging apparatus is opened for setting up a build or removing a three-dimensional object, can also be used to move the coater bar and to selectively open one or more valves on the cartridge to dispense the desired amount of solid imaging material.

The invention relates to a method for the production of a layered or stacked inorganic/organic composite material, a predominantly inorganic material being provided and a polymer material being provided, characterized in that the predominantly inorganic material has a glass transition temperature or melting temperature lower than 500° C., that the predominantly inorganic material and the polymer material are each molten, and that the predominantly inorganic material and the polymer material are coextruded from the melt and thus form the composite material.

Disclosed herein is a method for utilizing the exothermic energy generated by a low temperature cure reaction to access a high-temperature cure reaction, which is otherwise energetically inaccessible at a chosen tool temperature, thereby producing a cured resin matrix with properties closely matching to those produced via high-temperature cure reactions but achieved via a short cure time and low cure temperature. Also disclosed is a short-cure resin composition containing: (a) at least one multifunctional epoxy resin having an epoxy functionality of greater than 1; (b) a hardener composition containing (i) at least one aliphatic or cycloaliphatic amine curing agent having one or more amino groups per molecule; (ii) at least one aromatic amine curing agent having one or more amino groups per molecule; and optionally, (iii) an imidazole as curing accelerator. The improved properties of this resin composition include being curable at a temperature of ≦120° C. for a time period of less than 10 minutes to achieve a degree of cure higher than that derived from the same composition with just (i) aliphatic/cycloaliphatic amine or (ii) aromatic amine in isolation.

Method of manufacturing a fibre-reinforced composite moulding, the method comprising the steps of: (a) disposing at least one layer of fibrous reinforcing material within a mould; (b) disposing at least one pre-preg layer adiacent to the fibrous reinforcing material, the pre-preg layer comprising fibrous reinforcement at least partially impregnated with uncured first resin material, to form a laminar assembly of the at least one layer of fibrous reinforcing material and the at least one pre-preg layer within the mould; (c) applying a vacuum to the assembly; (d) infusing a flowable uncured second resin material, under the vacuum, into the at least one layer of fibrous reinforcing material; and (e) curing the first and second resin materials at least partially simultaneously to form the fibre-reinforced composite moulding which comprises at least one first structural portion formed from the fibrous reinforcement and the cured first resin material bonded to at least one second structural portion formed from the at least one layer of fibrous reinforcing material and the cured second resin material.

An injection tool for the production of components by an injection-molding method, the injection tool including several cavities for shaping one respective product, an injection nozzle for injecting plastic materials for each cavity, and an actuating device. The injection nozzle has an injection channel which can be closed by a nozzle needle in order to control the injection process. The actuating device is arranged to move the nozzle needle in an axial direction between a first end position and a second end position, with an adjustable stop being provided which defines the first end position.

When a molded fabric body (X) is impregnated with a powder (K) of a predetermined material, there are performed a first step of dispersing the powder (K) in a liquid to prepare a slurry, and a second step of burying the molded fabric body (X) made of fiber bundles in the slurry and vibrating the slurry by use of a predetermined vibrator (M). Furthermore, in the second step, the vibrator (M) is moved along a surface of the molded fabric body (X). As a result, it is possible to improve the rate of impregnation of the powder (K) more than that in the conventional cases, irrespective of the shape of the molded fabric body (X).

A thermoplastic composition that contains a rigid renewable polyester and has a voided structure and low density is provided. To achieve such a structure, the renewable polyester is blended with a polymeric toughening additive to form a precursor material in which the toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. The precursor material is thereafter stretched or drawn at a temperature below the glass transition temperature of the polyester (i.e., “cold drawn”). This creates a network of voids located adjacent to the discrete domains, which as a result of their proximal location, can form a bridge between the boundaries of the voids and act as internal structural “hinges” that help stabilize the network and increase its ability to dissipate energy. The present inventors have also discovered that the voids can be distributed in a substantially homogeneous fashion throughout the composition.

Compositions of thermoplastic polyesters containing dispersed nanoparticles of fibrous clay are made by polymerizing the polyester precursors in the presence of exfoliated fibrous clay that has not been organically modified. The compositions have good physical properties and can be melt molded into various articles. Many of these articles may be coated (painted) and are especially useful for appearance parts such as visible exterior automotive body parts.