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[ASAP] Enhanced Selectivity and Stability of Cu/SiO<sub>2</sub> Catalysts for Dimethyl Oxalate Hydrogenation to Ethylene Glycol by Using Silane Coupling Agents for Surface Modification

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00789




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[ASAP] Basic Study of the Reaction of Calcium Hydroxide with Hydrogen Chloride Using Single Crystals

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.9b06967




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[ASAP] Stacked Catalytic Membrane Microreactor for Nitrobenzene Hydrogenation

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c01234




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[ASAP] Carbon Xerogels for Effluent Treatment

Journal of Chemical & Engineering Data
DOI: 10.1021/acs.jced.0c00092




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[ASAP] Solubility Measurement and Data Correlation of Clopidogrel Hydrogen Sulfate (Form I) in Four Binary Solvents Systems at Temperature from 278.15 to 318.15 K

Journal of Chemical & Engineering Data
DOI: 10.1021/acs.jced.0c00190




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Electroweak baryogenesis and its phenomenology Kaori Fuyuto

Online Resource




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[ASAP] When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00090




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[ASAP] Reactive VOC Production from Photochemical and Heterogeneous Reactions Occurring at the Air–Ocean Interface

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00095




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Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00512F, Edge Article
Open Access
Lívia S. Mészáros, Pierre Ceccaldi, Marco Lorenzi, Holly J. Redman, Emanuel Pfitzner, Joachim Heberle, Moritz Senger, Sven T. Stripp, Gustav Berggren
The mechanism of hydrogen gas formation by [FeFe] hydrogenase is probed under whole cell conditions, revealing the formation of reactive metal hydride species under physiologically relevant conditions.
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Aerosol-assisted route to low-E transparent conductive gallium-doped zinc oxide coatings from pre-organized and halogen-free precursor

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00502A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Sanchez-Perez, Sebastian C. Dixon, Jawwad A. Darr, Ivan P. Parkin, Claire J. Carmalt
A pre-organised and halogen-free ZnO precursor is used to deposit GZO coatings via aerosol-assisted CVD with properties that exceed industrial standards for low-E coatings and photovoltaics.
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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01572E, Edge Article
Open Access
Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj Kumar
Base-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.
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Structural trends in the dehydrogenation selectivity of palladium alloys

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00875C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Stephen C. Purdy, Ranga Rohit Seemakurthi, Garrett M. Mitchell, Mark Davidson, Brooke A. Lauderback, Siddharth Deshpande, Zhenwei Wu, Evan C. Wegener, Jeffrey Greeley, Jeffrey T. Miller
Alloying is well-known to improve the dehydrogenation selectivity of pure metals, but there remains considerable debate about the structural and electronic features of alloy surfaces that give rise to this behavior.
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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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Hydrogen peroxide reduction on single platinum nanoparticles

Chem. Sci., 2020, 11,4416-4421
DOI: 10.1039/D0SC00379D, Edge Article
Open Access
Xin Chang, Christopher Batchelor-McAuley, Richard G. Compton
At the single platinum nanoparticle scale the hydrogen peroxide reduction reaction is a surface limited process.
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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
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Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
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Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
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Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article
Open Access
Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Helping children learn mathematics / Robert E. Reys, Anna Rogers, Sue Bennett, Audrey Cooke, Kylie Robson, Bronwyn Ewing, John West

Reys, Robert E., author




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Topology Optimization Design of Heterogeneous Materials and Structures


 
This book pursues optimal design from the perspective of mechanical properties and resistance to failure caused by cracks and fatigue. The book abandons the scale separation hypothesis and takes up phase-field modeling, which is at the cutting edge of research and is of high industrial and practical relevance. Part 1 starts by testing the limits of the homogenization-based approach when the size of the representative volume element is non-negligible

Read More...




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Multiplexed homogeneous digital immunoassay based on single-particle motion analysis

Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00079E, Paper
Kenji Akama, Hiroyuki Noji
Homogeneous digital immunoassay is a powerful analytical method for highly sensitive biomarker detection with a simple protocol. By using this method, we demonstrated the simultaneous multiple protein detection.
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Bioinspired reconfiguration of 3D printed microfluidic hydrogels via automated manipulation of magnetic inks

Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00280A, Communication
Amin Mansoorifar, Anthony Tahayeri, Luiz E. Bertassoni
We proposed a novel concept for reconfiguration of hydrogel microfluidic devices, where multiple fluidic pathways could be generated via reversible manipulation of magnetic inks.
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Catalytic exchange of hydrogen isotopes intensified by two-phase stratified flow in wettability designable microchannels

Lab Chip, 2020, Accepted Manuscript
DOI: 10.1039/D0LC00250J, Paper
Yuexiao Song, Feng Xin, Yongsheng Xu
This work develops a reliable method to achieve stratified flow in squared cross-section microchannels by endowing the four channel walls with very different wettabilities. The gas–liquid flows are studied experimentally...
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Selective cell propagation via micropatterning of a thermally-activated hydrogel

Lab Chip, 2020, 20,1544-1553
DOI: 10.1039/C9LC01230C, Communication
Jeffrey C. Y. Chiu, Joyce A. Teodoro, Jeong Hyun Lee, Kerryn Matthews, Simon P. Duffy, Hongshen Ma
Inverse gelation of methylcellulose enables hydrogel micropatterning to selectively propagate cells identified by microscopy.
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A high-throughput system combining microfluidic hydrogel droplets with deep learning for screening the antisolvent-crystallization conditions of active pharmaceutical ingredient

Lab Chip, 2020, Accepted Manuscript
DOI: 10.1039/D0LC00153H, Paper
Zhening Su, Jinxu He, Peipei Zhou, Lu Huang, Jianhua Zhou
Crystallization of active pharmaceutical ingredients (APIs) is a crucial process in the pharmaceutical industry due to its great impact in drug efficacy. However, conventional approaches for screening the optimal crystallization...
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[ASAP] SPREAD: A Fully Automated Toolkit for Single-Particle Cryogenic Electron Microscopy Data 3D Reconstruction with Image-Network-Aided Orientation Assignment

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b01099




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Elements of neurogeometry: functional architectures of vision / Jean Petitot

Online Resource




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Optics, ethics, and art in the thirteenth and fourteenth centuries: looking into Peter of Limoges's Moral treatise on the eye / edited by Herbert L. Kessler and Richard G. Newhauser ; with the assistance of Arthur J. Russell

Hayden Library - QP475.O68 2018




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Imaging, manipulation and optogenetics in zebrafish / Itia Amandine Favre-Bulle

Online Resource




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The Palgrave Handbook of Male Psychology and Mental Health [electronic resource] / edited by John A. Barry, Roger Kingerlee, Martin Seager, Luke Sullivan




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Variable protein expression in marine-derived filamentous fungus Penicillium chrysogenum in response to varying copper concentrations and salinity

Metallomics, 2020, Advance Article
DOI: 10.1039/C9MT00316A, Paper
Nikita Lotlikar, Samir Damare, Ram Murti Meena, Saranya Jayachandran
Copper is one of the essential trace dietary minerals for all living organisms, but is potentially toxic at higher concentrations, mainly due to the redox reactions in its transition state.
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Hydrogen sulfide increases copper-dependent neurotoxicity via intracellular copper accumulation

Metallomics, 2020, Advance Article
DOI: 10.1039/D0MT00015A, Paper
Norika Goto, Hirokazu Hara, Mao Kondo, Naomi Yasuda, Tetsuro Kamiya, Kensuke Okuda, Tetsuo Adachi
Copper (Cu) is an essential trace element and acts as a redox cofactor for many enzymes; however, excess Cu is toxic to cells.
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Bis(ethylmaltolato)oxidovanadium(IV) inhibited the pathogenesis of Alzheimer's disease in triple transgenic model mice

Metallomics, 2020, 12,474-490
DOI: 10.1039/C9MT00271E, Paper
Zhijun He, Shuangxue Han, Chong Wu, Lina Liu, Huazhang Zhu, Ang Liu, Qiying Lu, Jingqiang Huang, Xiubo Du, Nan Li, Qinguo Xie, Lu Wan, Jiazuan Ni, Lingling Chen, Xiaogai Yang, Qiong Liu
BEOV activates PPARγ to affect JAK2/STAT3/SOCS1 signaling and eventually prevents Aβ generation. Meanwhile, BEOV inactivates PTP1B to affect PI3K/Akt/GSK3β signaling and finally reduces tau hyperphosphorylation.
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Correction: Bis(ethylmaltolato)oxidovanadium(IV) inhibited the pathogenesis of Alzheimer's disease in triple transgenic model mice

Metallomics, 2020, 12,631-631
DOI: 10.1039/D0MT90008G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhijun He, Shuangxue Han, Chong Wu, Lina Liu, Huazhang Zhu, Ang Liu, Qiying Lu, Jingqiang Huang, Xiubo Du, Nan Li, Qingguo Xie, Lu Wan, Jiazuan Ni, Lingling Chen, Xiaogai Yang, Qiong Liu
The content of this RSS Feed (c) The Royal Society of Chemistry




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Zhongguo te se she hui zhu yi yan jiu. Li lun pian / Li Xiangqian, Liao Guogeng zhu bian




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[ASAP] Fe Single-Atom Catalyst for Visible-Light-Driven Photofixation of Nitrogen Sensitized by Triphenylphosphine and Sodium Iodide

ACS Catalysis
DOI: 10.1021/acscatal.0c00920




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[ASAP] Positive Effects of H<sub>2</sub>O on the Hydrogen Oxidation Reaction on Sr<sub>2</sub>Fe<sub>1.5</sub>Mo<sub>0.5</sub>O<sub>6-d</sub>-Based Perovskite Anodes for Solid Oxide Fuel Cells

ACS Catalysis
DOI: 10.1021/acscatal.9b05458




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[ASAP] Rh/TiO<sub>2</sub>-Photocatalyzed Acceptorless Dehydrogenation of N-Heterocycles upon Visible-Light Illumination

ACS Catalysis
DOI: 10.1021/acscatal.0c00556




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[ASAP] Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight

ACS Catalysis
DOI: 10.1021/acscatal.0c01406




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[ASAP] The Energetics of Hydrogen Molecule Oxidation in NiFe-hydrogenase

ACS Catalysis
DOI: 10.1021/acscatal.0c00396




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[ASAP] Removal of Hydrogen Poisoning by Electrostatically Polar MgO Support for Low-Pressure NH<sub>3</sub> Synthesis at a High Rate over the Ru Catalyst

ACS Catalysis
DOI: 10.1021/acscatal.0c00954




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[ASAP] Heterolytic Hydrogen Activation: Understanding Support Effects in Water–Gas Shift, Hydrodeoxygenation, and CO Oxidation Catalysis

ACS Catalysis
DOI: 10.1021/acscatal.0c01059




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[ASAP] Methanol Synthesis from CO<sub>2</sub> Hydrogenation over a Potassium-Promoted Cu<italic toggle="yes"><sub>x</sub></italic>O/Cu(111) (<italic toggle="yes">x</italic> = 2) Model Sur

ACS Catalysis
DOI: 10.1021/acscatal.9b05226




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[ASAP] Microenvironment of MOF Channel Coordination with Pt NPs for Selective Hydrogenation of Unsaturated Aldehydes

ACS Catalysis
DOI: 10.1021/acscatal.0c00682




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[ASAP] Isolated Pd Sites as Selective Catalysts for Electrochemical and Direct Hydrogen Peroxide Synthesis

ACS Catalysis
DOI: 10.1021/acscatal.0c01305




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[ASAP] Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate: Synchrotron Radiation Sheds Light on the Cu Cycle Mechanism

ACS Catalysis
DOI: 10.1021/acscatal.0c00918




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[ASAP] Highly Efficient Ultralow Pd Loading Supported on MAX Phases for Chemoselective Hydrogenation

ACS Catalysis
DOI: 10.1021/acscatal.0c00082