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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
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Organic dopant cyclization and significantly improved RTP properties

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06213B, Edge Article
Open Access
Shiguo Zhang, Guanyu Liu, Zhichao Mao, Shanfeng Xue, Qikun Sun, Wenjun Yang
Synthesized CDIA and ODIA via cyclization, obtained long-lived RTP polymers with lifetimes of 2146 and 2656 ms. Experimental and theoretical data show cyclization effectively restrains intramolecular rotation and stabilizes triplet populations.
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Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06335J, Edge Article
Open Access
Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin Yi
The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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An ear for music, an eye for art

Much sought-after exhibition designer Mark Prime’s first Indian solo art show is a playful mix of abstract patterns




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Curtains come down on MAMI

Diamond Island,Godless,Everything Else,Lady of the LakeandThe Narrow Pathamong big winners




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A fresh wind from the desert

Elite Zexer’s film about two Bedouin women was as warmly received in Mumbai as it was at Sundance and Berlin says Satya Kandala




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Spicing it up further

Chef Anees Khan’s Bandra patisserie is now a café with a must try theccha burger, small eats, galangal ice tea and thick smoothies




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Standing apart: Shivam Pradhan




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Subdued 62nd birthday for Kamal Haasan




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Entertainment with a finesse

Filmmaker Mansoor Khanon the cinema of his illustrious father and his comeback plans




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From text to speech : the MITalk system / Jonathan Allen, M. Sharon Hunnicutt, Dennis Klatt, with Robert C. Armstrong and David Pisoni

Cambridge [Cambridgeshire] ; New York : Cambridge University Press, 1987




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Why I hold a passive-only mutual fund portfolio: Vishal Jain, CEO, Zerodha Fund House

Vishal Jain of Zerodha Fund House on why he actively favours the passive route




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North prefers equity, South less of it, East and West a mix

Pan-India, the diversity ties in with the fact that B30 cities are aggressive on equity compared to T30




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Mutual Funds and NRIs: If you are a non-resident Indian, here is how you can partake in the India growth story

If you’re a Non-Resident Indian eyeing India’s growth story, here are the basics that matter




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Why this consistent ultra short-term fund is a worthy debt investment

ICICI Prudential Ultra Short-Term fund can make the most of persistently high short-term interest rates




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SBI Contra fund: Why this long-term outperformer is a worthy investment

A multi-cap and contrarian approach helps the fund figure among the best across equity categories




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SBI Innovative Opportunities Fund: What you should know

The recently-launched fund, open till August 12, is a high risk and unknown rewards scenario




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Franklin Templeton India makes a debt fund comeback: Should you invest in its ultra short duration NFO?

The ultra short duration scheme is a new offering from the fund house after a long gap




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5 top infrastructure funds for your portfolio

Exposure to multiple sub-sectors differentiates the funds in infrastructure




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Why this focused fund can be a worthy investment in heated markets

Mahindra Manulife Focused fund is large-cap heavy and takes moderate risks in its portfolio




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Amid volatile markets, this dividend yield fund is a smart investment

With geopolitical tensions, US elections and crude prices weighing on sentiments, it may be a good time to take the safer option of dividend yield investing




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Recent tweaks by SEBI in norms pertaining to nominations

A brief explainer on the amendments pertaining to investors recently brought in




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Why not considering liquid ETFs might be an opportunity cost

Liquid ETFs, trading on both NSE and BSE, predominantly invest in TREPS, which ensures daily returns, very low volatility, no interest or credit risk.




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Janjatiya Gaurav Divas: Mansukh Mandaviya to undertake padayatra in Chhattisgarh, over 10K volunteers to join




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Centre to hold mega Digital Life Certificate camp for pensioners in Hyderabad




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PM Modi participates in 200th year celebrations of Shree Swaminarayan Mandir in Gujarat




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Roger Ebert Books Make Amazon Best-Seller List


Three of the top 15 titles currently on Amazon’s Bestsellers in Books: Guides & Reviews List are from Roger Ebert:

YOUR MOVIE SUCKS, ROGER EBERT’S FOUR-STAR REVIEWS and ROGER EBERT’S MOVIE YEARBOOK 2009

http://www.amazon.com/gp/bestsellers/books/4494/ref=pd_zg_hrsr_b_1_4_last



  • Roger Ebert
  • Roger Ebert's Four-Star Reviews
  • Roger Ebert's Movie Yearbook 2009
  • Your Movie Sucks

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AOL Food Names The Art & Soul of Baking One Of The Best Cookbooks of 2008

The editors of AOL Food included The Art and Soul of Baking by Sur La Table with Cindy Mushet on their list of the Best Cookbooks of 2008:

http://food.aol.com/holidays/most-sought-after-cookbooks

The Art and Soul of Baking by Cindy Mushet

Cindy Mushet, a pastry chef at the legendary Chez Panisse and a culinary instructor at Le Cordon Bleu in Los Angeles, reveals the science behind baking in a language the home cook can understand. Take the time to read through the Baker's Pantry, which provides useful tips.

Recipes to try: Baci Tart with Frangelico Cream and Herbed Chicken Pot Pie




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Dilbert 2.0 Creator Scott Adams Interviewed By Barron's

No Laughing Matter By JIM MCTAGUE
Cartoonist and blogger Scott Adams is outspoken about economics, politics and more -- but tight-lipped about Dilbert, hero to cubicle jockeys.

JUST WHEN YOU THOUGHT THE ECONOMY COULDN'T POSSIBLY get worse comes this disturbing news: Dilbert's mismanaged high-tech company is foundering, jeopardizing the lovable cartoon character's oppressive but steady job as an electrical engineer in a stuffy cubicle, where he's manufactured laughs about illogical and inhumane corporate managers for nearly 20 years.

Barron's won't divulge the climax of the current plot. During a recent interview, Dilbert's creator, Scott Adams, asked that we merely hint at what lies ahead for the cylinder-headed nerd with the upturned, clip-on tie. But read the daily Dilberts carefully over the next few days or weeks; clues abound and they don't point to a happy conclusion.

That's fitting because, as Adams notes in Dilbert 2.0, his $85, 576-page 20th-anniversary collection of 4,000 of his more than 8,000 cartoon strips (plus a DVD): "Dilbert is most popular when the workplace is at its worse." In fact, the strip, a window on workplace absurdity, took off during the downsizing binge of the early 1990s. In one memorable sequence from that period, Dilbert competes with a monkey to keep his engineering job. Dilbert wins, but his victory jig is short-circuited by his pointy-haired boss' decision to place the monkey on the upper-management fast track. Sounds like a telling commentary on the corporate world of 21st century's first decade, too.

Adams' current strips and very funny blog (http://www.dilbert.com/blog/), which often feature the cartoonist's insightful economic and stock-market commentaries, provide more hints about Dilbert's fate. A Dec. 12 blog argues that the recession is anything but temporary: "I think we are on the verge of a change as profound as the Industrial Revolution. Society will have to retool its expectations to meet the reality that there just won't be enough money to provide necessary services if we insist on consuming in an inefficient way."

One clue about Dilbert's fate appeared on Dec. 13 in newspapers around the world (Dilbert is published in 70 countries and 25 languages) in what turned out to be one of the most popular episodes in the strip's history: A financial adviser recommends that Dilbert's pointy-haired boss invest all of the company's funds in sick livestock. Don't buy just one sick cow, the adviser urges; buy an entire herd, because by aggregating sick cows, the risk goes away. "It's called math," the adviser adds, in a send-up of the asset-backed securitizations that have helped topple the global economy.

The financial adviser, by the way, is a malicious canine. In his blogs, Adams is equally unkind to real advisers and money managers. In his view, formed long before the disrobing of Bernie Madoff, they're always conniving to steal investors' money. Perhaps this depiction is payback: Adams lost a bundle following advice during the tech bubble, which also convinced him that investing in individual stocks and "professionally managed" funds is a losers' game. His advisers put half of his portfolio into WorldCom, Enron and other sure things and lost 40% of his invested cash, he says. He managed the other half and lost 20% in the tech wreck.

"Most of the investments I made in individual stocks went bad because managements were lying. They are the source of the information for the markets." His conclusion: "It is even dumber to pay an expert to talk to the liar for you and charge you 1% of your portfolio." Some folks who bought funds of funds that invested with Madoff surely would agree.

Read entire article: http://online.barrons.com/article/SB123094660981850775.html




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The Art and Soul of Baking Named Best How-To Book

Library Journal included The Art and Soul of Baking by Sur La Table with Cindy Mushet on its list of Best How-To Books of 2008.

This addition to renowned culinary authority Sur La Table's cookbook series, The Art and Soul of Baking (Andrews McMeel Publishing, LLC; $40.00 hardcover), guides readers through the world of baking, where the tantalizing aromas of chocolate, vanilla, butter, and cinnamon fill the air and tempt the palate. Whether turning out a rustic olive and thyme bread or crafting a show-stopping triple-layer chocolate cake, pastry chef and baking instructor Cindy Mushet provides indispensable tips and tricks to help home bakers achieve professional-looking—and professional-tasting—results.

More than 275 tested and delectable recipes cover all the bases from tasty pies, tantalizing tarts, melt-in-your-mouth meringues, and delicious cookies to more complicated creations such as flaky pastries, decadent cakes, and lighter-than-air soufflés. Novice bakers and pastry perfectionists alike will be tempted by such treats as Dulce De Leche Éclairs with Milk Chocolate Glaze; Pumpkin Spice Cake with Maple-Cream Cheese Frosting; Gingerbread Shortcakes with Caramelized Apples and Cider Sabayon; and Warm Cranberry Crumble Tart. Of course, there are savory recipes, too, including fragrant Parmesan-Herb Popovers; Potato, Onion, and Gruyère Galette; and a perfect Herbed Chicken Pot Pie. And for a delicious twist on tried-and-true favorites, there are recipes for Bananas Foster Bread Pudding; Citrus-Goat Cheese Cheesecake; Chocolate Velvet Pound Cake; and Peanut Butter Thumbprints with Peanut Caramel.




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The Art & Soul of Baking Named James Beard Nominee

The Art & Soul of Baking has been named a nominee in the James Beard Foundation Awards 2009 in the Books: Baking Category

The James Beard Foundation Awards shine a spotlight on the best and brightest talent in the food and beverage industry.

The winners will be announced May 4th at a Black Tie Ceremony in New York

The Art and Soul of Baking guides readers through the world of baking, where alluring aromas of chocolate, vanilla, and cinnamon fill the air and tempt the palate. Culinary authority Sur La Table teams with professional pastry chef and baking instructor Cindy Mushet to create the ultimate book for bakers. The Art and Soul of Baking demystifies the friendly science of baking through delicious recipes and photography sequences that illustrate proper techniques for carmelizing sugar, or working with croissant dough.



  • The Art and Soul of Baking

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The Art and Soul of Baking a 2009 IACP Cookbook Awards Winner

The Art and Soul of Baking is a 2009 IACP Cookbook Awards Winner

Winners were announced at the 2009 International Association of Culinary Professionals Conference (IACP) International in Denver on April 4.

Art and Soul of Baking won in the cookbook/baking category!

Sur La Table teamed with pastry chef and baking teacher Cindy Mushet to bring you the ultimate guide to baking. Beautiful photographs and more than 250 easy-to-follow recipes lead you into a world of alluring aromas and light, flaky pastries. Illustrated asides take you step by step through important techniques, from carmelizing sugar to working with croissant dough. Plus, you'll find invaluable information on over 100 ingredients and 50 baker's tools. A true pleasure for anyone who loves to bake.

The cookbook is also nominated for a 2009 James Beard Foundation Award.



  • IACP
  • The Art and Soul of Baking

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Engineered cortical microcircuits for investigations of neuroplasticity

Lab Chip, 2024, 24,4974-4988
DOI: 10.1039/D4LC00546E, Paper
Nicolai Winter-Hjelm, Pawel Sikorski, Axel Sandvig, Ioanna Sandvig
An advanced microfluidic platform integrated with a microelectrode array for the study of structural and functional adaptations of neural networks in response to localized perturbations.
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Artificial intelligence performance in testing microfluidics for point-of-care

Lab Chip, 2024, 24,4998-5008
DOI: 10.1039/D4LC00671B, Paper
Open Access
Mert Tunca Doganay, Purbali Chakraborty, Sri Moukthika Bommakanti, Soujanya Jammalamadaka, Dheerendranath Battalapalli, Anant Madabhushi, Mohamed S. Draz
AI is revolutionizing medicine by enhancing diagnostics and patient care. Our study showed ML and DL AI models excel in microchip testing, underscoring AI's potential to improve precision medicine and POC diagnostics.
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Dynamic sampling from ex vivo adipose tissue using droplet-based microfluidics supports separate mechanisms for glycerol and fatty acid secretion

Lab Chip, 2024, 24,5020-5031
DOI: 10.1039/D4LC00664J, Paper
Md Moniruzzaman, Andresa B. Bezerra, Md Mohibullah, Robert L. Judd, James G. Granneman, Christopher J. Easley
Droplet-based microfluidic sampling of adipose tissue reveals unique information on lipolytic dynamics.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Inertial co-focusing of heterogeneous particles in hybrid microfluidic channels with constantly variable cross-sections

Lab Chip, 2024, 24,5032-5042
DOI: 10.1039/D4LC00479E, Paper
Tianwei Zhao, Peng Zeng, Yuanting Zhang, Jinxia Li, Hui Sun, Imrich Gablech, Honglong Chang, Xichen Yuan, Pavel Neužil, Jianguo Feng
Inertial focusing chips based on hybrid microfluidic channels were presented for high-efficiency heterogeneous particle co-focusing, offering significant applications in microfluidic flow cytometry and single-cell analysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Acoustic enrichment of sperm for in vitro fertilization

Lab Chip, 2024, 24,5113-5123
DOI: 10.1039/D4LC00604F, Paper
Open Access
Chunqiu Zhang, Ning Rong, Ziyi Lin, Peng-Qi Li, Jingyao Shi, Wei Zhou, Lili Niu, Fei Li, Rongxin Tang, Lei Li, Long Meng
This study introduces an acoustofluidic device that leverages acoustic streaming to efficiently accumulate sperm. Importantly, ultrasound significantly improves sperm motility, increases fertilization rates and accelerates multicellular development.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Real-time impedance-activated dielectrophoretic actuation for reconfigurable manipulation of single flowing particles

Lab Chip, 2024, 24,5145-5154
DOI: 10.1039/D4LC00622D, Paper
Alexis Lefevre, Cristian Brandi, Adele De Ninno, Filippo Ruggiero, Enrico Verona, Michaël Gauthier, Paolo Bisegna, Aude Bolopion, Federica Caselli
We present an original all-electrical platform that combines MIC-sensing and DEP-actuation for precise and selective trajectory control of single flowing particles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dual-drive acoustic micromixer for rapid nucleation and ultrafast growth of perovskite nanoparticles

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00721B, Paper
Zhifang Liu, Yuwen Lu, Wei Tan, Guorui Zhu
An acoustic micromixer driven by bubbles and sharp edges, controlling the nucleation and growth of perovskite nanoparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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SERS-based pump-free microfluidic chip sensor for highly sensitive competitive immunoassay of cortisol in human sweat

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00858H, Paper
Siyue Xiong, Chushu Zhu, Chengxuan Wang, Peitao Dong, Xuezhong Wu
Cortisol, known as the "stress hormone," is secreted by the adrenal cortex. Measuring cortisol levels in body fluids is essential for evaluating stress levels, adrenal function, hormone imbalances, and psychological...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Kerala State school sports meet off to a vibrant start with grand inaugural ceremony

The inaugural ceremony featured a march past with student athletes from 14 districts and the United Arab Emirates (UAE) parading from Durbar Hall Ground to the college ground




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A combat sport continues to attract Kerala’s youngsters

Nivediya L. Nair, a defending champion in the fencing Épée category, was drawn to the sport as an eight-year-old a decade ago. Nakshathra A.R. was captivated by the valiant display of sword play by C.A. Bhavani Devi, the first Indian fencer to qualify for an Olympics, at Tokyo Olympics held in 2021.




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KITE gives technological edge to coverage of State school sports meet




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Two youngsters from Kochi determined to smash their disabilities on the badminton court

Atul Krishna and Jyothish Kumar defy physical limitations to excel in badminton, inspiring with their determination and talent.




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No child will be left out of school sports meet in future, says Sivankutty




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RTO to probe operator’s failure to provide accommodation to students




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Drenched in sweat, student volunteers have a bittersweet experience at sports meet in Kochi




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HC holds that civil courts have jurisdiction to order execution of decree on Waqf disputes

Petitioners challenge a civil court’s dismissal of a petition filed by them seeking to execute the decree that was passed before the commencement of the Waqf Act. HC asks munsiff court to proceed with the execution petition and pass an order in three months