Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper

George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00974F, Paper

Melanie A. Kascoutas, Alison Sy-min Chang, Kiana E. Kawamura, Gabriela M. Bailey, Parker T. Morris, Elizabeth A. Borst, Lilliana H. Granados, Amanda K. Cook
A modular Ni(0)/silane E-selective alkene isomerization system has been developed with air-tolerant reagents.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00924J, Paper

Xihui Yang, Zekun Li, Zikun Yang, Dapeng Meng, Zhao Wang
CoNi@C core–shell catalysts from ZIF-67 were synthesized for efficient water splitting. The hydrophilic carbon shell inhibits metal oxidation. The CoNi alloy serves as the active site, while nitrogen doping promotes the electrocatalytic performance.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper

Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo₃S₄ clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00971A, Paper

Qianqian Shang, Hongbing Wang, Changjie Kan, Rui Ding, Yankai Li, Shiva Pandeya, Ziliang Li, Mahesh Kumar Joshi
Exfoliation and hetero-element doping are common procedures for band gap engineering and enhancing the photocatalytic properties of g-C₃N₄.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01029A, Paper

Haiting Ye, Takuma Sato, Taishi Nakanishi, Shigetomo Ito, Shigenobu Umemiya, Masahiro Terada
Chiral phosphoric acid catalysts were screened rationally and efficiently through the theoretical prediction model of the kinetic resolution of racemic γ-hydroxybutyrate without performing an exhaustive search for plausible lactonisation pathways.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper

Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper

Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
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Catal. Sci. Technol., 2024, 14,6155-6175
DOI: 10.1039/D4CY00627E, Review Article

A. Anantha Krishnan, Sreehari Harikumar, M. A. Aneesh Kumar, Revathy B. Nair, Sajith Kurian, M. Ameen Sha, P. S. Arun
NiFe₂O₄ is a potential catalyst for energy conversion and storage, owing to their electrical conductivity, catalytic activity, and stability.
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Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper

Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO₂ reduction, resulting in the dynamic evolution of i-CuO_x species. The in situ formed i-CuO_x plays decisive roles in promoting C–C coupling.
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper

Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper

Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO₂ with H₂O—known as artificial photosynthesis—is important.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6112-6154
DOI: 10.1039/D4CY00425F, Review Article

Sarita Yadav, Sangeeta Yadav, Mookan Natarajan, Kamal Kishore Pant, Ravi Tomar
From materials science and polymer chemistry to organic synthesis and medicinal chemistry, cross-coupling has influenced many scientific fields.
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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO₂ methanation and is extendable to other catalytic processes.
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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper

Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Catal. Sci. Technol., 2024, 14,6363-6371
DOI: 10.1039/D4CY00912F, Paper

Junchao Huang, Borui Li, Jiaxing Yu, Zhan Shu, Ming Li
The Z-scheme three-dimensional flower-like shape BiOBr/ZnIn₂S₄ showed excellent efficiency to degrade Congo red.
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Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper

Open Access

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Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO₂ phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO₂ hydrogenation to methane.
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Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper

Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C₃N₄ catalyst.
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Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper

Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH₃ can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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Catal. Sci. Technol., 2024, 14,6198-6206
DOI: 10.1039/D4CY00945B, Paper

Jinwon Choi, Amol Pophali, Byeongseok Kim, Kwangsuk Yoon, Thomas You-Seok Kim, Hocheol Song, Sang Eun Shim, Jaewoo Kim, Taejin Kim
RuO_x/BNNT catalysts were prepared with varying metal loadings and under oxidation and reduction conditions. RuO_x/BNNT showed superior catalytic activity than Ru/BNNT. The catalyst will be favorable to the ER mechanism over the LH mechanism.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00697F, Paper

Qingxiu Wang, Weisong Liu, Lijing Chang, Kuncheng Zhang, Yanbing Shen, Lingling Zhang
A synthetic pathway of L-guluronic acid and rational design of galactose oxidase.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01076K, Paper

Zhaochun He, Yonghua Liu, Tao Wang
We computationally identified Ni₃Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper

Open Access

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Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni₉₉Pt₁/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

Open Access

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01140F, Paper

Meiyan Guo, Wanxiang Yang, Yi Li, Yongfan Zhang, Wei Lin
Cadmium sulfide (CdS) exhibits remarkable light absorption capabilities and is widely employed in photocatalytic reduction of CO2. Nevertheless, the role of crystal facet effects on the micro-scale mechanisms governing CO2...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper

Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp²)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01018C, Paper

Open Access

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Martin Gerbaulet, Anja Hemschemeier, Thomas Happe
CbA5H from Clostridium beijerinckii is an oxygen-stable [FeFe]-hydrogenase. Here we report that CbA5H is stable in high concentrations of acetone and acetonitrile and also withstands intermediate concentrations of DMSO, ethanol and methanol.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper

Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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Catal. Sci. Technol., 2024, 14,6503-6512
DOI: 10.1039/D4CY00760C, Paper

Bruce A. Lobo Sacchelli, Suellen M. P. Onguene, Ruben S. M. Almeida, Alexandra M. M. Antunes, Dmytro S. Nesterov, Leandro H. Andrade, Elisabete C. B. A. Alegria, Martin H. G. Prechtl
Tuning selectivities with oxidants: O₂ oxidises methanol to the carboxylate level and N₂O oxidises it to the formaldehyde level.
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Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper

Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO₂ methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper

Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO₄ solution by electrochemical technology to catalyze the reduction of N₂ to NH₃. It was found that the applied magnetic field can significantly increase the current density.
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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper

Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper

Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper

Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO₂. The CO₂ conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper

Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper

Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO₂ with epoxides.
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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper

Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C₃N₄ as a CO₂ photo-thermal-reduction catalyst can effectively convert CO₂ to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Catal. Sci. Technol., 2024, 14,6496-6502
DOI: 10.1039/D4CY00869C, Communication

Elena Gkantzou, Theofilia Koulopoulou, Hannah Brass, David Schönauer, Anton Glieder, Selin Kara
In the context of empowering biocatalysis, an easy-to-develop, reproducible, and easy-to-scale biocatalytic system is demonstrated as a microfluidic screening platform.
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Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper

Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper

Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO₂ mitigation through conversion into useful chemicals.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper

Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
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Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper

Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper

Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper

Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Nanoscale, 2024, 16,20280-20287
DOI: 10.1039/D3NR06557J, Paper

Dalma M. Márquez, Carlos R. Lien-Medrano, Germán J. Soldano, Cristián G. Sánchez
Zinc oxide nanowires (ZnO NWs) possess a unique one-dimensional (1D) morphology that offers a direct pathway for charge transport.
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Nanoscale, 2024, 16,20147-20154
DOI: 10.1039/D4NR03283G, Paper

Hongmae Heo, Seonghyeon Cho, Yuhyeon Kim, Soomin Ahn, Jeong-hun Mok, Hookeun Lee, Dongil Lee
A novel approach was developed for the first time by combining ultrasmall Au₂₂ nanoclusters with boronic acid (BA) affinity chemistry, achieving highly efficient enrichment of early-stage glycated peptides.
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Nanoscale, 2024, 16,20342-20353
DOI: 10.1039/D4NR02984D, Paper

Open Access

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Rocío Sánchez-de-Armas, Nicolás Montenegro-Pohlhammer, Emilio M. Pérez, Enrique Burzurí, Carmen J. Calzado
A DFT study of mechanically bonded magnetic Co²⁺ and Cu²⁺ dimeric metal–porphyrin rings around carbon nanotubes (mMINTs) points to defcts in the NT as responsible for the different dimer–nanotube interactions and the loss of the Co²⁺ EPR signal.
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