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Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
The content of this RSS Feed (c) The Royal Society of Chemistry




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(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05156D, Paper
Hongjiao Chen, Kewei Zhang, Yanzhi Xia, Jian Li, Bin Hui
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts

Green Chem., 2024, 26,11351-11363
DOI: 10.1039/D4GC04447A, Paper
Open Access
Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen Li
A paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Comparison of microbial strains as candidate hosts and genetic reservoirs for the valorization of lignin streams

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03876B, Paper
Open Access
Rebecca A. Wilkes, Andrew J. Borchert, Valentina E. Garcia, Gina M. Geiselman, Sarah Liu, Adam M. Guss, Joshua K. Michener, Daniel R. Noguera, Eiji Masai, John M. Gladden, John Ralph, Gregg T. Beckham
Comparison of microbial strains for tolerance to and catabolism of lignin stream constituents toward evaluating microbial hosts for lignin bioconversion.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Is Thursday the new Friday?

A look at films being released a day earlier than usual




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Hero’s Vida V1 Plus, Pro e-scooters launched




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Maharashtra Assembly polls: Pawar vs Pawar in Baramati, Atram vs Atram in Aheri as NCP (SP) declares 45 candidates




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Shiv Sena (UBT) leader says won’t campaign for NCP candidates in Bhosari and Chinchwad




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Maharashtra Assembly elections: Jarange keeps candidates names under wraps




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‘Sex work is dignified work’: Network urges candidates to address sex workers’ rights in manifestos




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Police vehicles being used to provide financial aid to candidates of ruling parties: Sharad Pawar




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Pune voters want candidates to prioritise road infra, traffic laws enforcement




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Bureaucrat-turned-politician Zende is NCP candidate in Purandar friendly fight




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Who is Shameebha Patil, the lone transgender candidate in Maharashtra Assembly elections?




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IND vs SA, 2nd T20I: Varun Chakaravarthy on Gautam Gambhir’s guidance: ‘He gave me a lot of role clarity’




ida

'Rohit Bal, Alvida Mere Dost'

'He was Vibrant, Colourful, Funny, Genius, Compassionate, Larger than Life, Kind and many more things!' 'Above all A Great Human being.'




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683 candidates fight it out in Jharkhand polls today

However, in 950 booths, voting will end at 4 pm, though people standing in the queue at that time will be able to exercise their franchise.




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P Chidambaram writes: It is too early to tell




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P Chidambaram writes: Fasten your seat belt




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P Chidambaram writes: Bare-knuckle politics




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SC orders liquidation of Jet Airways' assets

The Supreme Court on Thursday exercised its extraordinary constitutional powers and ordered the liquidation of grounded air carrier Jet Airways' assets. A bench of Chief Justice D Y Chandrachud and Justices J B Pardiwala and Manoj Misra set aside the National Company Law Appellate Tribunal (NCLAT) decision upholding the resolution plan of Jet Airways and approved the transfer of its ownership to Jalan Kalrock Consortium (JKC).




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Watch Srikanth Kidambi Rescue His Bride

Shravya Varma, the talented niece of film-maker Ram Gopal Varma, and badminton ace Srikanth Kidambi sealed their bond in a grand wedding ceremony in Hyderabad on Saturday.





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From Farida Jalal to Kirron Kher, here are six of our favourite onscreen mothers in Bollywood

Mother’s have been an important part of Hindi cinema. Over the years, the portrayal of mothers in Bollywood has been changing. Mothers are given much more importance in cinema than just being a character actor who has to nod to everything the husband or the child says. 

On the occasion of Mother’s Day, here’s looking at some of the most popular on-screen mothers. 

Rakhee 

Her dialogue “Mere Karan Arjun aayenge'' is not something that one will forget anytime soon. She played mother to actors Shah Rukh Khan and Salman Khan in the hit film Karan Arjun. While Rakhee has played varied roles in her illustrious career spanning over 50 years, when it came to being a mother onscreen she has been seen as a woman of principles including in films like Baazigar, Ram Lakhan, Soldier, Khalnayak and others. 

Farida Jalal 

Farida Jalal too has been part of the industry for almost fifty years and continues to impress people with her charm. While the actress has played different kinds of roles, her motherly onscreen figure is the one most remembered by people. From being Shah Rukh Khan’s mother in Duplicate to Kajol’s in Dilwale Dulhania Le Jaayenge, she is the kind of mother who is always ready to make sacrifices for her child. She is also popular for the savage yet emotional grandmother of Jiya from the television series Shararat

Kirron Kher

She is often cast as the loud Punjabi mother with a soft heart always caring and worrying about her child. From Dostana, to Hum Tum to Singh is King to Om Shanti Om she was the mother who could also make you laugh with her snarky comments. While she started her career in film in 1983, most of her hit films including Main Hoon Na and Rang De Basanti see her play the role of a mother. 

Reema Lagoo

Best remembered for her role in Tu Tu Main Main, she has largely been seen in Bollywood films playing the emotional mother. She has played mother to most superstars in the late 80s and 90s. She was considered as a "new-age mother" in Hindi cinema. She was low on drama and was not too emotional either, perfectly maintaining the balance between the two. From Hum Saath Saath Hai to Hum Aapke Hai Kaun to Kal Ho Naa Ho, she is the kind of mother you just want to give a hug and say everything will be okay. 

 Jaya Bachchan 

How can an onscreen mother’s list be complete without Jaya Bachchan. She raised the bar for on-screen mothers with her performance in Kabhi Khushi Kabhi Gham. The scene with Shah Rukh Khan’s entry in the film will be remembered for Jaya Bachchan’s sixth sense rather than the superstar’s entry. She then went on to ditch the saree and all the parampara and thali and was seen playing a bold single mother in Kal Ho Naa Ho

Ratna Pathak Shah

She will always be remembered dearly as Maya Sarabhai who could accept anything else but being middle class. When it comes to playing a mother in Bollywood, she has never been typecast and has shown variety in her characters. In Jaane Tu Ya Jaane Na she was the protective and progressive mother to Imran Khan’s character who could not tolerate violence or any unjust activities. She once again played mother to Imran Khan in Ek Main Aur Ek Tu. She was a rich- sophisticated woman yet very different from her character Maya Sarabhai. Meanwhile, she played a middle-class mother to Taapsee Pannu in the film Thappad who worried more about “Log Kya Kahenge”. 

Let us know your favourites in the comment section.




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How UK hotels are preparing for the holiday season from hell

Across the country, hotels that were shuttered at the start of the coronavirus pandemic have become eerie, empty shells. Front desks are devoid of receptionists ready to check-in guests, rooms are collecting dust. And with the summer season on the h...




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Fresher Candidates For Banking Finance Customer Care -MNC Bank Payroll

Company: Hy Fly Consultancy
Experience: 1 to 6
Salary: 1.50 to 4.10
location: Mumbai, Mumbai City, Navi Mumbai, Thane, Pune
Ref: 24828886
Summary: Designation-Phone Banking AM Process-Inbound/OutBound Payroll-Bank Receive Calls of the Existing Bank Customers - Solve their banking....




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IT- SERVICE DESK | Technical support voice process @ Candidates from PUNE only

Company: Sky Scrapper Consulting
Experience: 0 to 3
location: Pune
Ref: 24828467
Summary: IT Service desk support system




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Hospital group NMC raises guidance for 2018

United Arab Emirates-based group anticipates strong growth next year




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I discovered the rest of America on my holiday

Driving across the US gave me a different perspective on the American economy




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Bank holiday road trippers caught and fined

Cumbria Police caught several would-be day-trippers flouting restrictions over the long weekend, including a driver who attempted to travel from Manchester to Dundee to buy a puppy on Saturday.




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You Should Totally Bookmark Lisa Ray’s Pink Bridal Lehenga From Four More Shots Please!

It was just a few days ago,when stylist Aastha Sharma shared a picture of Lisa Ray from the sets of Four More Shots Please!, where she was seen sporting a stunning white bridal ensemble by Gaurav Gupta. And now, recently,




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Tripeptide-dopamine fluorescent hybrids: a coassembly-inspired antioxidative strategy

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01882A, Communication
Jun Guo, Fan Zheng, Bo Song, Feng Zhang
Coassembling peptides with dopamine molecules can construct hybrid nanostructures with a large Stokes shift green fluorescence, which is an effective antioxidative strategy for biomolecules.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mayor eficiencia en el cruce de la frontera de Nogales mejora la calidad del aire y la salud pública

NOGALES, AZ – Hoy, la Agencia de Protección Ambiental de EE. UU.




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John Lennon’s former Florida estate on market for eye-popping $47.5M

The former Palm Beach, Fla., home of John Lennon and Yoko Ono is for sale at $47.5 million.




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Summer 2020: quarantine move will trigger 'bank holiday traffic every day' as prices soar above £2k for a week at Center Parcs

Exclusive: 'As well as staggered working hours we need to stagger holidays,' says AA president Edmund King




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ML 3.1 SOUTHERN IDAHO

Magnitude  ML 3.1
Region  SOUTHERN IDAHO
Date time  2020-05-10 01:54:18.4 UTC
Location  44.37 N ; 115.16 W
Depth  10 km




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ML 2.8 SOUTHERN IDAHO

Magnitude  ML 2.8
Region  SOUTHERN IDAHO
Date time  2020-05-10 02:50:57.9 UTC
Location  44.31 N ; 114.90 W
Depth  10 km




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ML 3.0 SOUTHERN IDAHO

Magnitude  ML 3.0
Region  SOUTHERN IDAHO
Date time  2020-05-10 05:02:02.4 UTC
Location  44.45 N ; 115.22 W
Depth  10 km




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Coronavírus avança mais rápido em cidades pequenas, mostra levantamento

Estudo da Fiocruz aponta aumento em torno 50% de novos casos nos municípios com até 20 mil habitantes nas duas últimas semanas.




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Man tased four times during Friday arrest: RPS

Police used a taser several times during the arrest of a man on Friday.




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Discover Something New at Home this Holiday Season

Filed under: , ,

Traveling "home" this holiday season? Don't fall into your old routine. Your high school hangout may be an easy go-to, but if you don't live there anymore there's a good chance you're missing out on some great new local spots. (Plus, be honest: you already know what all your classmates are up to from Facebook.)

We turned to local writers to help you rediscover your hometown over Thanksgiving and the winter holidays. Each city guide features a great new restaurant to try while you're in town, a cool neighborhood that wasn't on the radar last year or a store where you can pick up a keepsake to bring your old home back to your new home. We'll also catch you up to speed on the hot topics of conversation in each city, so you'll come back savvy enough to join the local sports banter or eat your holiday weight in Cronuts.

Click your city below to learn what's new since the last time you went home:

Continue reading Discover Something New at Home this Holiday Season

Discover Something New at Home this Holiday Season originally appeared on Gadling on Mon, 25 Nov 2013 12:15:00 EST. Please see our terms for use of feeds.

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Will You Be a Horrible Restaurant Customer This Holiday Season?

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Getty Images

So you've finished your Thanksgiving dinner and you're finally sick of turkey leftovers. It's time to get out there and hit the great new restaurant that just opened in your hometown or wherever you're spending the holidays. (FYI: Aol Travel knows the hot restaurants in cities around the U.S.)

Wherever you go, remember that there are appropriate ways to behave. And there are horrible ways to behave, as highlighted in this Montreal Gazette story by two Montreal-area restaurant servers. Among other things, they urge:

Continue reading Will You Be a Horrible Restaurant Customer This Holiday Season?

Will You Be a Horrible Restaurant Customer This Holiday Season? originally appeared on Gadling on Wed, 27 Nov 2013 16:31:00 EST. Please see our terms for use of feeds.

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ida

Discover Something New at Home this Holiday Season

Filed under: , ,

Traveling "home" this holiday season? Don't fall into your old routine. Your high school hangout may be an easy go-to, but if you don't live there anymore there's a good chance you're missing out on some great new local spots. (Plus, be honest: you already know what all your classmates are up to from Facebook.)

AOL Travel turned to local writers to help you rediscover your hometown over the winter holidays. Each city guide features a great new restaurant to try while you're in town, a cool neighborhood that wasn't on the radar last year or a store where you can pick up a keepsake to bring your old home back to your new home. AOL Travel also will catch you up to speed on the hot topics of conversation in each city, so you'll come back savvy enough to join the local sports banter or eat your holiday weight in Cronuts.

Click your city below to learn what's new since the last time you went home:

Continue reading Discover Something New at Home this Holiday Season

Discover Something New at Home this Holiday Season originally appeared on Gadling on Wed, 18 Dec 2013 11:04:00 EST. Please see our terms for use of feeds.

Permalink | Email this | Comments




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Glucocerebrosidases catalyze a transgalactosylation reaction that yields a newly-identified brain sterol metabolite, galactosylated cholesterol [Glycobiology and Extracellular Matrices]

β-Glucocerebrosidase (GBA) hydrolyzes glucosylceramide (GlcCer) to generate ceramide. Previously, we demonstrated that lysosomal GBA1 and nonlysosomal GBA2 possess not only GlcCer hydrolase activity, but also transglucosylation activity to transfer the glucose residue from GlcCer to cholesterol to form β-cholesterylglucoside (β-GlcChol) in vitro. β-GlcChol is a member of sterylglycosides present in diverse species. How GBA1 and GBA2 mediate β-GlcChol metabolism in the brain is unknown. Here, we purified and characterized sterylglycosides from rodent and fish brains. Although glucose is thought to be the sole carbohydrate component of sterylglycosides in vertebrates, structural analysis of rat brain sterylglycosides revealed the presence of galactosylated cholesterol (β-GalChol), in addition to β-GlcChol. Analyses of brain tissues from GBA2-deficient mice and GBA1- and/or GBA2-deficient Japanese rice fish (Oryzias latipes) revealed that GBA1 and GBA2 are responsible for β-GlcChol degradation and formation, respectively, and that both GBA1 and GBA2 are responsible for β-GalChol formation. Liquid chromatography–tandem MS revealed that β-GlcChol and β-GalChol are present throughout development from embryo to adult in the mouse brain. We found that β-GalChol expression depends on galactosylceramide (GalCer), and developmental onset of β-GalChol biosynthesis appeared to be during myelination. We also found that β-GlcChol and β-GalChol are secreted from neurons and glial cells in association with exosomes. In vitro enzyme assays confirmed that GBA1 and GBA2 have transgalactosylation activity to transfer the galactose residue from GalCer to cholesterol to form β-GalChol. This is the first report of the existence of β-GalChol in vertebrates and how β-GlcChol and β-GalChol are formed in the brain.




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Black Immigrant Mothers in Palm Beach County, Florida, and their Children's Readiness for School

This report draws on a six-year longitudinal study of Palm Beach County, FL, examining parenting, child care enrollment, and other factors that encourage early school success. The authors find kindergarten-age children of Black immigrants have significantly higher odds of being ready for school than children of Latina immigrant or Black U.S.-born mothers.




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Trinidad to start reopening Tuesday, but borders to remain closed until June

(CMC): Trinidad and Tobago says its borders are to remain closed until June, even as it embarks on softening restrictions to re energise the economy, which had been halted by COVID-19.   Prime Minister Dr Keith Rowley said the...




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Hoja de ruta para la participación de las diásporas en el desarrollo: Un manual para políticos y profesionales de los países de origen y de acogida

Este manual ofrece a los formuladores de políticas y especialistas una guía accesible y práctica sobre las iniciativas gubernamentales referentes a la diáspora. Este manual contiene un menú, seleccionado cuidadosamente, de opciones normativas y programáticas viables basadas en experiencias reales en distintas partes del mundo.




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Holiday Bible class becomes community event

The OM Philippines-Cebu team, in partnership with the local church, touches the lives of young and old through a five-day Bible class.