functional
Functionality is the key
Houses where elders live should be clutter-free, have non-slippery flooring and help free movement. By Nandhini Sundar
functional
Functionality is key
functional
Surface functionalization, particle size and pharmaceutical co-contaminant dependent impact of nanoplastics on marine crustacean – Artemia salina.
Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00010B, Paper
DOI: 10.1039/D4EM00010B, Paper
Durgalakshmi Rajendran, Mahalakshmi Kamalakkannan, George Priya Doss C, Natarajan Chandrasekaran
Despite a significant amount of research on micronanoplastics (MNPs), there is still a gap in our understanding of their function as transporters of other environmental pollutants (known as the Trojan...
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Despite a significant amount of research on micronanoplastics (MNPs), there is still a gap in our understanding of their function as transporters of other environmental pollutants (known as the Trojan...
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functional
Elucidating the impact of oxygen functional groups on the catalytic activity of M–N4–C catalysts for the oxygen reduction reaction: a density functional theory and machine learning approach
Mater. Horiz., 2024, 11,1719-1731
DOI: 10.1039/D3MH02115G, Communication
DOI: 10.1039/D3MH02115G, Communication
Liang Xie, Wei Zhou, Yuming Huang, Zhibin Qu, Longhao Li, Chaowei Yang, Yani Ding, Junfeng Li, Xiaoxiao Meng, Fei Sun, Jihui Gao, Guangbo Zhao, Yukun Qin
While current experimental and computational studies often concentrate on introducing external structures or idealized MN4 models, we emphasize the often-overlooked impact of inherent OGs within the carbon structure of MN4 materials, presenting a new perspective on their catalytic activity origin.
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While current experimental and computational studies often concentrate on introducing external structures or idealized MN4 models, we emphasize the often-overlooked impact of inherent OGs within the carbon structure of MN4 materials, presenting a new perspective on their catalytic activity origin.
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functional
A reflection on ‘A shape-memory scaffold for macroscale assembly of functional nanoscale building blocks’
Mater. Horiz., 2024, 11,1608-1610
DOI: 10.1039/D4MH90010C, Commentary
DOI: 10.1039/D4MH90010C, Commentary
Xiang-Sen Meng, Li-Bo Mao, Shu-Hong Yu
Yu et al. reflect on their first Materials Horizons paper (Mater. Horiz., 2014, https://doi.org/10.1039/c3mh00040k) published in the inaugural issue of the journal, and discuss how their work may have influenced the research field over the past decade.
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Yu et al. reflect on their first Materials Horizons paper (Mater. Horiz., 2014, https://doi.org/10.1039/c3mh00040k) published in the inaugural issue of the journal, and discuss how their work may have influenced the research field over the past decade.
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functional
A bioactive calcium silicate nanowire-containing hydrogel for organoid formation and functionalization
Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00228H, Communication
DOI: 10.1039/D4MH00228H, Communication
Wenping Ma, Yi Zheng, Guangzhen Yang, Hongjian Zhang, Mingxia Lu, Hongshi Ma, Chengtie Wu, Hongxu Lu
An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
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An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
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functional
Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption
Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
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Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
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functional
An ultra-soft conductive elastomer for multifunctional tactile sensors with high range and sensitivity
Mater. Horiz., 2024, 11,1975-1988
DOI: 10.1039/D3MH02074F, Communication
DOI: 10.1039/D3MH02074F, Communication
Ao Yin, Ruiguang Chen, Rui Yin, Shiqiang Zhou, Yang Ye, Yuxin Wang, Peike Wang, Xue Qi, Haipeng Liu, Jiang Liu, Suzhu Yu, Jun Wei
Our study shows an ultra-soft conductive material with excellent adhesive ability to solve the mismatch of the interface. With coupled microstructures, our sensor demonstrates a remarkable sensitivity and a fast response time.
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Our study shows an ultra-soft conductive material with excellent adhesive ability to solve the mismatch of the interface. With coupled microstructures, our sensor demonstrates a remarkable sensitivity and a fast response time.
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functional
Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes
Inorg. Chem. Front., 2024, 11,2128-2135
DOI: 10.1039/D4QI00002A, Research Article
DOI: 10.1039/D4QI00002A, Research Article
Ernan Pang, Shijia Li, Jie Wu, Qing Chang, Ning Li, Jinlong Yang, Shengliang Hu
Carbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.
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Carbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.
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functional
Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting
Inorg. Chem. Front., 2024, 11,2152-2163
DOI: 10.1039/D3QI02575F, Research Article
DOI: 10.1039/D3QI02575F, Research Article
Fengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju Hao
An iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.
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An iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.
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functional
Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation
Inorg. Chem. Front., 2024, 11,2355-2364
DOI: 10.1039/D4QI00339J, Research Article
DOI: 10.1039/D4QI00339J, Research Article
Dexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin Xuan
Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
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Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
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functional
Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands
Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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functional
Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence
Inorg. Chem. Front., 2024, 11,2413-2426
DOI: 10.1039/D4QI00454J, Research Article
DOI: 10.1039/D4QI00454J, Research Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung Lau
Di-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.
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Di-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.
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functional
Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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functional
Boronic ester-templated pre-rotaxanes as versatile intermediates for rotaxane endo-functionalisation
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04879B, Edge Article
DOI: 10.1039/D4SC04879B, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik Schaufelberger
Dynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.
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Dynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.
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functional
Delocalization error poisons the density-functional many-body expansion
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05955G, Edge Article
DOI: 10.1039/D4SC05955G, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dustin R. Broderick, John M. Herbert
Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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functional
Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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functional
Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
DOI: 10.1039/D4SC05707D, Perspective
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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functional
A novel multifunctional SERS microfluidic sensor based on ZnO/Ag nanoflower arrays for label-free ultrasensitive detection of bacteria
Anal. Methods, 2024, 16,2085-2092
DOI: 10.1039/D4AY00018H, Paper
DOI: 10.1039/D4AY00018H, Paper
Yue Liu, Guanwen Su, Wei Wang, Hongyuan Wei, Leping Dang
Design and working principle of bacterial capture and identification using a ZnO/Ag microfluidic SERS sensor array.
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Design and working principle of bacterial capture and identification using a ZnO/Ag microfluidic SERS sensor array.
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functional
Dual-functional porphyrinic zirconium-based metal–organic framework for the fluorescent sensing of histidine enantiomers and Hg2+
Anal. Methods, 2024, 16,2386-2399
DOI: 10.1039/D3AY02241B, Paper
DOI: 10.1039/D3AY02241B, Paper
Shili Qin, Fanshu Meng, Fenglong Jin, Xidi Xu, Ming Zhao, Hongtao Chu, Lidi Gao, Shuren Liu
L-Cys/PCN-222 as a novel and dual-functional fluorescent sensor was developed. It not only showed a higher chiral fluorescent recognition of L-histidine but also performed as a visual sensor for Hg2+ in actual surface water.
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L-Cys/PCN-222 as a novel and dual-functional fluorescent sensor was developed. It not only showed a higher chiral fluorescent recognition of L-histidine but also performed as a visual sensor for Hg2+ in actual surface water.
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functional
Quantifying platinum binding on protein-functionalized magnetic microparticles using single particle-ICP-TOF-MS
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00268G, Paper
DOI: 10.1039/D4AY00268G, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Veronica C. Bradley, Benjamin T. Manard, Lyndsey Hendriks, Daniel R. Dunlap, Amber N. Bible, Ada Sedova, Patricia Saint-Vincent, Brian C. Sanders, Hunter B. Andrews
This work describes an analytical procedure, single particle-inductively coupled plasma-time-of-flight-mass spectrometry (SP-ICP-TOF-MS), that was developed to determine the platinum binding efficiency of protein-coated magnetic microparticles.
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This work describes an analytical procedure, single particle-inductively coupled plasma-time-of-flight-mass spectrometry (SP-ICP-TOF-MS), that was developed to determine the platinum binding efficiency of protein-coated magnetic microparticles.
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functional
Design and fabrication of La-based perovskites incorporated with functionalized carbon nanofibers for the electrochemical detection of roxarsone in water and food samples
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00264D, Paper
DOI: 10.1039/D4AY00264D, Paper
Mariya Antony John Felix, Santhiyagu Sahayaraj Rex Shanlee, Shen-Ming Chen, Sundaresan Ruspika, Ramachandran Balaji, Narendhar Chandrasekar, Periyanayagam Arockia Doss
Fabrication of potent electrocatalyst, La-based perovskites coupled with functionalized carbon nanofibers (LMO/f-CNF) for ultrasensitive electrochemical detection of roxarsone in edible and water samples.
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Fabrication of potent electrocatalyst, La-based perovskites coupled with functionalized carbon nanofibers (LMO/f-CNF) for ultrasensitive electrochemical detection of roxarsone in edible and water samples.
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functional
A colorimetric tandem combination of CRISPR/Cas12a with dual functional hybridization chain reaction for ultra-sensitive detection of mycobacterium bovis
Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D3AY02200E, Paper
DOI: 10.1039/D3AY02200E, Paper
Qiong Liu, Mei Yang, He Zhang, Wenjie Ma, Xin Fu, Huiqing Li, Sainan Gao
Tuberculosis caused by Mycobacterium bovis poses a global infectious threat to humans and animals. Therefore, there is an urgent need to develop a sensitive, precise, and easy-to-readout strategy. Here, a...
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Tuberculosis caused by Mycobacterium bovis poses a global infectious threat to humans and animals. Therefore, there is an urgent need to develop a sensitive, precise, and easy-to-readout strategy. Here, a...
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functional
Chain stretching in brushes favors sequence recognition for nucleobase-functionalized flexible precise oligomers
Soft Matter, 2024, 20,8303-8311
DOI: 10.1039/D4SM00866A, Paper
DOI: 10.1039/D4SM00866A, Paper
Kseniia Grafskaia, Qian Qin, Jie Li, Delphine Magnin, David Dellemme, Mathieu Surin, Karine Glinel, Alain M. Jonas
Flexible oligomers having precise sequences of nucleobases do not specifically recognize surface-grafted target chains at low grafting density. Moderately higher grafting densities promote sequence-specific recognition thanks to chain stretching.
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Flexible oligomers having precise sequences of nucleobases do not specifically recognize surface-grafted target chains at low grafting density. Moderately higher grafting densities promote sequence-specific recognition thanks to chain stretching.
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functional
Functional equations and how to solve them [electronic resource] / Christopher G. Small
functional
Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01628A, Research Article
DOI: 10.1039/D4QO01628A, Research Article
Feng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min Lin
A novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.
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A novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.
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functional
Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01560F, Research Article
DOI: 10.1039/D4QO01560F, Research Article
Hong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu Wang
Through crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.
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Through crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.
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functional
Enhanced surface functionalization of 2D molybdenum/tin chalcogenide nanostructures for effective SERS detection of Escherichia coli
RSC Adv., 2024, 14,35021-35034
DOI: 10.1039/D4RA05315J, Paper
DOI: 10.1039/D4RA05315J, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zainab Ishfaq, Layla A. Almutairi, M. Yasir Ali, Salhah Hamed Alrefaee, Mohamed Abdelsabour Fahmy, Elsammani Ali Shokralla, Lamiaa G. Alharbe, Adnan Ali, Arslan Ashfaq, A. R. Abd-Elwahed
This study enhances MoS2/SnS2 nanoparticles for SERS, functionalizing them with L-cysteine. Successful detection of E. coli demonstrates their potential as cost-effective SERS substrates for real-world applications.
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This study enhances MoS2/SnS2 nanoparticles for SERS, functionalizing them with L-cysteine. Successful detection of E. coli demonstrates their potential as cost-effective SERS substrates for real-world applications.
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functional
Interfacial properties of a ZnO/PTFE composite from density functional tight-binding simulations
RSC Adv., 2024, 14,35097-35103
DOI: 10.1039/D4RA06790H, Paper
DOI: 10.1039/D4RA06790H, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chol Ryu, Jun-Gi Ri, Yun-Sim Kim, Chung-Hyok Rim, Chung-Il Kim, Chol-Jun Yu
We performed density functional tight-binding simulations of a ZnO/amorphous PTFE superlattice to reveal the interlayer binding strength, charge redistribution and enhancement of mechanical strength of the ZnO-reinforced PTFE plastic composites.
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We performed density functional tight-binding simulations of a ZnO/amorphous PTFE superlattice to reveal the interlayer binding strength, charge redistribution and enhancement of mechanical strength of the ZnO-reinforced PTFE plastic composites.
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functional
Low temperature synthesis of franklinite stabilized cefixime as a multifunctional nanoformulation
RSC Adv., 2024, 14,34156-34164
DOI: 10.1039/D4RA06435F, Paper
DOI: 10.1039/D4RA06435F, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Amna Munsaf, Muhammad Naeem Ahmed, Aroosa Zafar, Bilal Akram, Mahmoud A. A. Ibrahim
Cefixime, an antibiotic with low solubility, stability, bioavailability and therapeutic effectiveness, needs to be administered in larger doses for effective treatment.
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Cefixime, an antibiotic with low solubility, stability, bioavailability and therapeutic effectiveness, needs to be administered in larger doses for effective treatment.
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functional
Synthesis and characterization of carbonyl functionalized organotellurium(IV) derivatives
RSC Adv., 2024, 14,35650-35656
DOI: 10.1039/D4RA06023G, Paper
DOI: 10.1039/D4RA06023G, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Puspendra Singh, Mariya Khan, Andrew Duthie, Ray J. Butcher
Aryltellurium trichlorides, ArTeCl3 (Ar = C6H5, Ph; 4-Me-C6H4, p-Tol; 1-C10H7, 1-Nap; 2,4,6-Me3C6H2, Mes) react under mild conditions with acetylacetone/benzoylacetone to give carbonyl functionalized organotellurium(IV) derivatives.
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Aryltellurium trichlorides, ArTeCl3 (Ar = C6H5, Ph; 4-Me-C6H4, p-Tol; 1-C10H7, 1-Nap; 2,4,6-Me3C6H2, Mes) react under mild conditions with acetylacetone/benzoylacetone to give carbonyl functionalized organotellurium(IV) derivatives.
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functional
Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation
RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
DOI: 10.1039/D4RA05482B, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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functional
Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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functional
Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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functional
Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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functional
Two amino-functionalized metal–organic frameworks with different topologies for C2H2/C2H4 separation
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication
DOI: 10.1039/D4DT02592J, Communication
Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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functional
Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction
Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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functional
Multi-functional biotinylated platinum(IV)–SAHA conjugate for tumor-targeted chemotherapy
Dalton Trans., 2024, 53,17829-17840
DOI: 10.1039/D4DT01571A, Paper
DOI: 10.1039/D4DT01571A, Paper
Ajay Gupta, Pijus K. Sasmal
Herein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.
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Herein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.
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functional
The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries
Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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functional
Laser-induced high-entropy alloys as long-duration bifunctional electrocatalysts for seawater splitting
Energy Environ. Sci., 2024, 17,8670-8682
DOI: 10.1039/D4EE01093K, Paper
DOI: 10.1039/D4EE01093K, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Yunchao Xie, Shichen Xu, Andrew C. Meng, Bujingda Zheng, Zhenru Chen, James M. Tour, Jian Lin
This work presents a rapid in situ synthesis of FeNiCoCrRu high entropy alloy with porous structures via CO2 laser induction under ambient conditions. FeNiCoCrRu exhibits excellent seawater electrolysis and a superior long duration of >3000 hours.
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This work presents a rapid in situ synthesis of FeNiCoCrRu high entropy alloy with porous structures via CO2 laser induction under ambient conditions. FeNiCoCrRu exhibits excellent seawater electrolysis and a superior long duration of >3000 hours.
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functional
Enhancement of the flavor and functional characteristics of cod protein isolate using an enzyme–microbe system
Food Funct., 2024, 15,10717-10731
DOI: 10.1039/D4FO02272F, Paper
DOI: 10.1039/D4FO02272F, Paper
Zheng-Fei Yan, Jia-Yu Chen, Jing Yang, Shuai Yuan, Xue-Yi Qiao, Bo Xu, Ling-Qia Su
Cod protein isolate was first debittered using Streptomyces canus aminopeptidase (ScAPase) and then deodorized through probiotic fermentation, showing the most substantial. These products showed the most substantial proliferation effect on probiotics.
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Cod protein isolate was first debittered using Streptomyces canus aminopeptidase (ScAPase) and then deodorized through probiotic fermentation, showing the most substantial. These products showed the most substantial proliferation effect on probiotics.
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functional
Unravelling the potential of yolkin for nutraceutical use: the origin, structure, and functional insights of a hen egg yolk polypeptide complex
Food Funct., 2024, 15,10746-10760
DOI: 10.1039/D4FO03023K, Paper
DOI: 10.1039/D4FO03023K, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Aleksandra Zambrowicz, Katarzyna Kapczyńska, Paweł Kania, Jakub Stanisław Nowak, Marta Kaszowska, Katarzyna Szymczak-Kulus, Wioletta Kazana-Płuszka, Marta Piksa, Sabina Górska, Dominika Jakubczyk, Józefa Macała, Agnieszka Zabłocka
The nutraceutical potential of yolkin health benefits from hen egg yolk.
The content of this RSS Feed (c) The Royal Society of Chemistry
The nutraceutical potential of yolkin health benefits from hen egg yolk.
The content of this RSS Feed (c) The Royal Society of Chemistry
functional
Techno-functional, antioxidant, and amino acid characterization of hydrolyzed bioactive peptides from coconut (Cocos nucifera L.) meal protein
Food Funct., 2024, 15,11266-11279
DOI: 10.1039/D4FO02741H, Paper
DOI: 10.1039/D4FO02741H, Paper
Roshanak Zolqadri, Zahra Akbarbaglu, Khashayar Sarabandi, Seyed Hadi Peighambardoust, Seid Mahdi Jafari, Amin Mousavi Khaneghah
In this study, the techno-functional characteristics and nutritional value of coconut meal protein (CMP) and the obtained polypeptides by alcalase (H-Alc), trypsin (H-Try), pancreatin (H-Pan), and pepsin (H-pep) were investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry
In this study, the techno-functional characteristics and nutritional value of coconut meal protein (CMP) and the obtained polypeptides by alcalase (H-Alc), trypsin (H-Try), pancreatin (H-Pan), and pepsin (H-pep) were investigated.
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functional
Functional yogurt: a comprehensive review of its nutritional composition and health benefits
Food Funct., 2024, 15,10927-10955
DOI: 10.1039/D4FO03671A, Review Article
DOI: 10.1039/D4FO03671A, Review Article
Sangkaran Pannerchelvan, Leonardo Rios-Solis, Helmi Wasoh, Mohamad Zulfazli Mohd Sobri, Fadzlie Wong Faizal Wong, Mohd Shamzi Mohamed, Rosfarizan Mohamad, Murni Halim
Functional yogurt contains a variety of nutritional components that offer numerous health benefits, with limitations that can potentially be overcome.
The content of this RSS Feed (c) The Royal Society of Chemistry
Functional yogurt contains a variety of nutritional components that offer numerous health benefits, with limitations that can potentially be overcome.
The content of this RSS Feed (c) The Royal Society of Chemistry
functional
MOF-derived N-doped CoNi@C as bifunctional catalysts for efficient water splitting
Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00924J, Paper
DOI: 10.1039/D4CY00924J, Paper
Xihui Yang, Zekun Li, Zikun Yang, Dapeng Meng, Zhao Wang
CoNi@C core–shell catalysts from ZIF-67 were synthesized for efficient water splitting. The hydrophilic carbon shell inhibits metal oxidation. The CoNi alloy serves as the active site, while nitrogen doping promotes the electrocatalytic performance.
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CoNi@C core–shell catalysts from ZIF-67 were synthesized for efficient water splitting. The hydrophilic carbon shell inhibits metal oxidation. The CoNi alloy serves as the active site, while nitrogen doping promotes the electrocatalytic performance.
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functional
Vibrational frequencies utilized for the assessment of exchange–correlation functionals in the description of metal–adsorbate systems: C2H2 and C2H4 on transition-metal surfaces
Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper
DOI: 10.1039/D4CY00685B, Paper
Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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functional
Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts
Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
The content of this RSS Feed (c) The Royal Society of Chemistry
Ethylene oligomerization plays an important role in industrial production.
The content of this RSS Feed (c) The Royal Society of Chemistry
functional
All-in-one Rh(III)-covalent organic framework for sustainable and regioselective C(sp2)–H bond functionalization
Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper
DOI: 10.1039/D4CY01098A, Paper
Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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functional
Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines
Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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