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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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An insightful study on the reduction and extraction of neptunium assisted by molybdenum

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17909-17917
DOI: 10.1039/D4DT02547D, Paper
Huaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing Chen
Mo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.
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Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17852-17863
DOI: 10.1039/D4DT02538E, Paper
Kelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. Toledo
A structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
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Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17880-17892
DOI: 10.1039/D4DT02544J, Paper
Zhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing Cui
Three novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.
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Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper
Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02589J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef Holub
The objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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Thriving technology, waning memory

By www.thehindu.com
Published On :: Sun, 25 Aug 2024 03:33:00 +0530

Too many digital nannies are robbing us of the power of memory


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Learning languages

By www.thehindu.com
Published On :: Sun, 22 Sep 2024 02:10:00 +0530

Are our practices and actions pushing children away from languages?


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Marks mania

By www.thehindu.com
Published On :: Sun, 29 Sep 2024 01:48:00 +0530

A child may have great talent, but she is judged only by her marks


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Reimagining parenting

By www.thehindu.com
Published On :: Sun, 06 Oct 2024 01:31:55 +0530

Stringent discipline and control may fail to address the deeper emotional needs of children these days


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United by food and festival

By www.thehindu.com
Published On :: Sun, 13 Oct 2024 01:04:18 +0530

A Bengali raised in Jharkhand with a yen for celebrating Onam


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Learning it the hard way

By www.thehindu.com
Published On :: Sun, 27 Oct 2024 01:48:00 +0530

How a simple fix was given the go-by and how it led to worries


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Rising stars: Chani Nava and Will Chen

By physicsworld.com
Published On :: 2017-11-29T18:44:46Z

Interview with early-career scientists in astronomy and quantitative ecology


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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

By physicsworld.com
Published On :: 2018-01-19T14:46:48Z

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific


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Meeting on Nirmala Tungabhadra Abhiyana organised in Shivamogga

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 21:23:06 +0530


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Public campaigning for bypolls to end on November 11

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 03:52:34 +0530

The final day of public canvassing will see the Chief Minister and the Deputy Chief Minister besides top leaders of JD(S) and BJP seeking votes in Channapatna


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Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 16:39:36 +0530

The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka


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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 17:14:22 +0530

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process


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Yaduveer flays DKS for his remarks on Bandipur night traffic ban

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 20:25:56 +0530


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DKS remarks on night traffic ban through Bandipur rile activists

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 20:42:55 +0530

They held that the State government had already spent nearly ₹75 crore for strengthening alternate route via Hunsur-Gonikoppa-Kutta


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Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 07:00:00 +0530

Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign.


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Music is a great unifying and connecting factor even today, says Nagaraj Rao Havaldar

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 09:00:00 +0530

Bengaluru-based musician Dr. Nagaraj Rao Havaldar recently presented a lecture-demonstration highlighting Karnataka’s unique status as a state that has nurtured stalwarts in both Hindustani and Carnatic traditions


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I apologise if my remark about H.D. Kumaraswamy has hurt JD(S) workers: Karnataka Housing Minister B Z Zameer Ahmed Khan

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 16:22:44 +0530

Housing Minister’s remarks about colour of skin of Union Minister H. D. Kumaraswamy had drawn criticism from BJP and JD(S)


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Department of Pre-University Education to train PU students for K-CET and NEET in Shivamogga

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 19:02:56 +0530

Training programme to be inaugurated formally in Shivamogga tomorrow


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Don’t reduce quantum of advance, Minister Shivanand Patil tells NABARD

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 21:15:47 +0530


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PIX: United log first Europa League win

By www.rediff.com
Published On ::

The win leaves United in 15th place in the Europa League standings on six points from four games.


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Vinicius 'tricks' Real Madrid to win!

By www.rediff.com
Published On ::

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.


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EPL PIX: United thrash Leicester

By www.rediff.com
Published On ::

IMAGES from the English Premier League matches played on Sunday.


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Music resistance from 1900 to the present / edited by Igor Contreras Zubillaga, Helena Martín-Nieva.

By darius.uleth.ca
Published On ::

Turnhout : Brepols, 2022.


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Circuit breaking [electronic resource] : using neuroscience-informed psychotherapy to treat psychoactive substance abuse / Robert Youdin.

By darius.uleth.ca
Published On ::

New York, NY : Oxford University Press , 2024.


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The effects of COVID-19 on early childhood education [electronic resource] : research and implications / by Raquel Plotka and Ruth Guirguis.

By darius.uleth.ca
Published On ::

[Bradford/] : Ethics International Press Ltd, 2024.


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Handbook of art therapy [electronic resource] / edited by Cathy A. Malchiodi.

By darius.uleth.ca
Published On ::

New York : Guilford Press, 2012.


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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

By darius.uleth.ca
Published On ::

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]


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