y

Redox active Ni–Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22−xPd20+x(CO)48]6− (x = 0.62), [Ni29−xPd6+x(CO)42]6− (x = 0.09) and [Ni29+xPd6−x(CO)42]6− (x = 0.27)

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5513-5522
DOI: 10.1039/D0DT00337A, Paper
Beatrice Berti, Cristiana Cesari, Cristina Femoni, Tiziana Funaioli, Maria Carmela Iapalucci, Stefano Zacchini
Redox active molecular Ni–Pd alloy nanoclusters were obtained by redox condensation, their total structures and metal distribution were determined by X-ray crystallography, and their electron-sink behavior was ascertained by electrochemical studies.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper
Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5420-5423
DOI: 10.1039/D0DT00842G, Communication
Luis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La Pierre
The synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Prediction of ternary fluorooxoborates with coplanar triangular units [BOxF3−x]x− from first-principles

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication
Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BOxF4−x] (x = 1,2,3) like [BO4] and triangular elements [BOxF3−x] (x = 1,2) like [BO3].
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Coordination chemistry of [Y(pypa)]− and comparison immuno-PET imaging of [44Sc]Sc- and [86Y]Y-pypa-phenyl-TRC105

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5547-5562
DOI: 10.1039/D0DT00437E, Paper
Lily Li, María de Guadalupe Jaraquemada-Peláez, Eduardo Aluicio-Sarduy, Xiaozhu Wang, Todd E. Barnhart, Weibo Cai, Valery Radchenko, Paul Schaffer, Jonathan W. Engle, Chris Orvig
H4pypa was conjugated to an antibody via a newly synthesized H4pypa-phenyl-NCS; promising immuno-PET imaging with 44Sc was demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

A bimetallic MOF@graphene oxide composite as an efficient bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5730-5735
DOI: 10.1039/D0DT00976H, Paper
Yao Xiao, Beibei Guo, Jing Zhang, Chun Hu, Ruguang Ma, Deyi Wang, Jiacheng Wang
A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

NHC–Au(I) complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00908C, Paper
Carlos Ángel-Jijón, David Rendón-Nava, Jose M. Vazques-Pérez, Alejandro Álvarez-Hernández, Daniel Mendoza-Espinosa, Verónica Salazar-Pereda
Treatment of NHC–AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTpR2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3–6 with the general formula NHC–Au–TpR2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Syntheses, characterization and properties of two new dodeca-niobates presenting unprecedented features

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00953A, Paper
Ting-Ting Zhang, Po-Han Lin, Gui-Yang Yu, Xiao Zhang, Xiao-Bing Cui
Two new dodeca-niobate materials, K3[Nb2O2][H7SiNb12O40]·16H2O (1) and [Cu(en)2]9[(VNb12V1.69Nb0.31O42en0.31)2]·20.69H2O (2), have been obtained and characterized by IR, UV-Vis, XRD, and single crystal X-ray diffraction analysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Retraction: Determination of chemical affinity of graphene oxide nanosheets with radionuclides investigated by macroscopic, spectroscopic and modeling techniques

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Retraction: Enhanced adsorption of Eu(III) on mesoporous Al2O3/expanded graphite composites investigated by macroscopic and microscopic techniques

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5742-5742
DOI: 10.1039/D0DT90075C, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Changlun Chen, Xiaoli Tan, Dadong Shao, Jiaxing Li, Guixia Zhao, Shubin Yang, Qi Wang, Xiangke Wang
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Enhancing the energy barrier by replacing the counterions in two holmium(III)-pentagonal bipyramidal single-ion magnets

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper
Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, Ueff increases from 290 K to 320 K in two HoIII-SIMs with pentagonal-bipyramidal structures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper
Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Structural design of cubic Sr,V:CeFeO3 thin films with a strong magneto-optical effect and high compatibility with a Si substrate

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04837E, Paper
Nanxi Lin, Shengnan Zhang, Haixin Chen, Yunjin Chen, Xin Chen, Yongfan Zhang, Xiaolin Hu, Naifeng Zhuang
Orthorhombic CeFeO3 is optimized to be cubic perovskite with high compatibility with Si substrate by introducing Sr, V ions into lattice. Cubic Sr,V:CeFeO3 film exhibit strong magneto-optical effect due to spin-coupling hybrid of Ce 4f with Fe/V 3d.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper
Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH4 hydrogens are shown for clarity).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper
Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO3.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper
To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo2O4) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper
Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Accelerating charge transfer in ultrafine NiFe-LDHs/CB interface during electrocatalyst activation process for water oxidation

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00824A, Paper
Mengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin Li
Owing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper
Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

An ultra-effective pathway for fully removing the oxygen components of graphene oxide by a flame-assisted microwave process

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication
Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper
Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper
Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper
Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Recent advances in coordination-driven polymeric gel materials: design and applications

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier
Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper
Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Synthesis and reactivity of cyclobutadiene nickel bromide

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01510E, Paper
Nikita V. Shvydkiy, Egor A. Dlin, Klimentiy V. Ivanov, Anastasiya G. Buyanovskaya, Yulia V. Nelyubina, Dmitry S. Perekalin
The reaction of NiBr2 with 3-hexyne provides new access to various cyclobutadiene nickel complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

y

Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article