3

Wish him long, healthy life: PM Modi on Revanth Reddy's birthday




3

Nominated posts filled after screening 30,000 applications: Chandrababu Naidu




3

Gujarat govt appoints 123 veterinary officers to strengthen animal welfare




3

Gujarat DDU-GKY Program: Over 30,000 rural youth trained, 450 receive job appointment letters




3

Gujarat CM flags off 'Run For Unity' marathon in Ahmedabad; remembers Sardar Vallabhbhai Patel




3

'Run For Unity' marathon is symbol of integrity: Gujarat CM Bhupendra Patel




3

Priyanka Gandhi offers prayers at Thirunelli temple where Rajiv Gandhi's ashes immersed




3

'My most happiest': Priyanka Gandhi ends Wayanad bypoll campaign with Malayalam touch




3

How to Play Grand Poo World 3

The underground world of creating and streaming Super Mario World-based ROM hacks continues to gain popularity. This popularity is a tribute to the creativity of gamers and the quality of the original 30 year old video game’s mechanics. Over the past decade, incredible ROM hacks like Grand Poo World 1 and 2, Invictus, and Dram […]

The post How to Play Grand Poo World 3 appeared first on David Walsh Blog.




3

'He was simply larger than life'

The Denver Nuggets, who took Mutombo in the first round of the 1991 draft, said in a statement they were "heartbroken" by his passing.




3

'I've lost my voice. I can't quite believe it'

According to the BCC, the prince has been a supporter of Aston Villa since his school days.




3

Europa PIX: Maguire to Manchester United's rescue

IMAGES from the Europa League matches played on Thursday




3

Bihar to host Women's Asian Champions Trophy

'The design of the logo of this competition is a symbol of the rich cultural heritage and all-round progress of glorious Bihar.'




3

PIX: Lewandowski 'tricks; Frankfurt defies Bayern

Roundup of the matches being held across major football leagues in Europe on Sunday




3

'All we are here for is to try and win on the 12th'

The Blue Tigers held their first training session in Vietnam on Monday evening at the Nam Dinh Sports Palace Ground and will have four more full sessions before taking on the hosts on Saturday.




3

'You made me love tennis'

A true legend of the game who paved the way and taught so many of us how to be as a player and as a person.




3

PIX: Spain's first transgender football team

Fenix's first game of the season on September 21 ended with a 19-0 defeat. But for its fans and players, trans men having the right to play their favourite sport on equal terms is far more important than the score.




3

Kashmir Marathon: '42 kilometres in a paradise!'

Around 2000 runners, including 59 internationals athletes, took part in the inaugural Kashmir Marathon in Srinagar.




3

PIX: Real Madrid's stunning comeback!

Real Madrid fought back from two goals down as Vinicius Jr grabbed a hat-trick in a thrilling 5-2 win over visitors Borussia Dortmund in the Champions League.




3

PIX: Haaland stuns with 'amazing' goal against Sparta

Erling Haaland scored with a flying back-heeled volley out of the air -- that had social media in a frenzy and left his teammates in awe.




3

PIX: Fenerbache's Mourinho sees red as Man Utd draw

IMAGES from the Europa League matches played on Thursday




3

F1: Ferrari's Sainz wins in Mexico; Verstappen 6th

The win was a first for Ferrari in Mexico since 1990 and fourth of Carlos Sainz's career.




3

EPL: Salah's late strike helps Liverpool hold Arsenal

Mohamed Salah's late equaliser earned Liverpool a 2-2 draw with rivals Arsenal in an entertaining Premier League encounter.




3

PIX: Not Messi, Ronaldo; Rodri wins Ballon D'Or!

Rodri won the Ballon d'Or award for the best player in the world, beating Brazil's Vinicius Jr and England's Jude Bellingham.




3

PIX: Vinicius 'tricks' in Real win; PSG maintain lead

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.




3

PIX: Messi's Miami stunned by Atlanta in MLS play-offs

Miami were overwhelming favourites to win it all after producing a league record 74 points in the regular season but could not keep the momentum after Matias Rojas' close-range goal in the 17th minute and Messi's score in the 65th minute.




3

13/13:01 EDT Severe Thunderstorm Warning for parts of East Gippsland Forecast District.




3

Nvidia overtakes Apple as world's most valuable company

Nvidia's stock market value briefly touched $3.53 trillion, while that of Apple was $3.52 trillion, according to data from LSEG




3

Reliance Jio slashes price of JioBharat 4G phone by ₹300 for Diwali

BL Mumbai Bureau Users of JioBharat 4G phones can make unlimited voice calls, get access to over 455 television channels, and 14 GB data at ₹123 per month




3

Cyient acquires 27.3% stake in Azimuth AI

The investment aligns with India’s initiatives to boost domestic semiconductor innovation and follows Cyient’s establishment of a fully owned semiconductor subsidiary in July 2024




3

Airtel Q2 FY25 net profit jumps 168% YoY to ₹3,593 crore

Mobile ARPU increased to ₹233 in Q2 FY25 vs ₹203 in Q2 FY24




3

Cognizant reports 22% profit jump in Q3, bolstered by health sciences and financial services growth

Revenue also increased by 3% year-on-year, totalling $5 billion




3

IT/ITEeS demand for hybrid work model continuation in SEZs beyond Dec 31 being considered: Govt sources

Some units want long-term flexibility but government only open to only periodic extension




3

Four semiconductor projects in Gujarat to create 53,000 new jobs: Govt

The statement from the government pointed out that the foundation stone for Micron’s advanced semiconductor ATMP plant was laid in Sanand, marking an investment of over ₹22,500 crore




3

OpenAI's ChatGPT back up after brief outage

Outage tracking website Downdetector.com said ChatGPT's services were down for about half an hour, affecting over 19,403 users as of 7:13 p.m. ET (0013 GMT on Saturday)





3

Synthesis of 3,5-disubstituted isoxazoles by domino reductive Nef reaction/cyclization of β-nitroenones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00232F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Ehtisham Ibraheem Khan, Tomas Lighuen Cassini, Marino Petrini, Alessandro Palmieri
β-Nitroenones were converted into 3,5-disubstituted isoxazoles via a domino reaction promoted by tin(II) dichloride. The protocol efficiently works under both microwave and flow conditions.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00190G, Paper
Kai-Cheng Yang, Shi-Lu Zheng, Zhong Wen, Yu-Shan Zhang, Hai-Liang Ni, Long Chen
A HOTf or Fe(OTf)3-catalyzed dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes was developed, which represents a brand-new procedure for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

An efficient synthesis of mono-, di-, and tri-substituted 1,3-thiazoles employing functionalized thioamides as thiocarbonyl precursors

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00229F, Paper
Kalleshappa Sheela, Chikkappaiahnayaka Santhosh, Krishna Ravi Singh, Kalleshappa Sharath, Maralinganadoddi P. Sadashiva
Herein, we report an efficient strategy to synthesize functionalized 1,3-thiazoles using alkyl 2-amino-2-thioxoacetates.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Photoinduced decatungstate-catalyzed C(sp3)–H thioetherification by sulfinate salts

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00394B, Paper
Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang, Wujiong Xia
A visible light photoinduced decatungstate-catalyzed C(sp3)–H thioetherification of hydrocarbons by sodium sulfite is herein reported.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

HFIP-mediated C-3-alkylation of indoles and synthesis of indolo[2,3-b]quinolines & related natural products

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00414K, Paper
Auqib Rashid, Waseem I. Lone, Preeti Dogra, Showkat Rashid, Bilal A. Bhat
An expeditious metal free C-3 alkylation of indoles and its NIS-mediated deviation to indolo[2,3-b]quinolines is reported. Applications of these strategies in accessing bioactive natural products have also been demonstrated.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Rh(III)-catalysed C-H annulation of cis-stilbene acids with 2-diazo-1,3-diketones: A facile access to 6,7-dihydrobenzofuran-4(5H)-one and α-pyrone scaffolds

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00151F, Paper
Shankaraiah Nagula, Mary Sravani Galla, Nandini B. Kale, Akshay Kumawat, Darshana Bora
An efficient Rh(III)-catalysed C-H functionalization, tandem annulation of cis-stilbene acids using 2-diazo-1,3-diketones was devised. The protocol has solely afforded 6,7-dihydrobenzofuran-4(5H)-ones using alicyclic diazocarbonyls via decarbonylation and α-pyrones with aliphatic diazo...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Catalyst- and base-free visible light-enabled radical relay trihalomethylation/functional group-migration/carbonylation with CX3SO2Cl

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00292J, Paper
Jinkai Hu, Chenglei Yang, Xiaotao Qin, Hui Liu, Tongtong Ma, Ao-tong Shi, Qing-Long Lv, Xingman Liu, Jinhui Yang, Dianjun Li
A visible light-enabled photocatalyst-free radical trihalomethylation/cyano (or benzo[d]thiazol-2-yl) 1,4-migration/carbonylation reaction of 2-hydroxy-2-hex-5-enenitrile (or (benzo[d]thiazol-2-yl)-pent-4-enol) with CX3SO2Cl (X = F, Cl) is reported.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Covalently linked thieno[2,3-b]thiophene-fullerene dimers: synthesis and physical characterization

Org. Biomol. Chem., 2024, 22,2978-2984
DOI: 10.1039/D4OB00027G, Paper
Abdulrahman M. Alazemi, Mohammad H. BinSabt, Hamad M. Al-Matar, Alan L. Balch, Mona A. Shalaby
Linked thieno[2,3-b]thiophene-fullerene Dimers.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Vinylogous and stereoselective domino synthesis of pyrano[2,3-c]pyrroles from alkylidene meldrum's acids

Org. Biomol. Chem., 2024, 22,2948-2952
DOI: 10.1039/D4OB00233D, Communication
Mariia Savchuk, Giang Vo-Thanh, Sylvain Oudeyer, Hélène Beucher, Jean-François Brière
An expeditious diatereoselective synthesis of pyrano[2,3-c]pyrroles thanks to a domino Vinylogous aza-Michael-Aldol-Cyclocondensation (aza-VMAC) reaction to alkylidene Meldrum's acid derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

2-Azabicyclo[3.2.1]octane scaffold: synthesis and applications

Org. Biomol. Chem., 2024, 22,2902-2915
DOI: 10.1039/D4OB00199K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mariana Crespo Monteiro, João Rafael Vale, Filipa Siopa
This review focuses on the preparation and applications in total synthesis of 2-azabicyclo[3.2.1]octane structures, a class of natural and synthetic compounds with a range of biological activities.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Unusual immunosuppressive pyridine-containing bisnor- (c23), tetranor- (c21) and pentanor- (c20) sesterterpenoids from Tibetan Leucosceptrum canum

Org. Biomol. Chem., 2024, 22,3019-3024
DOI: 10.1039/D4OB00334A, Paper
Man Li, Ling Feng, Han Zhang, Yan-Chun Liu, Ting-Ting Zhou, Yu Zheng, Kai Guo, Yan Liu, Sheng-Hong Li
Six unusual pyridine-containing bisnor- (C23), tetranor- (C21) and pentanor- (C20) sesterterpenoids were obtained from the medicinal plant Leucosceptrum canum of Tibetan origin. The immunosuppressive activities of these sesterterpenoids were observed.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Stereoselective synthesis of (R)- and (S)-1,2-diazetidine-3-carboxylic acid derivatives for peptidomimetics

Org. Biomol. Chem., 2024, 22,2974-2977
DOI: 10.1039/D4OB00278D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew Nutter, Henry Stone, Michael Shipman, Stefan Roesner
Stereoselective synthesis of both enantiomers of orthogonally protected 1,2-diazetidine-3-carboxylic acid (aAze) from homochiral glycidol and its application in peptidomimetics.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Iron-catalyzed selective construction of indole derivatives via oxidative C(sp3)–H functionalization of indolin-2-ones

Org. Biomol. Chem., 2024, 22,3073-3079
DOI: 10.1039/D4OB00133H, Paper
Wei Chen, Lang-Qi Wen, Xiao-Bing Lu, Hui Zhou
We have developed a clean and efficient iron-catalyzed C(sp3)–H functionalization of indolin-2-ones for the chemodivergent synthesis of value-added indole derivatives, including isatins, and symmetrical and non-symmetrical isoindigos.
The content of this RSS Feed (c) The Royal Society of Chemistry