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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Inter-chain double-site synergistic photocatalytic hydrogen evolution in robust cuprous coordination polymers

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01785J, Communication
Ying Zang, Jiangwei Zhang, Rui Wang, Zhao-Di Wang, Yandi Zhu, Xiaoyan Ren, Shunfang Li, Xi-Yan Dong, Shuang-Quan Zang
We evaluate photocatalytic H2 generation of three Cu-based coordination polymers, a record-high rate of 57.64 mmol g−1 h−1 for Cu–MIM, and reveal that the excellent performances are due to the synergies of the inter-chain double-site Cu atoms.
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Correction: Colloidal synthesis of porous red phosphorus nanoparticles as a metal-free electrocatalyst for the hydrogen evolution reaction

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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A metal-organic framework with in-situ generated low-coordinate binuclear Cu(I) units as the highly effective catalyst for photodriven hydrogen production

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication
Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction

Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Halogen bonding for molecular recognition: new developments in materials and biological sciences

Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight
Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Control of microenvironment around enzymes by hydrogels

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01332C, Communication
Yuichiro Kobayashi, Kenji Kohara, Yusuke Kiuchi, Hiroki Onoda, Osami Shoji, Hiroyasu Yamaguchi
We prepared enzyme immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme immobilized hydrogels increased as...
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Is breaking of a hydrogen bond enough to lead to drug resistance?

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02164D, Communication
María José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran Friedman
Drug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...
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Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π(-)−π stacking

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02671A, Communication
Shweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivray
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...
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Formalism in ethics and non-formal ethics of values : a new attempt toward the foundation of an ethical personalism / Max Scheler ; translated by Manfred S. Frings and Roger L. Funk

Scheler, Max, 1874-1928, author




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Gadamer and Wittgenstein on the unity of language : reality and discourse without metaphysics / Patrick Rogers Horn

Horn, Patrick Rogers, 1964- author




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Zucked: waking up to the Facebook catastrophe / Roger McNamee

Dewey Library - HM743.F33 M347 2019




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Having a word with Angus Graham: at twenty-five years into his immortality / edited by Carine Defoort and Roger T. Ames

Hayden Library - B1626.G74 H38 2018




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Competitive hydrogen bonding in supramolecular polymerizations of tribenzylbenzene-1,3,5-tricarboxamides

Mol. Syst. Des. Eng., 2020, Advance Article
DOI: 10.1039/D0ME00030B, Paper
Mathijs F. J. Mabesoone, Sinan Kardas, Héctor Soria-Carrera, Joaquín Barberá, Jesús M. de la Fuente, Anja R. A. Palmans, Mathieu Fossépré, Mathieu Surin, Rafael Martín-Rapún
By combining experiments and molecular modelling we elucidate the role of competitive hydrogen bonding on the supramolecular behavior of tris(alkoxybenzyl)benzene-1,3,5-tricarboxamides.
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Experimental and theoretical investigation on MoS2/MXene heterostructure as an efficient electrocatalyst for hydrogen evolution in both acidic and alkaline media

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00956C, Paper
Le Hu, Yuyun Sun, Shi-Jing Gong, Hui Zong, Ke Yu, Ziqiang Zhu
A composite of MoS2/Nb2CTx with MoS2 nanoflowers grown between Nb2CTx flakes for electrolysis of water in acidic and alkaline solutions.
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Iodine-Catalyzed α,β-Dehydrogenation of Ketones and Aldehydes Generating Conjugated Enones and Enals

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01244K, Letter
Yuanjie Cao, Long Liu, Tianzeng Huang, Tieqiao Chen
A transition metal-free α,β-dehydrogenation of ketones and aldehydes was developed. This reaction was conducted in a facile I2/KI/DMSO system to produce the corresponding unsaturated compounds in good to high yields....
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A facile synthesis of Ru/N–C as an efficient and cost-effective electrocatalyst for hydrogen evolution

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01227K, Paper
Zichuang Li, Yu Pei, Qiangjian Ju, Beibei Guo, Yifan Hu, Qian Liu, Yufang Zhu, Jiacheng Wang
This work provides a HER catalyst synthesis strategy with performance comparable to commercial Pt/C at a cost of only 0.6%.
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Nitrogen doped graphitic porous carbon from Almond Shell as an efficient persulfate activator for organic compounds degradation

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01148G, Paper
Zakaria Anfar, Abdellah Ait El Fakir, Hassan Ait Ahsaine, Mohamed Zbair, Salaheddine Farsad, Fabrice Morlet-Savary, Amane Jada, Noureddine El Alem
Here, we have developed a simple and efficient low-temperature process for doping N into graphitic porous carbon to prepare a catalyst: N-GPC. Almond Shell (AS) as Bio-sourced material was used...
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Hydrogenation of CO2 to LPG over CuZnZr/MeSAPO-34 Catalyst

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00907E, Paper
Peng Lu, Tong Mingliang, Emmerson Hondo, Linet Gapu Chizema, Ce Du, Qingxiang Ma, Shuting Mo, Chengxue Lu, Noritatsu Tsubaki
The utilization of CO2 to synthesize environmentally begnin liquid fuels offers a solution to replacing depleting petroleum resources. Herein, a ternary CuZnZr (CZZ) metal oxide catalyst and a SAPO-34 zeolite...
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Cd(II) coordination compounds as heterogeneous catalysts for microwave-assisted peroxidative oxidation of toluene and 1-phenyletanol

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01408G, Paper
Manas Sutradhar, Tannistha Roy Barman, Elisabete Clara Bastos do Amaral Alegria, Hugo M Lapa, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro
The aroylhydrazone Schiff bases 2-hydroxy(2-hydroxybenzylidene)benzohydrazide (H2L1) and 2-amino(2-hydroxybenzylidene)benzohydrazide (H2L2) have been used to synthesize the new Cd(II) coordination polymer [Cd(-1ONO’:2O:3O’’-L1)(DMF)]n (1) and the dinuclear complex [Cd(1ONO’:2O-HL2)(OO’-Ac)]2·2DMF (2). Both 1 and...
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Fabrication of a 3D self-supporting Ni–P/Ni2P/CC composite and its robust hydrogen evolution reaction properties in alkaline solution

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00727G, Paper
Fan Yang, Shuqin Yang, Qianqian Niu, Siyue Huo, Zimo Song, Laizhou Song
The Ni–P/Ni2P/CC composite exhibits excellent alkaline HER properties derived from Ni–P filling the sites on the CC not occupied by Ni2P nanosheets.
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Synthesis of 3-halochromones with simple KX halogen sources enabled by in situ halide oxidation

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00825G, Paper
Yan Lin, Jie-Ping Wan, Yunyun Liu
An in situ oxidation strategy for generating molecular halogen has been developed for the synthesis of 3-halochromones by employing simple potassium halides as halogen sources.
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The effect of vicinal di-halo substituents on the organogelling properties of aromatic supramolecular gelators and their application as soft templates

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01440K, Paper
Andrea S. Mac Cormack, Verónica M. Busch, M. Laura Japas, Lisandro Giovanetti, Florencia Di Salvo, Pablo H. Di Chenna
Vicinal di-halo substituents have a determinant effect on the supramolecular self-assembly and properties of aromatic physical gelators with application as soft templates.
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Catalytic transfer hydrogenation of biomass-derived levulinic acid to γ-valerolactone over Sn/Al-SBA-15 catalysts

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01288B, Paper
Sakthivel Kumaravel, Sivakumar Thiripuranthagan, Mani Durai, Elangovan Erusappan, Thanigaivel Vembuli
The synthesized inexpensive catalysts show high catalytic transfer hydrogenation activity at ambient N2 pressure under non-corrosive conditions. The Sn/Al-SBA-15 (25) catalyst exhibited the highest catalytic activity with 99% conversion of levulinic acid and 100% selectivity towards GVL.
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Narrow bandgap difluorobenzochalcogenadiazole-based polymers for high-performance organic thin-film transistors and polymer solar cells

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01006E, Paper
Shengbin Shi, Qiaogan Liao, Hang Wang, Guomin Xiao
A series of difluorobenzochalcogenadiazole-bithiophene copolymers are developed for high-performance organic semiconductors.
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Proton conduction in two Cu/Zn dimer-based hydrogen-bonded supramolecular frameworks from imidazole multi-carboxylate

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01189D, Paper
Qingxu Wang, Zhejun Ye, Guoqing Shi, Kaimeng Guo, Gang Li
At 98% RH and 100 °C, two dimer-based HSFs show the best σ values of 3.13 × 10−4 S cm−1 for 1 and 0.55 × 10−4 S cm−1 for 2, which can be compared to the values of reported HSFs.
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Iron and chromium MOFs as sustainable catalysts for transfer hydrogenation of carbonyl compounds and biomass conversions

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00552E, Paper
Punitharaj Vasanthakumar, Dharmalingam Sindhuja, Duraisamy Senthil Raja, Chia-Her Lin, Ramasamy Karvembu
Fe and Cr based MOFs (MIL-88B) act as efficient and reusable catalysts for transfer hydrogenation of carbonyl compounds including bio-derived substrates.
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Novel phthalocyanine-based micelles/PNIPAM composite hydrogels: spatial/temporal-controlled drug release triggered by NIR laser irradiation

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01882A, Letter
Tao Jia, Lu Li, Enna Ha, Zheng Qu, Lei Shi, Tiedong Sun, Shengnan Tan, Wancheng Zhao
Near-infrared (NIR) light-responsive hydrogels hold significant potential for biomedical application, especially in remote-controlled release of anticancer drugs. Herein we report a novel NIR light responsive composite hydrogel system that undergoes...
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Conjugated nanoporous polycarbazole bearing a cobalt complex for efficient visible-light driven hydrogen evolution

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01534B, Paper
Bin Guo, Hai-Yan Li, Jianying Chen, David James Young, Jian-Ping Lang, Hong-Xi Li
A conjugated nanoporous polycarbazole (CNP) cross-linked by pyridine and coordinated to Co(III) displays high catalytic performance for visible light-driven H2 generation. The hydrogen evolution rate was up to 410 μmol·g-1·h-1....
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Cu(II)Cl2 Containing Bispyridine-based Porous Organic Polymer Support Prepared via Alkyne-Azide Cycloaddition as a Heterogeneous Catalyst for Oxidation of Various Olefins

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01174F, Letter
Jong Ho Yoon, Hye Min Choi, Suk Joong Lee
New class of porous organic polymer (POP) based heterogeneous catalyst Cu-POP was prepared from immobilizing Cu(II)Cl2 into bpy containing POP prepared via alkyne-azide cycloaddition. This new catalyst showed efficient catalytic...
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[ASAP] Target-Based Design of Promysalin Analogues Identifies a New Putative Binding Cleft in Succinate Dehydrogenase

ACS Infectious Diseases
DOI: 10.1021/acsinfecdis.0c00024




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New Year, New Insights: Working Together to Make a Difference for Students

As we step into the new year, Mathematica is proud to announce new partnerships with the U.S. Department of Education. On these projects, we will work together to evaluate education programs and produce insights that strengthen teaching and learning.




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Knowledge networks and tourism / edited by Michelle T. McLeod and Roger Vaughan




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International environmental law : the practitioner's guide to the laws of the planet / Roger R. Martella, Jr. and J. Brett Grosko, editors




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Peremptory international law -- jus cogens : a general inventory / Robert Kolb

Kolb, Robert, author




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Jus cogens : international law and social contract / Thomas Weatherall

Weatherall, Thomas, author




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Changing contempt of court / Andrew Nicol, Heather Rogers

Nicol, Andrew




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Douglas and Jones's administrative law / Roger Douglas, Michael Head, Yee-Fui Ng, Margaret Hyland

Douglas, Roger (Roger Neil), author




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Concise Australian commercial law / Clive Turner, John Trone, Roger Gamble

Turner, Clive, 1942- author




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Morality and the environmental crisis / Roger S. Gottlieb

Gottlieb, Roger S., author




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The limits of criminal law : Anglo-German concepts and principles / edited by Matthew Dyson, Benjamin Vogel




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Civil procedure : commentary and materials / Stephen Colbran, Peta Spender, Roger Douglas, Sheryl Jackson, Molly Townes O'Brien, Tania Penovic

Colbran, Stephen, author




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Equine Exercise Physiology Seminar, together with notes of lectures by Dr. R. Rose, 14 December 1985 ; venue, The Stephen Roberts Lecture Theatre, University of Sydney

University of Sydney. Post-Graduate Committee in Veterinary Science




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Mass cytometric study on the heterogeneity in cellular association and cytotoxicity of silver nanoparticles in primary human immune cells

Environ. Sci.: Nano, 2020, 7,1102-1114
DOI: 10.1039/C9EN01104H, Paper
My Kieu Ha, Jang-Sik Choi, Sook Jin Kwon, Jaewoo Song, Yangsoon Lee, Young-Eun Kim, Tae Hyun Yoon
Between-population and within-population heterogeneity in the uptake and toxicity of silver nanoparticles in primary human immune cells revealed by mass cytometry.
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Toxicity of single-walled carbon nanotubes (SWCNTs): effect of lengths, functional groups and electronic structures revealed by a quantitative toxicogenomics assay

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00230E, Paper
Tao Jiang, Carlo Alberto Amadei, Na Gou, Yishan Lin, Jiaqi Lan, Chad D. Vecitis, April Z. Gu
Single-walled carbon nanotubes (SWCNTs) have caused increasing public concerns associated with their potential toxicological effects. This study demonstrated that the physicochemical properties of SWCNTs have impacts on their toxicological effects.
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Mn3O4 nanozymes boost endogenous antioxidant metabolites in cucumber (Cucumis sativus) plant and enhance resistance to salinity stress

Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00214C, Paper
Li Lu, Min Huang, Yuxiong Huang, Philippe F.-X. Corvini, Rong Ji, Lijuan Zhao
Mn3O4 nanoenzymes boost endogenous antioxidants in, and enhance resistance of, the cucumber (Cucumis sativus) plant subjected to salinity stress.
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Existence of untypical halogen-involving interactions in crystal packings: a statistical and first-principles study

CrystEngComm, 2020, 22,2756-2765
DOI: 10.1039/C9CE01885A, Paper
Yaser Balmohammadi, Hamid Reza Khavasi, S. Shahab Naghavi
There is a common perception by the scientific community that a halogen-involving interaction forms when the distance between the donor atom and the acceptor atom is less than the sum of their van der Waals (vdW) radii.
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Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication
Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.
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Stabilization of hydrogen peroxide by hydrogen bonding in the crystal structure of 2-aminobenzimidazole perhydrate

CrystEngComm, 2020, 22,2866-2872
DOI: 10.1039/D0CE00096E, Paper
Andrei V. Churakov, Dmitry A. Grishanov, Alexander G. Medvedev, Alexey A. Mikhaylov, Mikhail V. Vener, Mger A. Navasardyan, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
2-Aminobenzimidazole peroxosolvate – the third H2O2 crystalline adduct stabilized with the maximum possible number of hydrogen bonds formed by one hydrogen peroxide molecule.
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Mesoporogen-free synthesis of hierarchical HZSM-5 for LDPE catalytic cracking

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper
Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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