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Influence of redox treatments on the low-temperature water gas shift reaction over Pt/CeO2 catalysts

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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper
Open Access
Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H2 reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO2 catalysts by increasing the number of active Pt0 NPs. A 12 h oxidative post-treatment at 500 °C which forms PtOx species easily activated also leads to improvement.
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Theoretical insights into Pt–Rh alloy nanoparticles: stability, elemental distribution, and catalytic mechanisms for NO + CO reactions

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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper
Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
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Accelerated design of nickel-cobalt based catalysts for CO2 hydrogenation with human-in-the-loop active machine learning

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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO2 methanation and is extendable to other catalytic processes.
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Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis

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Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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Construction of a flow-through catalytic reactor employing O3–Fe/TiO2 for efficient catalytic ozonation disinfection

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Catal. Sci. Technol., 2024, 14,6351-6362
DOI: 10.1039/D4CY00893F, Paper
Jiaxuan Li, Xin Chen, Siyu Li, Kunrong Mei, Lequan Liu, Jinhua Ye
An O3–Fe/TiO2 reactor is designed for efficient air disinfection by catalytically converting ozone into reactive oxygen species (ROS).
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High-temperature calcination enhances the activity of MnOx catalysts for soot oxidation

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Catal. Sci. Technol., 2024, 14,6278-6285
DOI: 10.1039/D4CY00983E, Paper
Open Access
Meng Wang, Jingyi Wang, Yan Zhang, Yunbo Yu, Wenpo Shan
High-temperature calcination usually induces the sintering of catalysts, thus resulting in negative effects on their performance.
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Construction of a highly efficient MoS2-based composite electrocatalyst for the oxygen evolution reaction

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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper
Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS2 play a similar role to the amino acid residues in PS II.
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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

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Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Acrylamides from 1,2-dichloroethane via palladium-catalyzed carbonylation

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Catal. Sci. Technol., 2024, 14,6180-6185
DOI: 10.1039/D4CY01117A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ren-Rui Xu, Chang-Sheng Kuai, Xiao-Feng Wu
An efficient strategy for the synthesis of acrylamides via palladium-catalyzed carbonylation, using 1,2-dichloroethane and amines as starting materials has been developed.
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Experimental and DFT study of the MoO2@Fe2O3 catalyst for overall water splitting in acidic and alkaline electrolytes

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00779D, Paper
Suchitra N. Sapakal, Arvind Singh, Ayesha Khan, Mayur Gaikwad, Jin H. Kim, Anamika Kadam
HER: overpotential for HER, OER: overpotential for OER; Rs: solution resistance, Rct: charge transfer resistance. The comparison of various parameters of the MoO2@Fe2O3 electrode in KOH and H2SO4 electrolytes.
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Engineering galactose oxidase for efficient cascade synthesis of L-guluronic acid from D-glucose

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00697F, Paper
Qingxiu Wang, Weisong Liu, Lijing Chang, Kuncheng Zhang, Yanbing Shen, Lingling Zhang
A synthetic pathway of L-guluronic acid and rational design of galactose oxidase.
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Effect of metal loading sequences in CO2 methanation activity on samarium-doped ceria supported bimetallic catalysts

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper
Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper
Open Access
Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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Catalytic activity and stability of NiPt/C catalysts for the synthesis of iso-butanol from methanol/ethanol mixtures

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni99Pt1/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Effects of zeolite porosity and acidity on catalytic conversion of carbohydrates to bio-based chemicals: a review

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article
Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

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Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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Oxygen vacancy-dependent low-temperature performance of Ni/CeO2 in CO2 methanation

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Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper
Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO2 methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Switching of selectivity from benzaldehyde to benzoic acid using MIL-100(V) as a heterogeneous catalyst in aerobic oxidation of benzyl alcohol

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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper
Open Access
Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Synergistic promotion of oxygen vacancy and Lewis acidity of Nb2O5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt

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Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper
Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt1/Nb2O5, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb2O5 selectively promotes the hydrogenolysis of the –CH2OH group rather than the hydrogenation of the –CHO group.
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Unsupervised pattern recognition on the surface of simulated metal nanoparticles for catalytic applications

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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper
Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

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Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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Photocatalytic H2O2 production with perylene(bis-imide)-doped periodic mesoporous silica using micropollutants as sacrificial donors

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Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper
Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H2O2 from aerated polluted water samples under light soaking.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review

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Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article
Open Access
Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Anthracene-based covalent organic framework supported palladium nanoparticles for visible-light-mediated Suzuki-Miyaura cross-coupling

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper
Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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Material design of biodegradable primary batteries: boosting operating voltage by substituting the hydrogen evolution reaction at the cathode

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Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview
Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Effect of graphene electrode functionalization on machine learning-aided single nucleotide classification

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Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper
Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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Electrostatic interactions and structural transformations in viral shells

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Nanoscale, 2024, 16,20182-20193
DOI: 10.1039/D4NR02612H, Paper
Open Access
Ivan Yu. Golushko, Daria S. Roshal, Olga V. Konevtsova, Sergei B. Rochal, Rudolf Podgornik
Considering the simplest energy of electrostatic interactions between proteins together with the mechanical energy of the continuum shell, one can model various structural transformations possible in viral capsids.
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An eco-friendly polycaprolactone/graphite composite as a robust freestanding electrode platform for supercapacitive energy storage

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Nanoscale, 2024, 16,20155-20167
DOI: 10.1039/D4NR03113J, Paper
Rajeev Gupta, Monika Singhal
A novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

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Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor

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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper
Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Nanoscopic visualization of microgel-immobilized cytochrome P450 enzymes and their local activity

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Nanoscale, 2024, 16,20194-20201
DOI: 10.1039/D4NR03435J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lukas Schubert, Chiara Nenninger, Maximilian Nöth, Thomke Belthle, Robert Dirk de Lange, Andrij Pich, Ulrich Schwaneberg, Dominik Wöll
The distribution and local catalytic activity of Cytochrome P450 enzymes immobilized in microgels by electrostatic interaction has been determined with a combination of in situ super-resolution fluorescence microscopy experiments.
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Preparation and application of high thermal conductivity phase change microcapsules with fluorescence characteristics based on a ZnWO4 shell

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Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper
H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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Effective enrichment of glycated proteome using ultrasmall gold nanoclusters functionalized with boronic acid

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Nanoscale, 2024, 16,20147-20154
DOI: 10.1039/D4NR03283G, Paper
Hongmae Heo, Seonghyeon Cho, Yuhyeon Kim, Soomin Ahn, Jeong-hun Mok, Hookeun Lee, Dongil Lee
A novel approach was developed for the first time by combining ultrasmall Au22 nanoclusters with boronic acid (BA) affinity chemistry, achieving highly efficient enrichment of early-stage glycated peptides.
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Nucleic acid detection with single-base specificity integrating isothermal amplification and light-up aptamer probes

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Nanoscale, 2024, 16,20067-20072
DOI: 10.1039/D4NR01638F, Communication
Jaekyun Baek, Jihyun Park, Youngeun Kim
CLASSIC is a label-free DNA detection platform with single-nucleotide specificity and attomolar sensitivity. This assay offers rapid and sequence-specific DNA analysis through single-strand conversion and split light-up aptamer probes.
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Active site engineering of intermetallic nanoparticles by the vapour–solid synthesis: carbon black supported nickel tellurides for hydrogen evolution

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Nanoscale, 2024, 16,20168-20181
DOI: 10.1039/D4NR03397C, Paper
Open Access
Daniel Garstenauer, Patrick Guggenberger, Ondřej Zobač, Franz Jirsa, Klaus W. Richter
The intermetallic phases Ni3Te2, NiTe, NiTe2−x & NiTe2 were synthesized as carbon-black supported nanoparticles using the vapour–solid synthesis approach and were characterized for their performance in electrocatalytic hydrogen evolution.
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Modulating the photodynamic modality of Au22 nanoclusters through surface conjugation of arginine for promoted healing of bacteria-infected wounds

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Nanoscale, 2024, 16,20089-20099
DOI: 10.1039/D4NR03278K, Paper
Xinyue Dou, Sariah Saalah, Chel-Ken Chiam, Jianping Xie, Coswald Stephen Sipaut
An Au nanocluster (NC)-based photodynamic antibacterial is designed by conjugating arginine on the surface of Au22 NCs, achieving healing of bacteria-infected wounds via producing reactive oxygen species (ROS) and reactive nitrogen species (RNS).
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Folic acid-targeted redox responsive polylactic acid-based nanoparticles co-delivering pirarubicin and salinomycin suppress breast cancer tumor growth in vivo

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Nanoscale, 2024, 16,20131-20146
DOI: 10.1039/D4NR02365J, Paper
Priya Gupta, Ankushi Bansal, Harshdeep Kaur, Mohd Anees, Neetu Singh, Harpal Singh
Schematic illustration of design, administration, and mechanism of action of Pira/Sal dual-loaded FA-conjugated redox responsive [S-(PLA-b-PEG-CONH)]2 block copolymeric nanoparticles.
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Correction: Ce6-Conjugated and polydopamine-coated gold nanostars with enhanced photoacoustic imaging and photothermal/photodynamic therapy to inhibit lung metastasis of breast cancer

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Nanoscale, 2024, 16,20354-20355
DOI: 10.1039/D4NR90194K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ziwei Li, Fan Yang, Di Wu, Yanhong Liu, Yang Gao, Haichen Lian, Hongxin Zhang, Zhibin Yin, Aiguo Wu, Leyong Zeng
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Retraction: Enhanced activity of vancomycin by encapsulation in hybrid magnetic nanoparticles conjugated to a cell-penetrating peptide

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Nanoscale, 2024, 16,20356-20356
DOI: 10.1039/D4NR90195A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wenjie Zhang, Reza Taheri-Ledari, Zoleikha Hajizadeh, Ehsan Zolfaghari, Mohammad Reza Ahghari, Ali Maleki, Michael R. Hamblin, Ye Tian
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Glycosylated AIE-active Fe (III) photosensitizer activated by tumor microenvironment for synergistic type I photodynamic and chemodynamic therapy

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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03871A, Paper
Gai-li Feng, Wei Zhou, Jinping Qiao, Guang-Jian Liu, Guo-Wen Xing
Photodynamic therapy (PDT) and chemodynamic therapy (CDT) are both promising cancer treatments to inhibit tumor cells by generating highly cytotoxic reactive oxygen species (ROS). Herein, we report a novel tumor...
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Cr2TiC2Tx MXene as an Adsorbent Material in Ultrasonic-Assisted d-µ-Solid Phase Extraction for Trace Detection of Heavy Metals

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Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02556C, Paper
Saman Bagheri, Rashmeet Kaur Khurana, Md. Ibrahim Kholil, Michael J. Loes, Shengyuan Luo, Alexander Sinitskii
MXenes are a large family of two-dimensional transition metal carbides, nitrides, and carbonitrides. While MXenes have great potential for applications in analytical chemistry, most of the studies in this field...
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Interfacial coupling of NiSe in heterostructures promotes electrocatalytic hydrolysis of MoS2

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03180F, Paper
Feng Jiao, Jun Tang, Jinzhao Huang, Zehui Liu, Jing Xiao
NiSe@MoS2 was prepared using a hydrothermal method. Interfacial effects between the two phases lead to electronic restructuring of the interfacial region, resulting in more active sites.
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Investigation of the temperature effect on the formation of a two-dimensional self-assembled network at the liquid/solid interface

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02600D, Paper
Open Access
Tamara Rinkovec, Eveline Croket, Hai Cao, Jeremy N. Harvey, Steven De Feyter
In this work, we investigate the temperature effect on the formation of self-assembled molecular networks (SAMNs) at the liquid/solid interface, focusing on an alkylated achiral glycine derivative at the 1-phenyloctane/HOPG interface.
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Macroscopic chiral symmetry breaking in gelation of Fmoc-amino acids: homochiral selective secondary nucleation promoted by the choice of solvent or stirring

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04011B, Communication
Kentaro Tashiro
Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the emergence of macroscopic chiral symmetry breaking in the gelation of Fmoc amino acids.
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Boosting Quantum Efficiency and Suppressing Self-Absorption in CdS Quantum Dots through Interface Engineering

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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02990A, Paper
Shyamashis Das, Poulomi Mukherjee, Arpita Mukherjee, Anirban Dutta, Biswajit Bhattacharyya, Ashutosh Mohanty, Anshu Pandey, Priya Mahadevan, Ranjani Viswanatha, Dipankar D. Sarma
Applications of photoluminescence from semiconductor quantum dots (QDs) have faced the dichotomy of excitonic emission being susceptible to self-absorption and shallow defects reducing quantum yield (QY) catastrophically and doped emissions...
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