ni Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01628A, Research ArticleFeng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min LinA novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01698J, Research ArticleHeng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen XuThe first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Pd-catalyzed S-glycosylation of cysteine-containing peptides at room temperature By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6347-6352DOI: 10.1039/D4QO01389A, Research ArticleLinhua Shen, Franck Le Bideau, Gong Chen, Samir MessaoudiThis study reports the synthesis of thioglycopeptides via a Pd-catalyzed coupling of cysteine-containing peptides with iodoglycals. A variety of cysteine-containing peptides and other thiol nucleophiles including thiosugars and thiophenols were used.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6358-6366DOI: 10.1039/D4QO01498G, Research ArticleHeng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong WangThis work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6418-6425DOI: 10.1039/D4QO01298D, Research ArticleWei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun YaoA phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni 18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6411-6417DOI: 10.1039/D4QO01594K, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. SzabóThis study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6393-6410DOI: 10.1039/D4QO01451K, Research ArticleJiaoyang Liu, Li-juan Huang, Zeang Sun, Juan LiDFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6450-6458DOI: 10.1039/D4QO01528B, Research ArticleXiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi HanA silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6459-6469DOI: 10.1039/D4QO01555J, Research ArticleXin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang ZhangA nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Activation of donor–acceptor cyclopropanes under basic conditions: ring opening of 2-(p-siloxyaryl)cyclopropane 1,1-dicarboxylates with nitro compounds and other C-nucleophiles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6483-6494DOI: 10.1039/D4QO01472C, Research ArticleYulia A. Antonova, Andrey A. TabolinA new activation mode for donor–acceptor cyclopropanes was proposed and implemented in their reaction with nitro compounds and other common C-nucleophiles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6495-6502DOI: 10.1039/D4QO01098A, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya EnomotoA Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Recent developments in the ring-opening transformations of gem-difluorocyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6518-6533DOI: 10.1039/D4QO01583E, Review ArticleLeiyang Lv, Junqi Su, Zhiping LiThis review summarizes the advances of gem-F2CPs as fluoroallylic synthons in transition metal-catalysed ring-opening/cross-coupling reactions via single, double or no C-F bond cleavage on the last two years.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6573-6588DOI: 10.1039/D4QO01644K, Review ArticleZhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You HuangRecent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01512F, Research ArticleRahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez KhanA new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01627K, Research ArticleBo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long ZhuWe report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01832J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh HariharanAchieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01734J, Research ArticleYuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing LiTransition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ni Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:06:15 +0530 Full Article Telangana
ni Woman arrested after kidnap attempt in Koti Government Maternity Hospital By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:41:29 +0530 The accused was a habitual offender and had made a vain bid on Tuesday night, before being caught by the hospital staff and police on Wednesday Full Article Telangana
ni 75th anniversary of Bharat Scouts and Guides celebrated By www.thehindu.com Published On :: Thu, 07 Nov 2024 22:58:00 +0530 Full Article Hyderabad
ni Nampally court takes cognisance of ED’s prosecution complaint against AgriGold By www.thehindu.com Published On :: Fri, 08 Nov 2024 03:03:10 +0530 Full Article Telangana
ni Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:20:10 +0530 Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika Full Article Entertainment
ni Varni police SI in ACB net By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:00:40 +0530 Full Article Telangana
ni Telangana Deputy CM seeks proposals for retaining wall to prevent monsoon flooding in Madhira By www.thehindu.com Published On :: Fri, 08 Nov 2024 20:26:50 +0530 Full Article Telangana
ni Charitable trust donates furniture to flood-affected residential school in Khammam By www.thehindu.com Published On :: Sat, 09 Nov 2024 18:07:04 +0530 Full Article Telangana
ni U.S. doctors explore institutional collaboration with NIMS By www.thehindu.com Published On :: Sat, 09 Nov 2024 19:38:44 +0530 Full Article Hyderabad
ni Three held for running brothel By www.thehindu.com Published On :: Sun, 10 Nov 2024 08:17:20 +0530 Following a tip-off, police raided Hotel Akshaya and arrested three persons Full Article Telangana
ni Guru Nanak’s 555th birth anniversary celebrations to begin in Hyderabad on November 11 By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:48:15 +0530 Full Article Telangana
ni Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:40:20 +0530 Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice Full Article Telangana
ni Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana By www.thehindu.com Published On :: Sun, 10 Nov 2024 23:47:20 +0530 Full Article Telangana
ni Hyderabad-based Raghu Vamsi Group acquires British precision machining firm PMC Group By www.thehindu.com Published On :: Mon, 11 Nov 2024 14:55:02 +0530 The Hyderabad-based MSME, Raghu Vamsi Group, has completed the acquisition of British precision machining firm PMC GGroup, that traces its roots to over 100 years Full Article Hyderabad
ni Modi’s parivar stands for division of people and Gandhi parivar works for country’s unity: Telangana CM Revanth By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:51:35 +0530 Referring to the lack of minority representation in his Cabinet, the Chief Minister attributed it to the absence of a Muslim MLA in Telangana Full Article Telangana
ni Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:05:04 +0530 The new order comes into effect from November 11 until further notice, said the commissioner Full Article Hyderabad
ni Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:43:54 +0530 Full Article Telangana
ni Three schoolgirls in Telangana tribal school hospitalised after suspected food poisoning, one critical By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:20:20 +0530 The girls, aged between 13 and 16, suffered acute gastroenteritis, dehydration, and kidney-related complications Full Article Telangana
ni India vs New Zealand, 3rd Test, Day 2: Spinners dominate, time for batters to salvage pride; Test poised for exciting finish By www.thehindu.com Published On :: Sat, 02 Nov 2024 12:28:49 +0530 New Zealand ended day two with an overall lead of 143, which might look small but even a target in the vicinity of 150 will pose serious challenge for the Indian batters Full Article Cricket
ni IND vs NZ third Test: India takes a narrow lead, with the Test poised on a knife’s edge By www.thehindu.com Published On :: Sat, 02 Nov 2024 19:19:18 +0530 Pant leads the way with an entertaining knock, while Gill is unlucky to miss his hundred; Azaz once again excels with a five-for to keep the Kiwis in the hunt on a turning track turning hostile for the batters with every passing hour Full Article Cricket
ni BCCI to discuss New Zealand whitewash, some senior players could be phased out post-Australia series By www.thehindu.com Published On :: Sun, 03 Nov 2024 18:27:36 +0530 There is a high possibility that the five-match Test series against Australia could be the final one for at least two of the four seniors among Rohit Sharma, Virat Kohli, Ravindra Jadeja and Ravichandran Ashwin. Full Article Cricket
ni Women’s ODI rankings: Harmanpreet Kaur rises to ninth, Smriti Mandhana remains fourth By www.thehindu.com Published On :: Tue, 05 Nov 2024 14:45:09 +0530 India are placed in third position in the ICC Women’s Championship standings with 25 points while New Zealand are sixth with 20 from 21. Full Article Cricket
ni Focus on Delhi’s batting unit in clash against Chandigarh By www.thehindu.com Published On :: Tue, 05 Nov 2024 17:49:48 +0530 A collective show of strength from the top six hasn’t yet been on view; Rawat and Badoni’s return bolsters the team’s batting options Full Article Cricket
ni Ranji Trophy | Shreyas and Lad’s regal partnership takes reigning champion to mammoth score By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:55:07 +0530 The duo’s 354-run stand for the fourth wicket helps Mumbai declare its first innings at 602 for four before dismissing five Odisha batters for 146 at the end of day two Full Article Cricket
ni Ranji Trophy | Lad revels in second innings for Mumbai By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:10:22 +0530 The batter’s unbeaten 169 against Odisha in the Ranji Trophy marks his highest First Class score Full Article Cricket
ni Denish leads Assam’s fightback against Tamil Nadu By www.thehindu.com Published On :: Fri, 08 Nov 2024 00:06:46 +0530 The skipper compiles a patient unbeaten 54 and forges an unbroken 71-run stand with southpaw Sibsankar Roy, denying the opposition bowlers a breakthrough till close of play Full Article Cricket
ni BCCI vs PCB spar on CT venue as Mohsin Naqvi denies receiving any official note from Indian board By www.thehindu.com Published On :: Fri, 08 Nov 2024 20:37:11 +0530 The Hybrid Model was followed during 2023 Asia Cup where Pakistan played its matches at home but India played its matches in Sri Lanka. Full Article Cricket
ni The building and breaching of Fortress India: chronicling a cycle of cricket dominance By www.thehindu.com Published On :: Sat, 09 Nov 2024 00:29:18 +0530 India was invincible at home for 12 years, winning 18 consecutive Test series before New Zealand snapped the record streak in a historic clean sweep. What went into the making of the unbeaten run, what are the consequences of defeat and what does the future look like? Full Article Cricket
