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Experimental and theoretical investigation of benzothiazole oxidation by OH in air and the role of O2

By pubs.rsc.org
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Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00461B, Paper
Natalia V. Karimova, Weihong Wang, R. Benny Gerber, Barbara J. Finlayson-Pitts
Products of the oxidation of BTH by OH in air.
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Polyethylene microplastics affect behavioural, oxidative stress, and molecular responses in the Drosophila model

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Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00537F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Himanshu Ranjan, Swetha Senthil Kumar, Sharine Priscilla, Subhashini Swaminathan, Masakazu Umezawa, Sahabudeen Sheik Mohideen
The study highlights the negative effects of PE MPs on motor functions, oxidative stress, and cellular stress responses in Drosophila, emphasizing the broader ecological risks associated with microplastic pollution.
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Validation of a laboratory spray generation system and its use in a comparative study of hexamethylene diisocyanate (HDI) evaluation methods

By pubs.rsc.org
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Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00513A, Paper
Hugues Ahientio, Loïc Wingert, Sébastien Gagné, Jacques Lesage, Livain Breau, Simon Aubin
Isocyanates are well-known irritants and sensitizers, and measuring their occupational airborne exposure is challenging due to their high chemical reactivity and semi-volatile nature. This study builds on a previous publication...
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Combining sequential extractions with bulk and micro X-ray spectroscopy to elucidate iron and phosphorus speciation in sediments of an iron-treated peat lake

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Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00402G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Melanie Münch, Andreas Voegelin, Luis Carlos Colocho Hurtarte, Jörg Goettlicher, T. Behrends
In shallow lakes, mobilization of legacy phosphorus (P) from the sediments can be the main cause for persisting eutrophication after reduction of external P input. In-lake remediation measures can be...
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Toronto the Good? : Negotiating Race in the Diverse City [Electronic book] / Shana Almeida.

By encore.st-andrews.ac.uk
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London : University of Toronto Press, 2022.


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Solidarität und ihre Widersprüche : Gewerkschaften im Sommer der Migration 2015 [Electronic book] / Neva Löw.

By encore.st-andrews.ac.uk
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Bielefeld : transcript Verlag, [2023]


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The Qur'ān's Legal Culture : The Didascalia Apostolorum as a Point of Departure [Electronic book] / Holger Michael Zellentin.

By encore.st-andrews.ac.uk
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[s.l.] : Mohr Siebeck GmbH & Co. KG, 2023.


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Octavia's brood : science fiction stories from social justice movements [Electronic book] / edited by Walidah Imarisha and adrienne maree brown ; foreword by Sheree Renée Thomas.

By encore.st-andrews.ac.uk
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Oakland, CA : AK Press ; [Albany, NY] : Institute for Anarchist Studies, [2015]


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Michel Foucault y la literatura : Teoría, vida, política [Electronic book] / Azucena G. Blanco.

By encore.st-andrews.ac.uk
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Berlin ; Boston : De Gruyter, [2023]


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Latin epic and didactic poetry [Electronic book] : genre, tradition and individuality / edited by Monica Gale ; contributors, Ray Clare [and ten others].

By encore.st-andrews.ac.uk
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Swansea, Wales : Classical Press of Wales, 2004.


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Evagrius Ponticus [Electronic book] / A. M. Casiday.

By encore.st-andrews.ac.uk
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Oxford : Routledge, 2006.


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Caring Cash : Free Money and the Ethics of Solidarity in Kenya [Electronic book] / Tom Neumark.

By encore.st-andrews.ac.uk
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London : Pluto Press, 2023.


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Amorphous MoaZr0.8Ox-500 catalyzed selective oxidation of sulfides to sulfoxides mediated by 1O2 from direct heterolytic cleavage of H2O2

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02008A, Research Article
Tong Li, Jiaheng Qin, Xueyao Zhang, Xiaoqi Tang, Mingzhe Lv, Weiwen Mao, Linkun Dong, Tongtong Fan, Yu Long, Jiantai Ma
Sulfoxides, a class of pharmaceuticals and fine chemicals of significant importance, are readily peroxidized to sulfones in the H2O2 system.
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Three-dimensional porous rhodium–copper alloy nanoflowers stereoassembled on Ti3C2Tx MXene as highly-efficient methanol oxidation electrocatalysts

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article
Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti3C2Tx lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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Facet-engineered CeO2 with Cu single atom drives photocatalytic selective oxidation of 5-hydroxymethylfurfural

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02230K, Research Article
Yifei Li, Senyao Meng, Ping Wang, Miao He, Jiasai Yao, Cheng Yang, Fangzhou Mo, Jiang Li, Zhenxing Li
The crystal facet of CeO2 is crucial in governing the catalytic performance. However, studies on the relationship between the photocatalytic oxidation performance of CeO2 and its crystal facets are scarce....
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Dissecting the role of anions in surface reconstruction in urea oxidation to maximize assisted hydrogen production

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02333A, Research Article
Weiwei Bao, Mameng Yang, Taotao Ai, Jie Han, Zhifeng Deng, Xiangyu Zou, Peng Jiang, Junjun Zhang
The oxygen-containing anion formed by electrooxidation and leaching on the electrode surface can effectively improve the catalytic activity of UOR and provide an accurate way for the energy saving hydrogen production assisted by urea.
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Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron phosphide

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article
Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO3RR and anodic MOR is a viable way to coproduce ammonia (NH3) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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Pentagonal-bipyramidal Dysprosium(III) complexes with two apical phosphine oxide ligands and equatorial pentadentate N3O2 Schiff-base ligands: Breakdown of the apical magnetic axiality by strong equatorial crystal field†

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article
Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(LCH3)(Cy3PO)2]ClO4∙CH3CN (1), [Dy(L2(t-Bu))(Ph3PO)2]ClO4∙0.63C2H5OH (2), [Dy(LOCH3)(Ph3PO)2]ClO4∙2H2O (3) including various chelating pentadentate ligands with a [N3O2]2− binding node in the equatorial plane,...
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Technoeconomic analysis of fine chemical electrosynthesis: a case study using electrooxidation of 2-methylnaphthelene to vitamin K3

By pubs.rsc.org
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00346B, Paper
Qifeng Yang, Liping Liang, Ning Xu, Yang Li, Zhihui Wang, Dadong Shen, Yiming Mo
A cerium-mediated electrooxidation method was developed for synthesizing vitamin K3 in a green and efficient manner. A systematic technoeconomic analysis was provided to understand its potential for practical implementation.
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Kinetics of the valorization of hexoses with Sn-USY catalysts in methanolic media: glycosidation vs. retroaldol cleavage

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00307A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
J. M. Jimenez-Martin, M. El Tawil-Lucas, C. García-Jerez, J. Moreno, A. García, B. Hernández, J. Iglesias
Two operational regions in the transformation of hexoses have been revealed by experimental and kinetic analysis: glycosidation and retroaldol cleavage at low and high temperatures, respectively.
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Complete kinetic model and process reengineering of glyoxal oxidation by nitric acid in a capillary microreactor

By pubs.rsc.org
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React. Chem. Eng., 2024, 9,3016-3028
DOI: 10.1039/D4RE00313F, Paper
Junnan Wang, Wei Zhan, Yating Li, Ting Wang, Chengxiang He, Chunying Zhu, Youguang Ma, Taotao Fu
The oxidation of glyoxal by nitric acid to glyoxylic acid is a complex process with parallel and consecutive side reactions.
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Selective Separation of Li, Ni, Co and Mn from Model Spent Li Ion Battery Cathode by Dry Processing using Combination of Chlorination and Oxidation

By pubs.rsc.org
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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00328D, Paper
Naoto Tsubouchi, Yuuki Mochizuki
The volatilization of Li, Ni, Co, and Mn during chlorination treatment of LNO, LCO, and LMO (model materials for used LIB cathode material) was investigated with the aim of developing...
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Thermoresponsive oil-continuous gels based on double-interpenetrating colloidal-particle networks

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Soft Matter, 2024, 20,3033-3043
DOI: 10.1039/D3SM01582C, Paper
Braulio A. Macias-Rodriguez, Roland Gouzy, Corentin Coulais, Krassimir P. Velikov
Gels of multicomponent building blocks offer promising opportunities for the development of novel soft materials with unique and useful structures and properties.
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Dilute gel networks vs. clumpy gels in colloidal systems with a competition between repulsive and attractive interactions

By pubs.rsc.org
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Soft Matter, 2024, 20,3143-3153
DOI: 10.1039/D3SM01717F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. Gimperlein, Jasper N. Immink, M. Schmiedeberg
Dilute and dense systems differ in the way structural properties emerge. Two regimes of percolation might be responsible for differences. Global and local structural properties give insights into these differences.
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Mechanical guidance to self-organization and pattern formation of stem cells

By pubs.rsc.org
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00172A, Paper
Wei-Hua Zhou, Lin-Ru Qiao, She-Juan Xie, Zhuo Chang, Xu Yin, Guang-Kui Xu
We introduce a mechanical model based on the dynamic balance between cell-ECM-culture environment, and demonstrate that it can capture specific phenomena in stem cell pattern formation experiments guided by geometric constraints.
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Effects of salinity on the flow of dense colloidal suspensions

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Soft Matter, 2024, 20,3367-3375
DOI: 10.1039/D4SM00035H, Paper
Open Access
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Marc Lagoin, Agnès Piednoir, Rémy Fulcrand, Antoine Bérut
We studied how the flowing dynamics of dense suspensions of silica micro-particles in microfluidic rotating drums experiments is modified when the inter-particles repulsion is progressively screened by increasing the ionic force of the suspension.
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Lipidation Alters the Phase-separation of Resilin-like Polypeptides

By pubs.rsc.org
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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00358F, Paper
Open Access
Zhe Zhang, Jingjing Ji, Md Shahadat Hossain, Briah Bailey, Shikha Nangia, Davoud Mozhdehi
Biology exploits biomacromolecular phase separation to form condensates, known as membraneless organelles. Despite significant advancements in deciphering sequence determinants for phase separation, modulating these features in vivo remains challenging. A...
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Discovery of new triterpene glycosides from Dendrobium officinale with their α-glucosidase and α-amylase inhibitory activity

By pubs.rsc.org
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RSC Adv., 2024, 14,12147-12157
DOI: 10.1039/D4RA01483A, Paper
Open Access
Pham Hai Yen, Bui Huu Tai, Dan Thi Thuy Hang, Le Doan Tung Lam, Duong Thi Dung, Do Thi Trang, Duong Thi Hai Yen, Nguyen Huy Hoang, Phan Thi Thanh Huong, Nguyen Viet Dung, Ngo Anh Bang, Nguyen Duc Duy, Phan Van Kiem
Seven new oleanane saponins were discovered from Dendrobium officinale. These saponins containing 29-noroleana-12,20(30)-dien-28-oic acid framework, caffeoyl, and coumaroyl moieties potentially inhibited α-glucosidase and α-amylase activities.
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Investigation into the impact of CeO2 morphology regulation on the oxidation process of dichloromethane

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RSC Adv., 2024, 14,12265-12277
DOI: 10.1039/D4RA01326C, Paper
Open Access
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Hao Wu, Xiaoliang Zhao, Jian Li, Bandna Bharti, Yuling Tan, Hongyan Long, Jiuhu Zhao, Gang Tian, Fan Wang
Four distinct CeO2 catalysts featuring varied morphologies (nanorods, nanocubes, nanoparticles, and nano spindle-shaped) were synthesized through a hydrothermal process and subsequently employed in the oxidation of dichloromethane (DCM).
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Synergistic effects of β-NaFeO2 ferrite nanoparticles for photocatalytic degradation, antibacterial, and antioxidant applications

By pubs.rsc.org
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RSC Adv., 2024, 14,12513-12527
DOI: 10.1039/D4RA02430C, Paper
Open Access
Tahira Jabeen, Muhammad Shahid Khan, Sana Javaid, Waqar Azeem, Rabia Ayoub, Martin Motola
Detailed antibacterial mechanism using by synthesized β-NaFeO2.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

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RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
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Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins

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RSC Adv., 2024, 14,12853-12863
DOI: 10.1039/D4RA01399A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hong-Bin Ju, Li-Zhi Zhang, De-Bao Li, Tao Geng, Ya-Jie Jiang, Ya-Kui Wang
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
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Development of an imidazole-based N,N-bidentate ligand for the manganese catalyzed direct coupling of nitriles with alcohols

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RSC Adv., 2024, 14,12978-12982
DOI: 10.1039/D4RA00817K, Paper
Open Access
Qian Tang, Dingguo Song, Kali Zhang, Wenhao Mao, Xianghua Zhao, Ding Du, Fei Ling, Weihui Zhong
This work describes the manganese catalyzed direct coupling of nitriles with alcohols with assistance of a set of simple and new imidazole-based N,N-bidentate ligands.
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Antioxidant-rich brilliant polymeric nanocomposites for quick and efficient non-enzymatic hydrogen peroxide sensor

By pubs.rsc.org
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RSC Adv., 2024, 14,13142-13156
DOI: 10.1039/D4RA01768D, Paper
Open Access
M. S. Hashem, Hend S. Magar, Asmaa M. Fahim, Rokaya A. Sobh
New polymeric nanocomposites with metal oxide nanoparticles enhance electrical impedance ratings, offer energy storage and supercapacitors, and enable rapid creation of hydrogen peroxide sensors through microemulsion polymerization.
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Mercaptoimidazole-capped gold nanoparticles as a potent agent against plant pathogenic fungi

By pubs.rsc.org
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J. Mater. Chem. B, 2024, 12,10949-10961
DOI: 10.1039/D4TB01032A, Paper
Open Access
Tang Xu, Wenshuai Hao, Ran Du, Dai Dai, Cuixia Wang, Suhua Li, Carol Sze Ki Lin, Ruitao Cha, Jianbin Yan, Chong Li
The first evidence that MI-Au NPs prevent plants from fungal infection is presented.
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One-pot rapid preparation of long-term antioxidant and antibacterial biomedical gels based on lipoic acid and eugenol for accelerating cutaneous wound healing

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01844C, Paper
Yungang Feng, Fangrui Xie, Rui Ding, Qingrong Zhang, Youzhi Zeng, Li Li, Lianbin Wu, Yunlong Yu, Linxuan Fang
A medical antibacterial gel with long term and high antioxidant activity prepared from eugenol and lipoic acid showed good tissue repair and regeneration for burns and trauma.
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Development of a Xanthene-Based NIR Fluorescent Probe for Accurate and Sensitive Detection of γ-Glutamyl Transpeptidase in Cancer Diagnosis and Treatment

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01841A, Paper
Chia-Kai Lai, KUPPAN MAGESH, Sivan Velmathi, Shu-Pao Wu
γ-Glutamyl transpeptidase (GGT) regulates glutathione (GSH), essential for cell functions and linked to cancer. High GGT levels in tumors make it a valuable cancer biomarker. Current GGT detection methods often...
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PIX: TV actors Karan-Ankita's beautiful Greece holiday

By www.rediff.com
Published On :: Tue, 09 May 2017 09:15:49 +0530

Let us tour Greece with television actors Karan Patel and Ankita Bhargava.


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PIX: Anita Hassanandani's ROMANTIC holiday!

By www.rediff.com
Published On :: Wed, 05 Jun 2019 09:45:00 +0530

A tour of Vietnam and Cambodia with Anita and Rohit.


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Kalidasa, the poet of the natural world

By www.thehindubusinessline.com
Published On :: Fri, 03 Sep 2021 09:23:36 +0530

As it rains, it is natural to turn to the epic writer whose verses bring home the monsoons and the plants in which the season become visible


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Selection of DNA aptamers for detecting metronidazole and ibuprofen: two common additives in soft drinks

By pubs.rsc.org
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Analyst, 2024, 149,5482-5490
DOI: 10.1039/D4AN01186D, Paper
Jin Wang, Xiangmei Li, Hongtao Lei, Juewen Liu
Using capture-SELEX, short aptamers for metronidazole and ibuprofen were isolated and they can be used for the detection of these drugs illicitly added to soft drinks.
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In silico validation of allosteric inhibitors targeting Zika virus NS2B–NS3 protease

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Phys. Chem. Chem. Phys., 2024, 26,27684-27693
DOI: 10.1039/D4CP02867H, Paper
Yeng-Tseng Wang, Yuan-Chin Hsieh, Tin-Yu Wu
The Zika virus (ZIKV), a member of the Flaviviridae family, poses a major threat to human health because of the lack of effective antiviral drugs.
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Oxidation of fine aluminum particles: thermally induced transformations in particle shells and kinetics of oxide nucleation

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Phys. Chem. Chem. Phys., 2024, 26,27602-27616
DOI: 10.1039/D4CP03355H, Paper
Andrey V. Korshunov
A submicron aluminum particle during oxidation is a shrinking spherical segment due to the growth of a single γ-Al2O3 nucleus.
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Modeling interfacial electric fields and the ethanol oxidation reaction at electrode surfaces

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Phys. Chem. Chem. Phys., 2024, 26,27544-27560
DOI: 10.1039/D4CP02765E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuhan Mei, Fanglin Che, N. Aaron Deskins
The electrochemical environment present at surfaces can have a large effect on surface reactivity.
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Two-dimensional Janus XWZAZ' (X = S, Se, Te; A = Si, Ge; Z, Z' = N, P, As): candidates for photocatalytic water splitting and piezoelectric materials

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27314-27324
DOI: 10.1039/D4CP03503H, Paper
Zhen Gao, Hongbo Wu, Yao He, Kai Xiong
Janus two-dimensional (2D) materials exhibit strong light absorption and high solar-to-hydrogen conversion efficiency, making them promising candidates for photocatalytic water splitting applications.
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DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01700E, Paper
Guowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran Fang
The mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).
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Deciphering the spectroscopic and thermodynamic aspects of binding of biologically important antioxidants with the alkali induced state of human serum albumin

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03636K, Paper
Anjali Maheshwari, Nand Kishore
Protein–ligand interactions are crucial for developing and identifying novel therapeutic targets.
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Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00097H, Review Article
Matthew J. Evans, Cameron Jones
This review summarises advances in the chemistry of low-oxidation state and hydrido group 2 metal complexes, focussing on their use for the reductive activation of feed-stock gaseous small molecules, and their subsequent transformation into value added products.
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