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Palladium supported on triazolyl-functionalized hypercrosslinked polymers as a recyclable catalyst for Suzuki–Miyaura coupling reactions

RSC Adv., 2020, 10,17123-17128
DOI: 10.1039/D0RA01190H, Paper
Open Access
Cijie Liu, Lijuan Zheng, Dexuan Xiang, Shasha Liu, Wei Xu, Qionglin Luo, You Shu, Yuejun Ouyang, Hongwei Lin
A novel hypercrosslinked polymer-palladium catalyst was prepared via external cross-linking reactions and applied in Suzuki–Miyaura reactions as a recyclable catalyst, resulting in TON numbers up to 1.66 × 104 and yields reaching 99%.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Retraction: Effect of temperature and large guest molecules on the C–H symmetric stretching vibrational frequencies of methane in structure H and I clathrate hydrates

RSC Adv., 2020, 10,16904-16904
DOI: 10.1039/D0RA90048F, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Go Fuseya, Satoshi Takeya, Akihiro Hachikubo
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced photodegradation of diphenhydramine in aqueous solution containing natural sand particles

RSC Adv., 2020, 10,17228-17234
DOI: 10.1039/D0RA02019B, Paper
Open Access
Chunlin Yi, Lihong Song, Qingfeng Wu, Zhaohui Li, Weibin Zhang, Ke Yin
Natural sand particles induced the generation of free radicals under simulated solar irradiation, resulting in the enhanced photodegradation of diphenhydramine.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural, optical and photocatalytic properties of erbium (Er3+) and yttrium (Y3+) doped TiO2 thin films with remarkable self-cleaning super-hydrophilic properties

RSC Adv., 2020, 10,17247-17254
DOI: 10.1039/D0RA02242J, Paper
Open Access
Raquel da Silva Cardoso, Suélen Maria de Amorim, Gidiane Scaratti, Camilla Daniela Moura-Nickel, Rodrigo Peralta Muniz Moreira, Gianluca Li Puma, Regina de Fatima Peralta Muniz Moreira
The self-cleaning and super hydrophilic properties of pristine TiO2 and of TiO2 doped with Er3+ or Y3+ transparent thin films deposited onto glass substrates were investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cost-effective smart microfluidic device with immobilized silver nanoparticles and embedded UV-light sources for synergistic water disinfection effects

RSC Adv., 2020, 10,17479-17485
DOI: 10.1039/D0RA00076K, Paper
Open Access
Amit Prabhakar, Mehul Agrawal, Neha Mishra, Nimisha Roy, Ankur Jaiswar, Amar Dhwaj, Deepti Verma
A novel microfluidic-device for water disinfection via diverse physiochemical effects has been demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Two-dimensional β-MoO3@C nanosheets as high-performance negative materials for supercapacitors with excellent cycling stability

RSC Adv., 2020, 10,17497-17505
DOI: 10.1039/D0RA01258K, Paper
Open Access
Xuexia Liu, Ying Wu, Huiwen Wang, Yinfeng Wang, Chunfang Huang, Limin Liu, Zhijun Wang
MoO3 has gained a great deal of attention as a promising electrode material in energy storage devices.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Promoting formic acid oxidation performance of Pd nanoparticles via Pt and Ru atom mediated surface engineering

RSC Adv., 2020, 10,17302-17310
DOI: 10.1039/D0RA01303J, Paper
Open Access
Dinesh Bhalothia, Tzu-Hsi Huang, Pai-Hung Chou, Kuan-Wen Wang, Tsan-Yao Chen
Pt atoms attract electrons from neighboring atoms. Ru atoms attract hydroxide ligands. These two characteristics respectively weaken the bonding and recovering of the Pt site from CO oxidation and then facilitate the FAO in ternary PdPtRu NCs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fabrication of a magnetic ternary ZnFe2O4/TiO2/RGO Z-scheme system with efficient photocatalytic activity and easy recyclability

RSC Adv., 2020, 10,17293-17301
DOI: 10.1039/D0RA01880E, Paper
Open Access
Yuwei Sun, Jiashuang Lei, Yizhu Wang, Qian Tang, Chunli Kang
A magnetic separable Z-scheme composite based on ZnFe2O4, TiO2 nanosheets and RGO exhibits efficient photocatalytic degradation of p-NP.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Transformation of ZIF-8 nanoparticles into 3D nitrogen-doped hierarchically porous carbon for Li–S batteries

RSC Adv., 2020, 10,17345-17352
DOI: 10.1039/C9RA10063F, Paper
Open Access
Guiqiang Cao, Da Bi, Jingxiang Zhao, Jing Zheng, Zhikang Wang, Qingxue Lai, Yanyu Liang
A novel transformation strategy assisted with ammonia treatment was successfully developed to fabricate ZIF-8-derived nitrogen-doped hierarchically porous carbon (NHPC/NH3).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dual-site mixed layer-structured FAxCs3−xSb2I6Cl3 Pb-free metal halide perovskite solar cells

RSC Adv., 2020, 10,17724-17730
DOI: 10.1039/D0RA00787K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yong Kyu Choi, Jin Hyuck Heo, Ki-Ha Hong, Sang Hyuk Im
Dual site mixing of FAxCs3−xSb2I6Cl3 forms stable 2D layer structure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dip-coating decoration of Ag2O nanoparticles on SnO2 nanowires for high-performance H2S gas sensors

RSC Adv., 2020, 10,17713-17723
DOI: 10.1039/D0RA02266G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tran Thi Ngoc Hoa, Nguyen Van Duy, Chu Manh Hung, Nguyen Van Hieu, Ho Huu Hau, Nguyen Duc Hoa
Ag2O nanoparticles decorated on the surface of on-chip growth SnO2 nanowires by a dip-coating method possessed excellent sensing performance for H2S gas.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effect of temperature and large guest molecules on the C–H symmetric stretching vibrational frequencies of methane in structure H and I clathrate hydrates

RSC Adv., 2020, 10,17473-17478
DOI: 10.1039/D0RA02748K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Go Fuseya, Satoshi Takeya, Akihiro Hachikubo
Temperature effect on C–H symmetric stretching frequencies of CH4 in water cages of sI and sH clathrate hydrates were clarified.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A highly sensitive, selective and renewable carbon paste electrode based on a unique acyclic diamide ionophore for the potentiometric determination of lead ions in polluted water samples

RSC Adv., 2020, 10,17552-17560
DOI: 10.1039/D0RA01435D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. A. Zayed, Walaa H. Mahmoud, Ashraf A. Abbas, Aya E. Ali, Gehad G. Mohamed
Due to the toxicity of lead(II) to all living organisms destroying the central nervous system and leading to circulatory system and brain disorders, the development of effective and selective lead(II) ionophores for its detection is very important.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A chitosan-based edible film with clove essential oil and nisin for improving the quality and shelf life of pork patties in cold storage

RSC Adv., 2020, 10,17777-17786
DOI: 10.1039/D0RA02986F, Paper
Open Access
Karthikeyan Venkatachalam, Somwang Lekjing
This study assessed chitosan (CS)-based edible films with clove essential oil (CO) and nisin (NI) singly or in combination, for improving quality and shelf life of pork patties stored in cold conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile synthesis of a direct Z-scheme BiOCl–phosphotungstic acid heterojunction for the improved photodegradation of tetracycline

RSC Adv., 2020, 10,17369-17376
DOI: 10.1039/D0RA02396E, Paper
Open Access
Haijuan Tong, Bingfang Shi, Shulin Zhao
A one-step hydrothermal approach for synthesizing BiOCl–phosphotungstic acid (BiOCl–HPW) heterojunctions is proposed. The prepared BiOCl–HPW heterojunction exhibited good stability and photocatalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Narrowing band gap and enhanced visible-light absorption of metal-doped non-toxic CsSnCl3 metal halides for potential optoelectronic applications

RSC Adv., 2020, 10,17869-17869
DOI: 10.1039/D0RA90054K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakiul Islam, A. K. M. Akther Hossain
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nitrogen-doped RuS2 nanoparticles containing in situ reduced Ru as an efficient electrocatalyst for hydrogen evolution

RSC Adv., 2020, 10,17862-17868
DOI: 10.1039/D0RA02530E, Paper
Open Access
Yan Xu, Xiaoping Gao, Jingyan Zhang, Daqiang Gao
The reasonable design that N-doping and in situ reduced Ru metal enhances the performance of N-RuS2/Ru for HER.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of heteroatom-containing pyrrolidine derivatives based on Ti(O-iPr)4 and EtMgBr-catalyzed carbocyclization of allylpropargyl amines with Et2Zn

RSC Adv., 2020, 10,17881-17891
DOI: 10.1039/D0RA02677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rita N. Kadikova, Ilfir R. Ramazanov, Azat M. Gabdullin, Oleg S. Mozgovoj, Usein M. Dzhemilev
The Ti(O-iPr)4 and EtMgBr-catalyzed regio and stereoselective carbocyclization of N-allyl-substituted 2-alkynylamines with Et2Zn, followed by deuterolysis or hydrolysis, affords the corresponding methylenepyrrolidine derivatives in high yields.
The content of this RSS Feed (c) The Royal Society of Chemistry




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UCL update their homepage

This week UCL have updated their homepage with a new design that I translated into XHTML, CSS, and Javascript.

UCL will gradually be updating other parts of their website as they move forward. You can read the UCL blog post about their new homepage and the history of the UCL homepage.

I was responsible for producing the XHTML, CSS, and Javascript that makes up the templates for this redesign. The members of UCL’s Web Services team then integrated the templates (and modified them as required) into their CMS.




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A new micro clearfix hack

The clearfix hack is a popular way to contain floats without resorting to using presentational markup. This article presents an update to the clearfix method that further reduces the amount of CSS required.

Demo: Micro clearfix hack

Known support: Firefox 3.5+, Safari 4+, Chrome, Opera 9+, IE 6+

The “micro clearfix” method is suitable for modern browsers and builds upon Thierry Koblentz’s “clearfix reloaded”, which introduced the use of both the :before and :after pseudo-elements.

Here is the updated code (I’ve used a shorter class name too):

/**
 * For modern browsers
 * 1. The space content is one way to avoid an Opera bug when the
 *    contenteditable attribute is included anywhere else in the document.
 *    Otherwise it causes space to appear at the top and bottom of elements
 *    that are clearfixed.
 * 2. The use of `table` rather than `block` is only necessary if using
 *    `:before` to contain the top-margins of child elements.
 */
.cf:before,
.cf:after {
    content: " "; /* 1 */
    display: table; /* 2 */
}

.cf:after {
    clear: both;
}

/**
 * For IE 6/7 only
 * Include this rule to trigger hasLayout and contain floats.
 */
.cf {
    *zoom: 1;
}

This “micro clearfix” generates pseudo-elements and sets their display to table. This creates an anonymous table-cell and a new block formatting context that means the :before pseudo-element prevents top-margin collapse. The :after pseudo-element is used to clear the floats. As a result, there is no need to hide any generated content and the total amount of code needed is reduced.

Including the :before selector is not necessary to clear the floats, but it prevents top-margins from collapsing in modern browsers. This has two benefits:

  • It ensures visual consistency with other float containment techniques that create a new block formatting context, e.g., overflow:hidden
  • It ensures visual consistency with IE 6/7 when zoom:1 is applied.

N.B.: There are circumstances in which IE 6/7 will not contain the bottom margins of floats within a new block formatting context. Further details can be found here: Better float containment in IE using CSS expressions.

The use of content:" " (note the space in the content string) avoids an Opera bug that creates space around clearfixed elements if the contenteditable attribute is also present somewhere in the HTML. Thanks to Sergio Cerrutti for spotting this fix. An alternative fix is to use font:0/0 a.

Legacy Firefox

Firefox < 3.5 will benefit from using Thierry’s method with the addition of visibility:hidden to hide the inserted character. This is because legacy versions of Firefox need content:"." to avoid extra space appearing between the body and its first child element, in certain circumstances (e.g., jsfiddle.net/necolas/K538S/.)

Alternative float-containment methods that create a new block formatting context, such as applying overflow:hidden or display:inline-block to the container element, will also avoid this behaviour in legacy versions of Firefox.




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Better conditional classnames for hack-free CSS

Applying conditional classnames to the html element is a popular way to help target specific versions of IE with CSS fixes. It was first described by Paul Irish and is a feature of the HTML5 Boilerplate. Despite all its benefits, there are still a couple of niggling issues. Here are some hacky variants that side-step those issues.

An article by Paul Irish, Conditional stylesheets vs CSS hacks? Answer: Neither!, first proposed that conditional comments be used on the opening html tag to help target legacy versions of IE with CSS fixes. Since its inclusion in the HTML5 Boilerplate project, contributors have further refined the technique.

However, there are still some niggling issues with the “classic” conditional comments approach, which Mathias Bynens summarized in a recent article on safe CSS hacks.

  1. The Compatibility View icon is displayed in IE8 and IE9 if you are not setting the X-UA-Compatible header in a server config.
  2. The character encoding declaration might not be fully contained within the first 1024 bytes of the HTML document if you need to include several attributes on each version of the opening html tag (e.g. Facebook xmlns junk).

You can read more about the related discussions in issue #286 and issue #378 at the HTML5 Boilerplate GitHub repository.

The “bubble up” conditional comments method

Although not necessarily recommended, it looks like both of these issues can be avoided with a bit of trickery. You can create an uncommented opening html tag upon which any shared attributes (so no class attribute) can be set. The conditional classes are then assigned in a second html tag that appears after the <meta http-equiv="X-UA-Compatible"> tag in the document. The classes will “bubble up” to the uncommented tag.

<!DOCTYPE html>
<html lang="en">
  <head>
    <meta http-equiv="X-UA-Compatible"
          content="IE=edge,chrome=1">
    <meta charset="utf-8">
    <!--[if lt IE 7]><html class="no-js ie6"><![endif]-->
    <!--[if IE 7]><html class="no-js ie7"><![endif]-->
    <!--[if IE 8]><html class="no-js ie8"><![endif]-->
    <!--[if gt IE 8]><!--><html class="no-js"><!--<![endif]-->

    <title>Document</title>
  </head>
  <body>
  </body>
</html>

Fork the Gist

The result is that IE8 and IE9 won’t ignore the <meta http-equiv="X-UA-Compatible"> tag, the Compatibility View icon will not be displayed, and the amount of repeated code is reduced. Obviously, including a second html tag in the head isn’t pretty or valid HTML.

If you’re using a server-side config to set the X-UA-Compatible header (instead of the meta tag), then you can still benefit from the DRYer nature of using two opening html tags and it isn’t necessary to include the conditional comments in the head of the document. However, you might still want to do so if you risk not containing the character encoding declaration within the first 1024 bytes of the document.

<!DOCTYPE html>
<html lang="en">
<!--[if lt IE 7]><html class="no-js ie6"><![endif]-->
<!--[if IE 7]><html class="no-js ie7"><![endif]-->
<!--[if IE 8]><html class="no-js ie8"><![endif]-->
<!--[if gt IE 8]><!--><html class="no-js"><!--<![endif]-->
  <head>
    <meta charset="utf-8">
    <title>Document</title>
  </head>
  <body>
  </body>
</html>

Fork the Gist

The “preemptive” conditional comments method

Another method to prevent the Compatibility View icon from showing was found by Julien Wajsberg. It relies on including a conditional comment before the DOCTYPE. Doing this seems to help IE recognise the <meta http-equiv="X-UA-Compatible"> tag. This method isn’t as DRY and doesn’t have the character encoding declaration as high up in the document, but it also doesn’t use 2 opening html elements.

<!--[if IE]><![endif]-->
<!DOCTYPE html>
<!--[if lt IE 7]><html class="no-js ie6"><![endif]-->
<!--[if IE 7]><html class="no-js ie7"><![endif]-->
<!--[if IE 8]><html class="no-js ie8"><![endif]-->
<!--[if gt IE 8]><!--><html class="no-js"><!--<![endif]-->
  <head>
    <meta http-equiv="X-UA-Compatible" content="IE=edge,chrome=1">
    <meta charset="utf-8">
    <title>Document</title>
  </head>
  <body>
  </body>
</html>

Fork the Gist

While it’s interesting to explore these possibilities, the “classic” method is still generally the most understandable. It doesn’t create invalid HTML, doesn’t risk throwing IE into quirks mode, and you won’t have a problem with the Compatibility View icon if you use a server-side config.

If you find any other approaches, or problems with those posted here, please leave a comment but also consider adding what you’ve found to the relevant issues in the HTML5 Boilerplate GitHub repository.

Thanks to Paul Irish for feedback and suggestions.




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Coronavirus | 390 new cases, 24 deaths in Gujarat; clashes in Ahmedabad

Two prominent medical experts — AIIMS director Dr Randeep Guleriya and Dr. Manish Suneja — flew into Ahmedabad on Friday following instructions from the Home Minister to guide local doctors




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COVID19 claims second life




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Success in selling [electronic resource] : developing a world-class sales ecosystem / Reza Sisakhti

Sisakhti, Reza, author




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Thriving under stress [electronic resource] : harnessing demands in the workplace / Thomas W. Britt, Ph.D., Professor of Psychology, Clemson University, Steve M. Jex, Ph.D., Professor of Psychology, Bowling Green State University

Britt, Thomas W., 1966-




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Tibco spotfire [electronic resource] : a comprehensive primer : create innovative enterprise-class informatics solutions using TIBCO Spotfire / Michael Phillips

Phillips, Michael, author




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To the cloud [electronic resource] : cloud powering an enterprise / Pankaj Arora, Raj Biyani, Salil Dave

Arora, Pankaj




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Validating your business continuity plan [electronic resource] : ensuring your BCP really works / Robert A. Clark

Clark, Robert A., author




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VersaStack solution by Cisco and IBM with Oracle RAC, IBM FlashSystem V9000, IBM Spectrum Protect [electronic resource] / Jon Tate, Dharmesh Kamdar, Dong Hai Yu, Randy Watson

Tate, Jon, author







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JAMA Internal Medicine : Effect of Exercise Intervention on Functional Decline in Very Elderly Patients

Interview with Mikel Izquierdo, Ph.D, and Nicolás Martínez-Velilla, PhD, authors of Effect of Exercise Intervention on Functional Decline in Very Elderly Patients During Acute Hospitalization: A Randomized Clinical Trial, and William J. Hall, MD, author of A Novel Exercise Intervention and Functional Status in Very Elderly Patients During Acute Hospitalization




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JAMA Cardiology : Association of Mutations Contributing to Clonal Hematopoiesis With Prognosis in Chronic Ischemic Heart Failure

Interview with Andreas M. Zeiher, MD, author of Association of Mutations Contributing to Clonal Hematopoiesis With Prognosis in Chronic Ischemic Heart Failure, and Peter Libby, MD, author of CHIPping Away at the Pathogenesis of Heart Failure















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JAMA Neurology : Clinical Effectiveness of Direct Oral Anticoagulants vs Warfarin in Older Patients With Atrial Fibrillation and Ischemic Stroke

Interview with Adrian F. Hernandez, MD, MHS, author of Clinical Effectiveness of Direct Oral Anticoagulants vs Warfarin in Older Patients With Atrial Fibrillation and Ischemic Stroke: Findings From the Patient-Centered Research Into Outcomes Stroke Patients Prefer and Effectiveness Research (PROSPER) Study






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JAMA Cardiology : Effect of 1 or 2 Doses of Inclisiran on Low-Density Lipoprotein Cholesterol Levels

Interview with Kausik K. Ray, MD, author of Effect of 1 or 2 Doses of Inclisiran on Low-Density Lipoprotein Cholesterol Levels: One-Year Follow-up of the ORION-1 Randomized Clinical Trial, and Maarten JG. Leening, MD, PhD, author of Safety and Tolerability of Sustained Lipid-Lowering Therapy: Trial Data and Public Perception in a World Where Vaccines and Statins Are About to Collide